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RWTH edition RWTH Aachen Fritz Klocke Manufacturing Processes 1 Cutting Translated by Aaron Kuchle 123 Professor Dr.-Ing. Dr.-Ing. E.h. Dr. h.c. Dr. h.c. Fritz Klocke Laboratory for Machine Tools and Production Engineering RWTH Aachen University Steinbachstr. 19 52074 Aachen Germany f.klocke@wzl.rwth-aachen.de Translated by Aaron Kuchle Yeungnam University Korean Language Institute 214-1 Dae-dong Gyeongsan Gyeongbuk 712-749 Korea aaronkuchle@yahoo.com ISSN 1865-0899 e-ISSN 1865-0902 ISBN 978-3-642-11978-1 e-ISBN 978-3-642-11979-8 DOI 10.1007/978-3-642-11979-8 Springer Heidelberg Dordrecht London New York Library of Congress Control Number: 2011925556 © Springer-Verlag Berlin Heidelberg 2011 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: deblik, Berlin, Germany Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com) Preamble About Compendium “Manufacturing Processes” Key factors for quality and economic efficiency of industrial production are the choice of the manufacturing processes and their design. Manufacturing Technology is an elemental part of the fundamental knowledge of machining engineers. Also design engineers have to gain knowledge in this field, since they have high respon- sibility for the manufacturing costs. However, the students as well as practising experts who are willing to enhance their knowledge have the problem to collect information. To the current day there is no extensive, but still clear description of manufacturing processes focussing on the technology itself. In order to counter this necessity the compendium at hand is supposed to present an overall picture of the most common machining and non-machining manufac- turing processes. Additional to the description of the techniques these volumes are desired to deliver an insight in the underlying physical principles whenever it is necessary for the understanding of the processes. The apportionment of the compendium “Manufacturing Processes” into Volume 1: Cutting Volume 2: Grinding, Honing, Lapping Volume 3: Electrical Erosion and Hybride Processes Volume 4: Forming Volume 5: Casting, Sintering, Rapid Prototyping groups techniques with similar active principles together. In front of the first volume is placed a technique-spanning section to the toler- ances and questions of the workpiece measuring techniques used in manufacturing. Within the individual volumes was tried to avoid an encyclopaedic listing of the techniques. The book series are primarily intended for junior scientists in the fields of manufacturing technology and construction. In addition, the practitioner will be able to refurbish or extend his knowledge. The variety of manufacturing problems v vi Preamble About Compendium “Manufacturing Processes” is as large as the multiplicity of the products, and alone with text book wise sayings manufacturing questions are not to be solved. We wish that this book offers starting points and ways to its readers, on which they can come up with successful solutions by engineering thinking. Aachen, Germany Fritz Klocke September 2010 Preamble for Volume 1 “Cutting” The available volume treats machining with geometrically defined cutting edges. It approaches both the practical engineer and the student of engineering sciences. This book is based on the lecture “Manufacturing Technologies I and II” and the pertinent exercises, which are held at RWTH Aachen University. The arrangement of the book results from the experiences, which were gained when lecturing in the chronology of the course. The structure of the book is oriented to a large extent at didactical criteria. The first section deals with the metrology and the workpiece quality, followed by a chap- ter about the fundamentals of cutting. Based on the common technological principle