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Capa MASTER PLANILHA - TCC ÁCIDO ACÉTICO Balanço de massa global Balanço de energia global PFR CSTR TANCAGEM Destiladoras Análise econômica Tratamento Ambiental BM e BE Processo BALANÇO DE ENERGIA TROCAS TÉRMICAS REAGENTE LIMITANTE Para gás GASES LIQUIDOS Legenda A B C D E Tmin Tmax Legenda A B C D tmin tmax Nitrogênio 29.342 -3.5395E-03 1.0076E-05 -4.3116E-09 2.5935E-13 50 1500 Nitrogênio 76.452 -3.5226E-01 -2.6690E-03 5.0057E-05 64 120 Oxigênio 29.526 -8.8999E-03 3.8083E-05 -3.2629E-08 8.8607E-12 50 1500 Oxigênio 46.432 3.9506E-01 -7.0522E-03 3.9897E-05 54 147 Para líquido Água 33.933 -8.4186E-03 2.9906E-05 -1.7825E-08 3.6934E-12 100 1500 Água 92.053 -3.9953E-02 -2.1103E-04 5.3469E-07 273 615 Acetaldeído 34.140 0.04002 1.5634E+00 -1.644E-04 4.7248E-07 100 1500 Acetaldeído 31.386 0.4485 -1.6607E-03 2.7000E-06 151 415 Etanol 27.091 0.11055 1.0957E-04 -1.505E-07 4.6601E-11 100 1500 Etanol 59.342 0.3636 -1.2164E-03 1.8030E-06 160 465 Monóxido de Carbono 29.556 -0.00658 2.0130E-05 -1.223E-08 2.2617E-12 60 1500 Monóxido de Carbono -19.312 2.5072 -2.8970E-02 1.2745E-04 69 120 Dióxido de carbono 27.437 0.04232 -1.9555E-05 3.997E-09 -2.9872E-13 50 5000 Dióxido de carbono -338.956 5.2796 -2.3279E-02 3.5980E-05 218 274 Entalpia da correnteE Metano 34.942 -0.03996 1.9184E-04 -1.530E-07 3.9321E-11 50 1500 Metano -0.018 1.1982 -9.8722E-03 3.1670E-05 92 172 Ácido Acético 34.85 0.03763 2.8311E-04 -3.077E-07 9.2646E-11 50 1500 Ácido Acético -18.944 1.0971 -2.8921E-03 2.9275E-06 291 533 Acetato de metila -22.287 0.48275 -4.6631E-04 2.329E-07 -4.3094E-11 298 1200 Acetato de metila 76.129 0.4328 -1.3694E-03 2.1850E-06 185 418 Formaldeído 34.428 -0.02978 1.5104E-04 -1.273E-07 3.3887E-11 50 1500 Formaldeído 44.222 0.3986 -1.5358E-03 3.0329E-06 191 331 Acetato de manganês Acetato de manganês Metanoato de metila 5.795 0.25072 -1.7515E-04 6.057E-08 -8.1015E-12 250 1500 Metanoato de metila 63.652 0.3516 -1.1409E-03 1.9023E-06 184 396 Ácido fórmico 31.745 0.00742 1.8791E-04 -1.947E-07 5.7613E-11 50 1500 Ácido fórmico -16.11 0.8723 -2.3665E-03 2.4454E-06 283 522 TQ-101 Tanque Etanol 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H E-101 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Misturador de linha 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H E-103 Aquecimento pré reação 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 0 0 25 25 0 0 Nitrogênio 0 0 25 89 0 -5684753143.41687 Nitrogênio 3434.81256 0.7532906584 89 89 0 0 Nitrogênio 3434.81256 0.7532906584 89 186.25 9754060.9822085 21506095608760.4 Oxigênio 0 0 298.15 295.15 0 Oxigênio 0 0 298.15 362.15 0 Oxigênio 913.05144 0.2002418206 362.15 362.15 0 Oxigênio 913.05144 0.2002418206 362.15 459.4 2593321.00692658 Água 10.59 0.0499811214 0 Água 10.59 0.0499811214 22842.7355085669 Água 10.59 0.0023224988 0 Água 10.59 0.0023224988 34618.1913752458 Acetaldeído 0 0 Acetaldeído 0 0 0 Acetaldeído 0 0 0 Acetaldeído 0 0 0 Etanol 201.29 0.9500188786 0 Etanol 201.29 0.9500188786 396376.954249261 Etanol 201.29 0.0441450222 0 Etanol 201.29 0.0441450222 641646.992900147 Total 211.88 1 0 Total 211.88 1 419219.689757828 Total 4559.744 1 0 Total 4559.744 1 13023647.1734105 B-101 Soprador Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H E-102 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 3434.81256 0.79 25 25 0 0 Nitrogênio 3434.81256 0.79 25 89 6428256.96078294 -2265032730271.28 Oxigênio 913.05144 0.21 298.15 298.15 0 Oxigênio 913.05144 0.21 298.15 362.15 1711633.43378522 Água 0 0 Água 0 0 0 Acetaldeído 0 0 0 Acetaldeído 0 0 0 Etanol 0 0 0 Etanol 0 0 0 Total 4347.864 1 0 Total 4347.864 1 8139890.39456816 R-101 Reator de Acetal Produtos 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H E-104 1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 3434.81256 0.7719650574 186.25 202.48 1634176.54420634 0 Nitrogênio 3434.81256 0.7391712793 202.48 30 -17626609.1122404 -449612954434993 Oxigênio 814 0.1829443516 459.4 475.645 389164.049145491 Oxigênio 814 0.1751727091 475.63 303.15 -4312290.54671004 Água 197 0.0442752301 108284.224786323 Água 197 0.042394378 -1188539.47997852 Acetaldeído 197 0.0442752301 548558.803911322 Acetaldeído 197 0.042394378 -537832662.08281 Etanol 4.03 0.0009057319 1831.2345071479 Etanol 4.03 0.0008672555 -13099.0694232646 Total 4646.84256 1.044365601 2682014.85655662 Total 4646.84256 1 -560973200.291162 Líquido (Alimentação TA-101) 5 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H 3atm Água 6500 1 30 5 -15032283.3836263 -2442746049839.27 Total 6500 1 303.15 278.15 -15032283.3836263 5 atm CONDENSADOR PARCIAL CW-101 Gás (Alimentação TA-101) 2 atm COLUNA ABSORÇÃO TA-101 Q5 - Gás (Vai para tratamento) Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Componente Vazão molar kmol/h Fração molar T entrada T saida Cp ∆H Nitrogênio 3434.81256 0.7719650574 30 -5 -3535396.12315385 -1381849035349.88 Nitrogênio 3434.447 0.8064304065 -5 5.2 1027269.98183719 -55443303230.2312 Oxigênio 814 0.1829443516 303.15 268.15 -846086.082965626 Oxigênio 813.825 0.1910913826 268.15 278.35 244729.881657421 Água 8.968 0.0020155343 -10701.0258685618 Água 9.35195 0.0021958984 3232.8680681387 Acetaldeído 189.9725 0.042695818 -4479668.99313986 Acetaldeído 1.20 0.0002823125 1085.5822500797 Etanol 1.6874 0.0003792387 -1488.4488130899 Etanol 0 0 0 Total 4449.44046 1 -8873340.67394099 Total 4258.82627 1 1276318.31381283 Líquido (Mistura com fundo da absorvedora) 2 atm Líquido (Mistura com Fundo do condensador) Componente Vazão molar kmol/h Fração molar T saída T saída Cp ∆H Componente Vazão molar kmol/h Fração molar T entrada T saída P (atm) Cp ∆H Nitrogênio 0 0 30 -5 0 -4284829919.12101 Nitrogênio 0.36556 0.0000546377 5.2 10.1 4.1 135.3626510911 -97016194669.9402 Oxigênio 0 0 303.15 268.15 0 Oxigênio 0.175 0.000026156 278.35 283.25 40.5980196704 Água 188.0322 0.952098892 -609809.042290871 Água 6499.61605 0.9714528241 2928544.12849839 Acetaldeído 7.0275 0.0355836658 -5615.2415288047 Acetaldeído 188.77018 0.028214178 30035.4621735875 Etanol 2.4326 0.0123174422 -4466.7801604693 Etanol 1.6874 0.0002522041 497.9401559999 Total 197.4923 1 -619891.063980145 Total 6690.61419 1 2959253.49149873 MISTURADOR DE CORRENTES (Mistura fundo da absorvedora com fundo do condensador) 3 atm Componente Vazão molar kmol/h Fração molar T saída P (atm) Cp ∆H Nitrogênio 0.36556 0.0000530712 9.7 3 ERROR:#NAME? ? Oxigênio 0.175 0.0000254061 282.85 ERROR:#NAME? Água 6687.64825 0.970897918 ERROR:#NAME? Acetaldeído 195.79768 0.0284254723 ERROR:#NAME? Etanol 4.12 0.0005981324 ERROR:#NAME? Total 6888.10649 1 ERROR:#NAME? E-105 Aquecer para alimentar o flash Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 0.36556 0.0000530712 9.7 131 2852.646696277 -61270450586336.2 Oxigênio 0.175 0.0000254061 282.85 404.15 1137.9250922896 Água 6687.64825 0.970897918 72062708.7472786 Acetaldeído 195.79768 0.0284254723 1226678.44334565 Etanol 4.12 0.0005981324 38097.2502187976 Total 6888.10649 1 73331475.0126316 T-101 Destilação do AcetaldeídoTOPO -> Vai para E-107 - gas ? Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 0.36556 0.0020629976 50 24.3 -276.1132383612 -7815049456.4055 Oxigênio 0.175 0.0009875932 323.15 297.45 -133.3458712358 Água 0.312 0.0017607376 -273.0091936803 TANQUE FLASH Gás LIQUIDO Acetaldeído 176.31 0.9950007466 -1715380.02375014 Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H E-106 Refriar para alimentar destilação Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Etanol 0.0333 0.0001879249 -21.9902078552 Nitrogênio 0.36556 0.0001619281 131 97.6 -359.0250845038 -469132786892.903 Nitrogênio 0.36556 0.0001619281 97.6 50 -1417.6375830708 -1000567287182.31 Total 177.19846 1 -1716084.48226127 Oxigênio 0.175 0.0000775179 404.15 370.75 -173.5327647323 Oxigênio 0.175 0.0000775179 370.75 323.15 -255.1283230397 Água 2065.771 0.9150521741 -2351745.86929375 Água 2065.771 0.9150521741 -9128047.07281177 Acetaldeído 187.7858 0.0831814391 -3866566.52905676 Acetaldeído 187.7858 0.0831814391 -173265.346582946 Etanol 3.447137 0.0015269409 -2911.3997906116 Etanol 3.447137 0.0015269409 -8158.4874930819 FUNDO -> DESCARTE/TRATAMENTO Total 2257.544497 1 -6221756.35599035 Total 2257.544497 1 -9311143.6727939 Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 0 0 50 98 0 -903723808108.033 Oxigênio 0 0 323.15 371.15 0 Água 2065.459 0.9928439612 9016654.52843158 Líquido -> DESCARTE/TRATAMENTO Acetaldeído 11.4732 0.005515044 22551.6954857472 Componente Vazão molar kmol/h Fração molar T saída T saída Cp ∆H Etanol 3.413837 0.0016409948 11008.9810178415 Nitrogênio 0 0 131 97.6 0 -2212857055521.01 Total 2080.346037 1 9050215.20493517 Oxigênio 0 0 404.15 370.75 0 Água 4621.87725 0.9981244732 -14300401.8548433 Acetaldeído 8.0119 0.0017302176 -6222.3912409992 Etanol 0.672863 0.0001453091 -1186.6320066907 Total 4630.561993 1 -14307810.878091 GÁS -> TRATAMENTO Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Nitrogênio 1260.22 0.7772032319 24.3 60 1317435.29863354 -159094828570.16 Oxigênio 163.97 0.1011240017 297.45 333.15 171999.81080512 LIQUIDO Acetaldeído 5.2893 0.0032620308 131672.990937821 E-107 Resfriamento Acetal pré reação Componente Vazão molar Fração molar T entrada T saída Cp ∆H R-102 Reator Ácido Acético Monóxido de carbono 38.400 0.0236821471 955937.997847036 Nitrogênio 0.36556 0.0020629976 24.3 9 -441.2578634377 -206262291.090963 Dióxido de Carbono 76.800 0.0473642943 77273.9299014799 Oxigênio 0.175 0.0009875932 297.45 282.15 -114.6606824354 Metano 76.800 0.0473642943 94065.780884605 Água 0.312 0.0017607376 -440.802315351 Total 1621.47 1 2748385.8090096 Acetaldeído 176.3126 0.9950007466 -75054.1537971393 Etanol 0.0333 0.0001879249 -28.7678856029 Total 177.19846 1 -76079.6425439664 LÍQUIDO -> DESTILAÇÃO Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H GAS Água 0.149 0.0002683867 24.3 60 485.4194721138 -10917070600.9341 B-102 Soprador de ar Componente Vazão molar Fração molar T entrada T saída Cp ∆H Ácido Acético 171.02 0.3080503414 297.45 333.15 -3395.3187046908 Nitrogênio 1260.2152980952 0.79 25 25 0 0 Acetato de metila 76.8 0.1383362544 228380.4822097 Oxigênio 334.99394 0.21 298.15 298.15 0 Formaldeído 76.8 0.1383362544 139058.986249838 Água 0 Acetato de manganês 76.8 0.1383362544 0 Acetaldeído 0 Metanoato de metila 76.8 0.1383362544 190453.938191607 Etanol 0 Ácido fórmico 76.8 0.1383362544 -4159.7097192509 Total 1595.2092380952 0 Total 555.169 1 550823.797699317 liquido liquido T-103 Destilação Ácido Acético TOPO ->TRATAMENTO 2 atm T-102 Destilação Ácido Acético TOPO -> TRATAMENTO Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Água 0.124 0.0012257085 105 110.9 67.5074814831 1229823.10968981 Água 0.02184 0.0001000802 60 37 -46.4513495435 -20436558648.4842 Ácido Acético 15.160 0.1492989008 378.15 384.05 -1407.9346667172 Ácido Acético 0 0 333.15 310.15 0 Acetato de metila 7.470 0.073566147 3410.804801947 Acetato de metila 69.33 0.3176995783 -113062.853864342 Formaldeído 0.000 0 0 Formaldeído 76.8 0.3519302987 -69522.2837522771 Acetato de manganês 0.000 0 0 Acetato de manganês 0 0 Metanoato de metila 4.727 0.0465506291 1803.693966659 Metanoato de metila 72.07319 0.3302700428 -98470.0556233949 Ácido fórmico 74.060 0.7293586145 -5926.8782388597 Ácido fórmico 0 0 0 Total 101.541 1 -2052.8066554878 Total 218.22503 1 -281101.644589558 3 atm liquido liquido FUNDO -> DESTILAÇÃO 2 FUNDO (PRODUTO FINAL) 2.1 atm Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Componente Vazão molar kmol/h Fração molar T entrada T saída Cp ∆H Água 0.127 0.0004888063 60 105 520.8563492005 -944160250.1164 Água 0.0027 0.0000170237 105 143.1 9.3814536186 -40364660.3415461 Ácido Acético 171.02 0.6574052053 333.15 378.15 29669.8078662891 Ácido Acético 155.86 0.982707104 378.15 416.25 3544.1465873202 Acetato de metila 7.47 0.0287148689 28569.9791260547 Acetato de metila 0 0 3189.3760287282 Formaldeído 0 0 0 Formaldeído 0 0 0 Acetato de manganês 0 0 Acetato de manganês 0 0 Metanoato de metila 4.72681 0.0181699772 15067.0835650504 Metanoato de metila 0 0 0 Ácido fórmico 76.8 0.2952211424 6825.0704328 Ácido fórmico 2.74 0.0172758724 -63.0688337121 Total 260.144 1 80652.7973393946 Total 158.6027 1 6679.8352359549 Q1 Balanço de massa (INATIVO) Ácido acético Conversão R-101 98.00% 211.8843702377 Produção, toneladas/ano 200,000 Conversão R-102 97.00% Produção, kg/h 23,148.15 Produção, kmol/h 385.48 Balanço de massa - Produção Acetaldeído TQ-101 /Alimentação 1 VS-101 Alimentação 2 M-101 Saída M-101 / Alimentação R-101 Saída R-101/Alimentação 1 CW-101 Componentes MM (kg/kmol) Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Etanol 46.070 201.29 0.950 Danielle: Pureza comercial alcool anidro 9273 201.29 Danielle: Danielle: Corrigido de acordo com simulação 0.044 9273 0.077 4.03 0.001 185 Água 18.015 10.59 0.050 191 10.59 2.32E-03 191 0.002 197 0.042 3554 Oxigênio 16.000 913 0.210 16 913.05 0.200 14609 0.121 814 0.175 13031 Nitrogênio 28.010 3435 0.790 28 3434.81 0.753 96209 0.800 3435 0.739 96209 Acetaldeído 44.050 197 0.042 8689 Total 211.9 1.000 9464 4348 PATRICIA: PATRICIA: Relação Ar:Etanol 21,6 (literatura) 1.000 44 4560 1.000 120,282 4648 1.000 121668 Balanço de massa - Purificação acetaldeído Saída Gás Topo CW-101-101/Alimentação gás TA-101 Saída liq fundo CW-101/ Alimentação TA-102 Alimentação 2 TA-101 /ÁGUA Topo TA-101 gás / descarte Fundo TA-101 líq / Alimentação 2 T-102 Fundo T-102 / Descarte Topo T-102 / tanqueacetaldeido Componentes MM (kg/kmol) Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Etanol 46.070 1.687 3.79E-04 78 4 0.014 182 5.63 0.007 259 Água 18.015 8.968 0.002 162 193 0.675 3483 454.6 1.000 8189.904 202.29 0.237 3644 660 0.995 11883 0.96 0.005 17 Oxigênio 16.000 814 0.183 13031 16.3 0.057 261 831 0.192 13291 Nitrogênio 28.010 3435 0.772 96209 69 0.240 1924 3504 0.808 98133 Acetaldeído 44.050 189.970 PATRICIA: PATRICIA: Rendimento absorvedora = 98% 0.043 8368 4 0.014 174 1.94E+00 4.47E-04 85 193.92 0.227 8542 3.315 0.005 146 190.6005198355 0.995 8396 Total 4450 0.998 117847 286 1.000 6023 454.6 8189.90 4336 1.000 111510 855 0.470 12446 663.0 1.000 12029 191.6 1.000 8413 Balanço de Massa - Produção Ácido Acético Saida tanque / Alimentação 1 R-102 Alimentação 2 R-102 Alimentação 3 R-102 (catalisador) Saida 1 R-102 - Gás / Descarte Saida 2 R-102 - líq - Alim T-103 Componentes MM (kg/kmol) Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Etanol 46.070 Água 18.015 0.958 0.005 17.255 0.0094 0.294 1.70E-01 0.967 0.003 17 Oxigênio 16.000 335.0 PATRICIA: PATRICIA: 90% de excesso deO2 0.174 5360 163.96 0.0930 2623.34 Nitrogênio 28.010 1595 0.905 44678.62 Acetaldeído 44.050 176.3 Danielle: Danielle: Corrigido de acordo com simulacao PATRICIA: PATRICIA: 90% de excesso deO2 0.995 7766.015 1595 0.826 70264 Ácido Acético 60.050 350.50 0.978 21047 Monóxido de carbono 28.010 0.855 4.85E-04 23.95 Dióxido de Carbono 44.010 1.710 9.70E-04 75.26 Metano 16.040 1.710 9.70E-04 27.43 Acetato de metila 74.080 1.710 0.005 127 Formaldeído 30.031 1.710 0.005 51 Acetato de manganês 173.027 0.0227 0.706 3.92E+00 0.023 6.33E-05 4 Metanoato de metila 60.050 1.710 0.005 103 Ácido fórmico 46.030 1.710 0.005 79 Total 191.6 1.000 7783.3 1930 1.000 