Exercício de Química Sintética e Organica Mista (787)

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CHAPTER 5
A-1. (a) 2,4,4-Trimethyl-2-pentene (c) (E)-2,7-Dibromo-3-(2-methylpropyl)-
2-heptene
(b) (E)-3,5-Dimethyl-4-octene (d) 5-Methyl-4-hexen-3-ol
A-2. (a) (c)
(b) (d )
A-3. (a)
(b) Isomer 5 (c) Isomers 1 and 4 (d) Isomers 2 and 3
A-4. Two sp2 C atoms; four sp3 C atoms; three sp2
�
sp3 � bonds
A-5. (a) (c)
(b)
A-6.
A-7. (a)
(b)
(c)
(d) CC(CH3)3H2C
CH3
(X � Cl, Br, I)
(CH3)2CHCHCH(CH3)2
X
� (major)
CH3CH2
CCH2CH2CH3 CHCH2CH3 (major)(CH3)2C�H2C
CH3
(Z )-3-Methyl-3-hexene (E)-3-Methyl-3-hexene
Cl
Cl
OH
1 2 3 4 5 6
OH
4-Methyl-4-penten-2-ol
5-Chloro-2-methyl-1-hexene
Cl
1,6-Dimethylcyclohexene2,3-Dimethyl-2-pentene
782 APPENDIX A