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A review on technological opt ions of w aste to energy for effect ive m anagem ent of m unicipal solid w aste Atu l Kum ar, S.R. Sam adder ⇑ Department of Environmental Science & Engineering, Indian Institute of Technology (Indian School of Mines), Dhanba d 826004, India a r t i c l e i n f o Article history: Received 21 April 2017 Revised 25 August 2017 Accepted 26 August 2017 Available on line xxxx Keywords: Municipal solid waste managem ent Waste to energy Waste to energy techn ologies Developing countries Developed countries Review a b s t r a c t Approxim ate ly one-fourth popu lat ion across the w orld rely on t rad itional fuels (kerosene, nat ural gas, biom ass residue, firewood, coal, an im al dung, etc.) for dom estic use despite sign ifican t socioecon om ic and technological developm ent. Fossil fuel reserves are being exploited at a very fast rate to m eet the increasing energy dem ands, so there is a need to find alternat ive sources of energy before a ll the fossil fuel reserves are dep leted. Waste to energy (WTE) can be considered as a poten tial alterna tive source of energy, w hich is econom ically viable and environm enta lly susta inable. The present study reviewed the curren t global scenario of WTE technological op tions (incineration , pyrolysis, gasificat ion , anaerobic digestion, and landfilling w ith gas recovery) for effect ive energy recovery and the challenges faced by developed and developing coun tries. Th is review will provide a fram ework for evaluat ing WTE techn o- logical op tions based on case stud ies of developed and develop ing coun tries. Unsanitary landfilling is the m ost com m only pract iced waste disposal op tion in the developing countries. How ever, developed coun tries have realised the potent ial of WTE technologies for effective m unicipal solid w aste manage- m ent (MSWM). This review w ill help the policy m akers and the im plem ent ing authorities involved in MSWM to understand t he curren t sta tus, challenges and barriers for effective m anagem ent of m unicipal solid w ast e. This review concluded WTE as a potential r enewable source of energy, which w ill partly m eet the energy dem and and ensure effect ive MSWM. Ó 2017 Elsevier Ltd. All righ ts reserved. Content s 1. In t roduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 1.1. Presen t scenario of waste to en ergy at global level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 1.2. Need of waste to energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 2. Waste generation, characterist ics and composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 3. Heat ing values of m unicipal solid waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4. Waste to energy options . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.1. Therm al conversion technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.1.1. Incinerat ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.1.2. Pyrolysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.1.3. Gasificat ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.2. Biological conversion t echnology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.2.1. Anaerobic d igestion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.3. Landfilling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 4.3.1. Modelling landfill gas generation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 5. Energy recovery potential and econom ics of WTE technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 6. Environm ental and health im pacts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 7. Im pact on climate change . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 http ://dx.doi.org/10.1016/j.w asman.2017.08.046 0956-053X/Ó 2017 Elsevier Ltd . All right s reserved. ⇑ Corresponding author. E-mail address: sukh_sam adder@yahoo.co.in (S.R. Samadder). Waste Managem ent xxx (2017) xxx–xxx Contents lists available at ScienceDirect Waste Managem ent j o u r n al h o m ep ag e: w w w .el sev i er .co m / l o cat e /w asm an Please cite this article in press as: Kum ar, A., Sam adder, S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 8 . Conclusions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 Acknow ledgem ents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 00 1. Int roduct ion Curren t ly fossil fue ls are the m ost reliable sources of energy, m eet ing alm ost 84% of the global energy dem and (Shafiee and Topal, 2009). It is t he tim e t o rea lise the poten tial of w aste t o energy (WTE) as an opt ion for susta inable solid w aste m anagem en t and as one of the m ost significant fu tu re renew able energy sources, wh ich is econom ically viable and environm entally susta inable (Bajic´ et a l., 2015; Kalyani and Pandey, 2014; Steh lik, 2009). Ali et al. (2012) concluded that WTE is not on ly sustainab le w aste m anagem ent solu t ion, bu t a lso an economica lly feasible, especially for developed coun tries. Baran et a l. (2016) reported t hat ene rgy recovery from wast e incinerat ion (one of the WTEtechnologies) is an in tegral part of environm entally sust ainab le w aste m anage- m ent st rategy. However, Yay (2015) d id not find incinerat ion as al- ways econom ically sustainable due to it s h igh operational and m ain tenance cost . WTE is a w ay to recover the energy from w aste m ate rials in the form of useable heat , elect ricity (by passing gas or steam through tu rbine ), or fuel (Zhao et al., 2016). WTE technolo- gies are now con sidered as the m ost su itable opt ions for solving the w aste re lated problem s. Th is paper aim s to invest igate m un icipal solid w aste (MSW) as a poten tial renew ab le energy source. The present paper review ed the available literat ures on curren t global scenar io of WTE tech- nologies, necessary requ irem en ts for effect ive energy recovery and environm ental im pacts of differen t w aste d isposal techn iques. The WTE technologies adop ted in developed coun tr ies have been assessed to iden tify the challenges and barr iers for effect ive im ple- m entation of WTE technologies in developing coun tr ies. In th is review , 155 article s published in repu ted jou rnals, techn ica l reports, and books related to WTE technologies (from year 1995 to 2017) w ere selected . More than 70% of the select ed refe rences were from year 2010 to 2017. For perform ing the review , a system - atic approach w as follow ed in which d ifferent aspects of WTE w ere ident ified. The ident ified aspects are: (i) the p resen t status of WTE at global level, (ii) need of WTE, (iii) generat ion, characteristics and com posit ional requirem ents for effect ive energy recovery, (iv) WTE technologica l opt ions and ch allenges associat ed w it h them in developed and develop ing countrie s, and (v) environm en tal and health im pacts of WTE facilities. The previously published litera- tu res and report s were selected and cat egorised based on these iden t ified aspects. Th is st udy will p rovide a source of scientific in form at ion and analysed gap in the field of WTE t o the scientific au dience and wast e m anagem ent planners. Global u rban popu la tion is increasing at a fast rate (1.5%) than that of the total popu lation (Ouda et al., 2016). At p resen t, m ore than half of the w orld populat ion live in u rban areas, so the global esca lat ion of MSW generation is m ainly due to the population grow th , urbanisat ion and econom ic deve lopm en t (Kum ar and Sam adder (in press)). Presen tly, the per capita MSW generation rate in developed coun tries is m ore t han that of the developing coun tr ies, because gen erat ion rate depends on econom ic and social p rosperit y of a country. It w as estim at ed that in com ing decades the developing countries of Asia and other parts of the w orld w ill m at ch the MSW generation rate of developed coun tries (Fazeli et al., 2016). Slow ly, the peop le of deve loping count rie s are adap t- ing life st yle of deve loped nat ions due t o globa lisation , resu lt ing in genera tion of large quant it ies of w ast es. Thus, the escalat ion in MSW generat ion rate is m ain ly due to changing food habits, con- sum pt ion pat tern and living standards of the urban population (Khan et al., 2016). Many researchers have reported t hat recycling is m ore pre- fe rred opt ion than energy recovery (Tan et al., 2014; Ouda et al., 2016). It w as observed from previous findings that the coun tries, w hich exercised h igh rate of energy recovery from w astes had appreciable rates of recycling, whereas, for the develop ing coun- t ries w here landfilling is t he m ost prevalen t wast e m anagement option , recycling rat es w ere low (Achillas et al., 2011). Arafat et al. (2015) reported the average recoverable energy con ten ts (in t erm s of electrical energy efficiency) for different com ponen ts of MSW using different WTE technologies (Fig. 1). From Fig. 1, it is eviden t that , anaerobic digest ion is the best su ited WTE option for food and yard wastes, w hereas, gasificat ion is the best WTE option for t rea ting plast ic wast es. Incinerat ion rem ains an at t rac- t ive opt ion am ongst all the w aste st ream s (as specified by Arafat et al., 2015), as it can be used for en ergy recovery from all t he 0 500 1000 1500 2000 2500 3000 Paper Plastic Textile Food waste Yard waste Wood En er gy (k ca l/k g) Incineration Anaerobic Digestion Gasification Fig. 1. Energy recovery potential of d ifferen t WTE technologies for d ifferen t MSW stream. 