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2006 CASTING SOURCE DIRECTORY ENGINEERED CASTING SOLUTIONS 41 Magnesium Alloys Table 1. Typical Mechanical Properties of Magnesium at Room Temperature Property Unit AZ91 AM60 AM50 AM20 AS41 AS21 AE42 Ultimate Tensile Strength MPa 240 225 210 190 215 175 230 (250) (240) (230) (210) (240) (220) (230) Tensile Yield Strength MPa 160 130 125 90 140 110 145 (0.2% offset ) (160) (130) (125) (90) (140) (120) (145) Compressive Yield Strength MPa 160 130 125 90 140 110 145 Fracture Elongation % 3 8 10 12 6 9 10 (7) (13) (15) (20) (15) (13) (11) Elastic Modulus, tension GPa 45 45 45 45 45 45 45 Elastic Modulus, shear GPa 17 17 17 17 17 17 17 Brinell Hardness 70 65 60 45 60 55 60 Impact Strength J 6 17 18 18 4 5 5 Charpy un-notched test bars (9) (18) (18) (18) (16) (12) (12) Note: Values in parentheses show mean property values obtained from separately diecast test bars. Table 2. Typical Physical Properties of Magnesium Property Unit Temp (F) AZ91 AM60 AM50 AM20 AS41 AS21 AE42 Density g/cu cm 68 1.81 1.8 1.77 1.75 1.77 1.76 1.79 Liquidus Temperature F 1,110 1,139 1,148 1,182 1,144 1,169 1,157 Incipient Melting Temperature F 788-815 788-815 788-815 788-815 788-815 788-815 1094 Linear Thermal Expansion Coeffi cient µm/m 68-212 26 26 26 26 26.1 26.1 26.1 Specifi c Heat of Fusion kJ/kg 370 370 370 370 370 370 370 Specifi c Heat kJ/kg*K 68 1.02 1.02 1.02 1.02 1.02 1.02 1.02 Thermal Conductivity W/K*m 68 51 61 65 94 68 84 84 Electrical Conductivity MS/m 68 6.6 nm 9.1 13.1 nm 10.8 11.7 Cast magnesium alloys have gained more popularity in recent years due to their ability to maintain high strengths at light weights. Mag- nesium possesses unique properties that can open the door to important markets for structural applications and has gained widespread use in automotive compo- nents. Further, non-automo- tive applications, spurred on by the computer, electronics and power tool industries, con- tinue to expand. Magnesium has a density two- thirds that of aluminum and only slightly higher than that of fi ber-reinforced plastics and possesses excellent mechanical and physical properties (Tables 1-2). When coupled with the inherent advantages of the metalcasting process, magnesium alloys yield cost-effective solutions to product needs by allowing for part con- solidation and weight savings over other materials and manufacturing methods. Advantages of Magnesium Magnesium alloy properties can pro- vide a casting designer with several ad- vantages as an engineering material over other lightweight alloys. Weight—The lightest of all structural metals, magnesium preserves the light weight of a design without sacrificing strength and rigidity (Fig. 1). This benefi t is important when portability is a key element of the product design, such as with chainsaws, pneumatic nailers, circu- lar saws, luggage, laptop computers and cellular phones. Automobiles and other transportation equipment continue to take advantage of magnesium’s low density in expanding application areas ranging from under-hood and driveline uses found in engine brackets and transfer cases to numerous interior parts, such as steering column components, pedal brackets, in- strument panel supports and seating. Damping Capacity—Magnesium is unique among metals because of its ability to absorb energy. Increased vibration absorption capacity provides for quieter operation of equipment when magnesium castings are used for housings and enclosures. Dimensional Stability—Annealing, ar- tifi cial-aging or stress-relieving treatments normally are not necessary to achieve stable fi nal dimensions. Metallurgical changes in the structure of some metals can affect dimensions after prolonged exposure to elevated temperatures, but this is not the case with magnesium al- loys. As a result, there have been few problems associ- ated with the dimensional change of castings in assem- blies. Magnesium shrinkage rates are more consistent and predictable in comparison to other nonferrous metals. Components release from the die with minimal force and distortion, hence they have minimal residual casting stress. Impact & Dent Resistance— The elastic energy absorption characteristics of magnesium result in good impact and dent resistance and energy management, which is one reason magnesium castings can be used for automotive safety-related The conversion of this military helicopter transmission housing from a fabrication to a magnesium casting allowed for a 30% cost reduction and lowered scrap rate by 40%. The American Foundry Society Technical Dept., Schaumburg, Illiniois 42 ENGINEERED CASTING SOLUTIONS 2006 CASTING SOURCE DIRECTORY Fig. 1. Magnesium’s light weight has allowed it to become the alloy of choice for a number of new markets and applications, such as the automotive, power tool, computer and electronics industries. applications, such as air bag systems. Portable tools and handheld electron- ics also benefit from this combination of proper- ties, offering mechanical shock resistance. Anti-Galling—Magne- sium alloys possess a low galling tendency and can be used as a bearing sur- face in conjunction with a shaft hardness above 400 Brinell measurement. Alloy Families Magnesium alloys can be used in multiple ap- plications, but they easily can be divided into two groups: sand casting alloys and diecast- ing alloys. Alloys also can be classified as general purpose, high-duc- tility and high-temperature with higher levels of iron, nickel and copper. Sand casting alloys often are produced with a fine