75623 3.21E-02 PATRICIA: PATRICIA: Relação acetaldeido : catalisador (Literatura) PATRICIA: PATRICIA: Rendimento absorvedora = 98% Danielle: Pureza comercial alcool anidro 1.000 4.09 1763.33 1.000 47429 358.33 1.000 21428 Balanço de massa - Purificação ácido acético Alimentação T-103 Topo T-103 / Descarte Fundo T-103 / Alimentação T-104 Fundo T-104 / vaso rec cat Topo T-104 / Produto final Componentes MM (kg/kmol) Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Vazão molar (kmol/h) Fração molar Vazão mássica (kg/h) Fração mássica Etanol 46.070 Água 18.015 0.967 0.003 17.425 0.967 0.003 17.42 2.73 0.987 4.92E+01 1.744 0.005 31.4 Oxigênio 16.000 Nitrogênio 28.010 Acetaldeído 44.050 Ácido Acético 60.050 350.496 0.978 21047.273 346.99 0.987 20836.80 0.0138 0.005 8.30E-01 346.99 0.995 20836.8 Monóxido de carbono 28.010 Dióxido de Carbono 44.010 Metano 16.040 Acetato de metila 74.080 1.710 0.005 126.685 1.710 0.250 127 Formaldeído 30.031 1.710 0.005 51.356 1.710 0.250 51 Acetato de manganês 173.027 0.023 0.000 3.922 0.0227 6.45E-05 3.92 2.27E-02 0.0082 3.92E+00 Metanoato de metila 60.050 1.710 0.005 102.692 1.710 0.250 103 Ácido fórmico 46.030 1.710 0.005 78.716 1.710 0.250 79 Total 358.33 1.000 21428.1 6.84 1.000 359 351.49 0.990 20858 2.77 1.000 53.9 348.72 20,868.2 Vazão cat 0.0069353338 produz 16.6527893422 subprodutos 1 mol 100 mol ác perac reagido x 77.1 fração molar 0.01 100% eficiencia x = 0.0321095898 x 97% x = 0.0097 CO 0.005 100% X 97% x = 0.00485 Tubulações e bombas GÁS BOMBA Densidade, kg/m³ 774.61 PERDA DE CARGA EM TUBULAÇÕES Material do tubo Rugosidade - ε Vazão, m³/h 13.0 Constantes Memória de cálculo (mm) g, m/s² 9.81 A 8.006 TRECHO T-101 A R-102 Cobre, chumbo, bronze e alumínio 0,001 - 0,002 head, bomba 14.8 B 1600.017 Fluido: Ácido acético Tubos plásticos e PVC 0,0015 - 0,007 h, sucção 0.94 C 291.809 Corrente: Resina epoxi, ester vinílica ou isoftálica 0.005 h, descarga 5.53 Estado físico: Gás Aço inoxidável 0.015 h, válvula 9.07 Trocador E-107 Material da linha: Aço carbono - SCH 40 Aço carbono comercial 0,045 - 0,090 h, trocador 1.3 Temperatura, K 416.25 Aço sem costura 0.015 Propriedades do fluido Características da linha Aço soldado 0.046 P1, Pa 101325 Densidade (kg/m3) : 1.28 Comprimento equivalente (m) : 22.5 Aço galvanizado 0.15 P2, Pa 101325 Viscosidade (cP) : 0.0119 Rugosidade (ε, m) : 0.045 Kika de Freitas: Ver tabela ao lado Aço enferrujado 0,15 - 4 v1, m/s 0.90 mm (kg/kmol): 44.05 Rugosidade relativa (ε/D): 1.8E-04 Ferro fundido novo 0,25 - 0,8 v2, m/s 1.67 Dados de processo Ferro fundido desgastado 0,8 - 1,5 P vapor, Pa 117172.05 Vazão de vapor (kmol/h): 227.5948 Velocidade econômica, m/s 30 Ferro fundido com corrosão 1,5 - 2,5 Z1, m 9.43 Vazão (m3/s) : 2.17 Diâmetro econômico, mm 303.4845511454 Cimento liso 0.3 Z 2, m 7.30 Vazão destilado (kmol/h): 176.31 Diâmetro comercial externo, m 0.27305 Concreto comum 0,3 - 1 Altura suporte, m 1.50 Razão de Refluxo: 0.2950 Diâmetro comercial, polegada 10.00 Concreto grosso 0,3 - 5 Vazão de refluxo (kmol/h): 52.0122 Diâmetro comercial interno, m 0.25451 Madeira aplainada 0,18 - 0,9 NPSH, disponivel 6.4 Velocidade real (m/s): 42.66 Madeira comum 5 Padrão escoamento Válvula - 7 a 10 PSI 68947.33 Considerar 10 PSI No de Reynolds: 1.17E+06 Turbulento delta P valv, Pa 14,761.06 Fator de atrito : 0.014 Gráfico delta P trocador 10000 L equivalente, m 22.5 Constantes cálculo viscosidade gás, cP T, °C 24.3 Perda de carga, kPa 1.35 A B C Viscosidade Critério, perda carga 5.99 Acetaldeído 0.069 0.30246 -0.000042375 0.011863 h fricção, m 106.99 Parâmetros 3500 RPM 1750 RPM Comprimento equivalente Tamanho Parâmetro Qtde Valor unitário Valor total Eficiência Saida 1 7.5 7.5 NPSH Entrada 1 4.5 4.5 Potência Curva 90° 2 3 6 Trecho reto 4.5 - 4.5 Total 22.5 SUCÇÃO VÁLVULA PERDA DE CARGA EM TUBULAÇÕES A B n Tc Densidade Densidade água 1000 Memória de cálculo Acetaldeído 0.28207 0.26004 0.2776 461 774.6072918221 Densidade fluido 774.61 TRECHO T-101 A R-102 Densidade relativa 0.775 Fluido: Ácido acético A B C D Viscosidade Vazão (galões/minuto) 57.2 Corrente: ??? Acetaldeído -6.6171 681.23 0.019979 -0.000025563 2.26E-05 Perda carga, PSI 10 Estado físico: Líquido Material da linha: Aço carbono - SCH 40 CV 15.91 Temperatura, K 297.45 Propriedades do fluido Características da linha Densidade (kg/m3) : 774.61 Comprimento equivalente (m) : 92.5 Diâmetro SCH 40S Viscosidade (cP) : 2.26E-05 Rugosidade (ε, m) : 0.045 Kika de Freitas: Ver tabela ao ladoNominal (pol) Externo (mm) Parede (mm) mm (kg/kmol): 44.05 Rugosidade relativa (ε/D): 7.2E-04 1/8" 10.29 1.73 Dados de processo 1/4" 13.72 2.24 Vazão (m3/s) : 0.0028 Velocidade econômica, m/s 1.5 3/8" 17.15 2.31 Vazão destilado (kmol/h): 176.3126 Diâmetro econômico, mm 48.6219105733 1/2" 21.34 2.77 Razão de Refluxo: 0.2950 Diâmetro comercial externo, m 0.07303 3/4" 26.67 2.87 Vazão de refluxo (kmol/h): 52.0122 Diâmetro comercial, polegada 2.1/2" 1" 33.4 3.38 Vazão de refluxo (m³/s): 0.0008 Diâmetro comercial interno, m 0.06271 2" 60.33 3.91 Velocidade real (m/s): 0.90 2.1/2" 73.03 5.16 Padrão escoamento 3" 88.9 5.49 No de Reynolds: 1.94E+06 Turbulento 4" 114.3 6.02 Fator de atrito : 0.018 Gráfico 8" 219.08 8.18 L equivalente, m 92.5 10" 273.05 9.27 Perda de carga, kPa 7.18 12" 323.85 9.53 Critério, perda carga 7.76 h sucção, m 0.94 Comprimento equivalente Parâmetro Qtde Valor unitário Valor total Saida 2 1.9 3.8 Entrada 2 0.9 1.8 Válvula de controle 1 0.4 0.4 Válvula de bloqueio 3 21 63 Válvula de segurança 1 5.2 5.2 Curva 90° 5 0.8 4 Te 1 4.3 4.3 Trecho reto 1 10 10 Total Total 92.5 DESCARGA PERDA DE CARGA EM TUBULAÇÕES Memória de cálculo TRECHO T-101 A R-102 Fluido: Ácido acético Corrente: ??? Estado físico: Líquido Material da linha: Aço carbono - SCH 40 Temperatura, K 297.45 Propriedades do fluido Características da linha Densidade (kg/m3) : 774.61 Comprimento equivalente (m) : 102.7 Viscosidade (cP) : 2.26E-05 Rugosidade (ε, m) : 0.045 Kika de Freitas: Ver tabela ao lado Kika de Freitas: Ver tabela ao lado mm (kg/kmol): 44.05 Rugosidade relativa (ε/D): 7.5E-04 Dados de processo Vazão (m3/s) : 0.0028 Velocidade econômica, m/s 2.5 Vazão destilado (kmol/h): 176.3126 Diâmetro econômico, mm 37.662 Razão de Refluxo: 0.2950 Diâmetro comercial externo, m 0.06033 Vazão de refluxo (kmol/h): 52.0122 Diâmetro comercial, polegada 2" Vazão de refluxo (m³/s): 0.0008 Diâmetro comercial interno, m 0.05251 Velocidade real (m/s): 1.67 Padrão escoamento No de Reynolds: 3.00E+06 Turbulento Fator de atrito : 0.020 Gráfico L equivalente, m 102.7 Perda de carga, kPa 42.02 Critério, perda carga 40.92 h recalque, m 5.53 Comprimento equivalente Parâmetro Qtde Valor unitário Valor total Saida 2 1.5 3 Entrada 2 0.7 1.4 Válvula de controle 1 0.4 0.4 Válvula de bloqueio 3 17.4 52.2 Válvula de segurança 1 4.2 4.2 Curva 90° 5 0.6 3 Te 1 3.5 3.5 Trecho reto 1 35 35 Total Total 102.7 Dimensionamento PFR Estequiometria: Etanol + 1/2 Oxigênio = Acetaldeido + Água 0.001 0.000001 100000 Entalpias de formação padrão a 298K Inerte A B C D Tabela - viscosidade dinâmica Composto Coeficiente Estequiométrico ΔH° (J/mol) Coef esteq 0 -1 -0.5 1 1 µi N2 O2 H2O ETOH ACETAL Nitrogênio 0 0 Composto Nitrogênio Etanol Oxigênio Água Acetaldeído C1 0.0000007632 0.0000008038 0.0000026986 0.0000001061 0.0000001222 Oxigênio -0.5 0 A 3.280 3.518 3.639 3.470 1.693 C2 0.58823 0.60478 0.498 0.8066 0.787 Água 1 -241,818 B 5.930E-04 2.0001E-02 5.06E-04 1.450E-03 1.798E-02 C3 67.75 70.3 1257.7 52.7 77 Etanol -1 -235,100 C 0 -6.002E-06 0 0 -6.158E-06 C4 0 0 -19570 0 0 Acetaldeído 1 -166,190 D 4.0E+03 0 -2.27E+04 