of the cutting processes and their variants, the second section deals with the mech- anisms occurring at the cutting edge and the resulting loads on the tools. The next section deals with the demands on the cutting materials as well as their manufac- turing processes and application. The text presents topics like the use of the finite element method for cutting processes as well as cutting fluids. A detailed chapter about the machinability of the most important work piece materials, such as steel and cast iron, light metal alloy and high temperature resistant materials imparts a broad knowledge of the alternating coactions of work piece material, the cutting material and the process parameters. The necessity for process control, used sensor systems and application possi- bilities are regarded. Due to the increasing relevance and application in industrial manufacturing plants, monitoring systems are discussed in their own chapter. Finally, the different cutting processes and their kinematic characteristics are presented in detail. For their cooperation with the compilation of the available edition I would like to thank my co-workers, Dr.-Ing. M. Abouridouane, Dr.-Ing. K. Gerschwiler, Dipl.-Ing. M. Arft, Dipl.-Ing. C. Essig, Dipl.-Ing. P. Frank, Dipl.-Ing. A. Krämer, Dipl.-Ing. D. Lung, Dipl.-Ing. H. Sangermann, Dipl.-Ing. R. Schlosser, Dipl.-Ing. vii viii Preamble for Volume 1 “Cutting” P. Vogtel, as well as Dipl.-Ing. S. E. Cordes, who was additionally responsible for the coordination of the work on this book. Further I would like to thank the many former co-workers, who participated in the past German editions and now have leading positions in industry and research companies. Aachen, Germany Fritz Klocke September 2010 Contents 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2 Metrology and Workpiece Quality . . . . . . . . . . . . . . . . . . 3 2.1 Manufacturing Disturbances and Manufacturing History . . . . 3 2.2 Measuring and Testing . . . . . . . . . . . . . . . . . . . . . . 8 2.2.1 Measurement Errors . . . . . . . . . . . . . . . . . . 9 2.2.2 Macro- and Microgeometry of Components . . . . . . 10 2.3 Length Testing Devices . . . . . . . . . . . . . . . . . . . . . . 13 2.3.1 Material Measures . . . . . . . . . . . . . . . . . . . 13 2.3.2 Gauges . . . . . . . . . . . . . . . . . . . . . . . . . 13 2.3.3 Indicating Measuring Instruments . . . . . . . . . . . 14 2.4 Surface Inspection . . . . . . . . . . . . . . . . . . . . . . . . 21 2.4.1 Surface Parameters . . . . . . . . . . . . . . . . . . . 22 2.4.2 Subjective Surface Inspection . . . . . . . . . . . . . 26 2.4.3 Surface Measurement . . . . . . . . . . . . . . . . . . 27 2.5 Inspection of the Workpiece Rim . . . . . . . . . . . . . . . . 30 2.5.1 Surface Layers . . . . . . . . . . . . . . . . . . . . . 31 2.5.2 Inspection of the Surface Rim Zone . . . . . . . . . . 33 3 Fundamentals of Cutting . . . . . . . . . . . . . . . . . . . . . . . . 39 3.1 The Cutting Part – Concepts and Terms . . . . . . . . . . . . . 39 3.2 Reference Systems . . . . . . . . . . . . . . . . . . . . . . . . 42 3.3 Basic Process Variants. . . . . . . . . . . . . . . . . . . . . . 45 3.4 Chip Formation . . . . . . . . . . . . . . . . . . . . . . . . . . 47 3.4.1 The Cutting Process . . . . . . . . . . . . . . . . . . 47 3.4.2 Different Types of Chip Formation . . . . . . . . . . . 49 3.5 Kinematic Surface Roughness . . . . . . . . . . . . . . . . . . 54 3.6 Mechanical and Thermal Strain on the Cutting Section . . . . . 55 3.6.1 Influence of the Geometry of the Cutting Section . . . 68 3.7 Wear . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 3.7.1 Wear Mechanisms . . . . . . . . . . . . . . . . . . . 71 3.7.2 Causes of Wear . . . . . . . . . . . . . . . . . . . . . 74 3.7.3 Forms and Dimensions of Wear . . . . . . . . . . . . 