Baixe o app para aproveitar ainda mais
Prévia do material em texto
CHAPTER 4 GEOMETRY 74 4.1 Orbitals and Hybridization States 74 4.2 Geometry 78 4.3 Lone Pairs 81 CHAPTER 5 NOMENCLATURE 83 5.1 Functional Group 84 5.2 Unsaturation 86 5.3 Naming the Parent Chain 88 5.4 Naming Substituents 90 5.5 Stereoisomerism 94 5.6 Numbering 97 5.7 Common Names 102 5.8 Going from a Name to a Structure 103 CHAPTER 6 CONFORMATIONS 104 6.1 How to Draw a Newman Projection 105 6.2 Ranking the Stability of Newman Projections 109 6.3 Drawing Chair Conformations 113 6.4 Placing Groups on the Chair 116 6.5 Ring Flipping 121 6.6 Comparing the Stability of Chairs 127 6.7 Don’t Be Confused by the Nomenclature 131 CHAPTER 7 CONFIGURATIONS 132 7.1 Locating Stereocenters 133 7.2 Determining the Configuration of a Stereocenter 136 7.3 Nomenclature 144 7.4 Drawing Enantiomers 149 7.5 Diastereomers 154 7.6 Meso Compounds 155 7.7 Drawing Fischer Projections 158 7.8 Optical Activity 163 CHAPTER 8 MECHANISMS 165 8.1 Curved Arrows 166 8.2 Arrow Pushing 171 8.3 Drawing Intermediates 173 viii CONTENTS
Compartilhar