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© Woodhead Publishing Limited, 2012 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 Related titles: Advances in structural adhesive bonding (ISBN 978-1-84569-435-7) Adhesive bonding is often regarded as a cost effective and effectual way to join mechanical structures. This important book reviews the most recent improvements in adhesive bonding and its wide-ranging potential in structural engineering. Part I reviews improvements in the most commonly used groups of adhesives. The second set of chapters discuss the various types of adherends and pre-treatment methods. A third set of chapters analyse methods and techniques for joint design. The fi nal group of chapters gives a useful and practical insight into the problems and solutions of adhesive bonding in a variety of hostile environments such as chemical, wet and extreme temperatures. Machining technology for composite materials (ISBN 978-0-85709-030-0) Machining processes play an important role in the manufacture of a variety of composite materials for use in a number of industries, including the aerospace, marine, civil and leisure sectors. This book reviews and analyses both traditional and non-traditional methods of machining for different composite materials. The fi rst part of the book examines traditionally-used machining processes such as turning, drilling and grinding. In the second part, several non-traditional machining methods are discussed, such as electrical discharge and laser machining. The fi nal group of chapters deal with special topics such as cryogenic machining and processes for metal matrix and wood-based composites. Failure mechanisms in polymer matrix composites (ISBN 978-1-84569-750-1) Polymer matrix composites are increasingly replacing traditional materials, such as metals, for applications in the aerospace, automotive and marine industries. This important book explores the main types of composite failure and examines their implications in specifi c applications. Part I discusses various failure mechanisms, including manufacturing defects, and addresses a variety of loading forms, such as impact and the implications for structural integrity. Testing techniques and model- ling methods for predicting potential failure in composites are also reviewed. Part II investigates the effects of polymer-matrix composite failure in a range of indus- tries and looks at recycling issues and environmental factors affecting the use of composite materials. Details of these and a complete list of titles from Woodhead Publishing can be obtained by: • visiting our web site at www.woodheadpublishing.com • contacting Customer Services (e-mail: sales@woodheadpublishing.com; fax: +44 (0) 1223 832819; tel.: +44 (0) 1223 499140 ext. 130; address: Woodhead Publishing Limited, 80 High Street, Sawston, Cambridge CB22 3HJ, UK) • in North America, contacting our US offi ce (e-mail: usmarketing@woodhead- publishing.com; tel.: (215) 928 9112; address: Woodhead Publishing, 1518 Walnut Street, Suite 1100, Philadelphia, PA 19102-3406, USA) If you would like e-versions of our content, please visit our online platform: www. woodheadpublishingonline.com. Please recommend it to your librarian so that everyone in your institution can benefi t from the wealth of content on the site. © Woodhead Publishing Limited, 2012 Adhesives in marine engineering Edited by Jan R. Weitzenböck Oxford Cambridge Philadelphia New Delhi © Woodhead Publishing Limited, 2012 Published by Woodhead Publishing Limited, 80 High Street, Sawston, Cambridge CB22 3HJ, UK www.woodheadpublishing.com www.woodheadpublishingonline.com Woodhead Publishing, 1518 Walnut Street, Suite 1100, Philadelphia, PA 19102- 3406, USA Woodhead Publishing India Private Limited, G-2, Vardaan House, 7/28 Ansari Road, Daryaganj, New Delhi – 110002, India www.woodheadpublishingindia.com First published 2012, Woodhead Publishing Limited © Woodhead Publishing Limited, 2012; except Chapters 6 and 7 which are Crown Copyright The authors have asserted their moral rights. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. Reasonable efforts have been made to publish reliable data and information, but the authors and the publisher cannot assume responsibility for the validity of all materials. Neither the authors nor the publisher, nor anyone else associated with this publication, shall be liable for any loss, damage or liability directly or indirectly caused or alleged to be caused by this book. Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfi lming and recording, or by any information storage or retrieval system, without permission in writing from Woodhead Publishing Limited. The consent of Woodhead Publishing Limited does not extend to copying for general distribution, for promotion, for creating new works, or for resale. Specifi c permission must be obtained in writing from Woodhead Publishing Limited for such copying. Trademark notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identifi cation and explanation, without intent to infringe. British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library. Library of Congress Control Number: 2012934586 ISBN 978-1-84569-452-4 (print) ISBN 978-0-85709-615-9 (online) The publisher’s policy is to use permanent paper from mills that operate a sustainable forestry policy, and which has been manufactured from pulp which is processed using acid-free and elemental chlorine-free practices. Furthermore, the publisher ensures that the text paper and cover board used have met acceptable environmental accreditation standards. Typeset by Toppan Best-set Premedia Limited Printed by TJI Digital, Padstow, Cornwall, UK © Woodhead Publishing Limited, 2012 ix (* = main contact) Editor and Chapters 1 and 2 Dr Jan R. Weitzenböck Det Norske Veritas AS Veritasveien 1, 1363 Høvik Norway Email: Jan.Weitzenboeck@dnv.com Chapter 3 Dr Holly J. Phillips Royal National Lifeboat Institution West Quay Road Poole Dorset BH15 1HZ United Kingdom Email: hphillips@rnli.org.uk Chapter 4 Dr Christof Nagel*, Andrea Sondag and Dr Markus Brede Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM – Adhesive Bonding Technology and Surfaces Wiener Str. 12 D-28359 Bremen Germany Email: christof.nagel@ifam. fraunhofer.de Chapter 5 Dag McGeorge Det Norske Veritas AS Veritasveien 1, 1363 Høvik Norway Email: dag.mcgeorge@dnv.com Chapters 6 and 7 Dr W. Broughton Materials Processing and Performance Materials Division National Physical Laboratory Hampton Road Teddington TW11 0LW United Kingdom Email: bill.broughton@npl.co.uk Chapter 8 Dr J. Comyn Department of Materials Loughborough University Loughborough Leicestershire LE11 3TU United Kingdom Email: comyn.john@yahoo.co.uk Contributor contact details © Woodhead Publishing Limited, 2012 xi Preface Adhesive bonding is an established joining method in the railway and automotive industry. In shipbuilding and offshore engineering, it has yet to gain the same broad acceptance. However, there are many benefi ts that make adhesive bonding very attractive. For example, in lightweight con- struction one may join plates that are too thin to weld or material combina- tions that cannot be welded. Furthermore, the lack of hotwork produces smooth surfaces, e.g. on superstructures, and also substantially reduces the risk of fi re or explosion during construction. Lack of experienceand lack of documented long-term performance are currently limiting the use of adhesive bonding. This book aims to provide a rigorous treatment of the subject with focus on practical application and use and it is thus also aimed at the practising engineer, not just an academic audience. The book focuses on adhesively bonded joints that transfer loads and moments and have a structural func- tion, and does not deal with adhesion of thin fi lms or sheets such as coatings. The book addresses many important aspects for the successful applica- tion of adhesive bonding in shipbuilding and offshore structures: • Requirements for bonded connections and application examples in ships and offshore structures (Chapter 1) • Selection of adhesives and predesign (Chapter 2) • Design and fabrication of bonded joints for advanced ships (Chapter 3) • Design of adhesively bonded joints for wind turbine blades (Chapter 4) • Predicting failure of bonded joints (Chapter 5) • Characterising adhesive properties by testing (Chapter 6) • Assessing moisture resistance of bonded joints (Chapter 7) • Assessing durability in wet conditions (Chapter 8) The editor would like to take this opportunity to thank all the authors of the chapters for their time, dedication and patience. It is their collective © Woodhead Publishing Limited, 2012 xii Preface effort that has made this book possible. We hope that this book will serve the needs of all those engaged in the design, fabrication, operation and repair of adhesively bonded joints for ships and offshore structures. J. R. Weitzenböck Det Norske Veritas AS Norway © Woodhead Publishing Limited, 2012 1 1 Introduction to using adhesives in marine and offshore engineering J. R. W E I T Z E N B Ö C K, Det Norske Veritas AS, Norway Abstract: The chapter provides a brief overview of the use of adhesives in marine and offshore engineering. Firstly, some basic terms for adhesive bonding are defi ned, followed by a general overview of future technology development that may infl uence the use of materials and joining methods such as adhesive bonding. Next, a state of the art study is presented on the actual and potential use of adhesives, based on the literature and the author’s personal experience, followed by a brief outline of the certifi cation and approval regimes for bonded structures. Finally, an outlook and references are presented for further information for the interested reader. Key words: adhesive bonding, ship building, wind turbines, offshore engineering, design for adhesive bonding, international regulations. 