85 ix x Contents 3.8 Cutting Theory . . . . . . . . . . . . . . . . . . . . . . . . . . 87 3.8.1 Shear Plane Theory . . . . . . . . . . . . . . . . . . . 87 3.8.2 Application of Plasticity Theory to Cutting . . . . . . 92 4 Cutting Tool Materials and Tools . . . . . . . . . . . . . . . . . . . 95 4.1 Overview of Cutting Tool Materials . . . . . . . . . . . . . . . 95 4.1.1 Classification of Hard Cutting Tool Materials . . . . . 97 4.2 Tool Steels . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 4.2.1 Cold Work Steels . . . . . . . . . . . . . . . . . . . . 100 4.2.2 High Speed Steels . . . . . . . . . . . . . . . . . . . 101 4.3 Cemented Carbides . . . . . . . . . . . . . . . . . . . . . . . . 110 4.3.1 Historical Development . . . . . . . . . . . . . . . . 111 4.3.2 Cemented Carbide Production . . . . . . . . . . . . . 112 4.3.3 Components of Cemented Carbides and Their Properties . . . . . . . . . . . . . . . . . . . . . . . . 114 4.3.4 Microstructure . . . . . . . . . . . . . . . . . . . . . 116 4.3.5 Classification of Cemented Carbides . . . . . . . . . . 117 4.3.6 Uncoated Cemented Carbides and Cermets . . . . . . 123 4.3.7 Function Gradient Cemented Carbides . . . . . . . . . 123 4.3.8 Coated Cemented Carbides and Cermets . . . . . . . . 126 4.4 Coatings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 4.4.1 Coating Methods . . . . . . . . . . . . . . . . . . . . 128 4.4.2 Specific Properties of Hard Material Coatings . . . . . 149 4.4.3 Substrate Pretreatment . . . . . . . . . . . . . . . . . 161 4.5 Ceramic Cutting Tool Materials . . . . . . . . . . . . . . . . . 161 4.5.1 Cutting Ceramics . . . . . . . . . . . . . . . . . . . . 162 4.5.2 Superhard Non-metallic Cutting Tool Materials . . . . 173 4.6 Tool Designs . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 4.6.1 Solid Tools . . . . . . . . . . . . . . . . . . . . . . . 185 4.6.2 Tools with Inserts . . . . . . . . . . . . . . . . . . . . 187 4.7 Tool Preparation . . . . . . . . . . . . . . . . . . . . . . . . . 193 5 Finite Element Method (FEM) . . . . . . . . . . . . . . . . . . . . 197 5.1 Basic Concepts of FEM . . . . . . . . . . . . . . . . . . . . . 197 5.2 Lagrangian and Eulerian Considerations of the Continuum . . . 199 5.3 Explicit and Implicit Methods of Solution . . . . . . . . . . . . 199 5.4 Combined Thermal and Mechanical FEA . . . . . . . . . . . . 200 5.5 Nonlinearities . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 5.6 Material Laws . . . . . . . . . . . . . . . . . . . . . . . . . . 201 5.7 Software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204 5.8 Hardware . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 5.9 Phases of a Finite Element Analysis (FEA) . . . . . . . . . . . 205 5.10 The Use of FEM in Cutting Technology . . . . . . . . . . . . . 206 5.10.1 Continuous Chip Simulation . . . . . . . . . . . . . . 207 5.10.2 Segmented Chip Simulation . . . . . . . . . . . . . . 209 5.10.3 Simulation of the Cutting Process . . . . . . . . . . . 212 Contents xi 6 Cutting Fluids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219 6.1 The Functions of Cutting Fluids . . . . . . . . . . . . . . . . . 219 6.2 Types of Cutting Fluids . . . . . . . . . . . . . . . . . . . . . . 219 6.2.1 Non Water-Miscible Cutting Fluids . . . . . . . . . . 220 6.2.2 Water-Based Cutting Fluids . . . . . . . . . . . . . . 221 6.3 Guidelines on the Use of Coolant Emulsions . . . . . . . . . . 222 6.4 Effects of the Cutting Fluid on the Machining Process . . . . . 223 6.5 Selection of Cutting Fluids . . . . . . . . . . . . . . . . . . . . 226 6.6 Reducing or Avoiding the Use of Cutting Fluids . . . . . . . . . 227 6.6.1 Reducing Cutting Fluids . . . . . . . . . . . . . . . . 228 6.6.2 Minimum Quantity Cooling Lubrication (MQCL) . . . 229 6.6.3 Avoiding Cutting Fluids . . . . . . . . . . . . . . . . 