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TECHNICAL ARTICLE—PEER-REVIEWED Fouling and Corrosion in an Aero Gas Turbine Compressor R. K. Mishra Submitted: 7 August 2015 � ASM International 2015 Abstract This paper deals with the study carried out on fouling and corrosion problems in an aero gas turbine engine which operates from coastal environment. Various parameters responsible for such problems are presented in the paper which causes deterioration in performance and leads to failure of the components. Prevention and control procedures for fouling and corrosion are also highlighted. Compressor washes such as performance recovery wash and desalination wash are found to be very effective in addressing these issues. The frequency of compressor wash is to be judiciously worked out from the corrosion rate and performance deterioration points of view. Keywords Corrosion failure analysis � Corrosion fatigue � Environmental degradation � Gas turbine Introduction Many military gas turbines operate from air bases in coastal regions or from offshore platforms even from small islets due to strategic reasons. Also many engines takeoff from unprepared runways and are subjected to arduous environment. The standard atmosphere is composed of a mixture of gases. Although the major constituents are nitrogen and oxygen, there are many other gases such as argon, neon, helium, hydrogen, xenon, carbon dioxide and carbon monoxide, methane, oxides of nitrogen, sulfur etc. are present in dry air. In addition, there is always the presence of salts, contaminants, and humidity in the engine inlet air depending on the local condition of the place where the aircraft or engine is positioned [1]. Their pres- ence in air deteriorates the engine performance due to foreign object damage, erosion, fouling, blockage of cooling passages, particle fusion, and cold and hot corro- sion [1, 2]. Low-pressure compressor (fan) and high- pressure compressor being the front-end components of the engine are affected most due to these elements. Thus, compressor fouling and corrosion have become a serious concern, and its control and prevention are of priority for engine operators. Fouling is the degradation in perfor- mance of a turbine engine due to the build-up of contaminants on the various aerodynamic surfaces [3]. An example of low-pressure compressor fouling is shown in Fig. 1. It results in a drop in airflow and isentropic effi- ciency which in turn reduces the thrust or power output of the engine. Fouling can also cause engine surge or flame blowout due to shifting of operating line toward surge line, flow distortion, and aerodynamic mismatch as shown in Fig. 2 [4, 5]. Investigations have shown that majority of low thrust, low spool speed, and high exhaust gas temperature cases are attributed to compressor fouling. Compressor fouling accounts for about 70–85% of gas turbine engine performance deterioration. Fouling also has a damaging effect on compressor blading which deteriorates the mechanical reliability of the compressor. Compressor fouling also results in a higher turbine entry temperature for a given power setting. This causes higher turbine entry temperature leading to degradation of hot-end components and higher emission levels. The parts of gas turbine engines which are operated in a chemically reactive environment generally suffer from R. K. Mishra (&) Regional Centre for Military Airworthiness (Engines), Bangalore, Karnataka 560093, India e-mail: rkmishra.drdo@gmail.com 123 J Fail. Anal. and Preven. DOI 10.1007/s11668-015-0023-8 corrosion. In gas turbines, there occur two types of corro- sion: cold corrosion and hot corrosion. Cold corrosion occurs in low- and high-pressure compressors which operate relatively at low temperature due to wet deposits of salts, acids, steam, and corrosive gases of various chlorides, sulfides, and oxides. The corrosion causes reduction in the cross-sectional properties of the material and also pitting of the material. Cold corrosion can initiate cracks and met- allurgical abnormalities in the material. The hot corrosion occurs in the hot-end components of the engine which are exposed to high-temperature combustion gases. Rapid chemical reaction takes place between oxygen and the material at high temperatures. Degradation becomes more severe with increasing contaminant concentration and is highly influenced by temperature [6, 7]. The present study will focus on cold corrosion and fouling only. The paper highlights various steps involved in the study for corrosion prevention in a gas turbine compressor. Engine Configuration The present study was carried on a low-bypass turbofan engine with afterburner. It is a twin-spool engine of 40 kN thrust class