1.1 Introduction During the design, fabrication and modifi cation of ships and offshore struc- tures there are innumerable joining tasks to assemble the structure and to install equipment. The vast majority will be done using welding and perhaps some other mechanical joining process such as bolting or riveting. However, there are situations where these joining processes are not the best option. Typically this is for the assembly of lightweight structures based on thin materials or material combinations such as composite and steel that cannot be welded. However, to be successful, adhesively bonded connections not only need to have suffi cient mechanical strength and long-term perfor- mance, but they fi rst and foremost have to be economically viable. What do we mean by ‘adhesive’? According to Adams et al. (1997), ‘an adhesive can be defi ned as a polymeric material which, when applied to surfaces, can join them together and resist separation’. Adams and co- workers describe structural adhesives ‘as one used when the load required to cause separation is substantial such that the adhesive provides for the major strength and stiffness of the structure’. The structural members of the joint, which are joined together by the adhesive, are the adherends. Adhe- sion as such is used widely on marine structures. One example is corrosion prevention coatings. However, for the purpose of this book we will focus 2 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 on load-bearing applications with structural adhesives. The simplest joint confi guration is the single lap joint as shown in Fig. 1.1. Why are adhesives being considered? The joining process is a conse- quence of the materials used. In the case of adhesive bonding this could mean that the plates are too thin to weld, a particular material combination that cannot be welded, requirement for smooth surfaces for aesthetic reasons, to avoid hotwork and risk of fi re and fi nally corrosion management where the adhesive provides an insulating layer to avoid galvanic corrosion. No joining process comes without weaknesses. An adhesively bonded joint usually requires the adherends to overlap, the strength is temperature dependent and fabrication requires careful process control. Furthermore, there is a shortage of skilled designers and shipyard workers. A good discus- sion of the pros and cons can be found in Lees (1990) which is still relevant today despite its age. 1.2 The need for adhesive bonding in the maritime and offshore industries The aim of this section is to examine the motivation for using adhesive bonding. Adhesive bonding is an enabling technology allowing novel designs by joining multi-materials and lightweight materials. However, adhesive bonding is not a technology driver – adhesives are not used for the sake of using adhesives. A pertinent question therefore is what are the important S b d g D F lo F 1.1 A single lap joint and its main parameters: F = tensile load, d = thickness of layer, S = thickness of adherend, b = width of joint, l0 = length of overlap region, γ = shear strain in adhesive, Δ = shear displacement due to F (from Weitzenböck and McGeorge, 2005). Introduction 3 © Woodhead Publishing Limited, 2012 industry trends and drivers that might affect and possibly favour the use of adhesive bonding in marine engineering. Future technology development is shaped by how the ‘world’ or society at large develops. DNV’s Technology Outlook (DNV Research and Innovation, 2011) identifi ed seven mega- trends that are believed to have a signifi cant impact on that development until 2020. These mega-trends are: population, economy, governance, infor- mation technology, energy, natural resources, climate change (see DNV Research and Innovation (2011)). Based on these mega-trends, scenarios were developed to evaluate the impact on future technology development. Technology uptake was assessed for different industry sectors; three of these industry sectors fall within the scope of this book: maritime, oil and gas and wind energy. The list below shows technologies within these three industry sectors that may potentially be relevant for adhesive bonding, as they require joining of either multi- materials or lightweight materials: The low energy ship. It is anticipated that in order to save weight and hence reduce fuel costs, the use of lightweight and hybrid materials will become more widespread. The green-fuelled ship. Signifi cant reductions in emissions such as SOx and particles can be achieved by switching to natural gas. The liquid natural gas (LNG) tanks used today require considerably more space than a diesel tank. New LNG tank concepts are under development using new material combinations to improve the current situation. The Arctic ship. Increased operations in the Arctic will require novel evacuation vessels that can also travel over ice, not just water. A number of material and joining issues are anticipated. The virtual ship. The use of integrated ship design tools will become more commonplace. This implies that joining processes including adhe- sive bonding also need to be modelled in the designtools. Subsea production. Deployment of much larger subsea processing equipment is predicted, and with it comes the need for larger housing that is both water- and pressure-proof. Arctic offshore development. Signifi cant research and development is underway to qualify and characterise materials for the use in Arctic operations. An increase in use of lightweight materials such as compos- ites and aluminium is predicted. This puts tough new requirements on the materials and joining methods such as adhesives, i.e. toughness at low temperatures. However, there is some experience of using adhesives for LNG containment systems at much lower temperatures (at about −163°C). Smart blade design. More sophisticated blade designs are anticipated within the next decade. This includes actuators for active control or new 4 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 geometries or fi bre lay-ups that react to different loadings and wind speeds. These new designs will impose new requirements on the bonded joints used in the blades. The list above is a discussion of the technology developments identifi ed in DNV’s Technology Outlook. It serves as an illustration on how new designs and material choices open up new possibilities for adhesives joining, but is by no means an exhaustive list. Further examples are shown later on in this chapter. 1.3 Potential uses of adhesives in the maritime and offshore industries 1.3.1 Maritime industry There are a number of actual and potential applications for adhesive bonding in the maritime industry. However, this section will not focus on composite structures onboard ships. Composites are only mentioned when they are to be joined by adhesive bonding. More information about com- posite applications including sandwich construction is found in Weitzen- böck et al. (2010) or for the sandwich plate system (SPS) panels in Welch (2005). One of the fi rst general reviews of marine applications of adhesive bonding was by Wacker (2000). He reported the bonding of window panes, propeller shafts and FRP pleasure boats. There are some earlier accounts of using adhesives in a marine environment for particular applications. Reavey (1981) summarises many years of experience of bonding hovercraft structures successfully, mainly aluminium honeycomb. Even though these structures resemble aircraft structures, they are used in a marine environ- ment. Interestingly, they chose a vinyl phenolic adhesive rather than an epoxy one as used in most studies reviewed in this section. A pioneering study by Hashim et al. (1989) proposed the use of hot curing epoxy adhesive to attach stiffeners to steel plates for structural ship applications. Results of fatigue and corrosion tests were presented. Many applications are related to the superstructure of a ship. There are two main thrusts: to repair cracks in aluminium superstructures and to join lightweight structures made of composite or aluminium to the steel hull. Allan et al. (1988) report on a research programme to repair aluminium superstructures of Royal Navy warships by using composite patches that are bonded to the aluminium surfaces. They report on a comprehensive design and experimental study. Grabovac and Whittaker (2009) report on the long-term experience of using carbon-composite patches to repair cracks in an aluminium superstructure of an Australian Navy frigate. They summarise 15 years of experience with this type of repair; not only with the Introduction 5 © Woodhead Publishing Limited, 2012 initial application of the composite patches but also in-service damage and wear and its subsequent repair. The authors believe this is a superior repair method for cracks with potential to be recognised as a permanent repair. There are no reports on applying bonded patch repairs to classed ships, such as container ships or oil tankers. However, there are considerable activities to repair fl oating objects, see also the section on oil and gas applications. The paper by Reichard (1997) reports on a research project to develop composite superstructures for commercial ship application. He