grain structure due to small ad- ditions of zirconium. Aluminum is the prin- cipal alloying element for many magnesium alloys as it can improve the mechan- ical strength, corrosion properties and castability of magnesium castings. The most widely used gen- eral purpose sand casting alloy is AZ91. In the alloy nomenclature, the letters A and Z denote the ma- jor alloy. However, not all properties improve with aluminum and zinc additions. Ductil- ity and fracture toughness are gradually reduced when more aluminum is added. This effect led to the introduction of a series of alloys with reduced aluminum contents (the AM series), which is used extensively for automotive safety-related components. These include manganese, which is added to control the iron content of the alloys. Several alloys, such as AM60 (6% aluminum, 0.05% manganese), have found widespread applications in parts, including instrument panel supports, steer- ing wheel armatures and seat parts. Some applications expose the cast- ing to higher operating temperatures or continuous stresses that lead to concerns about long-term deformation and creep. Castings for use in higher temperature service conditions can be produced in al- loys, such as the AS and AE series, based on the addition of either silicon or rare earth elements (E), which promote the formation of fi nely dispersed particles at the grain boundaries. Recent property and castability im- provements have been shown with new magnesium creep-resistant alloys that use specialized rare earth elements, such as calcium or strontium, as the signifi cant alloying elements. These new alloys can produce cast components with superior alloys. Most magnesium alloys are pro- duced as high-purity versions to reduce potential corro- sion problems associated This engine cradle for a high-performance sports car was redesigned from a low-pressure alumi- num permanent mold casting to two different processes: a magnesium vacuum die casting (top), which helped lower porosity defects; and a low-pressure permanent mold magnesiumcasting (bottom), which allowed for a sand core to form a hollow cross support beam rather than the ribbed support design of the die casting. 2006 CASTING SOURCE DIRECTORY ENGINEERED CASTING SOLUTIONS 43 mechanical properties at in-service higher temperature ranges. Casting Processes Along with magnesium’s multiple al- loys, the material can be cast by a variety of methods, including high-pressure diecasting, permanent mold casting, sand casting, semi-solid and squeeze casting. Different alloys may be specifi ed for these different processes, but in cases where the same alloy is used with different casting processes, the properties of the fi nished castings will depend on the method. The most prevalent casting method for magnesium is diecasting. In this process, complex, thin-walled parts are produced at high production rates aided by the low- heat content per volume of molten metal. Both hot chamber and cold chamber ma- chines currently are used for magnesium. For optimum performance, it is recom- mended that higher shot speeds are used for magnesium compared to aluminum, especially for thin-walled parts. Diecast- ing process variants (such as vacuum diecasting) can produce components with lower porosity and better properties than standard diecasting. Magnesium also is conducive to using semi-solid casting methods, typically with magnesium alloy granules or partially solidifi ed alloys rather than liquid mag- nesium. Semi-solid molding commonly is used for smaller parts, such as those used in the electronics industry. Design Considerations When evaluating the various alloys and processes for a magnesium casting, there are a number of characteristics to consider to obtain a quality, low-cost component. This includes the end-use application, the post- casting operations and how casting magnesium will factor into tooling costs. High Stiffness-to-Weight Ra- tio—This characteristic is important where resistance to defl ection is desired in a lightweight component. Improved Die Life—Unlike molten aluminum, molten magnesium does not react with tool steels, resulting in longer die life and increased productiv- ity. Because of low erosion and reduced heat input, which reduce the propensity for thermal fatigue (heat checking of the die), casting magnesium can warrant three to four times the die life than if aluminum were used. Machining—Magnesium is recognized as the easiest of structural metals to Cast through the rubber plaster molding process in AZ91D magnesium alloy, this projector frame and interface offered the customer improved durability and rigidity, high heat tolerance and eliminated EMI plating requirements when compared to its previous plastic injection mold design. This 2.3-lb AM60B magnesium shift tower assembly is a one-piece diecast component. Converted from a multiple steel fabrication, the magnesium casting design resulted in a 75% weight savings. machine and is the “standard” of the cutting tool industry when comparing machinability of metals. The low power requirements for machining magnesium alloys permit the use of deeper cuts and higher feed rates, thus permitting fast and efficient machining when compared to other metals. Magnesium alloys also normally produce well-broken chips, which are easy to handle. ECS This article was adapted with permission from materials prepared by the Interna- tional Magnesium Assn., McLean, Va., and the North American Die Casting Assn., Wheeling, Ill.
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