2 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 reported w aste st ream s. How ever, othe r types of w astes such as inert , m et als, glass, etc., w ere not considered in that st udy. A m ajor challenge, h ow ever, rem ains in iden t ifying better WTE technologies. There are som e social opposit ions for deve lopm en t of the WTE facilit ies due to potent ially toxic em issions (Zhao et a l., 2016). On the other han d, some characte ristics of WTE facilitie s are also not favourable, such as high cost s and difficult ies in arranging fund (Zhang e t a l., 2010). How ever, one of the m ajor problem s of WTE facilit ies is the protest s from local comm unitie s, especially in developing coun tries w ith h igh popu lat ion densit y (Ren et al., 2016; Kalyan i and Pandey, 2014). Thus, for successfu l im plem en tat ion of any WTE facility, it s accep tance by the local com m unity is im portant (Kikuch i and Gerardo, 2009). Developed count ries have realised the poten t ial of WTE opt ions and have started implem ent ing it for e ffect ive w aste m anagem en t successfully. 1.1. Present scenario of waste to energy a t global level The w orld popu lat ion w as 3 b illion in 1960, w hich has increased to 7 b illion in 2011 and it is expected to reach 8.1 billion by 2025 (FAO, 2013). The dram atic increase in global popu lat ion coupled w ith econom ic developm en t had led to rapid u rbanisat ion and industrialisat ion , w h ich changed the consum pt ion pat tern of the populat ion that ult im a tely lead to the proliferation of MSW at an alarming rate . Many countr ies star ted adopt ing the WTE technologies for effect ive m anagem en t of huge quan t ity of w aste to produce energy. An estim ate by t he In te rnat ional Renewable Energy Agency, show ed tha t the w orld has a potent ial of generat - ing approxim ately 13 Giga Watt of energy from WTE sector alone (IRENA, 2016). The WTE technologies have been great ly m od- ern ised and pr ioritised especially in t he developed nat ions. In 2012 , USA alone generated 14.5 m illion MWh of elect ricity from 84 WTE facilities (ERC, 2014). Incineration is the m ost w idely used WTE option in populous countr ies like China (Liu et al., 2006), wh ich had around 160 incineration plants in operat ion t ill 2010 (Lianghu e t a l., 2014). There w ere abou t 1900 waste incinerat ion plants in Japan , out of w hich , only 190 incinerat ion plants w ere equ ipped w ith pow er generat ion facilit ies (Mont ejo et al., 2011), bu t Bajic´ et al. (2015) reported that on ly 102 wast e incinerat ion plants w ere in opera tion for elect ricit y generat ion in Japan. Japan is follow ed by the European Union (m ainly France), and then the United States in term s of quantity of w aste incinerated (Montejo et al., 2011). Out of the tot al quan t ity of MSW genera ted , 74% in Japan , 54% in Denm ark, 50% in both Sw itzerland and Sw eden are incinera ted (The World Bank, 2012; Psom opoulos et al., 2009). Italy installed m any anaerobic co-d igestion plan ts w ith capacity ranging from 50 kW t o 1 MW (Pan ta leo e t al., 2013). The In ternational Solid Wast e Associat ion (ISWA) repor ted tha t, globally m ore t han 130 million tonnes of MSW per year (10%of the t ot al generated w aste globally) is t reated to generate elect ricity (ISWA, 2012). A study carried ou t by Earth Enginee ring Center of Colum bia University in 2013 regard ing the percen tage of w aste recycled/com posted , landfilled or dive rted tow ards WTE facility across different coun- trie s found that m ost of the developed coun tr ies prefe r to use envi- ronm en tally susta inable techn iques such as recycling/com posting and WTE for the m anagem ent of their generated w ast es (ERC, 2014). The European coun tries such as Net herlands, Belgium , Den- mark, Germ any, Aust ria, Sw eden and Switze rland divert m ost of their w ast es from landfi ll for recycling and com post ing facilitie s (Defra, 2013). In Asian countr ies, Singapore recycles 44% of the ir generated w astes, w h ile in othe r coun tries (m ostly developing), typ ically 8–11% w astes are recycled (Ngoc and Schnitzer, 2009). It has been reported that , som e cit ies such as Hanoi, ach ieved recy- clin g ra te of 20–30%(Velis et al., 2012). Many developing count rie s such as India, Viet nam , and Malaysia have started recovering energy from organ ic w astes, bu t at sm alle r scale . Nguyen et al. (2014) estim a ted t hat, food w ast e alone cou ld m eet up to 4.1% of Vietnam ’s elect ricity dem and if conver ted into biogas using anaerobic d igest ion process. The potent ial of WTE technologies has not yet been recogn ised by m any of the developing countr ies. 1.2. Need of waste to energy At t he end of this cen tury, th e global energy dem and is expect ed to be abou t six t im es m ore than that of t he cu rren t dem and (Kothari et al., 2010). The current available energy supp ly is m uch low er than the actual energy requ ired for consum pt ion in m any of th e developing countries. At presen t , one of the p rim ary sources of energy th roughou t the w orld is fossil fuels that meet the dem and of approxim ately 84% of the total elect ricity generat ion (Ouda et a l., 2016). Due to rapid dep let ion of fossil fuel rese rves, the w orld needs alt ernat ive sources of energy such as WTE for m itiga ting the fu tu re energy cr isis (Char ters, 2001). The problem of d isposal of huge quant ity of generated MSW and the requirem ent of reliable source of renew able energy are com m on in m any deve lop ing coun- tr ies. MSW causes se rious environm ental pollu tion, thus it s use as a potent ial renew able energy source w ould serve the purpose of m eeting increased energy dem and as w ell as waste disposal. Technological advancem ent , im proved pollu t ion control sys- tem s, governm en tal incent ives and st ringen t regu lat ions have m ade WTE technology a poten tia l alternat ive, especially for the developed countries. It not only provides a source of energy, but also reduces t he potent ial ha rm fu l im pacts of w aste on th e envi- ronm ent . If 1 tonne of MSW is incinerated for electricity generation instead of landfilling (withou t gas recovery), then 1.3 tonnes of CO2 equ ivalen t em issions can be avoided if equ ivalent CO2 em issions from fossil fuel based pow er plant s are also considered to generate th e sam e am oun t of e lectr icity (ASME, 2008). The w aste incine ra- tion p lan ts w ith energy recovery facility run w ith p re- treat ed MSW as a prim ary fuel have sligh tly low ne t carbon em ission fac- tor (0.04–0.14 kg/MJ) com pared to fossil fuel based pow er p lan ts (Pat um saw ad and Cliffe, 2002). The restrict ions on landfi ll sites for MSW disposal an d increase in pub lic awareness on environ- m en tal im pacts of MSW have forced the governm en ts to find more effective w ays of MSW disposal (Zhao et al., 2016). The land requ irem en t for WTE facilit ies is m uch less t han that of landfill facilit ies for handling sam e quant ity of w aste (Jam asb and Nepal, 2010). WTE plan t processing 1 m illion tonnes of w astes per year has an average w orking life of m ore t han 30 years and requ ires less th an 100,000 m 2 of land , w hereas a landfi ll for 30 m illion tonnes of MSW requires a land of 300,000 m 2. 2. Waste generat ion , char acter ist ics and com posi t ion Before select ion and im plem en tation of WTE technologies, it is necessary t o know the am ount of w aste generated its characteris- tics and com posit ions. According to the World Bank report 2012, th e global MSW generation rate was 1.3 billion tonnes per year w ith average generat ion rate of 1.2 kg/c/d. The generation rate of MSW is expected to reach 2.2 billion tonnes per year by 2025 and 4.2 billion t onnes per year by 2050 (Hoornw eg and Bhada- Tata , 2012). The solid waste generation ra te is d irect ly proport ional to the Gross Dom est ic Product (GDP) of developin g countries. Fig. 2 dep icts the re lat ionsh ips betw een GDP of some countr ies and their per capit a MSW generat ion rates. Countries w ere ca tegorised by In ternational Monetary Fund in to developed and develop ing coun- tr ies based on GDP per cap ita (Trosch inetz and Mihelcic, 2009). The countr ies w ith GDP per capita greater than US$ 10,000 per annum w ere term ed as developed nat ions. Accord ingly, t he coun tries w ith A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx 3 Please cite this article in press as: Kum ar, A., Sam adder, S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 a num erical value of m ore t han 4 [i.e . log10 {GDP per capita (US$/ yea r)}] w ere considered as developed and t he rest of the cou