presents an innovative bonding process where adhesive tape and paste adhesive are combined to form the bonded connection between the composite and steel interfaces. A recent study describes the concept design of a composite superstructure for a roll on–roll off ferry (McGeorge et al., 2007). The authors employed risk-based design and demonstrated that both structural and fi re safety are at least as good as for a conventional superstructure. An important detail of composite superstructures is the joint between the superstructure and the steel deck. Most composite-steel joints are hybrid joints where adhesive bonding is combined with vertical members that limit potential movement in the in-plane direction as illustrated in Fig. 1.2. Further information about hybrid joining can be found in Weitzenböck and McGeorge (2011). In order to facilitate more effi cient joining of composite superstructures to steel decks, a recent study looked at the pos- sibilities of surface engineering methods for metal to composite joints in order to improve the durability of current bonded solutions (Smith and Hutapea, 2007). A methodology for the design and construction of adhesively bonded aluminium superstructures was presented in Judd et al. (1996). In addition, the authors carried out some small scale materials tests. Cantrill et al. (2004) designed and constructed a full scale quarter section superstructure. They used a frame structure that was planked with aluminium plates. Both the plates and frame modules were joined by adhesive bonding. Adhesive bonding is used in outfi tting of ships. Bonding of windows, or direct glazing, has become standard practice on passenger ships. The operat- ing experience seems to indicate that there are no issues with adhesive joining (Weitzenböck, 2009). Bonded windows are typically hybrid solu- tions where bonded joints are secured with additional bolts and metal strips as shown in Fig. 1.3. A discussion of the design and approval process can be found in Weitzenböck and McGeorge (2011). Another documented application on a fast ferry is the use of adhesive bonding to attach passenger seat mountings to lightweight aluminium decks using adhesive bonding (Anon, 1998). A signifi cant application of adhesive bonding is the assembly of the sec- ondary barrier of the membrane type containment systems for LNG carri- ers (Weitzenböck, 2007). The majority of today’s LNG carriers on order 6 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 Composite face sheets Balsa core Steel plate Bolts Bolts Steel bulwark Metal Structure B alsa core Sandwich panel Sandwich (a) (b) (c) (d) Deck Welded steel assembly 1.2 Hybrid joint concepts for composite superstructures: (a) and (d) glued fork or rail design; (b) and (c) bonded and bolted connection (with kind permission from Springer Science+Business Media: Hybrid adhesive joints, Science and Technology of Bolt-Adhesive Joints, 2011, 6, p187, Weitzenböck and McGeorge, Fig. 1). have membrane type containment systems. In the past few years there have been cases where the secondary barrier started to develop leaks. A number of researchers and companies are addressing this problem by developing new or improved processing routes; one example is shown in Kim and Lee (2008) 1.3.2 Oil and gas There are not as many documented applications of structural adhesives in offshore structures. However, there is a large potential for use of adhesives as they can be used as a cold joining process, thus minimising the impact of maintenance work or modifi cations on oil production due to the greatly reduceddanger of explosions. One of the few documented examples is the use of fusion bonded epoxy to attach insulation materials to underwater pipelines and fl ow lines (Boye Hansen and Delesalle, 2000). These are very demanding applications as the design lifetime can be as much as 20 years without maintenance. During installation the pipes are reeled off which puts additional strain onto the pipeline insulation. Introduction 7 © Woodhead Publishing Limited, 2012 1.3 Bonded windows on a cruise ship. Note the small bolted metal strips where the corners of the window panes meet (with permission from Brombach & Gess). Another important application of adhesive bonding is the use of bonded composite patches to repair FPSOs (fl oating, production, storage, offl oading) and other fl oating offshore structures as shown in Fig. 1.4 (see Echtermeyer et al. (2005) and McGeorge et al. (2009) for further details). The patch repair may be used to repair corroded or cracked steel details. One of the main attractions is that no hot work is involved and none of the oil production processes need to be closed. In the above mentioned refer- ences, guidelines were developed to design and apply composite patches. Some fi eld repairs have already been carried out. This experience will be 8 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 collected and documented in a forthcoming DNV Recommended Practice on bonded patch repair. A further important application of the composite patch repair is that of steel pipes. Gibson (2003) discusses the state of the art. There are a number of commercial providers of the materials and docu- mented repair applications. Glass reinforced epoxy (GRE) composite pipes are used quite frequently offshore. One of the main joining methods is the use of adhesive bonding. Gibson (2003) provides a good overview of typical joint designs, mechanical performance and failure modes. 1.3.3 Wind energy While the book does not attempt to address every aspect of the design, fabrication and operation of (offshore) wind turbines, it will nevertheless cover large wind turbine blades for offshore applications. They are large bonded composite structures. As discussed by Hayman et al. (2008), wind turbine blades are usually assembled from two half-shells and a central web or a main spar (also known as load-carrying box) by adhesive bonding. Due to the fact that these blades are mass produced, fabrication and application technology is quite advanced compared with most of the other adhesive applications discussed in this section. Moveable metering and dispensing pumps are used to apply several beads of adhesive needed to assemble the blade structure (Subrahmanian and Dubouloz, 2009). Also, blade repair techniques are being developed. As these repairs have to be made on site by technicians climbing up the blades, fast curing repair resins are impor- tant. Marsh (2011) presented a repair technique that uses pre-pregs and a UV emitting light diode to accelerate the curing process. Corrosion pits or cracks Bonded patch Filler Adhesive layer Steel plate (a) (b) 1.4 Outline of patch repair process: (a) damaged plate – crack/ corrosion pits; (b) composite patch was applied to restore structural integrity and/or stiffness. Introduction 9 © Woodhead Publishing Limited, 2012 1.4 Industry specifi c regulations and how to deal with them New ship designs and offshore structures are developed in response to a commercial opportunity or need. Once the project has progressed from feasibility and concept studies to detailed design, the focus shifts towards technical issues. It is typically in this phase that adhesives may be consid- ered. Before the new designs may be realised, they usually require approval by authorities and or classifi cation societies. Adhesively bonded joints will be scrutinised more closely if they are load-bearing and provide a system- critical function. Wind turbine blades are quite different to ship or oil and gas applications when it comes to approval or certifi cation. Adhesive bonding is an integral part of the blade design. It would simply not work without adhesives. There are a number of design guidelines and rulers for wind turbine blades; see for example Det Norske Veritas (2010a). The approval regime for the blades is closer to aircraft design than shipbuilding as full scale testing is required to verify static and fatigue performance over a 20 year lifetime. Design and testing of wind turbine blades will be addressed in more detail later on in the book. All the remaining chapters of this book are concerned with material and joint performance, the testing and the fabrication of bonded joints. The fol- lowing subsections are meant to point out to engineers and designers some of the main challenges in gaining approval for their bonded joint designs. They have at least one challenge in common: the lack of long-term experi- ence of using adhesive bonding in a maritime environment for load-bearing (safety-critical) connections. It is not realistic to require full scale testing to simulate this as is common for wind turbine blades. An approach for dealing with the uncertainty will be presented at the end of this section. 1.4.1 Ship classifi cation Ship classifi cation is defi ned in Part 0 Chapter 2 of the DNV rules (Det Norske Veritas, 2003) as ‘the process of verifying ship standards against a set of requirements. The requirements are laid down in the rules established by the classifi cation society. Classifi cation implies that the ship is surveyed during construction on the basis of design approval, tested before taken into service and surveyed regularly during its whole operational life until scrapping.’ National authorities (fl ag authorities) have responsibility for the total safety control of ships fl ying their national fl ag. This includes fi re pro- tection and fi re fi ghting, lifesaving equipment and safety management systems. Many national authorities have delegated this responsibility to classifi cation societies authorising them to work and certify on their behalf. 