233 7 Tool Life Behaviour . . . . . . . . . . . . . . . . . . . . . . . . . . . 237 7.1 Determining Tool Life Parameters . . . . . . . . . . . . . . . . 239 7.2 Machinability . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 7.2.1 Tool Life . . . . . . . . . . . . . . . . . . . . . . . . 240 7.2.2 Resultant Force . . . . . . . . . . . . . . . . . . . . . 243 7.2.3 Surface Quality . . . . . . . . . . . . . . . . . . . . . 245 7.2.4 Chip Form . . . . . . . . . . . . . . . . . . . . . . . 248 7.2.5 Cutting Speed . . . . . . . . . . . . . . . . . . . . . . 248 7.3 The Machinability of Steel Materials . . . . . . . . . . . . . . 249 7.3.1 Metallographic Constituents . . . . . . . . . . . . . . 250 7.3.2 Carbon Content . . . . . . . . . . . . . . . . . . . . . 252 7.3.3 Alloying Elements . . . . . . . . . . . . . . . . . . . 254 7.3.4 Types of Heat Treatment . . . . . . . . . . . . . . . . 256 7.4 Machinability of Various Steel Materials . . . . . . . . . . . . 263 7.4.1 Machining Steels . . . . . . . . . . . . . . . . . . . . 263 7.4.2 Case-Hardened Steels . . . . . . . . . . . . . . . . . 266 7.4.3 Heat-Treatable Steels . . . . . . . . . . . . . . . . . . 267 7.4.4 Nitrided Steels . . . . . . . . . . . . . . . . . . . . . 268 7.4.5 Tool Steels . . . . . . . . . . . . . . . . . . . . . . . 269 7.4.6 Hardened Steels . . . . . . . . . . . . . . . . . . . . 271 7.4.7 Non-rusting Steels . . . . . . . . . . . . . . . . . . . 274 7.5 Machinability of Cast Iron . . . . . . . . . . . . . . . . . . . . 280 7.5.1 White Cast Iron . . . . . . . . . . . . . . . . . . . . . 280 7.5.2 Grey Cast Iron . . . . . . . . . . . . . . . . . . . . . 283 7.6 Machinability of Non-ferrous Metals . . . . . . . . . . . . . . 290 7.6.1 Aluminium Alloys . . . . . . . . . . . . . . . . . . . 290 7.6.2 Magnesium Alloys . . . . . . . . . . . . . . . . . . . 293 7.6.3 Titanium Alloys . . . . . . . . . . . . . . . . . . . . 296 7.6.4 Copper Alloys . . . . . . . . . . . . . . . . . . . . . 311 7.6.5 Nickel Alloys . . . . . . . . . . . . . . . . . . . . . . 314 7.7 Machinability of Non-metals . . . . . . . . . . . . . . . . . . . 327 7.7.1 Graphite . . . . . . . . . . . . . . . . . . . . . . . . . 327 7.7.2 Fibre-Reinforced Plastics . . . . . . . . . . . . . . . . 331 xii Contents 8 Process Design and Process Monitoring . . . . . . . . . . . . . . . 339 8.1 Finding Economical Cutting Parameters . . . . . . . . . . . . . 339 8.1.1 Cutting Parameter Limits . . . . . . . . . . . . . . . . 339 8.1.2 Optimizing the Cutting Parameters . . . . . . . . . . . 342 8.1.3 Calculating the Machine Hour-Rate . . . . . . . . . . 350 8.1.4 Planning Methods and Tools . . . . . . . . . . . . . . 351 8.2 Process Monitoring . . . . . . . . . . . . . . . . . . . . . . . . 352 8.2.1 Sensors for Process Monitoring . . . . . . . . . . . . 354 8.2.2 Signal Processing and Monitoring Strategies . . . . . 371 9 Processes with Rotational Primary Movement . . . . . . . . . . . . 383 9.1 Turning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 383 9.1.1 Face Turning . . . . . . . . . . . . . . . . . . . . . . 385 9.1.2 Cylindrical Turning . . . . . . . . . . . . . . . . . . . 386 9.1.3 Helical Turning . . . . . . . . . . . . . .. . . . . . . 387 9.1.4 Profile Turning . . . . . . . . . . . . . . . . . . . . . 388 9.1.5 Form Turning . . . . . . . . . . . . . . . . . . . . . . 389 9.1.6 Further Process Variants . . . . . . . . . . . . . . . . 390 9.2 Milling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 390 9.2.1 Process Variants, Specific Characteristics and Tools . . 395 9.3 Drilling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 416 9.3.1 Profile Counterboring . . . . . . . . . . . . . . . . . . 416 9.3.2 Rotary Drilling . . . . . . . . . . . . . . . . . . . . . 