ntries were considered as the developing coun tries in the present study. The MSW generat ion rate is direct ly linked w it h overall deve lop - m ent of a coun try. Most of the coun tries (as p resen ted in Fig. 2) show ed linear relat ionsh ips bet ween GDP per cap ita and MSW generat ion ra te per cap ita. This resu lt is consistent w ith the previ- ously reported studies (Hoornw eg and Bhada-Tata, 2012; Shekdar, 2009). How ever, Med ina (1997) reported a w eak correlat ion bet w een the w ealt h of a coun try an d MSW generat ion rate. Another im portan t observat ion from the Fig. 2 is that , a few of the developed countries such as Icelan d, Japan , Sin gapore, Sw eden , Aust ralia, and Norw ay had less MSW generat ion rate as com pared to the other developed coun tries; th is m ay be at tribu ted to the dif- feren t definit ions of MSW adopt ed by d ifferent coun tr ies (Aleluia and Ferrão, 2016) as w ell as t he adopted w aste reduct ion policie s in countries such as Japan (Tanaka, 2014). The typical w aste gener - ation rate of developed count rie s ranges from 1.00 to 2.50 kg/c/d and 0.50 t o 1.00 kg/c/d for developing coun tries (Thit am e et al., 2010). For an effect ive m anagem en t of MSW of a city using suitab le WTE facilities, it is absolut ely essent ial to know the characterist ics an d com posit ions of the generated w aste (Yadav and Sam adder, 2017). Actual en ergy product ion from MSW is significant ly depen- den t on these tw o param eters. The characteristics such as part icle size, m oistu re con ten t , calorific va lue and density (Alelu ia and Ferrão, 2016) are im portant factors for select ing and developing an appropriate WTE facilit y. The w aste character ist ics an d com po- sit ion vary sign ifican t ly across developed and develop ing coun- t ries, even the cit ies of the sam e country have differen t w aste characterist ics because of th e h eterogeneous nature of MSW. The w aste com posit ion in various incom e group coun tries is show n in Tab le 1 (Hoornw eg and Bhada-Tata, 2012). The physical com po- sit ion and characteristics of MSW depend upon various factors, such as socioeconom ic profile,clim atic condit ions of an area, extent of recycling, collect ion frequency, dem ography, etc. Using the previously reported st udies on physical classificat ion of MSW, the w aste stream has been d ivided in to six different com po- nen ts nam ely; kitchen/yard w aste, paper /cardboard, plast ic, m et- als and glass, iner t and miscellaneous (Tab le 2). The MSW of 0 1 2 3 4 5 6 N EP A L B A N G LA D ES H PA K IS TA N IN D IA V IE TN A M B H U TA N PH IL IP PI N ES SR I L A N K A IN D O N ES IA C H IN A SO U TH A FR IC A C O LO M B IA M A LA Y SI A TU R K EY B R A ZI L A R G EN TI N A R U SS IA N F ED ER A TI O N U R U G U A Y C H IL E B A H R A IN G R EE C E SA U D I A R A B IA SP A IN IT A LY U N IT ED K IN G D O M G ER M A N Y IC EL A N D B EL G IU M IR EL A N D N ET H ER LA N D S A U ST R IA JA PA N U N IT ED S TA TE S SI N G A PO R E C A N A D A SW ED EN D EN M A R K A U ST R A LI A SW IT ZE R LA N D N O R W A Y Log10[GDP per capita (US$/year)] Waste gen (kg/c/d) Fig. 2. Distr ibu tion of Waste generat ion rate and GDP of the different countries (Waste Atlas, 2016). Table 1 Average waste com posit ion in various incom e group countries. Type of countries Organ ic (%) Paper (%) Plast ic (%) Metals and glass (%) Others (%) Low income group 64 6 9 6 15 Middle incom e group 56 12 13 7 12 High income group 28 30 11 13 18 Table 2 Physical classification of MSW. Com ponent Material References Kitchen /yard w aste Food w aste (e.g., food and vegetab le refuse, fru it skins, corncob), yard w aste (e.g., leaves, grass, tree trim mings), etc. Bajic´ et al. (2015), Qu et al. (2009) and Eddine and Salah (2012) Paper/cardboard Paper bags, cardboard , corrugated board, box board, new sprint , magazines, tissue, office paper, and m ixed paper, etc. Plastic High-valued plastics [LDPE bott les (sham poo bottles, detergent bottles, etc.), polypropylene bottles (mess tins made from rigid plastics, etc.), PET bot tles (beverage bott les, etc.)], Low-valued plastics (Polythene plastic bags, polystyrene plastic packages such as mess tins made from flexible plastics and plastic cup for yoghurt, ice-cream , etc.) and others. Metals & glass Ferrous (e.g., food cans, etc.), non-ferrous (e.g., alumin ium cans, foil, ware, and bimetal, etc.), wire, fence, knives, bottle covers, etc., and bot tles, glassware, ligh t bulbs, ceramics, etc. Iner t Stones and silt , soil, ash, dust, oth er inorgan ic mater ial, etc. Miscellaneous Discarded clothes, rags, leather , rubber, used batt eries, m edical w aste, nappies/san itary product s, etc. 4 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 developed coun tries has less m oist ure con ten t, for e.g., in USA and European coun tries it var ies from 20 to 30% as com pared to 50 to 70% in developin g coun tries such as in China and India (Cheng et al., 2007; Mohee and Mudhoo, 2012). How ever, the w aste st ream of developed count ries has high calorific values (2000– 4000 kcal/kg) as com pared t o the develop ing coun tries (700– 1600 kcal/kg) due t o the presence of high percen tage of paper and other dry organ ic wast es (Patum saw ad and Cliffe, 2002). The calor ific valu es of MSW stream of som e of the coun tr ies are show n in Table 3 . In high incom e group count rie s, the decom posable organ ic fract ion in their MSW stream is less and t he fract ion of plast ics, paper, text iles and other recyclable w astes is m ore. The organ ic conten t in MSW is below 30% (by w eigh t) in developed count ries such as Japan, USA, Singapore and South Korea, but the sam e in developing coun tr ies such as China , Sri Lanka, Pakistan , and India is m ore than 50%(Aleluia and Ferrão, 2016). 3. Heat ing values of m unicipal sol id waste One of the im portant param ete rs for det erm inat ion of energy con tent of MSW is t he heat ing value or the calorific va lue. There - fore, it is necessary t o have reliab le and accurate heat ing valu e data of MSW com ponent s for efficien t design and successful operat ion and m aint enance of a WTE facilit y (Sh i et al., 2016). A m ajor prob- lem is the inconsistencies in report ing the energy con tent of MSW. Generally, the repor ted studies described the energy cont en t in term s of h igher h eat ing value (HHV), low er heat ing value (LHV), calor ific va lue, net heating value , gross heat ing value (Kathiravale et al., 2003; Gonzá lez et al., 2001). Although these values are inter-relat ed, but th is inconsistency causes confusion to t he read - ers in com paring the resu lts. The ca lorific value is norm ally classi- fied into HHV and LHV. LHV is the energy cont en t ava ilable from com plete com bustion and does not consider the latent heat of vapor isa tion of m oistu re presen t in w aste st ream . Whereas, HHV is the theoretical m axim um energy con tent in w hich laten t hea t of vaporisation of w astes is taken into consideration and is gener - ally m easu red w ith t he help of a bom b calorim e ter and som et imes with the help of equat ions, w h ich is a funct ion of u ltim ate analysis of the subst rate (Kom ilis et al., 2012). How ever, the m easu rem ents of heating va lue using bom b calorim e ter is tedious, requ ires skilled operator and all MSW m anagem ent (MSWM) facilit ies are not alw ays equipped w ith bom b ca lor im eter (Kat hiravale et a l., 2003). The m ost com m only used equation in t heoret ical estim at ion of heat ing value is Dulong equat ion (Ka th iravale et al., 2003), wh ich w as originally developed for est im ation of heating value of coal and m ay n ot be applicable for the estim at ion of heating value of MSW (Shi et al., 2016). LHV calcu lat ion is based on the HHV and moisture con tent of feedstock (Abu-Qudais and Abu -Qdais, 2000; Komilis et a l., 2012). LHV has more practical app lications t han HHV and it is la rgely used in energy est im at ion , as th is is the energy that is actua lly used in elect ricity generat ion from a MSW incinera tor (Kom ilis et al., 2014). 4. Waste to energy opt ions The aim s of any w aste m anagem en t system are m aterial and energy recovery, followed by disposal of t he residues. Bu t, an op ti- m al choice for a w aste p rocessing technology is not on ly subject to econom ic requ irem en ts, energy recovery or w aste dest ruction abil- it y, bu t also to look for environm en tal regula tory com pliance requ irem en ts of the concerned area. Therefore, it is necessa ry to select the best ava ilable technology for waste processing, w hich fu lfi ls all the required criteria for a successful operation (Ali et al., 2010). A variety of w aste conversion processes are availab le, in w hich the t hree m ost w idely used technologies a re (Kalyan i and Pandey, 2014): (i) therm al conversion [(incine rat ion, pyrolysis, gasificat ion , p roduction of energy from refuse derived fuel (RDF)], (ii) biological con version (anaerob ic d igest ion /biomethanation and com post ing), an d (iii) landfilling w ith gas recovery. The MSW treatm ent techniques along w ith the typical react ion prod- ucts are show n in Fig. 3. 