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218 7 QUANTUM THEORY (i) P = 0.10 W N = (0.10 W) × (1 s)(700 × 10−9 m) (6.6261 × 10−34 J s) × (2.9979 × 108ms−1) = 3.52 × 1017 (ii) P = 1.0 W N = (1.0 W) × (1 s)(700 × 10−9 m) (6.6261 × 10−34 J s) × (2.9979 × 108ms−1) = 3.52 × 1018 E7A.8(b) As described in Section 7A.2 on page 242, photoejection can only occur if the energy of the incident photon is greater than or equal to the work function of the metal ϕ. If this condition is ful�lled, the energy of the emitted photon is given by [7A.10–243], Ek = hν−Φ = hc/λ−Φ. To convert the work function to Joules, multiply through by the elementary charge, as described in Section 7A.2 on page 242, Φ = 2.09 eV × e = 2.09 eV × 1.602 × 10−19 J eV−1 = 3.35... × 10−19 J and since Ek = 1/2meυ2, υ = √ 2Ek/me (i) For λ = 650 nm Ephoton = hc λ = (6.6261 × 10−34 J s) × (2.9979 × 108ms−1) 650 × 10−9 m = 3.06... × 10−19 J �is is less than the threshold energy, hence no electron ejection occurs. (ii) For λ = 195 nm Ephoton = (6.6261 × 10−34 J s) × (2.9979 × 108ms−1) 195 × 10−9 m = 1.02... × 10−18 J �is is greater than the the threshold frequency, and so photoejection can occur, leading to a kinetic energy of Ek = hc/λ −Φ = 1.02... × 10−18 J − 3.35... × 10−19 J = 6.84 × 10−19 J υ = √ 2 × (6.84 × 10−19 J)/(9.109 × 10−31 kg) = 1.23 Mms−1 E7A.9(b) If the power, P, is constant, the total energy emitted in time ∆t is P∆t. �e energy of each emitted photon is Ephoton = hν = hc/λ. �e total number of photons emitted in this time period is therefore the total energy emitted divided by the energy per photon N = P∆t/Ephoton = P∆tλ/hc