418 9.4 Sawing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 439 9.4.1 Bandsawing . . . . . . . . . . . . . . . . . . . . . . . 439 9.4.2 Hacksawing . . . . . . . . . . . . . . . . . . . . . . . 442 9.4.3 Circular Sawing . . . . . . . . . . . . . . . . . . . . 442 10 Processes with Translatory Primary Movement . . . . . . . . . . . 445 10.1 Broaching . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445 10.1.1 Face and Circular Broaching . . . . . . . . . . . . . . 446 10.1.2 Profile Broaching . . . . . . . . . . . . . . . . . . . . 449 10.1.3 Form Broaching . . . . . . . . . . . . . . . . . . . . 451 10.2 Shaving . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 454 10.3 Planing and Shaping . . . . . . . . . . . . . . . . . . . . . . . 457 10.3.1 Face Shaping and Face Planing . . . . . . . . . . . . 458 10.3.2 Gear Shaping . . . . . . . . . . . . . . . . . . . . . . 459 10.3.3 Gear Planing . . . . . . . . . . . . . . . . . . . . . . 466 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 469 Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 497 Symbols and Abbreviations Capital Letters A mm2 Cross section A % Stretch ratio Ac1 Transformation temperature (Start of austenite formation) Ac3 Transformation temperature (End of austenite formation) Aα mm2 Flank face A′α mm2 Minor flank face Aγ mm2 Rake face A� mm2 Shear face AFK Aramid Faser reinforced plastics AIP Arc Ion Plating AV mm Offset BAZ Machining center Cf min Axis intercept of the expanded TAYLOR equation, f = 1 mm Cv min Axis intercept of the expanded TAYLOR equation, vc = 1 m/min CBN Cubic boron nitride CFK Carbon fibre reinforced plastics (CFRP) CNC Computerised Numerical Control CVD Chemical Vapour Deposition CWT Continuous wavelet transform D mm Tool diameter DC Direct current DLC Diamond-like carbon DMS Strain gauge DP Polycrystalline diamond DWT Discrete wavelet transform E Young’s modulus EB-PVD Electron beam-PVD xiii xiv Symbols and Abbreviations ECM Electro chemical machining EDX Energy-dispersive X-ray spectroscopy F N Resultant force Fa N Active force Fc N Cutting force FD N Thrust force Ff N Feed force Fp N Passive force F� N Shear force FFT Fast Fourier transform FVK Fibre-reinforced plastic (FRP) GFK Glass-reinforced plastic (GRP) H mm Stroke length HB Brinell hardness HC Diamond coated cemented carbide HF Fine grain cemented carbide HF-CVD Hot-Filament-Process-CVD HM Cemented carbide HRC Rockwell hardness HSC High Speed Cutting HSS High Speed Steel HT-CVD High temperature-CVD HV Vicker hardness KA C Imputed amortizations KE C Energy costs KI C Maintenance costs KF,min C/St. Minimal manufacturing costs per workpiece KMH C/h Machine hour-rate KML C Machine and labour cost hourly rate KR C Room costs KZ C Imputed interest KB mm Crater width KM mm Crater center distance KSS Cutting fluid KT mm Crater depth L C/h Hourly wage LARC Lateral Rotating Arc MQCL Quantity Cooling Lubrication MQC Minimum quantity cooling MQS Minimum quantity lubrication MQL Minimum quantity lubrication MSIP Magnetron Sputter Ion Plating MT-CVD Moderate Temperature-CVD NC Numerical control Symbols and Abbreviations xv NE-Metalle Non-ferrous metals PA-CVD Plasmaactivated-CVD Pc W Cutting power Pe W Effective power Pf Assumed working plane Pf W Feed power Pn Tool cutting edge normal plane Pne Effective cutting edge normal plane Po Tool orthogonal plane Pp Tool back plane Pr Tool reference plane Ps Cutting edge plane PW W Effective power PKD Polycrystalline diamond PM Powder metallurgy PM-HSS Powder Metallurgy High Speed Steel PVD Physical Vapour Deposition Q C Charge R � Electrical resistance Ra μm Average roughness Re N/mm2 Elastic limit REM Scanning electron microscope (SEM) Rkin μm Surface quality Rm N/mm2 Tensile strength Rp0,2 N/mm2 0.2%–yield strength Rt μm (Depth of) Surface roughness Rz μm Averaged surface roughness RF Radio