4.1. Thermal conversion technologies Therm al conversion involves thermal t rea tm ent of organ ic m at- te r p resent in MSW t o produce either heat energy, fuel oil or gas. Therm al conversion technology is generally usefu l for dry w aste (low m oistu re con tent ) w ith high percentage of non- biodegradable organ ic m at ter . Som et im es, therm al conversion technology is applied to RDF, w hich is a com bust ible m ater ial w ith h igh calorific value. For product ion of RDF, t he recyclable and non- com bust ible m at erials are removed from MSW follow ed by shred- d ing and /or pellet isat ion of the rem ain ing w aste . Incineration, w hich is a controlled com bust ion of w astes a t high tem peratu re is the most w idely used m ethod in t herm al conversion t echnology (Shi et al., 2016). The other th erm al conversion technologies (pyrolysis and gasificat ion ) are still in resea rch phase and they are not feasible for com m ercial pu rpose a t large scale, m ay be due to lack of proper MSW characterisat ion dat a, poor feedstock qua lity and inappropriate design of the facilit y (Appels et al., 2011; Sh i et al., 2016). There are very few com m ercially operat ing pyrolysis/gasifica tion plan ts across th e w orld for t reat ing MSW. These plants operate for treat ing MSW along w ith som e other type of w astes such as indust rial w aste, biom edical w ast e, biom ass, etc. (Ion escu et al., 2013). The typ ical react ion cond it ions and products from therm al t reatm ent processes are show n in Table 4. The main d ifferences am on g these th ree t herm al t reatm en t processes are the atm ospheric con dit ion (i.e., p resence of oxygen) and t he operat ing tem perature. The qualit y of t he final products and the usefu l inter- m ed iate products depends m ain ly on these tw o param eters. Oper- at ing tem peratu re of therm al processes la rgely depends on the process design and feedstock m ater ials. For incineration process, p re- treat m ent of MSW is genera lly not practiced in developing countr ies; raw MSW is directly used as a feedstock m at erials. Table 3 Calorific valu e of MSW of developed and developing coun tries. Countr ies Calor ific value (kcal/kg) References Developing Bangladesh (717) Hossain et al. (2014) China (1200–1600) Zhou et al. (2014) In dia (800–1100) Unnikrishnan and Singh (2010) Malaysia (1500–2600) Kathirvale et al. (2004) Sri Lanka (950–1250) Reddy (2011) Thailand (500–1500) Reddy (2011) Developed Japan (2000–2200) Hla and Roberts (2015) S. Korea (2600–3000) Yi et al. (2011) UK (2200–3000) Hla and Roberts (2015) A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx 5 Please cite this article in press as: Kum ar, A., Sam adder, S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 4.1.1. Incineration In itially t he incinerators w ere used for volum e reduction and protect ing the m en and environm ent from the hazardous w astes, bu t not for energy recovery (Brunner and Rechberge r, 2015). After advances in a ir pollu tion control technologies, incinerat ion is now considered as an att ract ive w ast e treatm ent opt ion, especially in the developed coun tries (Psom opoulos et al., 2009; Ouda et al., 2016). Scarlat et al. (2015) report ed that incine rat ion is one of the m ost com m on waste d isposal t echniques in the developed count rie s (EU, US and Japan) due to the st ringen t w aste-related regu lations on w aste d isposal using landfilling. The em ission s from waste incine rators have been reduced to such an exten t that in 2003, t he United Stat es Environm ental Protect ion Agency (US EPA) declared incine rat ion of MSW as a cleaner source of energy (Lem e et al., 2014). Incineration is the m ost com m on w aste treat - m ent techniques in w hich, the w ast e m ass and volu me can be reduced by 70% and 90% respect ively (Chen g and Hu, 2010; Nixon et al., 2013a,b; Gohlke and Mart in, 2007; Lombardi et al., 2015); at the sam e t im e, heat and/or e lectricity can a lso be pro- duced (Singh et al., 2011). From incinerators, heat is supp lied if the re is a requ irem ent for dist rict heating (in cold coun tr ies), som etim es it is supplied to the indust ries like paper m ill, and elec- t ricity is produced in all the other cases (Brunner and Rech berger, 2015). But in a few recent stud ies (Meylan and Spoerri, 2014; Allegrini et al., 2014), the scien t ist s h ighligh ted som e other advan- tages of incinerat ion apart from volum e reduct ion and elect ricity genera tion such as, ut ilisat ion of bot tom and fly ash of incineration p lan ts in road const ruct ion & cem en t product ion and recovery of fe rrous and non-ferrous subst ances. Thus, fu rt her technological developm en t in m eta l recovery from dry bot tom ash of in cinera- t ion p lan ts w ill enhance the accep tance of WTE facilitie s (Morf et al., 2013). Bu t in the developing coun tries, the incinerat ion is considered as the m ost reliable and econom ical w hen it is used for mass burn ing w ithout p re -t reatm en t of MSW for elect ricity genera tion. Incinerat ion generally t akes place at d ifferent stages depend ing upon the operat ing condit ions and t ype of w astes incin- erat ed (Table 5). One of the m ain advan tages of MSW incineration is the com plet e dest ruct ion of any living organ ism s and m inerali- sat ion of organic substances into harm less end products (Brunner an d Rechberger, 2015). MSW com posit ion and characterist ics are highly heteroge- neous, th us they m ust be evaluated before designing any WTE Table 4 Typical reaction condit ions and products from thermal treatment processes. Parameters Incineration Pyrolysis Gasification Princip le Full oxidat ive com bust ion Therm al degradation of organic mater ial in the absence of oxygen Partial oxidation Operat ing tem perature (°C) 850–1200 400–800 800–1600 Atmosphere Presence of sufficien t oxygen Absence of oxygen Controlled supply of oxygen Reaction products Solid Bottom ash , fly ash, slag, other non- combustible substances like m etals and glass Ash , char (combination of non-combustible and carbon) Ash , slag Liqu id Con densate of pyrolysis gas (pyrolysis oil, wax, tar) Gas CO2, H2O, O2, N2 Pyrolysis gas (H2, CO, hydrocarbons, H2O, N2) Syngas (H2, CO, CO2, CH4, H2O, N2) Pre- treatm ent Not necessary Required Required Raw MSW Usually preferred Usu ally not preferred Usually not preferred Biogas Landfill gas Bio-fuel Compost Soil conditioner Biological conversionThermal conversion Municipal Solid Waste Landfilling Incineration Gasification Pyrolysis Slow Pyrolysis Fast Pyrolysis Aerobic Composting Anaerobic Digestion Energy/ElectricityHeat/ Steam SyngasInert residue Fig. 3. Municipal solid waste treatment techniques and their products. 6 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 facility (Turcon i et al., 2011). Tan e t al. (2014) suggested t hat , incinera tion is su itable for com bust ible non-biodegradable MSW with low m oistu re conten t. Som et im es auxiliary fue ls are used along w ith MSW during incineration , but it is worth t o not e tha t the use of auxiliary fuels along w ith MSW is not requ ired w hen the LHV of wast e is bet w een 1000 kcal/kg and 1700 kcal/kg or above (Chen an d Christensen, 2010; Kom ilis et al., 2014). Accord - ing to t he World Bank report , the average calorific value of MSW should be at least 1700 kcal/kg (World Bank, 1999) for an effective incinera tion operation with energy recovery, w hereas, accordingto Internat ional Energy Agency, the values m ust be greater t han 1900 kcal/kg for t he incine rat ion operat ion to be feasible (Melikoglu , 2013). It is apparent that the presence of inert w ast e and m oist ure con tent reduces the calorific value an d affects the com bust ibility of MSW, w hich directly affects t he perform ance of an incinerator. As t he m oistu re con ten t increases in the w ast e st ream , it s calorific va lue star ts decreasing du e to lat en t heat of vapor isa tion . There fore, som et im es pre-t reatm ent (therm al, mech an ical, chem ical and biologica l) of w astes are done to rem ove the excess m oistu re conten t, inert wast e and toxic elements such as ch lorine and m ercury (Lom bardi et al., 2015). A typical inciner - ator gen erates 544 kWh of energy and 180 kg of solid residue per tonne of MSW incinerated (Zam an, 2010). 