10 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 Classifi cation societies issue rules setting requirements for the design, construction survey and testing of vessels. Many regulations in the interna- tional maritime conventions have been adopted in the class rules. In general, rules cover the structural strength and where relevant the watertight integ- rity and integrity of essential parts of the vessel’s hull and its appendages, and the safety and availability of the main functions in order to maintain essential services (see also Det Norske Veritas, 2011a). Furthermore, the rules provide requirements for certifi cation of materials, components and systems for use on ships approved by a particular classifi cation society (Det Norske Veritas, 2010b). Adhesive bonding is still a relatively new joining process in shipbuilding with limited or no previous experience. Currently, there are very few clas- sifi cation rules or requirements for approval of adhesively bonded joints which in turn discourages many to consider adhesive bonding as part of their design. Most approvals today are based on case by case approval. In response to radical new ship designs, classifi cation rules now permit the use of risk based assessment as a means of showing compliance with rule requirements. This is based on the guidelines for Formal Safety Assess- ment published by the International Maritime Organisation (IMO) (2002). Alternatives to, or deviations from, requirements in the rules may now be accepted when the overall safety and reliability level is equivalent to or better than that of current rules (see also B610 in Det Norske Veritas(2011a)). In this assessment one needs to demonstrate equivalent safety, in particular fi re safety. It is therefore important to involve fl ag authorities in the process. 1.4.2 Offshore installations Offshore installations are regulated by national authorities. According to the Norwegian Petroleum Act, the owner is fully responsible for verifi cation activities ensuring that the unit/ installation and related operations are in compliance with the applicable regulatory requirements (Det Norske Veritas, 2007). The owner can utilise internal as well as external verifi cation to demonstrate compliance with his verifi cation obligations. The regulatory body on the Norwegian Continental Shelf is the Petroleum Safety Author- ity (PSA). The PSA regulations make a distinction between mobile facilities and other offshore installations. Mobile (buoyant) units are in this context understood as units registered in a national register of shipping, and which follow a maritime concept and are classed as ships. One such example is drilling units. The UK sector of the North Sea has its own regulatory regime. The UK Safety Case Regulations (SCR) and Prevention of Fire and Explosion and Emergency Response Regulations (PFEER) require that all major accident hazards pertaining to an offshore installation are identifi ed and adequately Introduction 11 © Woodhead Publishing Limited, 2012 managed throughout the installation lifecycle (Det Norske Veritas, 2011b). This is achieved by a combination of assessment and verifi cation to assure an acceptable standard of integrity of the installation, safety of operation and protection of personnel. The regulations establish a non-prescriptive ‘goal setting’ approach which enables efforts to be focused on those items which provide the greatest contribution to safety. This implies that risks from major accident hazards are assessed and reduced to a level that is as low as reasonably practicable (ALARP). ALARP means that once risks are considered to be tolerable, further risk reduction measures are balanced against the cost of implementing such measures. As discussed above, offshore installations require independent verifi ca- tion in order to gain approval from the shelf regulators. One approach is the risk-based verifi cation process defi ned in Det Norske Veritas (2004) and summarised in Fig. 1.5. The term ‘asset’ is used to denote an onshore or Asset planned Asset completed Asset specification including overall company acceptance criteria and verification objectives Risk assessment including identification of hazards and ranking of hazards based on risk evaluation Definition of verification involvement including detailing of acceptance criteria Verification plan including list of verification activities Verification execution including reporting of compliance or non- compliance 1.5 Flow chart of the risk-based verifi cation process (from Det Norske Veritas, 2004). 12 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 offshore installation or part thereof, a system or process, or a development phase such as feasibility, design, construction, commissioning, operation and decommissioning. The requirements of current approval processes are based on risk-based assessments with independent verifi cation. Joining methods are not mentioned explicitly. However, they are one of the princi- pal items that (can) limit the durability and reliability of structures. The performance of an adhesively bonded joint is thus tested and documented for each case, for example attachment of a composite component to a steel structure. A re-occurring dilemma is that it is very costly and time- consuming to demonstrate that adhesively bonded joints have a long-term performance of perhaps 15 or more years as there are no reliable short-term tests to predict lifetime. 1.4.3 Approval of bonded joints Risk assessment to show compliance or equivalence is used routinely in the offshore industry and was recently also introduced for ships. The identifi ca- tion of hazards and risks and selection of the best risk control options is usually done according to the IMO guidelines for formal safety assessment (FSA) (IMO, 2002). There are fi ve steps: Step 1: Identifi cation of hazards Step 2: Risk analysis Step 3: Risk control options Step 4: Cost benefi t assessment Step 5: Recommendations for decision making. These fi ve steps represent a generally accepted structured approach to risk assessment and decision making. This concept provides the background for a pragmatic approach to approval of adhesively bonded joints. It was fi rst presented by Weitzenböck and McGeorge (2004) and comprises the follow- ing three steps: 1. Hazard identifi cation 2. Risk assessment 3. Adoption of suitable risk control measures. Three generic risk control options were proposed by Weitzenböck and McGeorge (2004): Use of best practice in material selection, joint design and fabrication technology. Ensure that the design allows detection of damage before ultimate failure. Furthermore, a design needs to have suffi cient reserve strength and/ or redundancy so that ‘detectable damage’ is tolerable. Introduction 13 © Woodhead Publishing Limited, 2012 Develop and demonstrate repair procedures to be able to repair the detected damage. The attraction of this approach is that one avoids the diffi cult task of demonstrating long-term performance a priori and thus paving the way for a more widespread application of adhesive bonding. The potential drawback is that one is limited to those applications that tolerate initial failure until it is detected. This could be achieved with a hybrid joint design, where a mechanical fastener is combined with adhesive bonding; see also Weitzenböck and McGeorge (2011). An example of how bonded joints are assessed and classifi ed according to their criticality and need for documentation is provided by McGeorge et al. (2009). The authors presented a classifi cation system to identify reliability classes pro- posed for composite bonded repair of fl oating offshore units. Moreover, the authors clearly identify those cases which are outside the scope their repair scheme because of their criticality and need for extensive and expensive testing. 1.5 Future trends The wind energy industry is expected to grow considerably over the next few years, mainly offshore. The wind turbines are expected to grow in size and possible functionality. This will pose new challenges to ever increasing blades and their constituent materials. Strength and stiffness requirements will increase as well as reliability of the blades as they are much more dif- fi cult to repair offshore. Hence the use of adhesives will continue to grow and with it the need for improved performance and reliability. Adhesive bonding in marine and offshore applications is still very much in its infancy in spite of some successes. However, much is still needed to establish this joining process as a standard process in shipbuilding or off- shore. What should or will happen in the next ten years, for example one obvious development is to move away from the ‘special process’ and case by case design and approval to standardise adhesive bonding by pre- qualifying applications and joint designs, materials and processes and people and inspection regimes. Furthermore, adhesively bonded joints need to be represented in fi nite element software and computer aided design software. This would allow simply specifying the joint using some kind of catalogue rather than having to design a solution for each application, thus speeding up the design and approval process considerably and also removing the risk of not getting approval. What is also needed is more transparencyin the decision making process. It is important that those taking the decision to use adhesive bonding involve those who are left with the uncertainty or potential risk of using 14 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 adhesive, for example the shipyard and ship owner. Due to the limited long-term experience of using adhesives in a marine environment one needs to gain experience by focusing on low risk applications and non-critical joints fi rst. Another possibility is the more widespread use of hybrid joints where the best of both worlds are combined to join components by using adhesives and a mechanical device. 