Frequency S Major cutting edge S′ Minor cutting edge SKV μm Rounded cutting edge STFT Short-Time Fourier Analysis SVα mm Displacement of the cutting edge in the direction of the flank face SVγ mm Displacement of the cutting edge in the direction of the rake face T min Tool life T ◦C Temperature Tm ◦C Melting temperature Tr ◦C Room temperature Tsp ◦C Temperature on the chip upper side U V Voltage U0 V Feeding voltage VB mm Width of flank wear land xvi Symbols and Abbreviations VBmax mm Maximal width of flank wear land VHM Cemented Carbide Wc J Cutting work We J Effective work Wf J Feed work WZ-D mm Tool diameter WSP Insert Z Atomic number ZTU Time Temperature Transformation (TTT) Small Letters ae mm Width of cut ap mm Depth of cut apmax mm Maximum depth of cut apok mm Optimal-cost depth of cut a-C Hydrogenfree amorphous carbon film a-C:H Hydrogenated amorphous carbon film at.-% Atomic ratio B mm Width of undeformed chip bfα mm Width of chamfer C m/min Speed of sound cp Process capability index cpk Rectified process capability index dij pC/N Piezoelectric coefficient dW/dt m/min Growth of wear f mm Feed fa mm Axial feed fok mm Optimal-cost feed fmax mm Maximal feed fmin mm Minimal feed fr mm Radial feed fz mm Feed per tooth/cutting edge f0 1/s Eigenfrequency H mm Undeformed chip thickness hch mm Chip thickness hcu,max μm Maximal chip thickness hmin mm Minimal chip thickness K Strain sensitivity kc1.1 N/mm2 Specific cutting force, b = h = 1 mm kf1.1 N/mm2 Specific feed force, b = h = 1 mm ki N/mm2 Specific resultant force kp1.1 N/mm2 Specific passive force, b = h = 1 mm Symbols and Abbreviations xvii lc m Cutting path lf m Feed path mc Exponent of the specific cutting force mn mm Normal module pKSS bar Cutting fluid pressure rε mm Corner radius rß mm Rounded cutting edge radius sd Coating thickness T mm Pitch T s Time te,min min Minimal time per unit tg min Basic time tv min Additional time te min Time per unit ter min Recovery time th min Main process time tn min Auxiliary process time tr min Setting-up time ta-C Tetrahedral hydrogenated amorphous carbon film vc m/min Cutting velocity vch m/min Chip velocity vf m/min Feed velocity vfax mm/min Axiale feed velocity ve m/min Effective velocity x mm Profile offset z Number of teeth Greek Letters α ◦ Tool clearance angle αeff ◦ Effective tool clearance angle αf ◦ First tool orthogonal clearance (Broaching) αF ◦ Clearance angle at the pitch diameter (Gear shaping) αo ◦ Tool clearance angle αoe ◦ Working clearance angle β ◦ Wedge angle βo ◦ Wedge angle βoe ◦ Working wedge angle γ o ◦ Tool orthogonal rake angle γ n ◦ Tool normal rake angle γ ne ◦ Working rake angle γ oe ◦ Wirk-Orthogonalspanwinkel γ eff ◦ Effective rake angle xviii Symbols and Abbreviations ε Strain ε¯ Shear strain ˙¯ε s–1 Shear strain speed ε˙ 1/s Strain rate εk Critical strain εr ◦ Tool included angle η ◦ Effective cutting speed angle ϑ ◦C Temperature κ r ◦ Tool cutting edge angle κ re ◦ Working cutting edge angle λs ◦ Tool cutting edge inclination λse ◦ Working cutting edge inclination angle μ Coefficient of friction φ ◦ Phase φ ◦ Shear angle φf ◦ Slide angle ϕ ◦ Feed motion angle ρ kg/m3 Density σN/mm2 Stress σn N/mm2 Normal stress ω rad/s Angular speed Chapter 1 Introduction From about 12,000 to 50,000 years ago, human beings could already adapt stone tools with intentionally produced edges to specific machining tasks by varying the geometry of the cutting edge, as is shown in early tool findings from the Palaeolithic Age (Fig. 1.1). The discovery of how to extract metals such as copper, tin and iron was a huge milestone in the history of material and manufacturing technology. Since about 700 B.C., tools were almost exclusively made of iron. At the beginning of the 17th century, constant improvements in iron smelting led to the preferred use of iron and