4.1.1.1. Incinera tion in developed and developing countries. Modern MSW incinerat ion p lan ts operate quit e well for recovering energy in the form of steam for elect ricity generat ion in cit ies of industr i- alised nations (Psom opou los et al., 2009). Less annual cap ita l cost , operational cost, bet ter skill of the operators, higher daily through- pu t (Psom opou los et al., 2009), and high calorific value of the MSW altogether m ade incinerat ion a m ore a tt ract ive than other WTE technologies for the citie s of developed coun tries. In Asian coun- trie s, Japan is part icularly fam ous for w aste incineration technol- ogy due to str ingen t regulation and lim it ed land area for w aste dum ping. Incinera tion of MSW is done w idely in d ifferent Western European coun tries ranging from 35% to as m uch as 80% of the total w aste generat ed (Reddy, 2011). Other European count ries also rely significan tly on incineration for handling m unicipal waste . The North -eastern US recovers energy from m ore t han 40% of its tota l solid w aste genera ted using incinerat ion only. Incineration is not feasib le for m any deve lop ing countries excep t those w ith fast grow ing econom ies (su ch as China, Malaysia, etc.), du e to (a) the h igh capital, operating and main tenance cost s, (b) un favourable characteristics and com posit ion of w astes, (c) lack of techn ical exper tise in the field , and (d ) availability of com para- tively low cost land for wast e d isposal. But , China had gone for huge expansion in MSW in cinerat ion in the past decade and is expected to reach up to 500,000 t on nes/d by 2020 (Lu et al., in press). Li e t al. (2015) reported t hat , t ill 2013 Ch ina had 166 oper- ational incineration plants for generat ion of electr icity using MSW at the rate of 166,000 t on nes/d . Cheng and Hu (2010) claim ed tha t th e waste incinerat ion had m ore con tribu tion to the overall renew- able energy generat ion in China. Bu t Lom bardi et al. (2015) reported that Ch ina is facing several problem s in MSW incineration due to poor w aste feedstock quality, incom ple te com bust ion , and increased air pollu t ion. High m oistu re conten t, var iable com posi- tion and low energy con ten t are som e other m ajor d ifficu lt ies faced in incinerat ing w astes in developing coun tries (Reddy, 2011). 4.1.2. Pyrolysis Pyrolysis is an advanced therm al t reatm ent m ethod . It takes p lace in t he temperature range of 400–800 °C in absence of oxygen. It p roduces pyrolysis gas, oil and char, w hose yield and qu ality m ainly depend upon the heat ing rate, process t em pera tu re, resi- dence tim e (Lom bardi et al., 2015), com posit ion of w astes, and par- ticle size of the waste (Ka lyani and Pandey, 2014). At low er tem perature (500–550 °C), pyrolysis oil, w ax and ta r a re the m ajor p roducts, and at higher tem peratu re (>700 °C), pyrolysis gases are th e m ajor p roducts. For good qua lity pyrolysis products, the feed- stock should be of specific type of w astes (plast ic, tyre, elect ron ic equ ipm ent , electric w aste, w ood wast e, etc.). Pyrolysis of specific type of w astes was repor ted in various previous studies, w hich focussed on the process it self rather than the possible com m ercial use of pyrolysis product s. In part icular, pyrolysis has received spe- cial at ten t ion recen tly for recycling of scrap t yres for recovery of oil, wire, carbon black and gas (Lom bardi et al., 2015). As, it is evi- den t that pyrolysis pe rform s w ell in treat ing specific w aste stream , but ve ry lim it ed studies have been reported abou t energy recovery from MSW using pyrolysis at com m ercial scale. A plan t of 110 ton- nes/d capacity in Burgau , Germ any has been successfully generat- ing elect ricity th rough MSW pyrolysis since 1987 (Lom bardi et al., 2015). Panepinto et al. (2014) reported abou t som e ot her success- fu lly operat ing MSW pyrolysis plants such as in Ham m , Germ any (275 tonnes/d ), Toyohash i, Japan (295 tonnes/d ), UK (22 tonnes/ d ), and France (191 tonnes/d). Baggio et al. (2008) reported that pyrolysis of MSW for product ion of gas can be used for energy recovery using Gas Turbines w it h a net conversion efficiency of 28–30%. 4.1.3. Gasification Gasificat ion is another therm al conversion t echnology, in w hich organic com pou nd ge ts converted in to syngas in cont rolled atm o- sphere of oxygen at h igh tem perature. Syngas is the m ain product of gasificat ion process, w hich can be used to produce energy th rough com bustion. It can a lso be used to produce feedstock for chem icals an d liquid fuel (Yap and Nixon , 2015). Most of the reported gasifica tion stud ies are focussed on hom ogeneous flow of solid fuel (coa l, w ood , etc.) and specific t ype of MSW. Gasifica- tion has been widely used in coal industry, but recently it has been considered as a potent ial energy recovery op tion from MSW (Arafat and Jijakli, 2013). Panep in to et al. (2014) invest igated 100 p lan ts around the w orld that use gasificat ion t echn ique to process Table 5 Stages of incineration process. S. No. Steps References 1 Drying and degassing Pyrolysis and gasification Oxidation Tabasová et al. (2012) 2 Incineration Energy recovery Air pollu tion cont rol Lee et al. (2007) and Zheng et al. (2014) 3 Waste delivery and storage section (bunker) Waste com bustion section (furnace) Energy recovery and conversion section Flue gas cleaning section Branchin i (2015) A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx 7 Please cite this article in press as: Kum ar, A., Sam adder, S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 MSW. MSW gasifica tion technology is w idely used in Japan, wh ere 85 plan ts w ere operat ing till 2007. In othe r coun tries (such as in USA, UK, Italy, Germ any, Norw ay and Iceland), gasification has been used to process MSW at sm aller scale (Panepin to et al., 2014). It has been reported that gasificat ion process generates less CO2 t han the incinerator of sim ilar capacity (Murphy and McKeogh , 2004). Defra (2013) repor ted t hat , m odern gasificat ion un its com e with enclosu res, w h ich effect ively reduce the ch ance of w at er and soil con tam inat ion. Asia has seen a huge leap in the gasificat ion technology in last few years and can be considered as one of the m ost favourable m arkets for gasificat ion t echnology follow ed by Europe, Africa and USA (Ouda et al., 2016). Zam an (2010) repor ted th at pyrolysis and gasificat ion technolo- gies a re m ore favourab le than the incinerat ion technology for MSW from environm en tal im pact an d energy recovery prospect ive . Pyrolysis and gasificat ion technologies can reduce t he w ast e vol- um e by 95% and require less intensive flue gas cleaning as com - pared to incineration (Yap and Nixon, 2015). Pyrolysis and gasificat ion t echniqu es are bet ter t han other WTE options in view of environm ent al em issions and energy recovery efficiency. How - ever, they are yet to be established at large scale across t he w orld (predom inan t ly in developing coun tries) for energy recovery from MSW (Luz et al., 2015) due to poor efficiency of gasifiers and gas clean ing syst em s, heterogeneity in MSW com position & part icle size, and h igh m oisture con ten t. 4.2. Biologica l conversion technology Biological conversion technology is based on m icrobial decom - position of the organ ic content of MSW. Many researchers reported this t echnology as environm ent ally suitable for energy recovery from w astes (Pan t e t al., 2010). It is genera lly p referred for the wastes w ith h igh percent age of organ ic b iodegradable m atter (pu trescible) and high m oistu re conten t. The m ain technologica l op t ion for energy recovery under th is category is anaerobic diges- tion or biom ethanat ion . 4.2.1. Anaerobic digestion Anaerobic d igestion (or biom ethanat ion ) is a p rocess of m icro- bial degrada tion of organic b iodegradable m at ter in absence of oxygen that produces biogas and stab ilises the sludge. The quality of the generated biogas depends on the process param eters and subst rat e com posit ion ; the biogas is typically com posed of 50– 75% CH4, 25–50% CO2 and 1–15% of ot her gases (such as, w ater vapour, NH3, H2S, etc.) (Surendra et al., 2014). The produced slu rry/sludge can be used as a soil condit ioner and /or as an organ ic am endm ent in agricu ltu ral field (Pivato et al., 2016; Tam bone et al., 2009). Anaerobic d igest ion is u sed to recover both nu tr ien t and energy from biodegradable w ast e. Ali e t a l. (2016) reported tha t, the quality (as a fert iliser) of solid p roducts of anaerobic digestion depends m ain ly on the quality of feedst ock (proteins, m inerals and vitam ins con tent of w aste). Brown e et a l. (2014) reported that European legislation prohibit ed the use of solid prod- ucts of anaerobic digest ion as a fert iliser, due to the presence of undesirable m aterials in feedst ock. In anaerobic d igestion, the organ ic fract ion of the biodegradable MSW gets degraded and con- verted into m ethane th rough a series of stages. The init ial st age is called hydrolysis, in w hich t he com plex organic com pounds of MSW like carbohydrates, proteins and fats ge t con vert ed in to sol- uble organ ic m aterials such as sugars, am ino and fa tty acids. Fer- m entation is the next stage of anaerobic digest ion process in which the organic m olecules break into acet ic acid, H2 and CO2. The final stage is m ethanogenesis, in w hich m ethane form at ion takes p lace. The detailed process flow for conversion of organ ic m atter into methane is show n in Fig. 4 . The anaerobic digest ion processes are m ainly of tw o types, ‘‘wet” (10–15% of dry m atter conten t), and ‘‘dry” (24–40% of dry m at ter conten t) processes (Lun ing et al., 2003). Wet process produces