with multi-stage axial fan and compressor each driven separately by single stage turbines. It has an annular type combustion system incorporating airblast atomizers. Schematic layout of the engine is shown in Fig. 3. The low-pressure (LP) compressor rotor disks are bolted together, each disk having peripheral flanges to which blades are secured by retaining pins. The LP stator vane assemblies are fabricated rings of vanes with inner and outer platforms The high-pressure (HP) compressor com- prises machined disks welded together to form a drum into which rotor blades are keyed. Compressor stator assembly consists of a series of vanes welded on the outer platform to form a ring behind each row of rotor blades in each stage. The low-pressure compressor blades are made of high-duty Al–Cu 2618A alloy, and the vanes are made of 5056 alloy (ASTM B316) which has strong corrosion resistance characteristics. The other modules of the engine are HP nozzle guide vanes and turbine rotor, LP nozzle guide vanes, LP turbine rotor disk, rotor support system, afterburner system, gear box, and accessories. Compressor Fouling Fouling is the build-up of material in cavities and low flow- rate locations along the air flow path as shown in Fig. 1. Besides small particles as a cause for fouling, oil vapors, water, salts, and other sticky substances working individ- ually or together create a mix of materials that find places to adhere. These particles adhere to compressor blade surfaces and turbine blade cooling passages. The effect is to change clearances, disrupt rotating balance, obstruct and plug flow paths, and reduce smoothness of rotating and stationary blade surfaces. Fouling is, however, usually recoverable since there are methods available to remove these deposits with online or offline washing or mechanical Fig. 1 Fouling of a low-pressure compressor in an aero gas turbine engine Fig. 2 Drift in compressor operating point due to fouling Fig. 3 Schematic layout of a twin-spool turbofan engine J Fail. Anal. and Preven. 123 cleaning. The cost of recovery is interrupted process output and sometimes extended shutdown. If recovery by cleaning is not performed, performance suffers. It is possible to recovery the engine’s performance to close to the original performance with regular cleanings. An example of change in engine performance over time is shown in Fig. 4. Researchers have found out several factors that affect compressor fouling. The design philosophy of the com- pressor is itself a major factor that contributes to its fouling. The other factors are loading of the aerofoil, incidence angle of the aerofoil, surface smoothness and nature of coating material, type and condition of airborne pollutants, and operational environment such as humidity. Based on these parameters, an index of sensitivity to fouling (ISF) has been defined by Tarabrin et al. [8, 9]. Fouling iscaused by particles in the range of 2–10 lm. The variation of quantity of those particles present in a local atmosphere has a major impact on the rate of fouling [10, 11]. The deposit of particles on the surface of blades takes plane under the action of inertia forces acting on the par- ticles and forcing them to move along the curved streamline. Particles of dirt that collides with the blade stick to the blade surface. Sticking of dirt increases with the presence of oily substances. Impact of Humidity on Fouling Fouling of engine parts is a result of particles adhering to water and oil when present on surfaces. Total humidity is directly related to the partial pressure of water vapor in the surrounding atmosphere. Generally water is present in the incoming air due to the pressure drop experienced at the engine inlet. The rate of fouling is a strong function of total humidity. As humidity increases, particles will adhere to the surface, and the performance of the engine deteriorates [12]. But at high humidity, some amount of the water present will flow off the aerodynamic surfaces rather than adhering to the surface. This will result in somewhat cleaning of the surface. The particulates will be washed away thus reducing the fouling rate. The inlet pressure drop leading to droplet formation varies from aircraft to aircraft and greatly depends on the operating environment as well as the engine-air intake characteristics. Erosion Hard particles 5–10 lm or larger create erosion of the metal surfaces bounding the air flow path. Figure 5 com- pares the particle size range for erosion with fouling [13]. Sand is one of the most common causes of erosion due to its prevalence at the installations of gas turbine. Impingement of small, hard particles against blade and stator aerodynamic airfoil shapes repeatedly removes tiny