1.21E+04 0 C5 80 80 373 200 294 C6 1500 1500 1073 1100 1000 ΔH°reação -172,908 J/mol Reação Exotérmica Equações modelo - adiabático e não isotérmico TR 298.15 Calculo espessura da parede do tubo R 21.6 Relação molar P0 101325 P, psi 14.6959 T 273.15 Kelvin T0 453.15 Dinterno, in 1.016002032 P 1 atm Massa catalisador 21,854.51 kg S, kgf/in² 6000.01 R 0.08206 L. atm/mol.K Volume catalisador 23 m³ E 1 R 8.314 m³.Pa/mol.K ρ aparente do leito 1429 kg/m³ Y 0.4 R 1.98721 cal/kmol ρ particula catalisador 930 kg/m³ A, in 0.07874 ρ do leito catalitico 2306 kg/m³ t min, pol 0.079983035 Ko (1) 1.70E+07 L reagente/min.gcat Porosidade leito 0.38 D exte 0.05 Ea (1) 17,356.98 cal/kmol.K Diâmetro externo tubo 0.05 m t min, mm 2.03 gc 1 Ko (2) 1.06E+09 L reagente/min.gcat Diâmetro interno tubo 0.04 m T Ka Ea (2) 23,132.98 cal/kmol.K Diâmetro particula 0.002 m 293 14.76 AST 1.26E-03 m² 300 14.89 Ko (3) 0.00 1/atm G 9.56E+07 kg/h.m² 350 15.79 Ea (3) 10,094.11 cal/kmol.K G 2.65E+04 kg/s.m² 400 16.61 FA0 (Etanol) 201.29 kmol/h 500 18.28 Ko (4) 1.80E+12 L reagente/min.gcat FB0 (Oxigênio) 913.05 kmol/h 600 19.77 Ea (4) 24,973.26 cal/kmol.K FI0 (Nitrogênio) 3434.81 kmol/h 700 21.21 MMA (Etanol) 46.07 kg/kmol 800 22.59 MMB (Oxigênio) 16.00 kg/kmol 900 23.99 MMI (Nitrogênio) 28.01 kg/kmol 1000 25.33 µm Variável de T Pa.s EA 0.3333333333 Fator DW 8.92 L 0.05 1 TUBO xa*ΔCP Pressões parciais (pa) Entalpia de reação na temperatura T TETA i. Cp,i Constantes cinéticas µm Condutividade aço Condutividade ar Coef interno TC Velocidade (m/s) Reynolds Coefi de TC CP, I n Z Conversão f(xa) ra Temperatura f(T) Pressão f(P) Nitrogênio Oxigênio Água Etanol Acetaldeído Oxigênio Agua Etanol Acetaldeido Oxigênio Nitrogênio Etanol C etanol (kmol/L) k1 k2 k3 k4 Nitrogênio Oxigênio Etanol Kaço K ar h v Nre u Oxigênio Agua Etanol Acetaldeido Nitrogênio 0 0 0.0000 5.01E-01 5.62E-02 453.150 11.41 101,325 -1.07E+00 0.00 4.42E-02 0.2007079646 0 0.0442477876 0 6152.0178157404 4524.5853968782 13108.87 9748.96 141.713 506.221 94.355 2.69E-05 1.17E-01 1.19E-02 8.26E-10 2.62E+00 0.1363358146 0.1428889848 0.0195228116 17.397523279 0.0471485272 66.52 0.2389 73.7364600865 66.52 31.2419184619 34.802344 94.3553608997 71.2943513715 29.6659929346 1 0.05 0.0251 5.08E-01 5.69E-02 453.720 11.43 101,325 -1.08E+00 -0.10 4.31E-02 0.2000424781 0.0011084902 0.0431147733 0.0011084902 6165.898138615 4546.5378002651 13162.70 9789.64 141.735 506.262 94.424 2.69E-05 1.20E-01 1.23E-02 8.38E-10 2.71E+00 0.1367015893 0.1432731044 0.0195745522 17.4065552869 0.0472119363 66.55 0.2392 73.6317327949 66.55 31.2466272502 34.807989 94.4243959414 71.3531223131 29.6683980642 2 0.10 0.0505 5.14E-01 5.76E-02 454.292 11.44 101,325 -1.09E+00 -0.20 4.20E-02 0.1993691425 0.0022300545 0.0419683956 0.0022300545 6179.8345380292 4568.5115232886 13216.67 9830.42 141.756 506.303 94.494 2.68E-05 1.22E-01 1.27E-02 8.50E-10 2.80E+00 0.1370684407 0.1436583561 0.0196264441 17.4155992709 0.0472754595 66.57 0.2395 73.5271336281 66.57 31.2513347928 34.813647 94.4935079209 71.4119530687 29.6708085435 3 0.15 0.0762 5.20E-01 5.83E-02 454.864 11.46 101,325 -1.10E+00 -0.30 4.08E-02 0.1986884112 0.0033639378 0.0408094265 0.0033639378 6193.8268714603 4590.5067780334 13270.75 9871.30 141.777 506.344 94.563 2.68E-05 1.25E-01 1.31E-02 8.62E-10 2.90E+00 0.1374363727 0.144044744 0.0196784877 17.4246552546 0.047339097 66.59 0.2398 73.4226623574 66.59 31.2560411105 34.819320 94.5626969512 71.4708437075 29.6732243814 4 0.20 0.1021 5.25E-01 5.89E-02 455.437 11.48 101,325 -1.11E+00 -0.40 3.96E-02 0.1980007846 0.0045093062 0.0396387179 0.0045093062 6207.8749960498 4612.5237707016 13324.97 9912.27 141.799 506.385 94.632 2.68E-05 1.28E-01 1.35E-02 8.74E-10 2.99E+00 0.137805389 0.1444322719 0.0197306835 17.4337232602 0.0474028492 66.62 0.2401 73.3183187779 66.62 31.2607462228 34.825006 94.6319631299 71.5297942854 29.6756455864 5 0.25 0.1284 5.30E-01 5.94E-02 456.011 11.50 101,325 -1.12E+00 -0.50 3.85E-02 0.1973068129 0.0056652438 0.0384572066 0.0056652438 6221.978768257 4634.5627012184 13379.31 9953.35 141.820 506.427 94.701 2.67E-05 1.31E-01 1.39E-02 8.86E-10 3.10E+00 0.1381754932 0.1448209438 0.0197830321 17.4428033073 0.0474667165 66.64 0.2404 73.2141027098 66.64 31.2654501481 34.830705 94.7013065381 71.588804844 29.6780721662 6 0.30 0.1549 5.35E-01 5.99E-02 456.586 11.52 101,325 -1.13E+00 -0.61 3.73E-020.196607098 0.0068307477 0.0372659172 0.0068307477 6236.1380435008 4656.6237628238 13433.77 9994.52 141.841 506.468 94.771 2.67E-05 1.34E-01 1.44E-02 8.99E-10 3.20E+00 0.1385466888 0.1452107632 0.019835534 17.4518954135 0.047530699 66.66 0.2407 73.1100139998 66.66 31.2701529039 34.836418 94.7707272389 71.6478754096 29.6805041283 7 0.35 0.1816 5.39E-01 6.04E-02 457.162 11.53 101,325 -1.14E+00 -0.71 3.61E-02 0.1959022959 0.0080047253 0.0360659666 0.0080047253 6250.352675791 4678.707141653 13488.36 10035.80 141.863 506.510 94.840 2.67E-05 1.37E-01 1.48E-02 9.12E-10 3.31E+00 0.1389189794 0.145601734 0.0198881896 17.4609995937 0.0475947971 66.69 0.2410 73.0060525235 66.69 31.274854506 34.842145 94.8402252764 71.7070059923 29.6829414791 8 0.40 0.2086 5.42E-01 6.08E-02 457.738 11.55 101,325 -1.15E+00 -0.82 3.49E-02 0.1951931187 0.0091859903 0.0348585674 0.0091859903 6264.6225173522 4700.8130163082 13543.08 10077.17 141.884 506.551 94.910 2.66E-05 1.40E-01 1.53E-02 9.24E-10 3.42E+00 0.1392923684 0.1459938596 0.0199409994 17.4701158603 0.047659011 66.71 0.2413 72.9022181866 66.71 31.2795549691 34.847886 94.9098006737 71.7661965839 29.6853842247 9 0.45 0.2357 5.45E-01 6.11E-02 458.316 11.57 101,324 -1.17E+00 -0.93 3.36E-02 0.194480337 0.0103732594 0.0336450313 0.0103732594 6278.9474182418 4722.9415574265 13597.93 10118.65 141.905 506.593 94.979 2.66E-05 1.44E-01 1.58E-02 9.38E-10 3.54E+00 0.139666859 0.1463871436 0.0199939638 17.4792442228 0.0477233409 66.73 0.2416 72.798510927 66.73 31.2842543064 34.853640 94.9794534319 71.8254471578 29.6878323702 10 0.50 0.2629 5.47E-01 6.13E-02 458.895 11.59 101,324 -1.18E+00 -1.04 3.24E-02 0.1937647808 0.0115651499 0.0324267715 0.0115651499 6293.3272259657 4745.0929272481 13652.90 10160.22 141.927 506.635 95.049 2.66E-05 1.47E-01 1.63E-02 9.51E-10 3.66E+00 0.1400424543 0.1467815892 0.0200470834 17.4883846875 0.0477877871 66.76 0.2419 72.6949307163 66.76 31.2889525293 34.859408 95.0491835284 71.8847576669 29.69028592 11 0.55 0.2902 5.48E-01 6.15E-02 459.474 11.61 101,324 -1.19E+00 -1.15 3.12E-02 0.1930473415 0.0127601771 0.0312053057 0.0127601771 6307.7617850968 4767.2672791924 13708.00 10201.90 141.948 506.677 95.119 2.65E-05 1.50E-01 1.68E-02 9.64E-10 3.78E+00 0.1404191575 0.1471771996 0.0201003586 17.4975372576 0.0478523497 66.78 0.2422 72.5914775613 66.78 31.2936496478 34.865190 95.1189909159 71.944128043 29.6927448776 12 0.60 0.3176 5.49E-01 6.15E-02 460.055 11.63 101,324 -1.20E+00 -1.26 3.00E-02 0.1923289725 0.0139567528 0.0299822571 0.0139567528 6322.2509368998 4789.4647574483 13763.23 10243.67 141.969 506.719 95.189 2.65E-05 1.54E-01 1.73E-02 9.78E-10 3.91E+00 0.1407969713 0.1475739779 0.0201537896 17.5067019328 0.0479170289 66.80 0.2425 72.4881515059 66.80 31.2983456703 34.870986 95.1888755207 72.0035581955 29.6952092456 13 0.65 0.3451 5.49E-01 6.15E-02 460.636 11.65 101,324 -1.21E+00 -1.37 2.88E-02 0.1916106898 0.0151531847 0.0287593555 0.0151531847 6336.7945189703 4811.6854965884 13818.59 10285.55 141.991 506.761 95.259 2.65E-05 1.57E-01 1.78E-02 9.91E-10 4.04E+00 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5581.453715901 15777.38 11769.66 142.712 508.248 97.681 2.53E-05 3.35E-01 4.96E-02 1.58E-09 1.22E+01 0.1547333304 