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Comparison of Color Difference Methods for multi-angle Application Konrad Lex, BYK-Gardner GmbH 10th BYK-Gardner User Meeting, Innsbruck Austria – April 2013 Page 2, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Effect Coatings 70% of todays automotive finishes are effect coatings • Pearlescent coatings result in a more spectacular color effect: Color Flop • Metallic coatings accentuate the curved profile: Light – Dark Flop • Effect finishes with special glitter effect (XirallicsTM) Page 3, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application L* = 100 +a* -a* +b* -b* Blue Red Green Yellow L* = + 58,12 a* = + 30,41 b* = + 36,26 L* = 0 CIELab - System: L*a*b*- Coordinates Page 4, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application E* = √ (L*)2 + (a*)2 + (b*)2 = Sample - Standard - + - + - + L* a* b* Sample E* L* b* a* Standard CIELab - System: Color Difference L*, a*, b* Page 5, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application L* = 100 +a* -a* +b* -b* 270° 0° 180° 90° L* = + 58,12 C* = + 47,32 h° = 50° L* = 0 h° C* CIELab - System: L*C*h°- Coordinates Page 6, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application +a* Sample Standard C*ab h°ab h°ab C*ab +H* +b* CIELab - System: Color Differences C* und H* E* = √ (L*)2 + (C*)2 + (H*)2 -C* Page 7, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application CIELab - System: Chromatic – Non Chromatic + b* - b* + a* - a* B P C* H* Non-chromatic colors: C* < 10 Use L*a*b* Chromatic colors: C* > 10 Use L*C*h° Page 8, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application CIELab - System: Typical Tolerances 0.5 0.5 1.0 45° b* a* L* Metallics 0.5 0.5 1.0 45° Solids 0.5 0.5 1.0 110° 0.5 0.5 1.0 75° 0.7 0.7 1.5 25° 1.0 1.0 2.0 15° -15° 1.0 1.0 2.0 *Measurement of Metallic & Pearlescent Colors Allan Rodrigues, DuPont, 1990 Achromatic Page 9, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application CIELab - System: Typical Tolerances 110° 1.0 1.0 75° 1.0 2.0 1.5 45° 25° 15° -15° H* C* L* 1.0 2.0 1.0 2.0 1.2 2.2 1.5 2.5 1.5 2.5 2.0 3.0 3.0 Chromatic Metallics 1.0 2.0 1.5 45° Solids Page 10, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Color Difference Delta CIE Lab: What causes the problem? Compare to tolerances: dH* is too large! Page 11, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Color Difference CMC – Color Difference Formula Delta E cmc: Page 12, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Color Difference CMC – Color Difference Formula H S c cS lS L • 3-dimensional ellipsoid with axes corresponding to hue, chroma and lightness • Weighting functions (= semi-axis) SL, SC and SH are dependent on color of standard • Factors l and c modify the lengths of relevant semi-axes ( ) 2 1 2 ab 2 ab 2 : CMC * H * C * L E + + = H C L c l S cS lS Page 13, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Color Difference General Color Difference Formula measurement geometry application parameter e.g. batch or production weighting factor tolerance 222 )( )(* )( )(* )( )(* )( + + = bbaaLL w Sg b Sg a Sg L E Achromatic: Chromatic: 222 )( )(* )( )(* )( )(* )( + + = HHCCLL w Sg H Sg C Sg L E g S Sg Page 14, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Color Components Achromatic: Chromatic: )( )(* )( L w Tol L L = )( )(* )( a w Tol a a = )( )(* )( b w Tol b b = )( )(* )( L w Tol L L = )( )(* )( C w Tol C C = )( )(* )( H w Tol H H = L w , a w, bw, Cw, Hw < 1.00 within Tolerance L w , a w, bw, Cw, Hw > 1.00 out of Tolerance Page 15, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Color Difference CMC – Color Difference Formula Delta E cmc: Weighted by dE cmc Tolerances dH* is 31% too large! Page 16, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application How to get Tolerances? Weighted Color Difference Methods E‘DIN E‘BMW Calculation of the weighting factors are measurement geometry dependent Weighting factors independent from measurement geometry ECMC E00 E‘AUDI2000 Weighting factors are dependent on lightness flop and color flop E94 With Lightness Correction There is only one standard, DIN 6175-Part 2 for gonio appearant colors Page 17 BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Silver Metallic Achromatic light metallic Page 18 BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Red Metallic Chromatic medium light metallic Page 19, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Yellow Metallic Chromatic light metallic Page 20, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Solid White Achromatic light solid Page 21, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application How to get Tolerances? Weighted Color Difference Methods E‘DIN E‘BMW Optimized for light metallic finishes Discontinuity between solid and gonioapparent colors Optimized for solid, high chromatic colors ECMC E00 E‘AUDI2000 Applicable for metallic and solid E94 With Lightness Correction Page 22, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Weighted Deltas Unweighted Deltas Weighted Deltas Unweighted Deltas Weighted Deltas Page 23, BYK-Gardner GmbH, Comparison of Color Difference Methods for multi-angle Application Conclusion • All color difference methods with weighting factors are closer to the visual than dE* method because L, a, b, C and H have different visual sensitivities depending on color. • Gonioappearant colors may end up with 5 to 25 different tolerances weighted color componentsmake the life much easier because the tolerances of weighted color components are always 1.00 Thank you for your Attention!
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