particles of metal, eventually re-shaping portions of the parts. In finely tuned contours of highly stressed parts, this is a double problem. Re-shaping aerodynamic surfaces changes the air flow paths, roughens the surfaces, changes clearances, and eventually reduces the cross-sectional areas that provide the strength necessary to resist the very high stresses of parts with minimal margins of safety. Also, changing the blade shape can create stress concentrations. This in turn reduces the fatigue strength and can lead to high cycle fatigue failures. The efficiency of the gas turbine is reduced until excessive stress takes over as the main cause of problem. Contaminants A contaminant consists of any substance which is entrained in the air flow path in gas turbine engine. A wide range of substances such as solid particles, gases, and liquids such Fig. 5 Typical atmospheric dust distribution Fig. 4 Deterioration of engine performance and its recovery through cleaning J Fail. Anal. and Preven. 123 as sea salts, dust, sand, exhaust fumes containing oil and fuel vapors, particles such as chemicals, fertilizers, mineral ores, and industrial by-products. The presence of contam- inants in the environment greatly depends on the location where it is operated and also on the local activities. They are also dependant on climatic conditions such as wind direction, wind speed, temperature, relative humidity, and precipitation which are constantly changing [10, 12]. Some common contaminants and their typical size are presented in Table 1. Generally inlet air filtration is widely used for land based gas turbine engines to prevent perfor- mance degradation and to prevent unscheduled maintenance. Ground test beds are also equipped with suitable filtrations for testing aero gas turbine engines. Performance Recovery Wash Compressor fouling is generally addressed by carrying out periodic compressor wash. These performance recovery wash uses approved chemical additives to remove deposits on airflow passages and blade surfaces. Compressor washing can be accomplished both online and offline [14]. On-line cleaning can be performed in a compressor wash rig as shown schematically in Fig. 6 with minimal effects and can cause rapid improvement in a heavily fouled compressor. Prior to performing a compressor cleaning, care should be taken not to disturb the critical speeds of rotors or natural frequencies of the blades. Engine is allowed for minimum 45 min to cool down to below 65 �C prior to activate compressor wash system. Depending on the ambient temperature, the cleaning solution tank is filled with appropriate cleaning solution as given in Table 2. The rinse solution tank is filled with normal drinking quality water for ambient temperature above ?2 �C and with water and isopropyl alcohol in equal volumetric proportion for ambient temperature from ?2 to �25 �C. Compressed air supply is connected to the wash tanks. The cleaning solutions are injected into the engine while motoring the engine at 5% rotor speed for 30 s. Cleaning solution is allowed to soak for 20–30 min. Then the rinse solution is injected for 30 s for 2–3 times till the wash fluid comes out through the exhaust drain valve. Subsequently, the engine is run to an intermediate power rating for one to two minutes for drying the engine. The compressor wash has been found to be very effective to remove flow paths and blade surfaces and to regain engine performance. The frequency of compressor wash is decided based on the environmental conditions that the engine is subjected to. But it is generally carried out on engines once in every 25–35 flight hours. As it is not possible to com- pletely remove the water particles and deposits from various ports and internal passages, the compressor mod- ules are dismantled after 100–125 flight hours to physically clean them for better service life. Corrosion Axial compressors suffer aqueous corrosion due to for- mation of aggressive acids. The presence of airborne salts and acids of sulfur and nitrogen make the environment corrosive for compressor material. This generally occurs during the coastal, marine, or offshore operation of the engine. The main difference between the operations in these areas is the high salt concentration in the atmosphere compared to that in land based operation. The high con- centration of salt in the atmosphere can also lead to fouling as explained earlier sections. Coastal areas refer to the land region within 15 km of the shoreline. Operation of gas turbines within coastal area presents a major challenge of higher salt concentrations and humidity compared to land based application. Fig. 6 Schematic of compressor wash rig Table 1 Common contaminants Grade Contaminants Coarse[10 lm Leaves, insects, textile fibers, sand, flying ash, mist, rain, pollen and fog Fine[1 lm Spore, cement dust, dust sediments, cloud, fog, accumulated carbon black, metal oxide smoke, oil smoke EPA[0.01 lm Metal oxide smoke, carbon black, smog, mist, fumes, oil smoke, aerosol micro particles J Fail. Anal. and Preven. 