1.6 References Adams, R. D., Comyn, J. and Wake, W. C. 1997. Structural Adhesive Joints in Engi- neering, London, Chapman & Hall. Allan, R. C., Bird, J. and Clarke, J. D. 1988. Use of adhesives in repair of cracks in ship structures. Materials Science and Technology, 4, 853–859. Anon 1998. Sonderfahrzeugbau: Kleben als Alternative zum Nieten oder Schweis- sen (Adhesive bonding as alternative to riveting or welding – in German). Adhä- sion KLEBEN & DICHTEN, 42, 4. Boye Hansen, A. and Delesalle, A. 2000. Cost effective thermal insulation systems for deepwater West Afrika in combination with direct heating. Offshore West Africa 2000 Conference and Exhibition. Abidjan, Ivory Coast. Cantrill, J., Kapadia, A. and Pugh, D. 2004. Lessons learnt from designing and pro- ducing adhesively bonded prototyping structures in a shipyard. Proc. Instn Mech. Engrs Part M: J. Engineering for the Maritime Environment, 218, 267–272. Det Norske Veritas. 2003. Introduction to Ship Classifi cation, Part 0, Chapter 2. Rules for Classifi cation of Ships [Online]. Available: http://exchange.dnv.com/ publishing/RulesShip/2011-07/ts002.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2004. Risk Based Verifi cation. Offshore Service Specifi cation DNV-OSS-300 [Online]. Available: http://exchange.dnv.com/publishing/Codes/ download.asp?url=2004-04/oss-300.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2007. Verifi cation for Compliance with Norwegian Shelf Regu- lations. Offshore Service Specifi cation DNV-OSS-201 [Online]. Available: http:// exchange.dnv.com/publishing/Codes/download.asp?url=2010-04/oss-201.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2010a. Design and Manufacture of Wind Turbine Blades, Offshore and Onshore Wind Turbines. DNV Standard, DNV-DS-J102 [Online]. Available: http://exchange.dnv.com/publishing/Codes/download.asp?url=2010-11/ ds-j102.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2010b. Fabrication and Testing of Ship Structures, Part 2, Chapter 3. Rules for Classifi cation of Ships, High Speed, Light Craft and Naval Surface Craft [Online]. Available: http://exchange.dnv.com/publishing/ RulesHSLC/2011-07/ts203.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2011a. General Regulations, Part 1, Chapter 1. Rules for Classifi cation of Ships [Online]. Available: http://exchange.dnv.com/publishing/ RulesShip/2011-07/ts101.pdf [Accessed 20.11.2011]. Det Norske Veritas. 2011b. Verifi cation for Compliance with UK Shelf Regulations. Offshore Service Specifi cation, DNV-OSS-202 [Online]. Available: http://exchange. dnv.com/publishing/Codes/download.asp?url=2011-04/oss-202.pdf [Accessed 20.11.2011]. Introduction 15 © Woodhead Publishing Limited, 2012 DNV Research and Innovation. 2011. Technology outlook 2020. Available: http:// www.dnv.com/moreondnv/research_innovation/foresight/outlook/index.asp [Accessed 20.11.2011]. Echtermeyer, A. T., McGeorge, D., Sund, O. E., Andresen, H. W. and Fischer, K. P. 2005. Repair of FPSO with Composite Patches. Fourth International Conference On Composite Materials For Offshore Operations. Houston, TX. Gibson, A. G. 2003. The cost effective use of fi bre reinforced composites offshore, UK, HSE Health & Safety Executive. Grabovac, I. and Whittaker, D. 2009. Application of bonded composites in the repair of ships structures – A 15-year service experience. Composite Part A, 40, 1381–1398. Hashim, S. A., Winkle, I. E. and Cowling, M. J. 1989. A Structural Role for Adhesives in Shipbuilding? Meeting of the Royal Institution of Naval Architects. London: The Royal Institution of Naval Architects. Hayman, B., Wedel-Heinen, J. and Brøndsted, P. 2008. Materials challenges in present and future wind energy. MRS Bulletin, 33, 343–353. IMO 2002. Guidelines for Formal Safety Assessment (FSA) for use in the IMO rule making process. London: International Maritime Organisation, MSC/Circ. 1023. Judd, G., Dodkins, A. and Maddison, A. 1996. Adhesively bonded aluminium super- structures. International Conference on Lightweight Materials in Naval Architec- ture. Southampton: The Royal Institution of Naval Architects. Kim, B. G. and Lee, D. G. 2008. Leakage characteristics of the glass fabric composite barriers of LNG ships. Composite Structures, 86, 27–36. Lees, W. A. 1990. Bonded assembly – pros, cons and ground rules. Materials and Design, 11, 227–234. Marsh, G. 2011. Meeting the challenge of wind turbine blade repair. Reinforced Plastics, 55, 32–36. McGeorge, D., Echtermeyer, A. T., Leong, K. H., Melve, B., Robinson, M. and Fischer, K. P. 2009. Repair of fl oating offshore units using bonded fi bre composite materials. Composites Part A: Applied Science and Manufacturing, 40, 1364–1380. McGeorge, D., Høyning, B. and Nordhammar, H. 2007. Risk based design – a case study on composite superstructures. SAFEDOR Mid-Term Conference. Brussels: The Royal Institution of Naval Architects. Reavey, D. G. 1981. Marine experience of structural adhesives in hovercraft. SAMPE Journal, September/ October, 18–21. Reichard, R. P. 1997. Low cost topside structures for commercial ship applications. Anaheim, CA, USA: SAMPE. Smith, M. and Hutapea, P. 2007. Surface engineering for adhesively bonded metal- composite joints. Journal of Ship Production, 23, 72–81. Subrahmanian, K. P. and Dubouloz, F. 2009. Adhesives for bonding wind turbine blades. Reinforced Plastics, 53, 26–29. Wacker, G. 2000. Adhesive Joining – A New Joining Technology for Shipbuilding (in German). Handbuch der Werften. Hamburg: Schiffahrtsverlag Hansa. Weitzenböck, J. R. 2007. Adhesive bonding of containment systems for LNG carri- ers. SwissBonding. Rapperswil, Switzerland. Weitzenböck, J. 2009. Sticking point. Materials World, 17, 22–23. Weitzenböck, J. R., Hayman, B., Hersvik, G., McGeorge, D., Noury, P., Hill, D. M. and Echtermeyer, A. 2010. Application of composites in ships and offshore – A 16 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 review and outlook. International Conference on Marine and Offshore Compos- ites. London. Weitzenböck, J. R. and McGeorge, D. 2004. The designer’s dilemma: How to deal with the uncertainty about the long-term performance of adhesively bonded joints. Proc. Instn Mech. Engrs Part M: J. Engineering for the Maritime Environ- ment, 218, 273–276. Weitzenböck, J. R. and McGeorge, D. (eds.) 2005. BONDSHIP project guidelines, Høvik, Norway: Det Norske Veritas AS. Weitzenböck, J. R. and McGeorge, D. 2011. Science and technology of bolt- adhesive joints. In: Da Silva, L. F. M., Pirondi, A. and Öchsner, A. (eds.) Hybrid adhesive joints. Berlin Heidelberg: Springer-Verlag. Welch, D. 2005. The Sandwich Plate System. Presentation at the Glasgow College of Nautical Studies. Glasgow: I.Mar.EST/IESIS. © Woodhead Publishing Limited, 2012 19 2 Selecting adhesives for marine environments and pre-design J. R. W E I T Z E N B Ö C K, Det Norske Veritas AS, Norway Abstract: The purpose of this chapter is to defi ne a framework for the selection of adhesives. Moreover, the interaction between adhesive selection and (ship) design will be explored. Design for adhesives implies design forproduction as the fabrication determines the quality of the bonded joint. A comprehensive framework for adhesive selection is presented which addresses both materials selection and fabrication process selection. It starts by specifying requirements followed by screening tests for preliminary selection. Simple formulae for pre-design of bonded connections are provided in order to assess feasibility. Links to further information about adhesive selection are included. Key words: adhesive bonding, material selection, adhesive selection, design, ship building, marine engineering, offshore, pre-design, requirement lists. 2.1 Introduction: the rationale for adhesive selection The aim of this chapter is to outline a selection process for adhesives in a marine environment. The selection process encompasses both material and process selection. While the purpose of this book is to provide an overview of the use of adhesives in marine environments, it is nevertheless important to refl ect upon when adhesives should be used, and when not. Adhesive bonding is a joining method with many advantages, but it is not always the best joining process for a given problem. Why is material selection important? Many ships or offshore installations are built using standard material specifi cations. However, recent develop- ments such as making shipping more environmentally friendly or arctic operations require that traditional solutions need to be re-examined and new design solutions are being developed. In many cases new materials are introduced and with them the need for new joining methods. Adhesive bonding is a joining process where the fi nal material properties are created during processing and application of the adhesive. Many designers of bonded joints are mainly concerned with the short- and long-term mechani- cal performance of the adhesively bonded joint. What is not always appar- ent is that by selecting a specifi c type of adhesive, most of the manufacturing 20 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 parameters are decided as well. Hence information about fabrication aspects is also crucial for the designer of bonded joints, more so than with traditional materials such as steel. 