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ANSWERS TO FIRST REVIEW PROBLEM SET The solutions in this section correspond with problems that can be found only in the WileyPLUS course for this text. WileyPLUS is an online teaching and learning solution. For more information about WileyPLUS, please visit http://www.wiley.com/college/wileyplus 1. (a) OH A− H A −H2O +H2O OH2 + 2° Carbocation 3° Carbocation methanide shift + HA + + H A− (b) ++ Br + Br −Br then, + Br − Br Cl Br Cl (c) The enantiomer of the product given would be formed in an equimolar amount via the following reaction: + Br − Cl Cl Br 259