m ore liquid w aste an d less solid product . The requ ired volum e of react or for w et pro- cess is less t han that of the dry process. The type of reactors (single st age or m ult i stage), p rocesses (wet or dry) and m ethane yield depend on t he region , quality of feedstock and the produ ct requ irem en ts. It has been estim ated that anaerobic d igest ion can produce 2– 4 tim es m ore methane per tonne of MSW in 3 w eeks than that of a landfill in 6–7 years (Ahsan , 1999; Saxena et al., 2009). Murphy et al. (2004) report ed that 1 m 3 of biogas produced from anaerobic d igestion process can genera te 2.04 kWh of elect ricity taking con- version efficiency of 35%. Abou t 150 kg of m ethane can be gener- at ed from anaerobic d igestion of 1 tonne of MSW considering 60% organ ic m at ter and 40% m oistu re (Scar lat e t al., 2015). How- ever, t he m ajor problem associat ed w ith th is process is the long dura tion (t yp ically 20–40 days) of m icrobial react ion (Pham et al., 2015). Som et im es, presence of nit rogen rich com ponen ts an d cat ions (such as sod ium , potassium , and calcium ) in the w aste st ream increases am m onia and salt concen trations (Fount ou lakis et a l., 2008 ; Chen et al., 2008) that m akes the process toxic for m et hanogenic act ivit ies. Several stud ies (Gom ez e t al., 2006; Cristancho and Arellano, 2006) suggested co-d igest ion of MSW w ith low nitrogen con tent w aste, sew age sludge, and food w aste to reduce the h igh am m onia con centrat ions an d to increase t he b iogas yield of the process. The m ethane yield of organ ic fraction of MSW un der different operat ing condit ions repor ted by various researchers is sum m arised in Table 6. Most of the researchers used food w astes along w ith the su itable inoculum for m axim um gas recovery. The quality of the biogas generat ed using anaerobic d igestion technology can be im proved by rem oving CO2 and other t race gases for use as a t ranspor tat ion fuel called biom et hane. Th is can subst itute natural gas in variety of dom est ic and industr ial app licat ions (Kastu rirangan, 2014; Appe ls et al., 2008). Earlier, an aerobic d igest ion w as used for t reatm en t of dom est ic sew age, agricu ltu ral w aste, organic w aste and an im al m anure, bu t now it is extensively used for energy recovery from MSW especially in the developing countries, wh ere w astes have h igh m oistu re con- tent (Yap and Nixon , 2015). Abbas et al. (2017) and Ali et al. (2013a,b) evaluated t he feasibilit y of biogas recovery and found that the biogas recovered from anaerobic digest ion t echnology is econom ically and environm entally sustainable. 4.3. Landfilling San itary landfilling is defined as the con trolled d isposal of w astes on land t o reduce t he negat ive im pact on the environm ent th rough biogas recovery and leachate m anagement (Fig. 5). How- ever, unsan itary landfilling offers a sim ple r and affordable solution Soluble H2, CO2 Acetic acid Volatile fatty acids CH4 + CO2 Hydrolysis Acetogenesis Acidogenesis Methanogenesis Methanogenesis Organic matter Fig. 4. Stages in anaerobic digestion process. 8 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 for disposal of the increasing w aste quan t ity and is the m ost com - mon pract ice in developing coun trie s, that poses a ser ious th rea t to the environm en t (Wang and Geng, 2015). Previous st ud ies show ed that landfilling causes the h ighest environm en tal im pact com pared to other w aste managem ent op tions (Cherubini et al., 2009; Em ery et al., 2007; Marchett ini et al., 2007 ; ISWA, 2012). It has been reported t hat m ost of the cit ies of developing coun tr ies, t he w aste is disposed on low lying areas loca ted at the outskirts of the cit y (Talyan et al., 2008 ; Kum ar and Chakrabarti, 2010). When the fac- tors such as environm enta l im pact , health im pact , land degrada- tion , and groundw at er cont am inat ion are conside red , landfi lling becom es the w orst op tion. How ever, developed coun tries have started to discourage landfilling of w astes t hrough str ingen t regu- lat ions, w aste reduct ion and recycling. The landfi ll leachate (a dark effluen t of unusually variable com posit ion with recalcit ran t com - pounds) is a m ajor polluting substance released from landfi lls or Table 6 Methane yield during anaerobic digestion of MSW. References Feedstock m ater ial Sam pling area Type of reactor Operating condit ions Inocu lum Methane yield Observations/rem arks Zhang et al. (2007) Food waste from restauran ts, hotels and grocerystore San Francisco, California Batch (1 L) Avg. moisture content and Volatile Solids/Total Solids (VS/TS) was 70%and 83% respectively, t emperature w as therm oph ilic (50 ± 2 °C). The reactor was m onitored for 28 days Sludge from w astewater treatment plant 435 mL CH4/g of VS Samples of w eekends w ere not t aken for the an alysis. Sam ples w ere taken from the w aste m an agement com pany (responsible for w aste collect ion). Thus, direct sampling from the source of generation could have reduced the contamination of food waste from other types of w astes and the m ethane yield might have increased. Macias-Corral et al. (2008) Organic fraction of MSW (OFMSW) New Mexico, USA Batch Avg. VS was 82%, temperature w as therm ophilic (55 °C) Supernatan t from anaerobic w astewater treatment plant 37 mL CH4/g of dry waste Samples w ere taken from kerbside collection truck and then segregated in to organic fract ion w hich might have reduced the quality of the samples. The OFMSW contains main ly paper waste (70%). Yong et al. (2015) Food waste and straw Beijing, China Batch (1 L) Organic loading w as 5 g VS/ L, perform ed at mesophilic temperature (35 °C) Anaerob ic granular sludge from starch processing w aste w ater 0.392 m 3 CH4/kg of VS The methane yield has been increased by 39.5%and 149.7% compared with individual digest ion resu lts of food waste and straw respect ively. The carbon to nitrogen (C/N) ratio for optim um digestion should be in range of 25–30. But the C/N rat io of food w aste and straw w as 28.4 and 43 .4 respectively and thus the C/N rat io of m ixed waste w as on slight ly h igher side of optimum values. Scano et al. (2014) Fru it and vegetable wastes Sardin ia, Italy Continuous (1.13 m 3) The reactor was monitored for 174 days and m ain tained at mesophilic conditions (35 ± 0.5 °C) Digestat e of pig m an ure 0.43 Nm 3 CH4/kg of VS Fruit w astes have h igh sugar conten t w hich increases the CO2 concen trat ion in the biogas and reduces the CH4 yield. Thus, optimum loading rate of substrates is very much essen tial. Kom emoto et al. (2009) Food waste Saitama, Japan Batch (2 L) TS and VS of the sam pled w aste w as 16%and 94% respectively. The experim ent w as performed at six d ifferen t temp. 15 °C, 25 °C, 35 °C, 45 °C, 55 °C and 65 °C No inoculum 64.7 mL CH4/g of VS Biogas production w as found more at mesophilic conditions (35 °C and 45 °C) than the thermophilic, which is contrary to the findings of several p revious researches. But at thermophilic condit ion the HRT is less which will effectively reduce the reactor size. Haider et al. (2015) Food waste and rice husk Islam abad and Faisalabad, Pakist an Batch (1 L) TS of food waste and rice h usk w as 24%and 90% resp ., w hereas VS was 92% and 81%resp. The reactor w as monitored for 45 days at m esophilic conditions (37 ± 1 °C) Acclimatised cow dung 584 mL biogas/g of VS Food w aste and rice husk were m ixed in d ifferent ratios to get the desired level of C/N rat io. Cow dung as inoculum reduces the accumulat ion of VFA, thus protects d igester from failure. Purity of the b iogas was not mentioned . Ma et al. (2011) Kitchen waste Belgium Batch (1.2 L) TS and VS of waste was 166 g/kg and 155 g/kg resp. The reactor operated at therm ophilic condit ions (55 ± 2 °C) Sludge from potato w aste treatment plant 520 mL biogas/g of COD Different pre- treatment techniques (acid, thermal, thermo-acid, p ressure-depressure, freeze-thaw) w ere applied to the kit chen waste and were found that the b iogas yield im proved w ith the pre- t reated kit chen waste as com pared to the raw kit chen w aste. However , the process is not feasible in the develop ing countries due to less conversion efficiency of biogas to energy, m aking the process cost ly. A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx 9 Please cite this article in press as: Kum ar, A., Sam adder, S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 dum psites (Mü ller e t al., 2015) that pollu tes the nearby sur face water courses and groundwater aqu ifers. Accord ing to experts, on ly 10–15%of the t ot al w aste generated should go for landfilling and it should be the last op t ion for citie s w h ere land is lim ited . 