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2006 November • JOM 51 FeatureMaterials World Introducing the Nominees for the Greatest Materials Moments in History A Great Materials Moment is defi ned as a pivotal or capstone event of human observation and/or intervention that led to a paradigm shift in humanity’s understanding of materials behavior, that introduced a new era of materials utilization, and/or that yielded signifi cant materials-enabled socio-economic changes. James J. Robinson Would it be too bold of me to say that the materials community suffers from an inferiority complex? I hear it all of the time: Who gets most of the funding? The health community. Who gets the best media coverage? The physics community. Who gets the best pay? The petroleum and chemical communities. Who gets the short- est shrift in the public’s eye? The materials community. Whether this litany is com- pletely or partially true, I dare say that the materials fi eld is worthy of much more favorable press and lively buzz than it conventionally receives—something more than once again blowing the dust off of our favorite adage concerning the early ages of civilization be- ing characterized with materials terms (“stone,” “bronze,” “iron”). We know that . . . and more. We know that ev- ery aspect of every culture relies upon engineered materials (from the farming tools used in agrarian communities to the silicon and fi ber optic enablers of the information age). Materials are the stuff that dreams are made of. So, how do we impress that knowl- edge on—nay, share our material en- thusiasm with—a public that typically prefers science in easy-to-understand and non-challenging terms? And, how do we have fun while doing it? How about this? Let us undertake to name the all-time greatest moments of materials science and engineering. This should prove intriguing for the general public (everyone loves a list) and intel- lectually stimulating for the science and engineering community. Plus, it could create some terrifi c arguments. defi nition of what constitutes a great materials moment (see the gray box). Key is the notion of human observa- tion and/or intervention—we want to emphasize feats of human intellect and ingenuity (i.e., the science and engi- neering of it all). Defi nition in hand, we invited doz- ens of materials professionals with a broad view of the fi eld and a strong historical perspective to nominate great moments. We supplemented their nom- inations with moments culled from the literature. The effort yielded an inven- tory of more than 650 suggestions. The JOM staff took this roster and distilled it into a list of 100 candidates. We then invited a select group to vet the draft list. Using the feedback, we refi ned the draft into the offi cial candidate list that you will fi nd on the following pages. Now is the time for you to tell us what you think by voting. For the list to have weight, it must have your input. We’ve created a web site to acquaint the public with our plan (www.materialmoments.org) as well as an on-line survey form that voters can use to build a top ten from the list of nominees. As someone who has already voted, I can confi rm that creating a person- alized ranking is a challenging and rewarding activity. We will accept votes through the end of the year and then announce the top ten during February’s TMS 2007 Annual Meeting & Exhibition in Walt Disney World. The announcement will be made during an all-conference ple- nary breakfast as TMS presidents from across the decades will count the mo- ments down from ten to one. The pres- ence of so many past presidents is of special signifi cance as 2007 marks the 50th anniversary of TMS as a member society of the American Institute of Mining, Metallurgical and Petroleum Engineers. Thus, the next annual meet- ing will not only be a celebration of TMS’s organizational history but the very history of materials science and engineering itself. Before we start unveiling moments in Orlando, however, there is the lit- tle matter of casting your vote for the greatest materials moments. To vote: www.materialmoments.org Here is JOM’s method- ology for devising such a list. First, we created a And the nominees are . . . James J. Robinson is editor of JOM. JOM • November 200652 Great Materials Moment Date Signifi cance The earliest fi red ceramics—in the form of animal and human 28,000 BC Introduces materials processing. fi gurines, slabs, and balls—(found at sites in the Pavlov Hills of (estimated) Moravia) are manufactured starting about this time. The earliest form of metallurgy begins with the decorative 8000 BC Leads to the replacement of stone tools with much hammering of copper by Old World Neolithic peoples. (estimated) more durable and versatile copper ones. In and around modern Turkey, people discover that liquid copper 5000 BC Introduces extractive metallurgy—the means of unlocking the can be extracted from malachite and azurite and that the molten (estimated) Earth’s mineralogical treasures. metal can be cast into different shapes. Egyptians smelt iron (perhaps as a by-product of copper refi ning) 3500 BC Unlocks the fi rst processing secret of what will become the world’s for the fi rst time, using tiny amounts mostly for ornamental or (estimated) dominant metallurgical material. ceremonial purposes. Metal workers in the region of modern Syria and Turkey discover 3000 BC Establishes the concept of metals alloying—blending two or more that addition of tin ore to copper ore before smelting produces bronze. (estimated) metals to create a substance that is greater than the sum of its parts. The peoples of northwestern Iran invent glass. 