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ELV Pbolha (Tcte) Psat Clorofórmio 1 69.36 4-Dioxano 2 15.79 Dados Experimentais T [K] P [kPa] x1 y1 323.15 15.79 0 0 323.15 17.51 0.0932 0.1794 323.15 18.15 0.1248 0.2383 323.15 19.3 0.1757 0.3302 323.15 19.89 0.2 0.3691 323.15 21.37 0.2626 0.4628 323.15 24.95 0.3615 0.6184 323.15 29.82 475 0.7552 323.15 34.8 0.5555 0.8378 323.15 42.1 0.6718 0.9137 323.15 60.38 0.878 0.986 323.15 65.39 0.9398 0.945 323.15 69.35 1 1 T [K] x1 x2 ln γ1 γ1 ln γ2 γ2 P [kPa] y1 323.15 0 1 -0.7958811588 0.4511834954 0 1 15.79 0 0.05 0.95 -0.745351781 0.4745673268 -0.0013068108 0.9986940427 16.6267094777 0.0989852798 0.1 0.9 -0.6948924383 0.4991281322 -0.0054109035 0.9946037091 17.596266035 0.1967435999 0.15 0.85 -0.6445692011 0.5248886149 -0.0126146545 0.9874645768 18.7141969662 0.2918073994 0.2 0.8 -0.5944593797 0.5518608324 -0.0232610428 0.9770074097 19.9969710672 0.3828286515 0.25 0.75 -0.5446536628 0.5800426389 -0.0377406115 0.9629626899 21.4618250135 0.4686432469 0.3 0.7 -0.4952587404 0.6094132071 -0.0564999099 0.9450665696 23.1264908062 0.5483179493 0.35 0.65 -0.4464005399 0.6399274043 -0.0800517971 0.9230685328 25.0087915524 0.6211766623 0.4 0.6 -0.3982282472 0.6715087402 -0.1089881044 0.8967410847 27.1260635235 0.6868058268 0.45 0.55 -0.3509193387 0.7040405404 -0.143995311 0.8658918082 29.4943507554 0.7450414328 Λ 12 2.407 0.5 0.5 -0.3046859271 0.7373549213 -0.1858741048 0.8303781291 32.1273039981 0.7959419399 Λ 21 0.9175 0.55 0.45 -0.2597828328 0.7712190511 -0.2355639984 0.7901250947 35.0346982225 0.8397521844 0.6 0.4 -0.2165179427 0.8053180852 -0.2941745952 0.7451463811 38.2204619777 0.876863222 0.65 0.35 -0.1752656368 0.8392340597 -0.3630256982 0.6955685584 41.6800879868 0.9077722763 0.7 0.3 -0.1364843791 0.8724199481 -0.4436993242 0.641658323 45.3972687977 0.9330458515 0.75 0.25 -0.1007400368 0.9041680528 -0.5381079609 0.5838518786 49.3395773957 0.9532878996 0.8 0.2 -0.0687371928 0.9335719973 -0.6485853091 0.5227848328 53.4529974895 0.9691139023 0.85 0.15 -0.0413617937 0.9594819326 -0.7780086526 0.4593197664 57.6551156858 0.9811309221 0.9 0.1 -0.0197401569 0.9804534043 -0.9299665104 0.394566924 61.8268444821 0.9899231284 0.95 0.05 -0.0053220522 0.9946920849 -1.1089924042 0.3298911907 65.8026999508 0.9960419695 1 0 0 1 -1.3208973009 0.2668957087 69.36 1 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0. 5 0.55000000000000004 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 15.79 16.626709477669703 17.596266034989139 18.714196966243275 19.996971067164964 21.46182501349994 23.12649080623893 25.008791552399437 27.126063523484071 29.494350755390236 32.127303998125498 35.03469822250414 38.220461977741174 41.680087986813959 45.397268797692419 49.33957739566511 53.452997489464046 57.655115685796936 61.826844482146662 65.802699950757997 69.36 0 9.8985279776644342E-2 0.19674359992058685 0.29180739942577838 0.3828286514827885 0.46864324687554704 0.54831794925964783 0.6211766623380417 0.68680582683227354 0.74504143282510582 0.79594193993775841 0.83975218440486765 0.87686322196490074 0.90777227631618096 0.93304585151485131 0.9532878996461428 0.96911390231483863 0.98113092214287789 0.98992312840344587 0.99604196947517432 1 15.79 16.626709477669703 17.596266034989139 18.714196966243275 19.996971067164964 21.46182501349994 23.12649080623893 25.008791552399437 27.126063523484071 29.494350755390236 32.127303998125498 35.03469822250414 38.220461977741174 41.680087986813 959 45.397268797692419 49.33957739566511 53.452997489464046 57.655115685796936 61.826844482146662 65.802699950757997 69.36 ELV Tbolha (Pcte) A B C P 1 atm Comp 1 acetona 4.42448 1312.253 -32.445 P em bar T em K 1.01325 bar Comp 2 methanol 5.20409 1581.341 -33.5 P em bar T em K Experimental T de partida: dados experimentais T (ºC) x1 y1 337.67 64.52 0 0 62.86 0.05 0.108 61.52 0.1 0.193 59.44 0.2 0.327 57.94 0.3 0.435 56.94 0.4 0.516 56.17 0.5 0.592 55.37 0.7 0.728 55.26 0.8 0.798 55.5 0.9 0.888 55.76 0.95 0.941 56.09 1 100 P 101.325 kPa Lei de Raould Modificada erro T (ºC) T(K) x1 x2 ln γ1 γ1 ln γ2 γ2 P1sat P2sat P(kPa) y1 (P-101,325)² 64.5488614019 337.6988614019 0 1 0.623974765 1.8663315479 0 1 133.5331991635 101.3236698221 101.3236698221 0 0.0000017694 62.8737087633 336.0237087633 0.05 0.95 0.5627984723 1.7555785703 0.001566951 1.0015681793 126.4351707337 94.8257160581 101.3240426062 0.1095331723 