0.1622108254 0.0221239336 17.8348610333 0.0502539325 67.65 0.2535 68.9543558692 67.65 31.4619720214 35.082379 97.6811659577 74.1190839948 29.7848276338 36 2.40 0.9729 7.92E-02 8.88E-03 481.553 12.27 101,322 -1.47E+00 -4.10 1.17E-03 0.1754071276 0.0421431983 0.0011722176 0.0421431983 6878.6079261982 5604.5227546626 15837.26 11815.09 142.733 508.294 97.754 2.53E-05 3.43E-01 5.11E-02 1.60E-09 1.26E+01 0.1551522001 0.1626507763 0.0221831262 17.8444404846 0.0503227728 67.68 0.2538 68.8558254896 67.68 31.4666244869 35.088660 97.7536224695 74.1804706628 29.787482699 36 2.45 0.9769 6.93E-02 7.78E-03 482.166 12.29 101,322 -1.47E+00 -4.13 1.00E-03 0.1753063001 0.0423111451 0.0010005552 0.0423111451 6894.9841518095 5627.6174642753 15897.26 11860.62 142.754 508.339 97.826 2.53E-05 3.50E-01 5.26E-02 1.62E-09 1.31E+01 0.1555722496 0.1630919678 0.0222424844 17.8540310988 0.0503917293 67.70 0.2542 68.7574309633 67.70 31.4712757675 35.094953 97.8261463569 74.2419077006 29.7901430049 36 2.50 0.9804 6.04E-02 6.77E-03 482.781 12.31 101,322 -1.47E+00 -4.15 8.50E-04 0.1752180598 0.0424581256 0.000850323 0.0424581256 6911.4085552093 5650.7380125719 15957.39 11906.26 142.775 508.384 97.899 2.52E-05 3.58E-01 5.42E-02 1.64E-09 1.35E+01 0.1559934827 0.163534404 0.0223020085 17.8636328969 0.0504608024 67.73 0.2545 68.659171988 67.73 31.4759258848 35.101260 97.898737704 74.3033951505 29.7928085595 36 2.55 0.9834 5.24E-02 5.87E-03 483.396 12.33 101,322 -1.47E+00 -4.17 7.19E-04 0.1751412043 0.0425861426 0.0007194737 0.0425861426 6927.8810726997 5673.884569663 16017.66 11952.00 142.796 508.430 97.971 2.52E-05 3.66E-01 5.58E-02 1.67E-09 1.39E+01 0.1564159034 0.1639780892 0.0223616993 17.873245901 0.0505299923 67.75 0.2548 68.561048251 67.75 31.4805748612 35.107580 97.9713966036 74.3649330616 29.7954793711 36 2.60 0.9860 4.52E-02 5.07E-03 484.012 12.34 101,322 -1.47E+00 -4.19 6.06E-04 0.1750745852 0.042697109 0.0006060523 0.042697109 6944.4016436128 5697.0573070303 16078.05 11997.85 142.817 508.476 98.044 2.52E-05 3.74E-01 5.75E-02 1.69E-09 1.44E+01 0.1568395158 0.1644230275 0.0224215572 17.8828701341 0.0505992995 67.78 0.2551 68.4630594338 67.78 31.4852227195 35.113914 98.0441231544 74.4265214881 29.7981554485 36 2.65 0.9883 3.88E-02 4.35E-03 484.629 12.36 101,322 -1.48E+00 -4.20 5.08E-04 0.1750171164 0.0427928338 0.0005082097 0.0427928338 6960.9702097299 5720.2563967348 16138.58 12043.80 142.838 508.521 98.117 2.51E-05 3.82E-01 5.92E-02 1.71E-09 1.48E+01 0.1572643239 0.1648692234 0.0224815828 17.8925056196 0.0506687242 67.80 0.2555 68.3652052149 67.80 31.4898694824 35.120261 98.1169174582 74.4881604866 29.8008368003 36 2.70 0.9902 3.31E-02 3.72E-03 485.247 12.38 101,321 -1.48E+00 -4.22 4.24E-04 0.1749677806 0.0428750117 0.0004242137 0.0428750117 6977.5867147786 5743.4820107425 16199.25 12089.86 142.859 508.567 98.190 2.51E-05 3.91E-01 6.10E-02 1.73E-09 1.53E+01 0.157690332 0.1653166811 0.0225417768 17.902152381 0.0507382669 67.83 0.2558 68.2674852729 67.83 31.4945151728 35.126621 98.1897796179 74.5498501146 29.8035234356 37 2.75 0.9919 2.82E-02 3.16E-03 485.866 12.40 101,321 -1.48E+00 -4.23 3.52E-04 0.1749256325 0.042945217 0.0003524552 0.042945217 6994.2511040078 5766.7343203656 16260.04 12136.02 142.880 508.613 98.263 2.51E-05 3.99E-01 6.28E-02 1.76E-09 1.58E+01 0.1581175439 0.1657654049 0.0226021396 17.9118104419 0.0508079278 67.85 0.2561 68.1698992893 67.85 31.4991598138 35.132995 98.2627097356 74.6115904287 29.8062153631 38 2.80 0.9933 2.38E-02 2.67E-03 486.486 12.42 101,321 -1.48E+00 -4.25 2.91E-04 0.1748898015 0.0430049002 0.0002914516 0.0430049002 7010.9633238375 5790.0134958121 16320.98 12182.29 142.901 508.659 98.336 2.51E-05 4.08E-01 6.46E-02 1.78E-09 1.63E+01 0.158545964 0.1662153993 0.0226626719 17.9214798257 0.0508777074 67.88 0.2565 68.0724469496 67.88 31.5038034279 35.139382 98.3357079115 74.6733814836 29.8089125918 39 2.85 0.9945 2.01E-02 2.25E-03 487.107 12.43 101,321 -1.48E+00 -4.26 2.40E-04 0.1748594915 0.0430553872 0.0002398476 0.0430553872 7027.7233215767 5813.3197058356 16382.04 12228.66 142.922 508.705 98.409 2.50E-05 4.17E-01 6.66E-02 1.80E-09 1.68E+01 0.1589755963 0.1666666684 0.0227233743 17.9311605552 0.0509476059 67.90 0.2568 67.9751279454 67.90 31.5084460376 35.145783 98.4087742422 74.7352233312 29.8116151303 40 2.90 0.9955 1.68E-02 1.88E-03 487.729 12.45 101,321 -1.48E+00 -4.27 1.96E-04 0.1748339801 0.043097881 0.0001964136 0.043097881 7044.5310452049 5836.6531174753 16443.24 12275.14 142.943 508.752 98.482 2.50E-05 4.26E-01 6.85E-02 1.83E-09 1.74E+01 0.1594064449 0.1671192166 0.0227842472 17.940852653 0.0510176238 67.93 0.2571 67.877941975 67.93 31.5130876651 35.152197 98.4819088205 74.7971160195 29.8143229875 41 2.95 0.9963 1.40E-02 1.57E-03 488.351 12.47 101,321 -1.48E+00 -4.28 1.60E-04 0.1748126166 0.0431334658 0.0001600416 0.0431334658 7061.3864432099 5860.0138958755 16504.58 12321.73 142.964 508.798 98.555 2.50E-05 4.35E-01 7.06E-02 1.85E-09 1.79E+01 0.159838514 0.1675730483 0.0228452914 17.9505561408 0.0510877613 67.95 0.2574 67.7808887446 67.95 31.5177283323 35.158625 98.5551117343 74.8590595927 29.8170361718 42 3.00 0.9970 1.16E-02 1.30E-03 488.975 12.49 101,321 -1.48E+00 -4.29 1.30E-04 0.1747948187 0.0431631115 0.0001297401 0.0431631115 7078.2894644723 5883.4022041722 16566.05 12368.42 142.985 508.844 98.628 2.49E-05 4.45E-01 7.26E-02 1.88E-09 1.85E+01 0.1602718075 0.1680281677 0.0229065073 17.96027104 0.0511580188 67.98 0.2578 67.6839679679 67.98 31.5223680607 35.165066 98.6283830662 74.9210540902 29.8197546916 43 3.05 0.9976 9.56E-03 1.07E-03 489.599 12.51 101,321 -1.49E+00 -4.30 1.05E-04 0.1747800689 0.04318768 0.000104628 0.04318768 7095.2400581937 5906.8182034387 16627.65 12415.22 143.007 508.891 98.702 2.49E-05 4.54E-01 7.48E-02 1.90E-09 1.91E+01 0.1607063296 0.1684845791 0.0229678955 17.969997371 0.0512283967 68.00 0.2581 67.587179367 68.00 31.5270068716 35.171521 98.7017228938 74.9830995469 29.8224785551 44 3.10 0.9981 7.84E-03 8.79E-04 490.224 12.52 101,321 -1.49E+00 -4.31 8.39E-05 0.1747679103 0.0432079325 0.0000839274 0.0432079325 7112.238173858 5930.2620526779 16689.39 12462.13 143.028 508.937 98.775 2.49E-05 4.64E-01 7.70E-02 1.93E-09 1.97E+01 0.1611420843 0.1689422869 0.0230294567 17.9797351538 0.0512988953 68.03 0.2584 67.4905226719 68.03 31.5316447857 35.177989 98.7751312893 75.0451959931 29.8252077704 45 3.15 0.9985 6.39E-03 7.17E-04 490.851 12.54 101,321 -1.49E+00 -4.32 6.70E-05 0.174757942 0.0432245365 0.000066956 0.0432245365 7129.2837612213 5953.7339088526 16751.27 12509.14 143.049 508.984 98.849 2.48E-05 4.74E-01 7.93E-02 1.95E-09 2.03E+01 0.1615790757 0.1694012951 0.0230911913 17.9894844077 0.0513695148 68.06 0.2588 67.3939976206 68.06 31.5362818236 35.184471 98.8486083193 75.1073434544 29.8279423454 46 3.20 0.9988 5.18E-03 5.81E-04 491.478 12.56 101,321 -1.49E+00 -4.33 5.31E-05 0.1747498146 0.0432380741 0.0000531189 0.0432380741 7146.3767703248 5977.233926947 16813.29 12556.26 143.070 509.031 98.922 2.48E-054.84E-01 8.16E-02 1.98E-09 2.10E+01 0.1620173078 0.1698616082 0.0231530999 17.9992451511 0.0514402557 68.08 0.2591 67.2976039584 68.08 31.5409180054 35.190966 98.9221540457 75.1695419519 29.8306822879 47 3.25 0.9990 4.18E-03 4.68E-04 492.106 12.58 101,321 -1.49E+00 -4.34 4.19E-05 0.1747432257 0.0432490492 0.000041901 0.0432490492 7163.5171515246 6000.7622600491 16875.44 12603.50 143.091 509.078 98.996 2.48E-05 4.95E-01 8.40E-02 2.01E-09 2.17E+01 0.1624567847 0.1703232302 0.0232151831 18.0090174023 0.0515111182 68.11 0.2594 67.2013414377 68.11 31.5455533511 35.197476 98.9957685253 75.2317915025 29.8334276055 48 