2200 BC Introduces the second great nonmetallic engineering material (estimated) (following ceramics). Potters in China craft the fi rst porcelain using kaolin. 1500 BC Begins a long tradition of exceptional craftsmanship and artistry (estimated) with this class of ceramics. Metal workers in the Near East develop the art of lost-wax casting. 1500 BC Establishes the ability to create and replicate intricate and complex (estimated) metallurgical structures. Metal workers in south India develop crucible steel making. 300 BC Produces “wootz” steel which becomes famous as “Damascus” (estimated) sword steel hundreds of years later, inspiring artisans, blacksmiths, and metallurgists for many generations to come. Chinese metal workers develop iron casting. 200 BC Introduces the primary approach to manufacturing iron objects for (estimated) centuries in China. Glass blowing is developed, probably somewhere in the region of 100 BC Enables the quick manufacture of large, transparent, and leak-proof modern Syria, Lebanon, Jordan, and Israel—most likely by Phoenicians. (estimated) vessels. Iron smiths forge and erect a seven meter high iron pillar in 400 Defi es deleterious environmental effects for more than one and a Delhi, India. (estimated) half millennia, creating an artifact of long-standing materials science and archaeological intrigue. Johannes Gutenberg devises a lead-tin-antimony alloy to cast in 1450 Establishes the fundamental enabling technology for mass copper alloy molds to produce large and precise quantities of the type communication. required by his printing press. Johanson Funcken develops a method for separating silver from lead 1451 Establishes that mining and metals processing operations can and copper, ores of which are often mixed in deposits. recover metals as a by-product of other operations. Vannoccio Biringuccio publishes De La Pirotechnia. 1540 Provides the fi rst written account of proper foundry practice. Georgius Agricola publishes De Re Metallica. 1556 Provides a systematic and well-illustrated examinationof mining and metallurgy as practiced in the sixteenth century. Galileo publishes Della Scienza Mechanica (“on mechanical 1593 Deals scientifi cally with the strength of materials. knowledge”), which he writes after he has been consulted regarding shipbuilding problems. Anton van Leeuwenhoek develops optical microscopy capable of 1668 Enables study of the natural world and its structures that are magnifi cations of 200 times and greater. (estimated) invisible to the unaided eye. Abraham Darby I discovers that coke can effectively replace charcoal 1709 Lowers dramatically the cost of ironmaking (enabling large-scale in a blast furnace for iron smelting. production) and saves regions from deforestation. In Britain, the fi rst glue patent is issued (for fi sh glue, an 1750 Initiates a rapid succession of adhesive developments with natural exceptionally clear adhesive). and then synthetic sources. John Smeaton invents modern concrete (hydraulic cement). 1755 Introduces the dominant construction material of the modern age. Luigi Brugnatelli invents electroplating. 1805 Originates the widely employed industrial process for functional and decorative applications. Sir Humphry Davy develops the process of electrolysis to separate 1807 Establishes the foundation for electrometallurgy and elemental metals from salts, including potassium, calcium, strontium, electrochemistry. barium, and magnesium. Auguste Taveau develops a dental amalgam from silver coins and 1816 Enables repeatable and low-cost dental fi lling material and mercury. establishes one of the earliest examples of metallic biomaterials. Augustin Cauchy presents his theory of stress and strain to the 1822 Provides the fi rst careful defi nition of stress as the load per unit French Academy of Sciences. area of the cross section of a material. Friedrich Wöhler isolates elemental aluminum. 1827 Unlocks the most abundant metallic element in the Earth’s crust. Nominees for the Greatest Moments in Materials Science and Engineering (cont.) 2006 November • JOM 53 Wilhelm Albert develops iron wire rope as hoisting cable for mining. 1827 Presents an exponential leap of large-scale construction and industrial opportunities over the limitations of hemp rope. Charles Goodyear invents the vulcanization of rubber. 