2.1.1 The link between design, material selection and fabrication A design is initiated by defi ning a market need or new idea and a statement specifying what task this device will actually perform and the requirements that have to be fulfi lled (Pahl et al., 2007). It is usually documented in a list of requirements. This is followed by conceptual design, embodiment design and fi nally detailed design. These different design phases are used to specify functions and working principles, overall layout and fi nally the arrange- ments, forms, dimensions and materials are specifi ed. All the different stages of design require information about the materials being used. The scope and degree of detail varies from all/many materials with low precision and detail for concept design to one material and high precision and detail for detailed design (Ashby, 2007). The motivation for selecting or changing the existing material choice depends also on the type of design (Ashby, 2007). For a new design, new materials with unique properties can be exploited. Sometimes design needs drive materials development, for example, lightweight materials for ships. When adaptive design takes place, existing materials are sometimes replaced to improve performance, such as the use of glass fi bre composites for skis instead of wood. Variant design may sometime lead to material change because, for example, the current material choice will not meet the stiffness requirements for the longer variant. Another reason for material substitu- tion could be quality problems, such as corrosion, that require the selection of a new material. An interesting observation is that text books on design almost never mention materials. Pahl et al. (2007) refer to materials in their index once – in the cost estimation chapter. However, as Fig. 2.1 illustrates, there are many interactions between function, material, shape and process. As Ashby puts it, the shape, both macro-shape and micro-shape, such as a panel made of honeycomb, is subject to a (manufacturing) process to be able to produce it (Ashby, 2007). This includes forming and joining pro- cesses. A process is infl uenced by the material and it interacts with the shape. Function dictates materials and shape. Materials are usually only considered in the earlier phases of the design process of marine structures when they affect the global design, For example, to: save weight in order to reduce fuel consumption and emissions, improve stability and increase payload, Adhesives for marine environments and pre-design 21 © Woodhead Publishing Limited, 2012 reduce price – not only of new construction, but also lifetime cost through reduced maintenance and increased lifetime, modify/upgrade existing designs: the additional structure needs to be as light as possible to minimise impact on stability and fuel consumption. In many ways, new materials, such as composites, enable modifi cation of ships and redeployment to new services, simplify recycling of ships in the future and possibly reduce the CO2 footprint of ship building. The joining process is a consequence of the materials used. In the case of adhesive bonding this could mean that the plates are too thin to weld, a particular material combination that cannot be welded, requirement for smooth surfaces for aesthetic reasons, and corrosion management – to have an ‘insulating’ layer between the materials to be joined. 2.1.2 Design for adhesive bonding Adhesive selection is part of the initial design process when not all the details of the design have been decided. It is therefore useful to review briefl y the factors that make a design more adhesive friendly. One of the most important processes in achieving this is ‘design for production’. Why is design for production important? Adhesive selection focuses on selecting adhesives for their mechanical performance. The designer is not always aware that by selecting a particular material he or she also specifi es a fab- rication process and joining method. Hence it is even more important for a designer to consider fabrication and assembly early on in the process. Ashby has proposed some simple rules for designers to minimise process- ing costs (Ashby, 2007, p203): Shape Material ProcessFunction 2.1 The interaction between function, material, shape and process (after Ashby, 2007). 22 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 ‘Keep things standard’: to minimise inventory costs, use standard mate- rials and components. ‘Keep things simple’: to minimise the number of process steps required to make the component. This includes ease of access, e.g. for an adhesive gun or to what extent clamping is needed. ‘Make the parts easy to assemble’: to minimise the assembly time (and cost). This is mainly achieved by minimising part count, by designing components to be self-aligning on assembly and by using fast joining methods. ‘Do not specify more performance than needed’: high performance materials have stricter processing requirements; hence, specifying too high performance not only leads to increase in materials costs, but also processing costs. Design for assembly is another important element in an ‘adhesive- friendly’ design. Pahl et al. (2007) argue that design for assembly should at least consider the following operations: storing of parts to be assembled handling of components, including identifying and moving the parts positioning or placing the part correctly and aligning it before joining joiningprocess – here of course adhesive bonding adjusting to equalise tolerances securing the assembled parts against unwanted movement inspecting. Datsko developed his 11 ‘Datsko’s Design Rules for Optimal Produce- ability’ (Datsko, 1997). Many are similar to those mentioned previously. However, the following rules have not been considered yet and are added for completeness: Select the material on the basis of ease of fabrication as well as function and cost. It is important to remember that each adhesive has its own chemistry and specifi c requirements for the fabrication process due to different curing mechanisms (e.g. heat or humidity). Provide clamping, locating and measuring surfaces. This is important for the assembly of bonded structures. Evaluate the preliminary design and consider changes in the confi gura- tion that will simplify the fabrication, then go through the design rules again. Repeat until the optimal design is achieved. 2.2 Material and process selection Material and process selection is an iterative solution-fi nding process. One of the conceptual challenges with adhesive bonding is that one selects an Adhesives for marine environments and pre-design 23 © Woodhead Publishing Limited, 2012 adhesive for its mechanical performance but at the same time also selects a joining process. Ashby presented a systematic approach to selecting mate- rials and fabrication processes (Ashby, 2007). He developed a structured process for selecting materials in mechanical designs. It is based on a four step approach: (i) translate design requirements: express as function, constraints, objec- tives and free variables, (ii) screen using constraints: eliminate materials that cannot do the job, (iii) rank using objective: fi nd the screened materials that do the job best and fi nally (iv) seek supporting information: research the family history of the top- ranked candidates. In parallel to the material selection, Ashby also introduces a method for selecting appropriate processing routes for the material and product. It is also divided into four steps: (i) translate design requirements: the design requirements are expressed as constraints on material, shape, size, tolerance, and other process related parameters. (ii) screen using constraints: eliminate processes that cannot meet the translated design requirements. (iii) rank using objective: order by relative cost or batch size and fi nally (iv) seek supporting information: research history and experience with the top ranked processes. Reuter (2007) extends part of the approach by Ashby. Rather than simply seeking supporting information, he uses ‘verifi cation’ of the material selec- tion as the fi nal step. This can be based partly on a risk analysis such as Fault-Tree Analysis and mostly on verifi cation by calculation and testing of the selected material. While Ashby’s method is widely recognised, it needs to be modifi ed nonetheless to adjust to the particular requirements of adhesive bonding, i.e. the need to select process and material simultane- ously. The fi nal material selection depends to a considerable degree on local conditions. As both Ashby and Reuter point out, previous experience, avail- able knowledge and production capabilities are the main selection factors. This may mean that the selected material is not always the ‘best’ material for the particular design. This chapter will not discuss the different types of adhesives as this infor- mation can readily be found in other publications. For a brief introduction see for example (Lees, 1988, 1991) while a comprehensive overview can be found in Packham (2005) and section 2 of Brinson (1990). For information about commercial products see technical information from the different 24 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 adhesive suppliers. Moreover, the surface preparation of the adherends is not considered in this chapter. 