123 The salt present in the ambient air is derived from seawater aerosols carried by the wind. Depending on the relative humidity, the salt particles may be present in aerosols, in the sticky state, or as dry particles. The humidity will also have an effect on the size of the salt particles or aerosols. Relative humidity lower than 50% can cause salt particles to reduce in size below 1 lm. The salt concentration present in the air from the seawater is the highest at the shore and falls rapidly until approximately 15 km off the shoreline. However, the concentration can vary significantly depending on the wind speed, direction, elevation, and topography. Aero gas turbines operated from ship decksor offshore platforms or from small islets face similar problems. The corrosion on air intake fairings and measurement probes are shown in Fig. 7 for the aero gas turbine engine under study which is stationed and operated from a coastal region. Air flow passages in the internal cooling air flow path are also seen affected by corrosion. In a marine environment, the gas turbines are installed on ships. The inlet to the engine turbines is typically within 30 m from the ocean surface. However, in offshore appli- cations, the gas turbine engine inlets are positioned above 30 m from the ocean surface. The primary contaminants in these cases are salt and seawater. Salt is generated naturally and is always present in the wet form due to the closeness of the gas turbine inlet to the ocean surface. The height, orientation, and location of the engine inlet control the size and quantity of salt at the inlet. The distance of the inlet from the ocean surface significantly affects the amount of sea water and salt aerosols. Concentration of salt decreases as the height of engine inlet increases above the ocean surface. The particle size also decreases with height. In all such cases, the presence and amount of corrosive species, moisture levels, and materials of engine compo- nents determine the amounts and rates of corrosion. The inlet stages of the compressor are the most susceptible to corrosion damage during normal operation of the com- pressor. The first few sages of the compressor are the most susceptible to corrosive attack. These stages generally operate at subatmoshperic pressure, and the water vapor in the air condenses into water droplets that readily combine with the other airborne contaminants. Toward the rear end of the compressor, the compressed air and water droplets increase in the both temperature and pressure. Thus, the liquid water comes back into a gaseous state thereby reducing the corrosion potential. The compressor fouling aggravates the corrosion by allowing the water droplets to form or agglomerate in the flow path. The flow path deposits tend to hold the acidic conditions on the surface of the compressor blades and vanes. Corrosion pitting on airflow paths caused by salt deposits can be seen in Fig. 8. Pitting corrosion is very significant in industrial axial flow compressors as well as in aero engines operating at sandy atmosphere. The pits are often the crack initiator in blade fatigue failures. Salt deposits and pitting corrosion marks on blade sur- face are presented in Figs. 9 and 10, respectively. Pitting in many materials can lead to failure by corrosion occurring in localized areas. Fig. 7 Corrosion seen on air intake fairing and pressure probe Table 2 Formulation of cleaning solution (by % volume) Ambient temperature Cleaning agent Aviation kerosene Isopropyl alcohol Water Cleaning agent: Magnus 1214, R-MC-G21, TURCO-5884 etc. [2 �C 25 0 0 75 �25 to 2 �C 25 15 20 40 \25 �C 25 15 40 20 Cleaning agent: Ardrox-6367, Turboclean-2, ZOK-27 etc. [5 �C 20 0 0 80 �5 to ?5 �C 20 0 20 60 �21 to �5 �C 20 0 30 50 \21 �C 20 0 40 40 J Fail. Anal. and Preven. 