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Chapter 1: Matter – Its Properties and Measurement 17 70. (D) We first determine the volume of steel needed. This volume, divided by the cross- sectional area of the bar of steel, gives the length of the steel bar needed. 3 3 1000 gsteel 1 cm steel V = 1.000 kg steel × × = 129.87 cm of steel 1 kg steel 7.70 g steel 2 2 2 23 2 (2.50 in.)s For an equilateral triangle of length s, area = = = 2.706 in. 4 4 volume 129.87 cm 1 in. 1 in. length = = × = 2.93 in. area 2.706 in. 2.54 cm 2.54 cm 3 3 71. (D) Conversion pathway approach: 3 3 3 5280 ft 12 in. 2.54 cm 1 mL 1.03 g NaCl mass 330,000,000 mi 1 mi 1 ft 1 in. 1 cm 1 mL tons105.5 lb 2000 ton1 g 453.6 lb 1 watersea g 0.100 chloride sodium g 5.3 16 Stepwise approach: 3 3 19 3 3 19 3 22 3 3 22 3 24 3 24 3 24 3 5280 ft 330,000,000 mi 4.9 10 ft 1 mi 12 in. 4.9 10 ft 8.4 10 in. 1 ft 2.54 cm 8.4 10 in. 1.4 10 cm 1 in. 1 mL 1.03 g 1.4 10 cm = 1.4 10 g 1 cm 1 mL 24 22 22 20 20 16 3.5 g sodium chloride 1.4 10 g 4.9 10 g NaCl 100.0 g sea water 1 lb 4.9 10 g NaCl 1.1 10 lb 453.6 g 1 ton 1.1 10 lb 5.4 10 tons 2000 lb The answers for the stepwise and conversion pathway approaches differ slightly due to a cumulative rounding error that is present in the stepwise approach. Chapter 1: Matter – Its Properties and Measurement 18 72. (D) First, we find the volume of the wire, then its cross-sectional area, and finally its length. We carry an additional significant figure through the early stages of the calculation to help avoid rounding errors. 3 3 2 2 2 3 2 453.6 g 1 cm V = 1 lb × × = 50.85cm Note: area = r 1 lb 8.92 g 0.05082 in. 2.54 cm area = 3.1416× × = 0.01309cm 2 1 in. volume 50.85 cm 1 m length = = × = 38.8 m area 0.01309 cm 100 cm 73. (M) 5 seawater 1000 g seawater2000 lb Mg 453.6 g Mg 0.001 L V = 1.00×10 ton Mg× × × × 1 ton Mg 1 lb Mg 1.4 g Mg 1.025 g seawater 3 7 31 m 6 10 m seawater 1000 L 74. (D) (a) 2 2 10 ton 1 mi 1 ft 39.37 in. 2000 lb 454 g 1000 mg dustfall 1 mi 1 mo 5280 ft 12 in. 1 m 1 ton 1 lb 1 g 3 2 2 3.5 10 mg 1 month 1 d 5 mg 1m 1mo 30 d 24 h 1m 1h (b) This problem is solved by the conversion factor method, starting with the volume that deposits on each square meter, 1 mm deep. 22 2 2 3 5 1 (1.0 mm 1 m ) 1 cm 100 cm 2 g 1000 mg 1 m h 1 m 10 mm 1 m 1 cm 1 g 4.9 mg 4.1 10 h 5 10 y It would take about half a century to accumulate a depth of 1 mm. 75. (D) (a) 311 22 ft 10 54.1 mi 1 ft 5280 acre 640 mi 1 feet -acre 103.54volume (b) 39 3 311 m 1036.4 cm 100 m 1 in. 1 cm 54.2 ft 1 in. 12 ft 10 1.54 volume (c) gal 1015.1 L3.785 gal 1 m1 L 1000 m 10 4.36 volume 12 3 39
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