P1 cinetica 23 1 - Soraia e Vitória

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Questão 2
		Tempo( h)	MEAD(mol/L)		Ordem 0								Ordem 1								Ordem 2
		0	4.28		Tempo(h)	CA(mol/L)							Tempo( h)	ln( CA0/CA)							Tempo( h)	(1/CA)
		4	4.1		0	4.28							0	0							0	0.2336448598
		6	4.1		4	4.1							4	0.0429660359							4	0.243902439
		10	3.8		6	4.1							6	0.0429660359							6	0.243902439
		18	3.52		10	3.8							10	0.1189519429							10	0.2631578947
		24	3.3		18	3.52							18	0.19549202							18	0.2840909091
		30	3.03		24	3.3							24	0.2600305411							24	0.303030303
		34	2.92		30	3.03							30	0.3453903901							30	0.3300330033
		44	2.65		34	2.92							34	0.3823693933							34	0.3424657534
		48	2.5		44	2.65							44	0.4793933696							44	0.3773584906
		54	2.45		48	2.5							48	0.5376622777							48	0.4
		58	2.35		54	2.45							54	0.557864985							54	0.4081632653
		64	2.2		58	2.35							58	0.5995376814							58	0.4255319149
		72	2.1		64	2.2							64	0.6654956492							64	0.4545454545
		100	1.65		72	2.1							72	0.7120156649							72	0.4761904762
		120	1.41		100	1.65							100	0.9531777217							100	0.6060606061
					120	1.41							120	1.1103633052							120	0.7092198582
					 = -kt								 = -kt								 = -kt
Ordem 0
0	4	6	10	18	24	30	34	44	48	54	58	64	72	100	120	4.28	4.0999999999999996	4.0999999999999996	3.8	3.52	3.3	3.03	2.92	2.65	2.5	2.4500000000000002	2.35	2.2000000000000002	2.1	1.65	1.41	Tempo (s)
Concentração (mol/L)
Reação de Ordem 1
0	4	6	10	18	24	30	34	44	48	54	58	64	72	100	120	0	4.2966035883443554E-2	4.2966035883443554E-2	0.11895194286136548	0.19549201998369981	0.260030541121271	0.34539039007242778	0.3823693933135151	0.47939336959557466	0.53766227771955044	0.55786498503706983	0.59953768143763786	0.66549564922943516	0.71201566486432799	0.95317772168121628	1.1103633052036286	Tempo (s)
CA0/CA
Ordem 2
Ordem 2 (1/CA)	
0	4	6	10	18	24	30	34	44	48	54	58	64	72	100	120	0.23364485981308411	0.24390243902439027	0.24390243902439027	0.26315789473684209	0.28409090909090912	0.30303030303030304	0.33003300330033003	0.34246575342465752	0.37735849056603776	0.4	0.4081632653061224	0.42553191489361702	0.45454545454545453	0.47619047619047616	0.60606060606060608	0.70921985815602839	Tempo (s)
1/CA
 Questão 3a
		Tempo(h)	Butanol(M)		Ordem 0						Ordem 0,5
		0	1		Tempo( h)	CA(mol/L)					Tempo( h)	CA1/2
		0.25	0.94		0	1					0	1
		0.5	0.9		0.25	0.94					0.25	0.9695359715
		0.7	0.86		0.5	0.9					0.5	0.9486832981
		1.1	0.8		0.7	0.86					0.7	0.9273618495
		1.5	0.72		1.1	0.8					1.1	0.894427191
		1.9	0.66		1.5	0.72					1.5	0.8485281374
		2.5	0.59		1.9	0.66					1.9	0.8124038405
		3	0.55		2.5	0.59					2.5	0.7681145748
		4	0.43		3	0.55					3	0.7416198487
		5.1	0.35		4	0.43					4	0.6557438524
		6	0.28		5.1	0.35					5.1	0.5916079783
					6	0.28					6	0.5291502622
					 = -kt						 = -kt
					Ordem 1						Ordem 2
					Tempo( min)	ln( CA0/CA)					Tempo( h)	(1/CA)
					0	0					0	1
					0.25	0.0618754037					0.25	1.0638297872
					0.5	0.1053605157					0.5	1.1111111111
					0.7	0.1508228897					0.7	1.1627906977
					1.1	0.2231435513					1.1	1.25
					1.5	0.328504067					1.5	1.3888888889
					1.9	0.415515444					1.9	1.5151515152
					2.5	0.5276327421					2.5	1.6949152542
					3	0.5978370008					3	1.8181818182
					4	0.8439700703					4	2.3255813953
					5.1	1.0498221245					5.1	2.8571428571
					6	1.2729656758					6	3.5714285714
					 = -kt						 = -kt
Ordem 0 
Ordem 0 CA(mol/L)	
0	0,25	0,5	0,7	1,1	1,5	1,9	2,5	3	4	5,1	6	 = -kt	1	0.94	0.9	0.86	0.8	0.72	0.66	0.59	0.55000000000000004	0.43	0.35	0.28000000000000003	Tempo (s)
CA (mol/L)
Ordem 0,5
Ordem 0,5 CA1/2	
0	0.25	0.5	0.7	1.1000000000000001	1.5	1.9	2.5	3	4	5.0999999999999996	6	1	0.96953597148326576	0.94868329805051377	0.92736184954957035	0.89442719099991586	0.84852813742385702	0.81240384046359604	0.76811457478686085	0.74161984870956632	0.65574385243020006	0.59160797830996159	0.52915026221291817	
Ordem 1 ln( CA0/CA)	
0	0.25	0.5	0.7	1.1000000000000001	1.5	1.9	2.5	3	4	5.0999999999999996	6	0	6.1875403718087453E-2	0.10536051565782635	0.15082288973458369	0.22314355131420976	0.32850406697203605	0.41551544396166579	0.52763274208237199	0.59783700075562041	0.84397007029452897	1.0498221244986776	1.2729656758128873	Tempo (s)
ln (CA0/CA)
Ordem 2
Ordem 2 (1/CA)	
0	0.25	0.5	0.7	1.1000000000000001	1.5	1.9	2.5	3	4	5.0999999999999996	6	1	1.0638297872340425	1.1111111111111112	1.1627906976744187	1.25	1.3888888888888888	1.5151515151515151	1.6949152542372883	1.8181818181818181	2.3255813953488373	2.8571428571428572	3.5714285714285712	Tempo (s)
1/CA
Questão 3b
		Temperatura(ºC)	Temperatura K	K	1/T	ln K 
		51	324	0.0088	0.0030864198	-4.7330035575
		56	329	0.0167	0.0030395137	-4.0923465596
		66	339	0.09	0.0029498525	-2.4079456087
		71	344	0.2153	0.0029069767	-1.5357228746
		78	351	0.4356	0.0028490028	-0.8310308879
ln K 	
3.0864197530864196E-3	3.0395136778	115501E-3	2.9498525073746312E-3	2.9069767441860465E-3	2.8490028490028491E-3	-4.7330035574979759	-4.0923465595594273	-2.4079456086518722	-1.5357228746118197	-0.83103088792333168	1/T
ln K