1844 Enables enormous progress in the transportation, electricity, manufacturing, and myriad other industries. George Audemars patents “artifi cial silk” created using the fi brous 1855 Leads to the manufacture of rayon and the era of synthetic fi bers, inner bark of a mulberry tree. creating sweeping effects on the textiles and materials industries. Henry Bessemer patents a bottom-blown acid process for melting 1856 Ushers in the era of cheap, large-tonnage steel, thereby enabling low-carbon iron. massive progress in transportation, building construction, and general industrialization. Emile and Pierre Martin develop the Siemens-Martin open-hearth 1863 Produces large quantities of basic steel by heating a combination of furnace process. steel scrap and iron ore with gas burners—helping to make steel the world’s most recycled metal. Henry Clifton Sorby uses light microscopy to reveal the 1863 Leads to the use of photomicrography with metals and the science microstructure of steel. of metallurgy. Dmitri Mendeleev devises the Periodic Table of Elements. 1864 Introduces the ubiquitous reference tool of materials scientists and engineers. Alfred Nobel patents dynamite. 1867 Proves of immeasurable assistance in conducting large-scale mining. J. Willard Gibbs publishes the fi rst part of the two-part paper “On the 1876 Provides a basis for understanding modern thermodynamics and Equilibrium of Heterogeneous Substances.” physical chemistry. William Siemens patents the arc-type electric furnace. 1878 Leads to the modern electric arc furnace, which is the principle furnace type for the modern electric production of steel. Pierre Manhès constructs the fi rst working converter for copper matte. 1880 Initiates the modern period of copper making. Charles Martin Hall and Paul Héroult independently and simultaneously 1886 Provides the processing foundation for the proliferation of discover the electrolytic reduction of alumina into aluminum. aluminum for commercial applications. Adolf Martens examines the microstructure of a hard steel alloy and 1890 Initiates the use of microscopy to identify the crystal structures in fi nds that, unlike many inferior steels that show little coherent metals and correlate these observations to the physical properties patterning, this steel had many varieties of patterns, especially banded of the material. regions of differently oriented microcrystals. Pierre and Marie Curie discover radioactivity. 1896 Marks the beginning of modern-era studies on spontaneous radiation and applications of radioactivity for civilian and military applications. William Roberts-Austen develops the phase diagram for iron 1898 Initiates work on the most signifi cant phase diagram in metallurgy, and carbon. providing the foundation for the indispensable tool for other material systems. Johann August Brinell develops a test to estimate the hardness of 1900 Establishes a reliable (and still commonly used) method to metals that involves pressing a steel ball or diamond cone against determine the hardness properties of virtually all materials. the specimen. Charles Vincent Potter develops the fl otation process to separate 1901 Opens the opportunity for the large-scale recovery of metals from metallic sulfi de minerals from otherwise unusable minerals. increasingly diffi cult-to-treat low-grade ores from mining operations. Leon Guillet develops the alloying compositions of the fi rst 1904 Expands the versatility of steel for use in corrosive environments. stainless steels. Alfred Wilm discovers the precipitation hardening of aluminum alloys. 1906 Yields the “hard aluminum” duraluminum, the fi rst high-strength aluminum alloy. Leo Baekeland synthesizes the thermosetting hard plastic Bakelite. 1909 Marks the beginning of the “plastic age” and the modern plastics industry. William D. Coolidge devises ductile tungsten wire, using a powder 1909 Spurs the rapid expansion of electric lamps and initiates the metallurgical approach, for use as an energy-effi cient, high-lumen science of modern powder metallurgy. lighting fi lament. Kammerlingh Omnes discovers superconductivity while studying 1911 Forms the basis for modern discoveries in low- and high- pure metals at very low temperatures. temperature superconductors and resulting high-performance applications. Max von Laue discovers the diffraction of x-rays by crystals. 1912 Creates means to characterize crystal structures and inspires W.H. Bragg and W.L Bragg in developing the theory of diffraction by crystals, providing insight into the effects of crystal structure on material properties. Albert Sauveur publishes Metallography and Heat Treatment of 1912 Promulgates the “processing-structure-properties” paradigm that Iron and Steel. guides the materials science and engineering fi eld. Great Materials Moment Date Signifi cance Nominees for the Greatest Moments in Materials Science and Engineering (cont.) JOM • November 200654 Niels Bohr publishes his model of atomic structure. 1913 Introduces the theory that electrons travel in discrete orbits around the atom’s nucleus, with the chemical properties of the element being largely determined by the number of electrons in each of the outer orbits. Jan Czochralski publishes the paper “Ein Neues Verfahren zur 1918 Becomes the method of choice for growing high-performance Messung des Kristallisationsgeschwindigkeit der Metalle” (“A New materials, such as the silicon crystals used in thesemiconductor Method for the Measurement of the Crystallization Rate of Metals”), computer chip industry. in which he describes a method of growing metallic monocrystals. A.A. Griffi th publishes “The Phenomenon of Rupture and Flow in 1920 Gives rise to the fi eld of fracture mechanics. Solids,” which casts the problem of fracture in terms of energy balance. Hermann Staudinger publishes work that states that polymers are long 1920 Paves the way for the birth of the fi eld of polymer chemistry. chains of short repeating molecular units linked by covalent bonds. John B. Tytus invents the continuous hot-strip rolling of steel. 