0.0000009166 61.5023132428 334.6523132428 0.1 0.9 0.5050888032 1.6571326725 0.0062446687 1.0062642073 120.8515402437 89.7682029395 101.3241802017 0.1976497964 0.0000006721 60.36886503 333.51886503 0.15 0.85 0.4507491215 1.5694874821 0.014006282 1.0141048296 116.3871599188 85.7600014442 101.3244154865 0.270420791 0.0000003417 59.4240983257 332.5740983257 0.2 0.8 0.3996943205 1.4913687471 0.0248351605 1.025146122 112.767733907 82.5342964415 101.323425952 0.3319632601 0.0000024776 58.6317763519 331.7817763519 0.25 0.75 0.3518502909 1.421695667 0.0387247362 1.0394843119 109.8023705441 79.9078516454 101.3236072425 0.3851658036 0.0000019398 57.9636974969 331.1136974969 0.3 0.7 0.3071534857 1.3595496235 0.0556784108 1.0572576264 107.3508863075 77.7479101536 101.3243567828 0.4321237115 0.0000004137 57.3981656407 330.5481656407 0.35 0.65 0.2655505738 1.3041488083 0.0757095469 1.0786492316 105.310188404 75.9578850779 101.3247991892 0.4744056266 0.0000000403 56.9186804342 330.0686804342 0.4 0.6 0.2269981789 1.2548275828 0.0988415427 1.103891366 103.6044842725 74.4673548914 101.3246278934 0.5132247402 0.0000001385 56.5128698317 329.6628698317 0.45 0.55 0.1914627024 1.2110196642 0.1251079915 1.1332708301 102.1782651069 73.2250544151 101.3240497435 0.5495531404 0.000000903 Λ 12 0.732 56.171714369 329.321714369 0.5 0.5 0.1589202265 1.1722444289 0.1545529283 1.167136051 100.9915165305 72.1941523952 101.3235702742 0.5842013971 0.0000020441 Λ 21 0.688 55.8889839739 329.0389839739 0.55 0.45 0.1293564987 1.1380957816 0.1872311671 1.2059060186 100.0164211569 71.3490361118 101.3236512838 0.6178769326 0.000001819 55.6608450967 328.8108450967 0.6 0.4 0.1027669994 1.10823316 0.223208734 1.2500814811 99.2351324113 70.6731565925 101.3242803332 0.6512298771 0.0000005179 55.4857047385 328.6357047385 0.65 0.35 0.0791570931 1.0823743423 0.2625634045 1.3002589079 98.6386784506 70.1579363461 101.324802154 0.6848923668 0.0000000391 55.3644105609 328.5144105609 0.7 0.3 0.0585422691 1.0602898023 0.3053853511 1.3571478807 98.227293613 69.8029660618 101.3244626449 0.7195160626 0.0000002888 55.3008068062 328.4508068062 0.75 0.25 0.0409484763 1.0417984268 0.3517779148 1.4215927739 98.012125294 69.6174304773 101.3235674833 0.7558128909 0.0000020521 55.3023244941 328.4523244941 0.8 0.2 0.0264125588 1.0267644618 0.4018585115 1.494599849 98.0172551386 69.6218528369 101.3238695222 0.7946055333 0.000001278 55.3800426064 328.5300426064 0.85 0.15 0.0149828027 1.0150956075 0.4557596913 1.5773712432 98.2802341387 69.8486289572 101.3258416887 0.836896664 0.0000007084 55.5488207907 328.6988207907 0.9 0.1 0.0067196046 1.0067422318 0.5136303674 1.6713478011 98.8532919225 70.3432444456 101.3246080463 0.88396893 0.0000001536 55.8336448702 328.9836448702 0.95 0.05 0.0016962758 1.0016977153 0.5756372401 1.7782633467 99.8264532277 71.1845942915 101.3253813577 0.9375354165 0.0000001454 56.2682277677 329.4182277677 1 0 0 1 0.641966441 1.9002138663 101.32612027 72.4845553994 101.32612027 1 0.000001255 Somatório 0.0000199142 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55000000000000004 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 64.548861401869999 62.873708763260993 61.502313242831235 60.368865030007214 59.424098325659259 58.631776351942676 57.963697496883469 57.39816564072072 56.918680434215844 56.512869831682622 56.171714368995708 55.88898397391506 55.66084509670884 55.48570 4738531524 55.364410560913427 55.300806806189087 55.302324494052755 55.380042606368647 55.548820790680907 55.833644870241926 56.2682277677211 0 0.10953317226983128 0.197649796390802850.27042079102089517 0.33196326012347788 0.3851658036046578 0.43212371151362799 0.47440562657176572 0.51322474018925157 0.54955314039983461 0.58420139706044993 0.61787693258646181 0.65122987708937563 0.68489236679246535 0.71951606259632372 0.75581289091594683 0.79460553326766825 0.83689666398863605 0.8839689299 6565224 0.9375354165056653 1 64.548861401869999 62.873708763260993 61.502313242831235 60.368865030007214 59.424098325659259 58.631776351942676 57.963697496883469 57.39816564072072 56.918680434215844 56.512869831682622 56.171714368995708 55.88898397391506 55.66084509670884 55.485704738531524 55.364410560913427 55.300806806189087 55.302324494052755 55.380042606368647 55.548820790680907 55.833644870241926 56.2682277677211
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