123 The cause of this local corrosion is related to material build ups on the surface of the material. The area in or immediately under the deposit can form a local environ- ment that is oxygen deprived. Oxygen on the metal surface is required to maintain the corrosion resistant surface film. In addition, the localized corrosion can be further accel- erated by the creation of aggressive acids. The damage shown in Figs. 7, 8, 9, and 10 can result in mechanical failure of the component if allowed for prolong period or preventive measure is not initiated. Corrosion Prevention & Control A number of steps are generally considered at design stage to prevent the compressor from corrosion [15, 16]. Such steps include • Selection of suitable materials • Adaption of appropriate heat treatment process of the material • Use of corrosion resistant coatings In spite of the best design practices, compressor corrosion is often unavoidable due to its operational environments. In such case, controlling the corrosion level by cleaning is left the only choice. Desalination Wash Compressor wash at scheduled intervals has been found very effective in controlling the compressor corrosion. Flow path wash removes many of the deposits through either a liquid wash dissolving the deposit or an abrasive scrubbing of the deposits off the blade surfaces. The two most commonly used methods of cleaning the compressor are a liquid wash often referred to as water wash and an abrasive cleaning [17]. Compressor desalination wash is a recommended prac- tice worldwide adopted by aero engine operators. Compressor wash is done by injecting applicable cleaning fluid into the engine intake using either an installed com- pressor wash ring or a hand held wash wand. Water-based non-flammable non-toxic and readily biodegradable blend surfactants and inhibitors are commonly used as com- pressor cleaning agents [16]. These agents will have no harmful effect on the compressor material. The cleaning fluid formulation for few cleaning agents is presented in Table 2. The solutions generally have specific gravity of about 1.0 and pH value of 7.2–7.6. Alternatively, a motoring wash can also be done at 10– 25% of high-pressure spool speed, and the water or the cleaning mixture, depending on ambient temperature, is injected into the engine intake at a rate of 7.5–11.5 L/min depending on the engine configuration. Fig. 8 Pitting corrosion in compressor air flow passages Fig. 9 Deposit of corrosive salts on compressor blade surface Fig. 10 Corrosion pitting on compressor blade surface J Fail. Anal. and Preven. 123 Normal drinking quality water or demineralized water is commonly used as the wash fluid for motoring wash pro- cedure. Although the quality of water varies according to location and season, it should meet the following minimum standards: (a) Appearance: free of visible extraneous impurities (b) Total solids: 175 ppm (mg/L) max (c) pH value: 6.0–8.0 inclusive (d) Chlorides: 15 ppm (mg/l) max (e) Sulfates: 10 ppm (mg/L) max Compressor washing is most effective if it is performed on a regular basis. The recommended wash schedule is presented in Table 3. However, the frequency of wash is decided based on the operational environment and the rate of corrosion experienced at a particular location. Abrasive compressor cleaning is accomplished by injecting an abrasive media into the compressor inlet during normal operation. Walnut shells, rice, fluid catalytic cracking (FCC) catalyst, glass beads, and other media have been utilized. The size and quantity of the cleaner are important for obtaining a good flow path cleaning and not causing damage to the compressor flow path components. Aggressive abrasive cleaning can readily cause erosion damage to both the corrosion resistant coatings and the compressor airfoils. In the present study, 10 aero engines were monitored on daily basis for 15 days in an air base at a coastal location. The exercise was started from the day of after the desali- nation wash of the compressors. Whitish-color salt deposits and carbon deposits were noticed on LP compressor rotor blade surfaces. Leading edge of the stage 1 blades was also observed with minor salt deposits. Mild corrosion noticed on some of the bolt heads. No corrosion marks noticed on the rotor flow path area and air intake fairing. The quantity of salt deposits found to increase up to day 3 or day 4. After that, the progressive daily variation of salt deposits and corrosionmarks on the blades and rotor path areas were found to be negligible. Also no additional area was affected by corrosion in subsequent days. It was observed that the engines which have logged less service hours or consumed less calendar life are less prone to corrosion than the old engines with less life left. Further, it was observed that the components of the engines or aircrafts which are parked inside the hangar shed with intake and exhaust blanked are less prone to corrosion than those parked outside. The engines engaged in night flight were found to be less prone to salt deposits and corrosion. The problem of corrosion was found to be more serious during rainy days. Occasional operation from offshore platforms showed a steep rise in salt deposits and corrosion spreading to larger areas in LP compressor. These observations have helped in defining