3.30 0.9992 3.35E-03 3.75E-04 492.735 12.60 101,321 -1.49E+00 -4.34 3.29E-05 0.1747379148 0.0432578955 0.000032859 0.0432578955 7180.7048555345 6024.319059451 16937.73 12650.84 143.112 509.125 99.069 2.47E-05 5.06E-01 8.65E-02 2.03E-09 2.23E+01 0.1628975102 0.1707861654 0.0232774414 18.0188011785 0.0515821027 68.13 0.2597 67.1052098178 68.13 31.55018788 35.203999 99.0694518102 75.2940921191 29.8361783056 49 3.35 0.9994 2.67E-03 2.99E-04 493.365 12.62 101,320 -1.49E+00 -4.35 2.56E-05 0.1747336593 0.0432649837 0.000025614 0.0432649837 7197.9398334783 6047.9044747587 17000.16 12698.28 143.133 509.172 99.143 2.47E-05 5.17E-01 8.90E-02 2.06E-09 2.31E+01 0.1633394884 0.1712504181 0.0233398755 18.0285964968 0.0516532095 68.16 0.2601 67.0092088639 68.16 31.5548216117 35.210535 99.1432039484 75.3564438108 29.8389343956 50 3.40 0.9995 2.11E-03 2.37E-04 493.996 12.64 101,320 -1.49E+00 -4.36 1.98E-05 0.1747302701 0.043270629 1.98E-05 0.043270629 7215.222036947 6071.5186540088 17062.73 12745.84 143.154 509.219 99.217 2.47E-05 5.28E-01 9.16E-02 2.09E-09 2.38E+01 0.1637827233 0.1717159923 0.0234024858 18.0384033736 0.0517244389 68.18 0.2604 66.9133383466 68.18 31.5594545651 35.217085 99.2170249839 75.4188465832 29.8416958827 51 3.45 0.9996 1.66E-03 1.86E-04 494.627 12.65 101,320 -1.49E+00 -4.37 1.53E-05 0.1747275876 0.0432750973 0.0000152767 0.0432750973 7232.5514180596 6095.1617437874 17125.44 12793.51 143.175 509.266 99.291 2.46E-05 5.39E-01 9.43E-02 2.12E-09 2.45E+01 0.1642272188 0.1721828923 0.0234652729 18.0482218248 0.0517957911 68.21 0.2607 66.817598042 68.21 31.564086759 35.223649 99.2909149572 75.4813004388 29.8444627741 52 3.50 0.9997 1.30E-03 1.45E-04 495.260 12.67 101,320 -1.49E+00 -4.37 1.17E-05 0.1747254778 0.0432786115 0.0000116847 0.0432786115 7249.927929524 6118.8338893481 17188.28 12841.29 143.196 509.313 99.365 2.46E-05 5.51E-01 9.70E-02 2.14E-09 2.53E+01 0.164672979 0.1726511223 0.0235282373 18.0580518662 0.0518672666 68.23 0.2611 66.7219877303 68.23 31.5687182121 35.230227 99.3648739053 75.5438053772 29.8472350768 53 3.55 0.9998 1.01E-03 1.13E-04 495.894 12.69 101,320 -1.49E+00 -4.38 8.88E-06 0.1747238293 0.0432813574 0.0000088781 0.0432813574 7267.3515246973 6142.5352347271 17251.27 12889.18 143.217 509.361 99.439 2.46E-05 5.62E-01 9.99E-02 2.17E-09 2.61E+01 0.1651200077 0.1731206864 0.0235913798 18.0678935129 0.0519388656 68.26 0.2614 66.626507196 68.26 31.5733489428 35.236818 99.4389018625 75.6063613954 29.8500127978 54 3.60 0.9998 7.76E-04 8.70E-05 496.528 12.71 101,320 -1.50E+00 -4.39 6.70E-06 0.1747225498 0.0432834886 0.0000066997 0.0432834886 7284.8221576432 6166.265922853 17314.39 12937.17 143.238 509.408 99.513 2.45E-05 5.75E-01 1.03E-01 2.20E-09 2.69E+01 0.1655683091 0.1735915888 0.0236547006 18.0777467801 0.0520105885 68.29 0.2617 66.5311562272 68.29 31.5779789693 35.243423 99.5129988606 75.6689684882 29.8527959441 55 3.65 0.9999 5.94E-04 6.66E-05 497.164 12.73 101,320 -1.50E+00 -4.40 5.02E-06 0.1747215635 0.0432851315 0.0000050205 0.0432851315 7302.3397831857 6190.0260956507 17377.66 12985.28 143.259 509.456 99.587 2.45E-05 5.87E-01 1.06E-01 2.23E-09 2.78E+01 0.1660178869 0.1740638337 0.0237182006 18.0876116823 0.0520824354 68.31 0.2621 66.4359346149 68.31 31.58260831 35.250042 99.5871649289 75.7316266482 29.8555845224 56 3.70 0.9999 4.51E-04 5.06E-05 497.800 12.75 101,320 -1.50E+00 -4.40 3.74E-06 0.1747208086 0.043286389 0.0000037351 0.043286389 7319.9043569587 6213.8158941378 17441.07 13033.50 143.280 509.503 99.661 2.45E-05 5.99E-01 1.09E-01 2.26E-09 2.87E+01 0.1664687453 0.1745374253 0.0237818801 18.0974882341 0.0521544068 68.34 0.2624 66.340842153 68.34 31.5872369827 35.256674 99.6614000948 75.7943358662 29.8583785397 57 3.75 0.9999 3.40E-04 3.82E-05 498.438 12.77 101,320 -1.50E+00 -4.41 2.76E-06 0.1747202349 0.0432873446 0.0000027584 0.0432873446 7337.5158354503 6237.635458513 17504.61 13081.83 143.301 509.551 99.736 2.44E-05 6.12E-01 1.12E-01 2.29E-09 2.96E+01 0.1669208882 0.1750123677 0.0238457397 18.1073764499 0.0522265029 68.36 0.2628 66.2458786379 68.36 31.5918650054 35.263321 99.7357043839 75.8570961315 29.8611780026 58 3.80 1.0000 2.55E-04 2.86E-05 499.076 12.79 101,320 -1.50E+00 -4.42 2.02E-06 0.1747198021 0.0432880654 0.0000020216 0.0432880654 7355.1741760425 6261.4849282371 17568.30 13130.27 143.322 509.599 99.810 2.44E-05 6.25E-01 1.15E-01 2.32E-09 3.05E+01 0.1673743195 0.1754886652 0.0239097801 18.1172763437 0.0522987241 68.39 0.2631 66.1510438679 68.39 31.596492396 35.269981 99.8100778204 75.9199074319 29.863982918 59 3.85 1.0000 1.89E-04 2.12E-05 499.715 12.80 101,320 -1.50E+00 -4.43 1.47E-06 0.1747194782 0.043288605 0.0000014701 0.043288605 7372.8793370455 6285.3644421051 17632.13 13178.83 143.343 509.647 99.885 2.44E-05 6.39E-01 1.19E-01 2.35E-09 3.15E+01 0.1678290433 0.1759663219 0.0239740017 18.1271879296 0.0523710706 68.42 0.2634 66.0563376431 68.42 31.6011191722 35.276655 99.8845204271 75.9827697538 29.8667932926 60 3.90 1.0000 1.39E-04 1.56E-05 500.356 12.82 101,320 -1.50E+00 -4.43 1.06E-06 0.1747192376 0.0432890058 0.0000010605 0.0432890058 7390.6312777266 6309.2741383111 17696.10 13227.49 143.364 509.695 99.959 2.44E-05 6.52E-01 1.22E-01 2.38E-09 3.25E+01 0.1682850636 0.1764453421 0.0240384051 18.1371112215 0.0524435427 68.44 0.2638 65.9617597651 68.44 31.6057453518 35.283343 99.9590322256 76.0456830829 29.8696091332 Determinação massa do catalisador Determinação diâmetro do reator 1° tentativa D ext tubo, mm 50 P, atm 1 K1 0.6897712973 L etanol/min.g cat densidade particula cat, kg/m³ 930 Arranjo triangular Arranjo quadrado D int tubo 40 T, °C 240.00 K2 0.1491224712 L etanol/min.g cat Tubo diâmetro, m 0.040 R0 21.6 K3 0.0000000031 1/atm Volume catalisador 23 Nº passes 1 Nº passes 1 yet 0.0441 K4 41.5429652535 L etanol/min.g cat Número de tubos 6,926 K1 0.319 K1 0.215 R, L.atm/mol.K 0.08206 Área tubo 1.26E-03 N1 2.142 N1 2.207 L 0.05 Comprimento tubo 2.70 T, K 273.15 Volume tubo 3.39E-03 D int reator, m 5.3 D int reator, m 5.5 C et, mol/L 0.0010 Área reator 22.0 Área reator 24 Pressões parciais 1/ra Massa catalisador, kg 21,854.51 D, trian 0.0355457819 D, trian 0.0494718394 n W/FAO x f(x) P02 PET PH20 PAC Área triang 9.92E-04 Área triang 0.0019222329 0 0 0 0.4568416829 0.2007079646 0.0442477876 0 0 0 1 0.050 0.0228 0.4492722635 0.2001014863 0.0432152369 0.0010102012 0.0010102012 2.2258218041 OD, m 0.05 OD, m 0.05 2 0.100 0.0453 0.4417511198 0.199505654 0.0422008112 0.0020026695 0.0020026695 2.2637180872 ID, m 0.04 ID, m 0.040000 3 0.150 0.0674 0.434279082 0.1989203729 0.0412043495 0.0029775628 0.0029775628 2.3026667447 p 0.0625 p 0.0625 4 0.200 0.0891 0.4268570105 0.1983455481 0.04022569 0.0039350393 0.0039350393 2.3427048762 5 0.250 0.1105 0.419485795 0.1977810843 0.0392646703 0.0048752576 0.0048752576 2.3838709484 N° de triang 22,160 N° de triang 12,429 6 0.300 0.1314 0.412166352 0.1972268858 0.0383211278 0.0057983772 0.0057983772 2.4262048443 7 0.350 0.1520 0.4048996233 0.1966828565 0.0373948987 0.0067045579 0.0067045579 2.4697479139 Volume Reator 59.4 Volume Reator 64.5 Arranjo triangular, pt = 1,25d0 8 0.400 0.1723 0.3976865735 0.1961489001 0.0364858189 0.0075939607 0.0075939607 2.5145430261Nº Passes 1 2 4 6 8 9 0.450 0.1922 0.3905281882 0.1956249193 0.0355937232 0.008466747 0.008466747 2.5606346231 K1 0.319 0.249 0.175 0.0743 0.0365 10 0.500 0.2117 0.3834254715 0.1951108169 0.0347184456 0.0093230792 0.0093230792 2.6080687758 Determinação tempo de residência N1 2.142 2.207 2.285 2.499 2.675 11 0.550 0.2309 0.3763794436 0.1946064945 0.033859819 0.0101631208 0.0101631208 2.6568932416 Pressão, Pa 