steel as construction materials instead of other metals known then and in place of wood, which had predominated until then. Inspired by the growth of the textile industry and the discovery of the steam engine, there was increased exploration into manufacturing technology at the begin- ning of the 19th century, leading by the second half of the 19th century to the first systematic investigations into cutting methods and initiating a completely new research area. At the end of the 19th century further research led to the discovery of new cutting tool materials and, at the turn of the century, to the development of high speed steel by F.W. TAYLOR, a significant contribution to the history of manu- facturing technology [Tayl07]. In light of these developments, SCHLESINGER said: “The dividends may lie on the cutting edge of steel, but the speed of these cutting edges is a function of the machine moving them, so as wages increase, the cutting machine is a trump card.” [Schl11]. Subsequent research followed in this direction, leading to the development of cemented carbide in 1923 by SCHRÖTER [Schr23, DRP25] at the SOCIETY FOR ELECTRIC LIGHTING as well as its use in machining by FRIEDR. KRUPP AG as WIDIA cemented carbide. Following this was the invention of oxide-ceramic cutting tool materials and their application in cutting after 1938 by OSENBERG as well as WENTORF’s development and synthesis of the superhard cutting tool material cBN (cubic-crystalline boron nitride) in 1956 [Went57]. The refinement of cutting tools with wear-resistant cemented carbide coats starting in 1968 by the companies Sandvik Coromant and Friedr. Krupp AG was a major contribution to improving productivity and economy [Sche88]. In order to fulfill the constantly increasing requirements made on workpiece quality and to make machining processes more economical, all the influencing 1F. Klocke, Manufacturing Processes 1, RWTH edition, DOI 10.1007/978-3-642-11979-8_1, C© Springer-Verlag Berlin Heidelberg 2011 2 1 Introduction Saw Drill End scraper Gravettian point Notched point Stemmed-base hafted scraper Side scraperRound scraperDouble tines Fig. 1.1 Flint tools, acc. to KERND’L [Kern72] parameters relevant for productivity and workpiece quality must be considered: cutting edge geometry, process kinematics, cutting parameters, materials, cutting tool materials and their coatings, wear behaviour as well as auxiliary materials. In this pursuit, the following quotation by SCHLESINGER can act as a guideline: “The machine tool must be designed with a view to the place it is used”. As an introduction to the subject matter, the compendium will be preceded by a general chapter providing a survey of the most important attributes of workpieces and their test methods. Chapter 2 Metrology and Workpiece Quality 2.1 Manufacturing Disturbances and Manufacturing History The basic task of manufacturing is to provide workpieces with specified quality characteristics in the required quantity in the most time- and cost-efficient way possible. Every manufacturing process is affected by variable disturbances, which can be both external and internal (occurring within the process itself). For this rea- son, the functionally determinative properties of the components are provided with tolerances. If a characteristic value lies outside of the permissible tolerance, it is defective. Thus important functional characteristics must be tested either already during manufacturing or at the end of manufacturing. Important disturbance factors which must be taken into consideration as possible causes of defects are: distur- bances caused by static forces, such as deflections effected by the workpiece weight or clamping errors; disturbances caused by dynamic forces which lead to either self-starting or forced oscillations; disturbances