2.3 Adhesive selection step 1: translate design requirements The fi rst task in the selection process is to establish suitable selection criteria and optimisation objectives. Adhesive bonding is a joining process used to assemble structures and structural elements. Hence, one will get the relevant information from the design requirements. This information needs to be translated in order to identify the adhesive specifi c criteria and optimisation objective. A very comprehensive approach to specifying requirements was presented by Pahl et al. (2007) and is shown in Table 2.1. It covers design, fabrication, operation and maintenance of the component. Each item on this list will be classifi ed according to how important it is. D = demand: must be met at all circumstances; W = wishes: should be taken into consideration. This table should also include quantitative (e.g. numbers and magnitudes such as number of items, maximum weight, power output) and qualitative (e.g. permissible variation, waterproof, corrosion proof) criteria. Next, the requirements on design and process are expressed as function, constraints, objective and free variables as shown in Table 2.2 and Table 2.3. A typical result for process requirements is shown in Table 2.4. When it comes to the optimisation objective there is probably only one – minimisa- tion of cost! When costing the process, one should also consider savings further down the line such as reduced time for rectifi cation of distorted structures or repair of damaged coating. 2.3.1 Pre-design The design and process requirements say little or nothing about the con- fi guration or loading of the bonded joint. In particular for applications that are new, with no similar previous examples, it may be useful to get some initial idea about possible joint confi guration, estimate of the loading of the adhesive and joint dimensions. The initial assumption must be confi rmed later on in step 4 of the selection process. There are many catalogues of bonded joint confi gurations; a possible starting point is Section 5.1.2 in Weitzenböck and McGeorge (2005) and Adams et al. (1997). Adhesively bonded joints should be loaded in shear where they are strongest. For signifi cant loads in out-of-plane direction one should consider redesigning the joint to reduce the infl uence of peel loading. Another option might be the use of hybrid joining methods as discussed for example in Adhesives for marine environments and pre-design 25 © Woodhead Publishing Limited, 2012 Table 2.1 Requirement list (Pahl et al., 2007) Main headings Examples Geometry Size, height, width, length, diameter, space requirements, number, arrangement, connection, extension Kinematics Type of motion, direction of motion, velocity, acceleration Forces Direction of force, magnitude of force, frequency, weight, load, deformation, stiffness, elasticity, inertia force, resonance Energy Output, effi ciency, loss, friction, ventilation, state, pressure, temperature, heating, cooling, supply, storage, capacity, conversion Material Flow and transport of materials, physical and chemical properties of the initial and fi nal product, auxiliary materials, prescribed materials (food regulation etc.) Signals Inputs and outputs, form, display, control equipment Safety Direct safety systems, operational and environmental safety Ergonomics Man–machine relationship, type of operation, operating height, clarity of layout, sitting comfort, lighting, shape compatibility Production Factory limitations, maximum possible dimensions, preferred production methods, means of production, achievable quality and tolerances, wastage Quality control Possibilities of testing and measuring, application of special regulations and standards Assembly Special regulations, installation, siting, foundationsTransport Limitations due to lifting gear, clearance, means of transport (height and weight), nature and conditions of despatch Operation Quietness, wear, special uses, marketing area, destination (e.g. sulphurous atmosphere, tropical conditions) Maintenance Servicing intervals (if any), inspection, exchange and repair, painting, cleaning Recycling Reuse, reprocessing, waste disposal, storage Costs Maximum permissible manufacturing cost, cost of tooling, investment and depreciation Schedules End date of development, project planning and control, delivery date Table 2.2 Translation of design requirements (after Ashby, 2007) Function What does component do? Constraints What non-negotiable conditions must be met? What are the negotiable but desirable conditions? Objective What is to be maximised or minimised? Free variables What parameters of the problem is the designer free to change? 26 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 Table 2.3 Translation of process requirements (after Ashby, 2007) Function What must the process do? (Shape, join, fi nish?) Constraints What material, shape, size, precision, etc. must it provide? Objective What is to be maximised or minimised? (Cost, time, quality?) Free variables Choice of process/process chain options Table 2.4 Translation of process requirements (Table 2.3 and Weitzenböck and McGeorge, 2005) Function What must the process do? (i) Join two (dissimilar) materials, (ii) mix different adhesive component (two or one), (iii) control viscosity by varying temperature, (iv) provide suffi cient humidity for humidity curing adhesives to cure Constraints What material, shape, size, precision, etc. must it provide? (i) Must be able to accommodate fairly large bond line thicknesses – tolerance of components to be joined (>10 mm), (ii) have a certain handing strength after a given time to achieve desired throughput, (iii) mainly fl at, parallel interfaces, (iv) large bonding surfaces with corresponding extended open time (typically >30 minutes), (v) materials: different steel alloys, different aluminium alloys, composites, (vi) one-component polyurethane humidity adhesives can take weeks to cure, (vii) control of bonding conditions – e.g. humidity, surface cleanliness and structure and application temperature Objective What is to be maximised or minimised? Cost is to be minimised – cheaper than a welded solution while quality is to be maximised to achieve expected lifetime and reliability Free variables Choice of process/process chain options. Select adhesive chemistry to eliminate some of the constraints – the optimal solution is very dependent on the application case. Will it be used for small or large batch sizes? Will it be used in a controlled workshop or in the dock? Weitzenböck and McGeorge (2011). The following formulae apply to in- plane shear. For fl exible adhesives, Burchardt et al. (1998) propose the following for- mulae to determine lap-shear strength: A S F f S F A f K K Shear B t B K Shear K t or= = τ τ [2.1] with AK = area of bond face SK = safety factor Adhesives for marine environments and pre-design 27 © Woodhead Publishing Limited, 2012 ft = reduction factor for exposure to constant static stress τB = lap-shear strength FShear = shear force Burchardt et al. specify a minimum safety factor of 2 and reduction factor of 0.06 for exposure to constant static stress. Bigwood and Crocombe proposed a closed form solution that can be applied to stiff adhesives in L- and T-joints, T-peel and single lap joints (Bigwood and Crocombe, 1989). Even though the formulae are more complex, once implemented in a spreadsheet they are easy to use. It is pos- sible to compute both shear and peel stresses in the adhesive. Another important piece of information early on is the minimum overlap length of the bonded connection. Brede developed simple formulae for determining the minimum overlap length of a lap-shear joint (Section 11.2 in Weitzenböck and McGeorge, 2005): l E s d G E s E s G l E s d * = +( ) = = +( ) ∗ρ δ δ ρ δ 1 1 1 1 2 2 2 1 11 1with and [2.2] with l* = minimum overlap length l = overlap length E1 and E2 = Young’s modulus of adherends 1 and 2 s1 and s2 = thickness of adherends 1 and 2 d = thickness of adhesive layer G = shear stiffness of adhesive The minimum overlap length l* is estimated by selecting ρ to be 5 in Equa- tion [2.2]. Experience has shown that increasing ρ beyond 5 does not lead to any signifi cant changes in the stress distribution. Bigwood and Crocombe (1989), Burchardt et al. (1998) and Weitzenböck and McGeorge (2005, Section 11.2) provide an estimate of the linear elastic behaviour of bonded joints – they should not be used for predicting failure. However, because of their simplicity the formulae can be used to get a fi rst estimate of the required adhesive performance. This needs to be confi rmed and refi ned later on (see also step 4 of the selection process). 2.4 Adhesive selection step 2: screen using constraints The results of the previous exercise form the basis for identifying adhesives that are suitable for the job. Some of the constraints formulated above will exclude certain adhesives. For example gap fi lling capabilities, operating temperature, loading requirements will only be met by some adhesives. As 28 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 Lees remarked (Lees, 1995), even though the individual requirements may be quite vague, the fact that there are many of them results in quite a fi ne ‘fi lter’. In practical terms, one usually approaches adhesive suppliers with the list of requirements and asks them to recommend suitable products from their range of adhesives. 