101325 Arranjo quadrado, pt = 1,25d0 12 0.600 0.2497 0.3693911385 0.1941118537 0.0330176755 0.0109870361 0.0109870361 2.707157524 R, Pa.m³/mol.K 8.314 Nº Passes 1 2 4 6 8 13 0.650 0.2681 0.3624616014 0.1936267951 0.032191846 0.0117949905 0.0117949905 2.7589129337 T 453.15 K1 0.215 0.156 0.158 0.0402 0.0331 14 0.700 0.2863 0.3555918857 0.1931512188 0.0313821605 0.0125871503 0.0125871503 2.8122126526 Componente Massa esp y AST 1.26E-03 N1 2.207 2.291 2.263 2.617 2.643 15 0.750 0.3041 0.3487830507 0.1926850241 0.0305884476 0.0133636833 0.0133636833 2.8671117991 Nitrogênio 7.53E-01 0.7533 Area total tubos 8.7 16 0.800 0.3215 0.3420361589 0.1922281099 0.029810535 0.014124758 0.014124758 2.9236674956 Oxigênio 4.30E-01 0.2002418206 17 0.850 0.3386 0.3353522726 0.1917803742 0.029048249 0.0148705442 0.0148705442 2.9819389392 Etanol 1.24E+00 0.0441450222 Velocidade (m/s) 5.42 Massas molares 18 0.900 0.3554 0.3287324517 0.1913417142 0.0283014149 0.0156012131 0.0156012131 3.0419874732 0.7083 Vazão (m³/s) 47.17 Etanol 46.070 19 0.950 0.3718 0.3221777502 0.1909120266 0.0275698566 0.0163169368 0.0163169368 3.1038766622 Vazão (kg/s) 33.41 Água 18.015 20 1.000 0.3879 0.3156892139 0.1904912074 0.026853397 0.0170178887 0.0170178887 3.1676723691 6.8292975163 Resultado integral Oxigênio 16.000 21 1.050 0.4037 0.3092678767 0.1900791516 0.0261518575 0.0177042433 0.0177042433 3.233442835 Tempo, s 0.498190149 Nitrogênio 28.010 22 1.100 0.4192 0.3029147584 0.1896757539 0.0254650586 0.0183761764 0.0183761764 3.3012587612 Acetaldeído 44.050 23 1.150 0.4343 0.2966308612 0.189280908 0.0247928194 0.019033865 0.019033865 3.3711933944 24 1.200 0.4491 0.2904171673 0.1888945069 0.024134958 0.019677487 0.019677487 3.4433226146 25 1.250 0.4637 0.2842746356 0.1885164432 0.0234912912 0.0203072216 0.0203072216 3.517725026 Temperatura ótima de alimentação T 485.247 26 1.300 0.4779 0.2782041991 0.1881466087 0.0228616347 0.0209232491 0.0209232491 3.5944820507 27 1.350 0.4918 0.272206762 0.1877848943 0.0222458033 0.0215257509 0.0215257509 3.6736780256 28 1.400 0.5054 0.2662831974 0.1874311909 0.0216436106 0.0221149091 0.0221149091 3.7554003029 k a b p f(a) f(b) f(p) f(a).f(p) Erro 29 1.450 0.5187 0.2604343441 0.1870853882 0.0210548693 0.0226909071 0.0226909071 3.8397393532 1 420 473.0 446.5 -4.54E+01 3.69E+01 -8.09E+00 3.68E+02 5.30E+01 30 1.500 0.5317 0.2546610048 0.1867473758 0.0204793912 0.0232539289 0.0232539289 3.9267888733 2 446.5 473.0 459.75 -8.09E+00 3.69E+01 1.52E+01 -1.23E+02 2.65E+01 31 1.550 0.5445 0.248963943 0.1864170425 0.0199169872 0.0238041597 0.0238041597 4.0166458962 3 446.5 459.8 453.125 -8.09E+00 1.52E+01 3.04E+00 -2.46E+01 1.33E+01 32 1.600 0.5569 0.2433438814 0.1860942769 0.0193674673 0.0243417852 0.0243417852 4.1094109059 4 446.5 453.1 449.8125 -8.09E+00 3.04E+00 -2.65E+00 2.14E+01 6.63E+00 33 1.650 0.5691 0.2378014991 0.1857789671 0.0188306411 0.0248669918 0.0248669918 4.2051879555 5 449.8125 453.1 451.46875 -2.65E+00 3.04E+00 1.66E-01 -4.39E-01 3.31E+00 34 1.700 0.5810 0.2323374303 0.1854710006 0.0183063173 0.0253799666 0.0253799666 4.3040847897 6 449.8125 451.5 450.640625 -2.65E+00 1.66E-01 -1.25E+00 3.31E+00 1.66E+00 35 1.750 0.5926 0.2269522618 0.1851702648 0.0177943041 0.0258808973 0.0258808973 4.4062129715 7 450.640625 451.5 451.0546875 -1.25E+00 1.66E-01 -5.44E-01 6.79E-01 8.28E-01 36 1.800 0.6039 0.2216465317 0.1848766469 0.0172944092 0.026369972 0.026369972 4.5116880123 8 451.0546875 451.5 451.26171875 -5.44E-01 1.66E-01 -1.89E-01 1.03E-01 4.14E-01 37 1.850 0.6150 0.2164207276 0.1845900336 0.0168064399 0.0268473792 0.0268473792 4.620629508 9 451.26171875 451.5 451.365234375 -1.89E-01 1.66E-01 -1.19E-02 2.26E-03 2.07E-01 38 1.900 0.6258 0.2112752854 0.1843103116 0.0163302033 0.0273133076 0.0273133076 4.7331612785 10 451.365234375 451.5 451.4169921875 -1.19E-02 1.66E-01 7.69E-02 -9.18E-04 1.04E-01 39 1.950 0.6364 0.2062105881 0.1840373675 0.0158655062 0.0277679463 0.0277679463 4.8494115128 11 451.365234375 451.4 451.3911132813 -1.19E-02 7.69E-02 3.25E-02 -3.88E-04 5.18E-02 40 2.000 0.6467 0.2012269646 0.1837710876 0.0154121554 0.0282114843 0.0282114843 4.9695129181 12 451.365234375 451.4 451.3781738281 -1.19E-02 3.25E-02 1.03E-02 -1.23E-04 2.59E-02 41 2.050 0.6568 0.1963246889 0.1835113586 0.0149699575 0.0286441108 0.0286441108 5.0936028754 13 451.365234375 451.4 451.3717041016 -1.19E-02 1.03E-02 -8.44E-04 1.01E-05 1.29E-02 42 2.100 0.6666 0.1915039796 0.1832580669 0.0145387194 0.0290660148 0.0290660148 5.2218235997 14 451.3717041016 451.4 451.3749389648 -8.44E-04 1.03E-02 4.71E-03 -3.97E-06 6.47E-03 43 2.150 0.6762 0.186764999 0.1830110991 0.014118248 0.029477385 0.029477385 5.3543223054 15 451.3717041016 451.4 451.3733215332 -8.44E-04 4.71E-03 1.93E-03 -1.63E-06 3.23E-03 44 2.200 0.6855 0.1821078532 0.1827703421 0.0137083507 0.0298784101 0.0298784101 5.4912513782 16 451.3717041016 451.4 451.3725128174 -8.44E-04 1.93E-03 5.43E-04 -4.59E-07 1.62E-03 45 2.250 0.6946 0.1775325918 0.1825356829 0.0133088352 0.0302692781 0.0302692781 5.6327685527 17 451.3717041016 451.4 451.3721084595 -8.44E-04 5.43E-04 -1.51E-04 1.27E-07 8.09E-04 46 2.300 0.7035 0.1730392076 0.1823070089 0.0129195096 0.0306501767 0.0306501767 5.7790370962 18 451.3721084595 451.4 451.3723106384 -1.51E-04 5.43E-04 1.96E-04 -2.96E-08 4.04E-04 47 2.350 0.7121 0.1686276375 0.1820842078 0.0125401828 0.031021293 0.031021293 5.9302259986 19 451.3721084595 451.4 451.372209549 -1.51E-04 1.96E-04 2.29E-05 -3.45E-09 2.02E-04 48 2.400 0.7206 0.1642977621 0.1818671677 0.0121706643 0.0313828132 0.0313828132 6.0865101696 20 451.3721084595 451.4 451.37 -1.51E-04 2.29E-05 -6.38E-05 9.61E-09 1.01E-04 49 2.450 0.7288 0.1600494068 0.1816557772 0.0118107645 0.031734923 0.031734923 6.248070642 50 2.500 0.7368 0.1558823422 0.1814499254 0.0114602946 0.032077807 0.032077807 6.4150947828 51 2.550 0.7446 0.1517962849 0.1812495022 0.011119067 0.0324116487 0.0324116487 6.5877765114 52 2.600 0.7522 0.1477908987 0.1810543979 0.010786895 0.0327366308 0.0327366308 6.7663165255 53 2.650 0.7595 0.1438657955 0.1808645036 0.0104635933 0.0330529347 0.0330529347 6.9509225348 54 2.700 0.7667 0.1400205368 0.1806797113 0.0101489779 0.0333607403 0.0333607403 7.141809503 55 2.750 0.7737 0.1362546345 0.1804999137 0.009842866 0.0336602263 0.0336602263 7.3391998985 56 2.800 0.7806 0.1325675533 0.1803250043 0.0095450767 0.03395157 0.03395157 7.5433239539 57 2.850 0.7872 0.1289587111 0.1801548778 0.0092554303 0.034234947 0.034234947 7.754419934 58 2.900 0.7936 0.1254274817 0.1799894296 0.0089737489 0.0345105314 0.0345105314 7.9727344141 59 2.950 0.7999 0.121973196 0.1798285564 0.0086998564 0.0347784954 0.0347784954 8.1985225675 60 3.000 0.8060 0.1185951438 0.1796721556 0.0084335786 0.0350390096 0.0350390096 8.4320484635 61 3.050 0.8119 0.1152925759 0.1795201262 0.0081747431 0.0352922427 0.0352922427 8.6735853759 62 3.100 0.8177 0.1120647058 0.1793723679 0.0079231794 0.0355383613 0.0355383613 8.9234161014 63 3.150 0.8233 0.1089107119 0.1792287819 0.0076787192 0.0357775302 0.0357775302 9.1818332912 64 3.200 0.8287 0.1058297392 0.1790892706 0.0074411962 0.036009912 0.036009912 9.449139792 65 3.250 0.8340 0.10282090170.1789537375 0.0072104463 0.0362356673 0.0362356673 9.7256490006 66 3.300 0.8392 0.0998832841 0.1788220875 0.0069863076 0.0364549544 0.0364549544 10.0116852304 67 3.350 0.8442 0.0970159439 0.178694227 0.0067686206 0.0366679296 0.0366679296 10.3075840911 68 3.400 0.8490 0.0942179137 0.1785700636 0.0065572279 0.0368747467 0.0368747467 10.6136928809 69 3.450 0.8537 0.091488203 0.1784495061 0.0063519746 0.0370755573 0.0370755573 