4.3.1. Modelling landfill gas generation The organ ic m att er present in the deposit ed w astes in landfills undergoes com plex biological and chem ical decom posit ion t hat result s in the product ion of landfill gas (LFG). The degradat ion of organ ic m at ter in to LFG occurs in five differen t phases (Noor et al., 2013). The first phase is hydrolysis/aerob ic degradat ion , in which t he aerobic bacteria breaks com plex organic m at ter int o CO2 and H2O. The second phase is hydrolysis and ferm en tat ion , in w hich the soluble organ ic com ponent s are decom posed int o CO2, H2, NH3 and organ ic acids in p resence of facu ltat ive bacteria . The third phase is acidogenesis/ace togenesis, in w hich the organ ic acids produced during second phase get convert ed in to acetic acid , form ic acid, alcoh ols, H2 and CO2 by anaerobic bacteria. In the fou rth phase (m ethan ogenesis), the m ethanogen ic bacte ria con- sum es the product of t he th ird phase and produces p rimarily CH4, CO2, as w ell as oth er t race gases in sm aller am oun t. The fina l phase is oxidat ion , in w h ich CH4 gets conver ted in to CO2 and H2O under aerobic condition. The LFG production rate inside a landfill depends on various factors, such as, type of landfill, w aste com po- sition , clim atic cond ition (tem peratu re and precipitat ion ), m ois- ture con tent , and w aste age (Scarlat et a l., 2015). LFG conta ins 50–60% m ethan e (Unn ikrishnan and Singh, 2010) and is consid - ered as one of the m ajor source of an th ropogenic m ethane em is- sions. As per an est ima te, 30–70 m illion tonnes of m ethane gas is em itt ed per year from w aste landfi lls (Johari et al., 2012). There- fore, recovery of m ethane from a landfill for elect ricity generat ion or other use is necessary t o reduce t he em ission. Som et imes, recov- ery of LFG is techn ically not feasible, in tha t case on-site flaring of LFG is done. Bu t , for this it is necessary to get t he estim a tes of trapped LFG inside a landfill. The recom m ended approach involves m odelling of LFG gen erat ion . There are various m odels ava ilable t o predict the m ethane em issions from landfills. Som e of t he m ost widely used m odels (seven m odels) are descr ibed in Tab le 7. How - ever, differen t em ission m odels give differen t results for a single landfi ll and the m odels give accura te resu lts for t he region it has been deve loped , as t he w ast e com posit ion differs across the coun- tries. Ou t of the seven m odels, six m odels are based on the Euro- pean scenario and one on the USA scenario. These m odels have great ly reduced the t ediou s m easurem en t techn iques generally app lied for m et hane estim at ion from landfi lls. Although , TNO- m odel w as developed for the w aste character ist ics of Netherlan d, but th is can be used for the est im at ion of LFG for other coun tr ies also as it has less relat ive error (22%) be tw een observed and calcu- la ted values. In a st udy, it w as estim a ted t hat 1 tonne of MSW gen- erat es 80 m 3 of LFG and China alone m ay cont ribute 10 billion m 3 LFG to the global LFG em issions in 2020 (Qu et al., 2009). 5. Energy r ecovery poten t ial and econom ics of WTE technologies At present, Ch ina generates abou t 300 m illion t onnes of w aste an nually (World Energy Resources, 2016) andthe wast e con tains h igh propor tion of food waste of low ca lor ific value and h igh m ois- tu re cont en t sim ilar t o tha t of other deve loping coun tries. There- fore , the convent ional in cinerat ion plants used in developed coun tr ies are expected t o perform poorly in such condit ion s. Thus, China has developed new circu lat ing fluidised bed based in cinera- t ion plan ts to coun ter this p roblem and curren t ly 28 such p lan ts are successfully generat ing electr icity by processing 800 tonnes/d of MSW (World Energy Resources, 2016 ; Zhao et al., 2016). Cheng et al. (2007) report ed that the grate based circu lat ing flu- id ised bed incinerator is w ell su ited for MSW w ith h igh m oistu re an d low energy con ten t . A wast e incinerat ion plant in Eth iop ia w ith capacity of 50 MW (the fir st WTE facility in Sub-Saharan Africa) is expected to be com m issioned in 2017 , w hich w ill process 350,000 t onnes of w aste per yea r. However, the p lan t m ay struggle for it s operational cost due to m any issues such as low calorific valu e of incom ing MSW stream , lack of local techn ical expertise, an d low energy prices (World Energy Resources, 2016). Perkou lidis et a l. (2010) reported that a WTE facilit y in Central Greece w as expected to recover 0.55 MW elect ricity pe r t on ne of MSW, with net conversion efficiency of 22.5%. As per the estim a te, Malaysia is expected t o generate 2.63 109 kWh of elect ricity from LFG alone by the year 2020, w hich w ill generate revenues w or th of US$ 262 m illion for Malaysia (Noor et al., 2013). The en ergy recovery potent ial of five anaerob ic digest ion plan ts of Greece Municipalit y w as found to be 695 kWh/tonne w ith an aver- age operat ing cost of 84 US$/ tonne (Karagiann idis and Perkou lid is, 2009). Brazil has a poten tial of generat ing approxim ately 660 MW electricity per day from MSW landfills alone. The presen t study review ed m ore than 100 published art icles from 2010 to 2017 on WTE technologies, ou t of which t he crit ical observat ion on som e of the recen t lite rat ure on WTE technologica l op tions across Fig. 5. A typical engineered landfill with biogas recovery system. Source: Zaman, 2010. 10 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 Table 7 Description of m ethane generation potential m odels. Models Formula Model descrip tion Rem arks IPCC-m odel (IPCC, 2006) Q ¼ P T 1 x¼S f MSWTx MSWFx L0 ;xðe kðT x 1Þ e kðT xÞÞg R h i ð1 OXÞ where, L0 = m ethane generat ion poten tial (Gg of CH4/Gg of waste) = 1.33 F DOC DOCF F = fraction by volum e of CH4 in landfill gas DOC = amount of degradab le organ ic carbon (Gg C/Gg MSW) DOCF = fract ion of DOC decomposes Q = m ethane emissions (Gg/year) MSWT= total MSW generated (Gg/year) MSWF = fraction of MSW landfilled k = react ion constant (year-1) T= inventory year for w hich emissions are calcu lated x = year in which waste was landfilled S = start year of in ventory calculation R = recovered m ethane (in Gg/year) OX= oxidat ion factor (fract ion) First order decay model (the IPCC-2006 revised equation). It takes into account the rates of w aste degradation and methane generat ion over t ime. Based on waste landfilled and degradable organ ic fraction. Emissions est im ations produced by the model will allow countries to assess the im pacts of d ifferen t waste m anagem ent and emission mitigation practices. It was basically developed for the European count ries. LandGEM (US-EPA, 2001) QCH4 ¼ P n i¼1 P 1 j¼0:1 kL0ðMi=10Þðe ktij Þ where, QCH4 = estim ated m ethane generation flow rate (m 3/year) L0 = m ethane generat ion poten tial (m 3/tonne) Mi = m ass of solid waste disposed in the ith year (tonne) tij = age of the jth section of waste mass disposed in the ith year (decim al years) i = on e year time increm ent n = (year of the calcu lat ion) (in itia l year of waste acceptance) j = 0.1 year increment k = m ethane generation rat e (year 1) Microsoft Excel-based software applicat ion developed by EPA that uses a first-order decay rate equation to calcu lat e estimates for methane and LFG generation. It assum es that methane generat ion is at its peak shortly after in itia l w aste placement and rate of methane generation then decreases exponentially as organic mater ial is consum ed by bacteria. Based on US waste composit ion . Inaccurate assum pt ions about variables such as organic conten t, fu tu re d isposal rates, site closure dates and collect ion efficiencies can resu lt in large errors. TNO-m odel (Oonk and Boom , 1995) at ¼ 11:87AC0 k1 e k1 t where, at = landfill gas product ion at a given time (m 3/year) 1= dissim ilation factor 0.58 1.87 = conversion factor A= am ount of waste (in tonne) C0 = amount of organ ic carbon in waste (kg of C/ tonne of waste) k1 = degradation rate constant 0.094 (year 1) t = time elapsed since depositing (year) First order model w hose parameters were based on real data of landfill gas generation . Direct estim at ion of methane or landfill gas. Information on organic com ponent of waste com ponents are not available. The model is validated by emission measurem ent at 20 landfills across Netherlands and was found that the mean relative error between observed and calculated landfill gas w as 22%. It is one of the few m odel, where the models data were validated with the actual site landfill gas measurement. GasSim (Gregory et al., 2003) Not available GasSim is a first order m ult iphase m odel, w hich quantifies all landfill gas relat ed prob lems of a lan dfi ll, ranging from m ethane emissions, effects of ut ilisation of landfill gas on local air quality to landfill gas m igration via the subsoil to adjacen t bu ild ings. GasSim is based on UK w aste stat istics. Calculation modules in the program are protected . Afvalzorg (Scharff and Jacobs, 2006) at ¼ 1 P 3 i¼1 cAC0;ik1;ie k1; i t where, at = landfill gas product ion at a given time (m 3/year) 1= dissim ilation factor i = waste fraction with degradation rate k1 ,i c = conversion factor (m 3 of LFG/kg of org. matter degraded) A= am ount of waste (tonne) C0 = amount of organ ic matter (kg of org. m at ter /tonne of waste) k1,i = degradation