1923 Provides the basis for the inexpensive, large-scale manufacturing of sheet and plate products. Karl Schroter invents cemented carbides as a class of materials. 1923 Provides the basis for the workhorse materials of the tool and metal-cutting industries. Cornelius H. Keller patents alkyl xanthates sulfi de collectors. 1925 Begins a revolution in sulfi de mineral fl otation, turning worthless mineral deposits into bonanzas. Werner Heisenberg develops matrix mechanics and Erwin 1925 Forms the basis of quantum mechanics. Schrödinger invents wave mechanics and the non-relativistic Schrödinger equation for atoms. Waldo Lonsbury Semon invents plasticized polyvinyl chloride (PVC). 1926 Becomes one of the world’s most versatile and widely used construction materials. Paul Merica patents the addition of small amounts of aluminum to 1926 Leads to the commercialization of the jet engine, along with Ni-Cr alloy to create the fi rst “superalloy.” increased effi ciency for modern power turbine machinery. Clinton Davisson and Lester Germer experimentally confi rm the 1927 Provides fundamental work necessary for much of today’s solid- wave nature of the electron. state electronics. Siegfried Junghans perfects a process for the continuous casting of 1927 Provides the basis for commercial exploitation of high-volume nonferrous metal. continuous casting. Arnold Sommerfeld applies quantum statistics to the Drude model of 1927 Supplies a simple model for the behavior of electrons in a crystal electrons in metals and develops the free-electron theory of metals. structure of a metallic solid and contributes to the foundation of solid-state theory. Fritz Pfl eumer patents magnetic tape. 1928 Establishes the technology and leads to many subsequent innovations for data storage. Arne Olander discovers the shape-memory effect in an alloy of gold 1932 Leads to the development of the commercial shape-memory alloys and cadmium. that are employed in medical and other applications. Max Knoll and Ernst Ruska build the fi rst transmission electron 1933 Accesses new length scales and enables improved understanding of microscope. material structure. Egon Orowan, Michael Polyani, and G.I. Taylor, in three independent 1934 Provides critical insight toward developing the modern science of papers, propose that the plastic deformation of ductile materials could solid mechanics. be explained in terms of the theory of dislocations. Wallace Hume Carothers, Julian Hill, and other researchers patent 1935 Greatly reduces the demand for silk and serves as the impetus for the polymer nylon. the rapid development of polymers. Erich Schmid and Walter Boas publish Kristallplastizitaet, which details 1935 Leads to a much better understanding of plastic deformation, a 15 years of research on plastic deformation of metallic single crystals. critical property of metals. Norman de Bruyne develops the composite plastic Gordon-Aerolite, which 1937 Paves the way for the development of fi berglass. consists of high-grade fl ax fi ber bonded together with phenolic resin. André Guinier and G.D. Preston independently report the observation 1937 Leads to the improved understanding of precipitation-hardening of diffuse streaking in age-hardened aluminum-copper alloys. mechanisms. Otto Hahn and Fritz Strassmann fi nd that they can split the nucleus 1939 Establishes nuclear fi ssion and leads to applications in energy and of a uranium atom by bombarding it with neutrons. atomic weapons. Russell Ohl, George Southworth, Jack Scaff, and Henry Theuerer 1939 Provides a necessary precursor to the invention of the transistor discover the existence of p- and n-type regions in silicon. eight years later. Wilhelm Kroll develops an economical process for titanium extraction. 1940 Establishes the primary means of producing the high-purity titanium needed for products ranging from high-performance aircraft to corrosion-resistant reactors. Frank Spedding develops an effi cient process for obtaining high- 1942 Enables the development of the atomic bomb in the Manhattan purity uranium from uranium halides. Project. Great Materials Moment Date Signifi cance Nominees for the Greatest Moments in Materials Science and Engineering (cont.) 2006 November • JOM 55 John Bardeen, Walter H. Brattain, and William Shockley invent 1948 Becomes the building block for all modern electronics and the the transistor. foundation for microchip and computer technology. Bill Pfann invents zone refi ning. 1951 Enables the preparation of high-purity materials, such as the improved semiconductors critical for electronic applications. Nick Holonyak, Jr., develops the fi rst practical visible-spectrum light- 1952 Marks the beginning of the use of III-V alloys in semiconductor emitting diode (LED). devices, including heterojunctions and quantum well heterostructures. S. Donald Stookey discovers a heat-treatment