10.9303709936 70 3.500 0.8583 0.0888258002 0.1783324651 0.0061527081 0.0372705107 0.0372705107 11.2579903395 71 3.550 0.8627 0.0862296747 0.1782188523 0.0059592784 0.0374597536 0.0374597536 11.5969357811 72 3.600 0.8671 0.0836987791 0.1781085811 0.0057715377 0.0376434307 0.0376434307 11.947605584 73 3.650 0.8712 0.0812320505 0.1780015661 0.0055893409 0.0378216838 0.0378216838 12.3104118839 74 3.700 0.8753 0.0788284132 0.1778977237 0.0054125454 0.0379946525 0.0379946525 12.6857811699 75 3.750 0.8792 0.0764867799 0.1777969714 0.0052410111 0.038162474 0.038162474 13.074154785 76 3.800 0.8831 0.074206054 0.1776992284 0.0050746003 0.0383252828 0.0383252828 13.4759894435 77 3.850 0.8868 0.0719851308 0.1776044155 0.004913178 0.0384832111 0.0384832111 13.8917577671 78 3.900 0.8904 0.0698228999 0.1775124549 0.0047566118 0.0386363885 0.0386363885 14.3219488402 79 3.950 0.8939 0.0677182462 0.1774232703 0.0046047717 0.0387849419 0.0387849419 14.7670687834 80 4.000 0.8973 0.0656700521 0.1773367868 0.0044575305 0.0389289961 0.0389289961 15.2276413488 81 4.050 0.9005 0.0636771982 0.1772529312 0.0043147634 0.039068673 0.039068673 15.7042085343 82 4.100 0.9037 0.0617385658 0.1771716317 0.0041763482 0.0392040922 0.0392040922 16.1973312213 83 4.150 0.9068 0.0598530375 0.1770928181 0.0040421652 0.0393353708 0.0393353708 16.7075898332 84 4.200 0.9098 0.0580194986 0.1770164216 0.0039120975 0.0394626233 0.0394626233 17.235585018 85 4.250 0.9127 0.0562368388 0.1769423748 0.0037860303 0.0395859617 0.0395859617 17.7819383541 86 4.300 0.9155 0.054503953 0.1768706121 0.0036638517 0.0397054958 0.0397054958 18.3472930815 87 4.350 0.9182 0.0528197427 0.176801069 0.0035454521 0.0398213326 0.0398213326 18.9323148579 88 4.400 0.9209 0.0511831168 0.1767336827 0.0034307245 0.0399335769 0.0399335769 19.5376925418 89 4.450 0.9234 0.0495929928 0.1766683917 0.0033195643 0.040042331 0.040042331 20.1641390026 90 4.500 0.9259 0.0480482975 0.1766051361 0.0032118694 0.0401476949 0.0401476949 20.8123919596 91 4.550 0.9283 0.0465479681 0.1765438572 0.0031075398 0.0402497662 0.0402497662 21.4832148495 92 4.600 0.9307 0.0450909531 0.1764844978 0.0030064784 0.0403486402 0.0403486402 22.1773977251 93 4.650 0.9329 0.0436762125 0.1764270022 0.0029085901 0.0404444097 0.0404444097 22.8957581847 94 4.700 0.9351 0.0423027192 0.1763713159 0.0028137822 0.0405371655 0.0405371655 23.6391423349 95 4.750 0.9372 0.040969459 0.1763173857 0.0027219642 0.0406269961 0.0406269961 24.408425786 96 4.800 0.9393 0.0396754317 0.17626516 0.0026330481 0.0407139875 0.0407139875 25.2045146828 97 4.850 0.9412 0.038419651 0.1762145883 0.002546948 0.040798224 0.040798224 26.0283467715 98 4.900 0.9432 0.0372011458 0.1761656214 0.0024635801 0.0408797874 0.0408797874 26.8808925037 99 4.950 0.9450 0.0360189596 0.1761182114 0.0023828629 0.0409587575 0.0409587575 27.7631561788 100 5.000 0.9468 0.0348721517 0.1760723117 0.002304717 0.041035212 0.041035212 28.6761771267 101 5.050 0.9486 0.0337597973 0.1760278767 0.0022290649 0.0411092265 0.0411092265 29.6210309316 102 5.100 0.9503 0.0326809874 0.1759848624 0.0021558315 0.0411808748 0.0411808748 30.5988306986 103 5.150 0.9519 0.0316348294 0.1759432256 0.0020849433 0.0412502286 0.0412502286 31.6107283643 104 5.200 0.9535 0.0306204474 0.1759029244 0.0020163292 0.0413173576 0.0413173576 32.657916054 105 5.250 0.9550 0.0296369818 0.1758639182 0.0019499197 0.0413823297 0.0413823297 33.741627485 106 5.300 0.9565 0.0286835901 0.1758261672 0.0018856473 0.0414452109 0.0414452109 34.8631394204 107 5.350 0.9579 0.0277594464 0.1757896329 0.0018234464 0.0415060655 0.0415060655 36.0237731722 108 5.400 0.9593 0.0268637418 0.1757542779 0.0017632532 0.0415649558 0.0415649558 37.2248961582 109 5.450 0.9606 0.0259956844 0.1757200657 0.0017050057 0.0416219425 0.0416219425 38.4679235124 110 5.500 0.9619 0.0251544991 0.1756869609 0.0016486436 0.0416770846 0.0416770846 39.754319752 111 5.550 0.9632 0.0243394276 0.1756549291 0.0015941083 0.0417304395 0.0417304395 41.0856005025 112 5.600 0.9644 0.0235497287 0.1756239368 0.0015413429 0.0417820628 0.0417820628 42.4633342833 113 5.650 0.9656 0.0227846775 0.1755939517 0.0014902922 0.0418320085 0.0418320085 43.8891443551 114 5.700 0.9667 0.0220435662 0.1755649422 0.0014409024 0.0418803292 0.0418803292 45.3647106327 115 5.750 0.9678 0.0213257031 0.1755368776 0.0013931214 0.041927076 0.041927076 46.8917716633 116 5.800 0.9689 0.0206304132 0.1755097282 0.0013468986 0.0419722983 0.0419722983 48.4721266755 117 5.850 0.9699 0.0199570374 0.1754834651 0.0013021849 0.0420160442 0.0420160442 50.1076376982 118 5.900 0.9709 0.0193049329 0.1754580604 0.0012589325 0.0420583604 0.0420583604 51.8002317548 119 5.950 0.9719 0.0186734727 0.1754334869 0.0012170952 0.0420992922 0.0420992922 53.5519031334 120 6.000 0.9728 0.0180620452 0.1754097181 0.001176628 0.0421388834 0.0421388834 55.3647157362 121 6.050 0.9737 0.0174700546 0.1753867286 0.0011374874 0.0421771768 0.0421771768 57.240805511 122 6.100 0.9746 0.0168969202 0.1753644933 0.0010996312 0.0422142137 0.0422142137 59.1823829683 123 6.150 0.9755 0.0163420761 0.1753429883 0.0010630182 0.0422500342 0.0422500342 61.191735785 124 6.200 0.9763 0.0158049713 0.1753221903 0.0010276087 0.0422846772 0.0422846772 63.2712315 125 6.250 0.9771 0.0152850695 0.1753020765 0.0009933643 0.0423181804 0.0423181804 65.4233203037 126 6.300 0.9778 0.0147818485 0.175282625 0.0009602474 0.0423505805 0.0423505805 67.6505379247 127 6.350 0.9786 0.0142947999 0.1752638144 0.0009282218 0.0423819129 0.0423819129 69.9555086175 128 6.400 0.9793 0.0138234295 0.1752456243 0.0008972524 0.0424122119 0.0424122119 72.3409482544 129 6.450 0.9800 0.0133672563 0.1752280345 0.0008673052 0.0424415109 0.0424415109 74.8096675256 130 6.500 0.9806 0.0129258126 0.1752110257 0.0008383471 0.0424698423 0.0424698423 77.3645752503 131 6.550 0.9813 0.0124986436 0.175194579 0.000810346 0.0424972372 0.0424972372 80.0086818046 132 6.600 0.9819 0.0120853074 0.1751786763 0.0007832711 0.0425237261 0.0425237261 82.7451026682 133 6.650 0.9825 0.0116853743 0.1751632999 0.0007570923 0.0425493383 0.0425493383 85.5770620952 134 6.700 0.9831 0.0112984269 0.1751484328 0.0007317805 0.0425741022 0.0425741022 88.5078969129 135 6.750 0.9837 0.0109240596 0.1751340583 0.0007073074 0.0425980456 0.0425980456 91.5410604536 136 6.800 0.9842 0.0105618786 0.1751201604 0.0006836458 0.042621195 0.042621195 94.6801266237 137 6.850 0.9847 0.0102115012 0.1751067237 0.0006607692 0.0426435764 0.0426435764 97.9287941142 138 6.900 0.9853 0.0098725561 0.1750937329 0.000638652 0.0426652149 0.0426652149 101.2908907591 139 6.950 0.9857 0.0095446826 0.1750811737 0.0006172695 0.0426861347 0.0426861347 104.7703780454 140 7.000 0.9862 0.0092275306 0.1750690318 0.0005965974 0.0427063592 0.0427063592 108.371355781 141 7.050 0.9867 0.0089207604 0.1750572936 0.0005766127 0.0427259114 0.0427259114 112.0980669249 142 7.100 0.9871 0.0086240424 0.1750459458 0.0005572927 0.0427448132 0.0427448132 115.9549025873 143 7.150 0.9876 0.0083370567 0.1750349757 0.0005386158 0.0427630859 0.0427630859 119.9464072025 144 7.200 0.9880 0.008059493 0.1750243708 0.0005205606 0.0427807502 0.0427807502 124.0772838846 145 7.250 0.9884 0.0077910503 0.1750141192 0.0005031069 0.0427978262 0.0427978262 128.352399968 146 7.300 0.9888 0.0075314366 0.1750042093 0.0004862348 0.042814333 0.042814333 132.7767927433 147 7.350 0.9891 0.007280369 0.1749946297 0.0004699252 0.0428302896 0.0428302896 137.3556753919 148 7.400 0.9895 0.0070375729 0.1749853696 0.0004541595 0.042845714 0.042845714 142.0944431292 149
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