2.5 Adhesive selection step 3: rank using objective The aim of this step is to fi nd the screened materials that do the job best and to rank the (adhesive) joining processes by relative cost or batch size. Here the optimisation objective is used to prioritise the different candidate adhesives. Ashby (2007) has developed a material index to compute a solu- tions space for possible candidate materials. This can easily be done using his general material selection CES software. However, for adhesives it is often diffi cult to defi ne absolute performance criteria. It is therefore up to the designers and engineers to make the fi nal selection. 2.5.1 Ranking mechanical performance by screening tests Many maritime applications are unique. Materials or the surface coatings used are usually different from one application to another. Hence, there is rarely detailed information about the mechanical performance of the adhe- sives being considered for the material confi guration used in the new design. It is therefore quite common to carry out screening tests in order to assess the pre-selected adhesives. The methods described in this section are com- monly used for screening purposes. They are simple to carry out which is important when many combinations are to be examined. The test results do not always result in an absolute value but can be compared with the other competing adhesives. While these tests provide some basic material char- acterisation, they may not be suffi cient to provide the required input to some of the advanced analysis methods used elsewhere in the book. Most of the test procedures can be found in Weitzenböck and McGeorge (2005), including deviations from the standards. Measurement of Tg Many room temperature curing (rigid) adhesives have a glass transition temperature (Tg) of around 50°C to 70°C. It is therefore important to estab- lish the precise Tg in order to select a suitable temperature for accelerated ageing tests. These measurementsare not applicable to fl exible adhesives (e.g. polyurethanes) as their Tg is well below 0°C. The applicable test is the torsion-pendulum test according to ASTM E 1356 or ISO 6721. Adhesives for marine environments and pre-design 29 © Woodhead Publishing Limited, 2012 Measurement of pH value The measurement of the pH value of all adhesives is important since experi- ence has shown that some adhesive can be quite acidic or alkaline under the long-term infl uence of water. This can create corrosion problems in the joint. It is therefore important to select adhesives with a ‘neutral’ pH value. The test procedure follows the IFAM test standard WP-AA-60 (see Weitzenböck and McGeorge, 2005 or Det Norske Veritas, 2011a). Lap-shear test – strength This is the most common test used for all types of adhesives. Lap-shear strength is measured before and after ageing to assess the ability of the adhesives to withstand adverse environments. The relevant test standards are: ASTM D 1002, DIN EN 1465, ISO 4587. Lap-shear test – strain to failure Flexible adhesives show creep when loaded. The aim of this test is to assess the ability of the adhesive to sustain strain. This test is a slightly modifi ed standard lap-shear test where a constant displacement (strain) is applied. The details of the tests are documented in Det Norske Veritas (2011a). An alternative based on IFAM test standard WP-AA-11 can be found in Weitzenböck and McGeorge (2005). Boeing wedge test The Boeing wedge test (ASTM D 3762) can be used to assess the durability of the bonding system – the complete surface preparation and coating and the adhesive. This test is only used for rigid adhesives. Measurement of electrical resistance The measurement of electrical resistance of all adhesives is important to make sure that all selected adhesives have suffi cient specifi c resistance. This will ensure that the adhesive layer acts as electrical insulator and prevents electrochemical corrosion not only at the joint but anywhere in the structure. The applicable test procedure is the Sika Test Procedure 316 ‘Determination of electrical specifi c volume resistance’ (Weitzenböck and McGeorge, 2005). Bead test The bead test (Sika SQP033-0, Sika SQP034-0; see also Weitzenböck and McGeorge, 2005) was selected to assess the durability of the bonding system 30 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 – the complete surface preparation and coating and the adhesive. This test is only used for fl exible adhesives. 2.6 Adhesive selection step 4: seek supporting information Ashby proposes that the last step in the selection process is dedicated to researching the history and experience with the top-ranked material and process. Reuter (2007) suggests that rather than simply seeking supporting information, one uses ‘verifi cation’ of the material selection as the fi nal step. This can be based partly on a risk analysis such as Fault-Tree Analysis or FMEA (Failure Mode and Effect Analysis) and mostly on verifi cation by calculation and or rapid prototyping and or testing of the selected material or a bonded assembly. Several chapters in this book are concerned with detailed analysis and testing of bonded connections and structures. In many marine applications the use of adhesive bonding is quite new. Most of the established criteria and test and analysis methods are not suit- able to assess whether the bonded connection is acceptable or not as they were designed with other joining methods in mind. Hence the verifi cation activity needs to demonstrate that adhesive bonding is at least as safe as traditional solutions. This could be done using a risk-based approach, such as the ‘Qualifi cation of new technology’ process described in Det Norske Veritas (2011b). 2.6.1 Simplifi ed approach In certain situations it is quite possible to shorten the selection process. Having said that, the fi rst step – translating design requirements – is essen- tial to successful adhesive joining. It is here that structural and fabrication requirements are translated to adhesive specifi c requirements. However, the other steps may be modifi ed or simplifi ed as shown for example for elastic bonding by Burchardt et al. (1998). The authors suggest a simplifi ed selection process as most fl exible adhesives have quite similar mechanical properties. Burchardt et al. select (fl exible) adhesives according to only two criteria: (i) compatibility with the materials to be joined and (ii) cost – simple and economical to apply. Moreover, they emphasise the importance of good process and quality control. Sometime additional criteria are used such as non-sag and high early strength during cure. 2.7 Future trends As mentioned in the introduction, adhesive bonding is still a relatively young joining method in marine engineering with many research and Adhesives for marine environments and pre-design 31 © Woodhead Publishing Limited, 2012 development opportunities. However, this does not preclude it from being used today, albeit for less demanding applications. However, to make adhesive bonding more attractive as an industrial process, one needs to remove as many potential barriers as possible. In particular there is a need for standard solutions that are pre-qualifi ed and pre-approved. Usually there is no time to develop and qualify new designs, hence the need for off-the-shelf technology. Another important area is the integration of adhesive bonding in Finite Element Analysis (FEA) and Computer Aided Design (CAD) software. Modern ships and offshore structures are designed and analysed using advanced FEA and CAD systems. Hence, adhesives and the adhesive bonding process needs to be character- ised suffi ciently to be able to model them in these systems. Arenas and Guillamón (2007) present a solution on how to represent adhesive bonding in design software. These developments will lead to a signifi cant decline in the need for adhesive selection. Pre-approved standard solutions may be selected from catalogues or standards including material and process speci- fi cations. However, more demanding applications still require ‘adhesive selection’. While there is clearly need for industry wide standard solutions, Reuter points out that this at the same time might hamper development of novel solutions or solutions to non-standard problems (Reuter, 2007). Another observation is that adhesives are today mainly considered late in a construc- tion project; usually because the original solution did not work. Hence, adhesive selection will have to be carried out when most parameters have already been fi xed – with few degrees of freedom. This is not an ideal situ- ation but not uncommon. Adhesive specifi c designs will become more common in the future. 2.8 Sources of further information Useful textbooks for adhesive selection are listed below. Michael Ashby is the materials selection ‘guru’. In his book, Ashby (2007) provides a systematic approach to selecting materials and fabri- cation processes with many good examples (and his software). Reuter (2007) presents the Ashby approach in the context of engineer- ing design and analysis (in German). Weitzenböck and McGeorge (2005) offer a pragmatic approach to mate- rial selection with emphasis on specifi cation of requirements for design, fabrication and use of the new product. Sharpe (1990) discusses adhesive selection. His chapter is part of one of the most comprehensive books on adhesive technology; it covers every- thing from chemistry to engineering. 32 Adhesives in marine engineering © Woodhead Publishing Limited, 2012 The book by Adams et al. (1997) is one of the leading text books on adhesive design and analysis, with a good chapter on adhesive
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