the fre- quency for desalination wash without sacrificing the life and performance of the engines and at the same time avoiding over-maintenance. Adopting compressor wash at suitable intervals using R-MC-G21 cleaning agent, the corrosion has been prevented to a large extent. Figures 11 and 12 show almost corrosion-free low compressor pas- sages and blades which have been significantly improved compared to that in Figs. 7 and 8. Compressor-turbine desalination wash is also strongly recommended when operating in salt laden atmosphere. When desalination washes are done in conjunction with each other it is essential that the compressor wash is done first. Fig. 11 State of air intake fairing with scheduled compressor wash Table 3 Compressor wash schedule Environment Type of wash Frequency Continuously salt laden Desalination wash Daily. After last flight of day Frequently salt laden Desalination wash Weekly. To suit engine condition Occasionally salt laden Desalination wash Bi-weekly. To suit engine condition All Performance recovery wash Generally at every 30 ± 5 h but based on engine operating conditions. Motoring wash is recommended J Fail. Anal. and Preven. 123 Blade Coatings Application of coatings to rotating and stationary parts has also become a common practice in gas turbine industries. These coatings enhance the performance by improving the resistance to corrosive environments, minimizing the rate of solid particle and liquid droplet erosion, improving the foulant release ability of the component and minimizing fretting between two components. Diffused aluminide, aluminum- ceramic, and titanium-nitride coatings have been found to provide good corrosion protection for both high salt and acidic environments [18–20]. Care should be taken to maintain the coating for a specified life. But if the coating is lost during service exploitationordue to handling errors, the exposed area will suffer pitting corrosion as shown in Fig. 13. Since frequent compressor wash increases the down- time of engines as well as an increase in the maintenance overheads, their frequency should be judiciously selected. Apart from the desalination wash schedule, the compressor modules are also dismantled from the engine, and thorough desalination process is performed. This 2nd level corrosion prevention procedure is followed in every 6–9 months of time or after every 100–125 flight hours. Conclusion Fouling and corrosion are serious concerns in an aero gas turbine compressor. This paper summarized the review of compressor fouling and corrosion problems and practices followed in gas turbine engines. Further, it presents the results of comprehensive corrosion studies carried out in ten aero gas turbine axial flow compressors. The following conclusions can be made on the basis of the studies: • The local environment where the aero engine is stationed or operated can cause very corrosive envi- ronments in the compressor. Salts and sulfur in the air are the primary cause for the formation of corrosive deposits. • Surface corrosion often occurs on the flow path of compressors, also on the cooling air passages. • Compressor blading is the most affected by corrosion pitting and can cause engine performance deterioration. • The inlet stages of the compressors are the most susceptible to in-service corrosion. • Salt and carbon deposits were noticed on LP compres- sor rotor blade surfaces. But progressive daily variation of salt deposits and corrosion marks on the blades and rotor path areas can be maintained minimum with frequent compressor desalination wash. • Engines which have logged less service hours or consumed less calendar life are less prone to corrosion than the old engines with less life left. • The components of the engines or aircraftswhich are parked inside the hangar shed with intake and exhaust blanked are less prone to corrosion than those parked outside. • The engines engaged in night flight were found to be less prone to salt deposits and corrosion. • A comprehensive corrosion control program should be adopted to minimize the corrosion. • Online water/detergent washing of the compressor at suitable frequency will help in controlling corrosion. • Appropriate metallurgy and coatings should be consid- ered for engine front-end components [18–20]. References 1. S.O.T. 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Anal. and Preven. 123 Fouling and Corrosion in an Aero Gas Turbine Compressor Abstract Introduction Engine Configuration Compressor Fouling Impact of Humidity on Fouling Erosion Contaminants Performance Recovery Wash Corrosion Corrosion Prevention & Control Desalination Wash Blade Coatings Conclusion References
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