rat e constan t of fraction i (year -1) t = time elapsed since depositing (year) In th is m ultiphase m odel, eight w aste categories and three fract ions are dist inguished . For each fraction LFG production is calcu lat ed separately. Based on Netherlands waste characteristics. Organic m att er or carbon conten t data were not available for all waste categories. EPER France (Scharff and Jacobs, 2006) FECH4 ¼ P xFE0 ð P 1 ;2;3 Ai pi ki e ki t Þ where, FECH4 = annual methane produ ction (m3/year) FE0 = methane generation potential (m 3/tonne of waste) Ai = norm alisation factor pi = w aste fraction w ith degradat ion rat e ki ki = degradation rate of fraction i (year 1) t = age of waste (year) It gives tw o approaches, either of w hich can be used for the estimat ion of methane generat ion from landfill. The second approach has been explained in this paper based on ADEME model. The left and righ t hand side of the equation is not d imensionally m atched. However, a normalisat ion factor is included in the m odel equation, but it seems it is missing from the spreadsheets. The model m ent ions three waste category and different k values for each category. (continued on next page) A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx 11 Please cite this article in press as: Kum ar, A., Sam adder,S.R. A review on tech nological op tions of w aste to energy for effective m anagement of m u nicipal solid w aste. Waste Managem ent (2017), http://dx.doi.org/10.1016 /j.w asm an.2017.08.04 6 differen t countr ies has been sum marised in Tab le 8. In most of the studies listed in Table 8 , WTE opt ion w as recom mended as a poten tia l t echnology w ith m in im um environm ent al im pacts. The cost analysis of differen t WTE technologies w as taken from the previously published literatu res (Ouda et al., 2016; Yap and Nixon , 2015; Tolis et al., 2010) and are presented in Tab le 9. The cap ital cost is t he in it ial investm en t cost such as, land acquisit ion , equ ipm en t p rocurement , raw m ateria l requ irem ent ; and the indirect costs include t he cost of p lann ing, con tractua l support, an d techn ical & financial services throughou t the development st age. Th e operation cost is t he daily running cost such as labour an d m ain tenance cost . The cap ital cost for a WTE plan t depends on t he quality of w aste to be processed , t he technology em ployed an d its loca tion. The average lifet im e of a WTE facility has been considered as 30 years. The range of cost as given in Table 9 is valid for bot h developed and develop ing coun tries. The low er va lue of a range of cost rep resents the cost in deve lop ing count ries (such as India) and t he higher va lue represen ts the cost in developed coun- t ries (such as UK) (Yap and Nixon, 2015). The cost s as show n in t he Table 9 are the estim ated costs, as the actua l cost depends on var- ious ot her factors such as, govern m en tal incen t ives, raw m ater ial an d the availability of skilled labour (Ouda et al., 2016). 6. Environm ental and heal t h im pacts MSW incineration m ay resu lt in air pollu t ion (due to the em is- sions of SOx, NOx, COx, d ioxin and fu rans), soil and w ater pollution (due to the presence of heavy m etals in the fly ash and bottom Table 7 (continued) Models Form ula Model descrip tion Rem arks EPER Germ any (Sch arff and Jacobs, 2006) Me ¼ M BDC BDCf F D C wh ere, Me = am ount of d iffuse methane emission (tonne/year) M = annual am ount of landfilled w aste (tonne/year) BDC = prop. of biodegradable C (tonne of C/tonne of waste), 0.15 BDCf = proportion of biodegradable C converted, 0.5 F = calcu lation factor of carbon converted into CH4, 1.33 D = collection efficiency (for, active degassing, D = 0.4, for no recovery, D = 0.9, and for active LFG recovery and cover , D = 0.1) C= methane concent ration , 50% It is a zero order model that takes unconditioned resident ial and com mercial waste. For the em ission estimate purpose, coarse household w aste, household w aste and commercial waste w ere considered. The model is useful for the estimation of large fluctuation of m ethane emissions. It is basically used in Germany. Table 8 Observation s on the case studies of available WTE options. References Study area Description of the study Critical observation Abila (2014) Nigeria Review of opt ions for deriving energy and im proving mater ial recovery from MSW Due to the high percentage of biodegradable conten t in Nigeria, biogas product ion from MSW is the best option. Paleologos et al. (2016) UAE Role of recycling and in cineration for effective managem ent of w aste of h igh incom e countries by energy and m aterial recovery. Recycling and incineration appeared to be most feasible w aste managem ent solu tion , because the Abu Dhabi and Dubai, the two most urban ised and populated cities were located in the coastal areas of UAE, w here landfilling is not advisable due to lack of appropriate hydrogeological condition. Korai et al. (2016) Hyderabad, Pakistan Differen t t reatment options have been evaluated using pow er generat ion poten tial for possible w aste to energy recovery. Maximum power generating potential w as show n by biochemical and thermochemical m ethods respectively, but again the single strat egy is not sufficien t to provide the solut ion . Jesw ani and Azapagic (2016) UK Identification of environm entally sustainable WTE option amongst incineration and landfi ll gas recovery using Life Cycle Assessm ent. From energy recovery perspective, incin eration has lesser impact than landfilling w ith gas recovery. In current scenario, divert ing all the MSW intended for landfilling to incinerat ion with energy recovery, it could meet 2.3%of UK’s electr icity dem and and would save 2–2.6 million tonnes of GHG emissions per year. Fruergaard and Astrup (2011) Denmark Evaluat ion of energy recovery and em ission potent ial of incineration and AD for source separat ed organ ic w aste and m ixed high calor ific waste using LCA. Waste incineration w ith energy recovery proved to be an environmentally sust ainable solu tion for overall waste managem ent, whereas AD is a least preferable based on Danish condition. Psom opoulos et al. (2009) USA Current status of WTE facilities in USAw ith regard to GHG, dioxin and mercu ry em issions, energy production and land conservation. The emission of toxic and dangerous substances from WTE facilit ies have been sign ificant ly reduced in the last decade with the advancement of technologies. Also, the WTE facilities in USA have quite lesser emission as com pared to other power production facilit ies from con ventional fuel. Cheng and Hu (2010) China Environmental and economic im pact of w aste incineration technology in China. WTE incinerat ion is expected to have a greater cont ribution in fu ture renewable energy resources along w ith the solu tions to waste relat ed problems of developing countries. Noor et al. (2013) Malaysia Estim at ion of energy potential of landfill gas for possible m ethan e recovery. Methane recovery from landfill gas will not only reduce the burden of GHG from the environm ent, but also provides a cleaner fu el, which will act as an alternative to fossil fuels. Curry and Pillay (2012) Montreal, Canada Feasibility analysis of AD process by estim at ion of biogas product ion poten tial of urban food wastes using ultim ate analysis, m olecu lar formula analysis, com puter sim ulation techniques and a lit erature review. The decentralised or sm all-scale AD un it is an ideal solution for the generat ed organic waste of an urban centres, which will save the waste transportation cost along w ith reduction in the amount of waste sen t for landfilling. Table 9 Cost comparison of WTE technologies. WTE technologies Capital cost (US$/tonne of MSW/year) Operational cost (US$/ tonne of MSW/year) Incineration 400–700 40–70 Pyrolysis 400–700 50–80 Gasification 250–850 45–85 Anaerobic digestion 50–350 5–35 Landfilling w ith Gas recovery 10–30 1–3 12 A. Kumar, S.R. Samadder / Waste Management xxx (2017) xxx–xxx Please cit e this article in press as: Ku m ar, A., Sam add er, S.R. A review on tech nological options of wast e to energy for e ffective managem ent of m u n icipal solid waste. Waste Managem en t (2017), h ttp://dx.doi.org/10.1016/j.w asm an.2017.08.046 ash ). Bu t t here has been a sign ifican t developm ent in the pollu t ion con trol techn ologies and energy recovery system s for incinerat ion, wh ich m ade it an at t ractive MSWM option (Dam gaard et al., 2010). The use of air pollut ion cont rol equ ipm ent in incineration plan ts is main ly to captu re part icu late m atte rs, n itrogen oxides, dioxin and furans for m in im isat ion of the en vironm en tal im pact s than the convent ional coal based the rm al pow er plan ts (Liam sanguan and Gheewala, 2007). Num erous studies reported the perceived health risk of w aste incinera tion plan ts. Even t he developed coun tries (such as UK) are facing public opposit ion due to perce ived healt h risk due to em issions from incinerat ion p lan ts (Nixon
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