process for transforming 1952 Leads to the introduction of Pyroceram and CorningWare. glass objects into fi ne-grained ceramics. A team in Sweden produces the fi rst artifi cial diamonds by using high 1953 Gives rise to the industrial diamond industry, with applications in heat and pressure. machining, electronics, and a variety of other areas. Gerald Pearson, Daryl Chapin, and Calvin Fuller unveiled the Bell 1954 Serves as the very foundation for solar energy production as well Solar Battery—the world’s fi rst device to successfully convert useful as photo-detector technology. amounts of sunlight directly into electricity. Peter Hirsch and coworkers provide experimental verifi cation by 1956 Not only is dislocation theory verifi ed unequivocally, but the transmission electron microscopy of dislocations in materials. power of transmission electron microscopy in materials research is demonstrated. Jack Kilby integrates capacitors, resistors, diodes, and transistors into 1958 Makes possible microprocessors and, thereby, high-speed, effi cient, a single germanium monolithic integrated circuit or “microchip.” convenient, affordable, and ubiquitous, computing and communications systems. Frank VerSnyder develops the directionally solidifi ed columnar- 1958 Enables performance enhancements for jet engines, saving airlines grained turbine blade. millions of dollars per year in fuel costs alone. Pol Duwez uses rapid cooling to make a gold-silicon alloy that 1959 Represents the fi rst true metallic glass, which has been applied in remains amorphous at room temperature. transformer cores and offers signifi cant potential. Richard Feynman presents “There’s Plenty of Room at the Bottom” 1959 Introduces the concept of nanotechnology (while not naming it as at a meeting of the American Physical Society. such). Arthur Robert von Hippel publishes Molecular Science and 1959 Creates an emerging discipline aimed at designing new materials Molecular Engineering. on the basis of molecular understanding. Stephanie Kwolek invents the high-strength, low-weight plastic 1964 Improves the performance of tires, boat shells, body armor, Kevlar. components for the aerospace industry, and more. Cambridge Instruments introduces a commercialscanning electron 1965 Provides an improved method for the high-resolution imaging of microscope. surfaces at greater magnifi cations and with much greater depth of fi eld than possible with light microscopy. Karl J. Strnat and coworkers discover magneto-crystalline anisotropy 1966 Leads to the fabrication of high-performance permanent magnets in rare-earth cobalt intermetallic compounds. of samarium-cobalt and, later, neodymium-iron-boron for use in electronic devices and other areas. Larry Hench and colleagues develop bioactive glass for orthopedic use. 1969 Changes the paradigm in biomaterials to include interfacial bonding of the implant with host tissues. James Fergason, utilizing the twisted nematic fi eld effect, makes 1970 Completely redefi nes many products and applications, including fi rst operating liquid crystal displays. computer displays, medical and industrial devices, and the vast array of consumer electronics. Bob Maurer, Peter Schultz, and Donald Keck invent low-loss optical 1970 Provides the basis for the increased bandwidth that revolutionized fi ber. telecommunications. Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger announce the 1977 Leads to the development of fl at panel displays using organic light- discovery of electrically conducting organic polymers. emitting diodes, solar panels, and optical amplifi ers. Heinrich Rohrer and Gerd Karl Binnig invent the scanning tunneling 1981 Provides three-dimensional atomic-scale images of metal surfaces microscope. and quickly becomes widely used in research to characterize surface roughness and observe surface defects. Robert Curl, Jr., Richard Smalley, and Harold Walter Kroto discover 1985 Opens the possibility that carbon can assume an almost infi nite that some carbon arranges itself in the form of soccer-ball-shaped number of different structures. molecules with 60 atoms called buckminsterfullerenes or “buckyballs.” Paul Chu creates a superconducting yttrium-barium-copper oxide 1987 Opens the possibility of large-scale application of superconducting ceramic. materials. Don Eigler spells out “IBM” with individual xenon atoms using a 1989 Demonstrates that atoms can be manipulated one by one, the basis scanning tunneling electron microscope. for “bottoms-up” production of nanostructures. Sumio Iijima discovers nanotubes, carbon atoms arranged in tubular 1991 Creates expectations of important structural and nonstructural structures. applications as nanotubes are about 100 times stronger than steel at just a sixth of the weight while also possessing unusual heat and conductivity characteristics. Eli Yablonovich produces “photonic crystals” by drilling holes in a 1991 Forms a basis for the development of “photonic transistors.” crystalline material so that light of a certain wavelength cannot propagate in the material. Great Materials Moment Date Signifi cance Nominees for the Greatest Moments in Materials Science and Engineering
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