caused by thermal influences, such as process heat or internal sources of heat in the machine tool; and disturbances caused by tool wear (Fig. 2.1). This group also includes disturbances resulting from the engagement kinematics between the tool and the workpiece, such as generated cut deviations occurring during hobbing or diffraction effects on optical surfaces caused by systematically applied tool marks. Functionally determinative quality characteristics can be defined through macro- geometrical properties. Macro-geometrical properties include, for example, the accuracy of dimension, form and position of geometrical elements. Micro- geometrical parameters include, for example, characteristic surface values, such as roughness, mean roughness value and polishing depth. However, the functional integrity of the process requires that certain properties are tolerated although they lie below the surface in the peripheral surface zone. These may include hardness values, residual stresses or certain structural properties. The fluctuations of characteristics occurring in every manufacturing process can basically be derived from the influence of either systematically or randomly occur- ring disturbances. Systematic errors are caused by the system. They are reproducible under identical boundary conditions and change the characteristic in a single direc- tion; they cause manufacturing trends. Systematically acting disturbances cause deviations in characteristics. If the causes of systematic errors are known, they can 3F. Klocke, Manufacturing Processes 1, RWTH edition, DOI 10.1007/978-3-642-11979-8_2, C© Springer-Verlag Berlin Heidelberg 2011 4 2 Metrology and Workpiece Quality Prozess Statical disturbances • Clamping fault • Deflection • Thermal disturbances • Internal heat sources • Strain • Process heat • Environmental effect • Tool wear • Displacement of cutting edge • Flank wear • Flank roughness • Grinding wheel wear • Dynamic disturbances • Self-starting oscillation • Forced oscillation e.g. triggered over basement • • • • • • • • • • • • • Fig. 2.1 Variable disturbances in manufacturing be corrected and compensated. Examples of systematic errors are geometric errors of machine guiding elements and the development of cutting edge offset through the continuous wear of turning tools used in turning processes. Changes of the cut- ting force caused by sudden cutting depth fluctuations and the workpiece deflections associated with them may also be of systematic nature (Fig. 2.2). Randomly occurring disturbances lead to changes to characteristics, the effects of which cannot be predicted in a strictly deterministic way. They influence the result in both a positive and a negative direction. Thereby, the work result becomes unstable. The influence of random disturbances on the work result can, however, be statistically recorded. Examples of this include fluctuations in the structure of a material, random temperature fluctuations or sudden self-starting oscillations (rat- tling oscillations). Within real processes, it is not always easy to clearly decide between systematic and random influences. An important parameter describing the effect of random disturbances on a quality characteristic (i.e. on the variation of a quality characteristic) is process capabilityor the process capability index (Fig. 2.3). These process capability indices can only be applied if the variation of the characteristics are normally distributed. In practice, it is frequently required that cp ≥ 1.33. The process capability index is always taken as the dominant process 2.1 Manufacturing Disturbances and Manufacturing History 5 N om in al d ia m et er Pa ss iv e fo rc e F P / N D im en si on al e rr or / µ m Feed direction Cutting path 600 400 200 10 5 0 Workpiece material Cutting tool material Cutting speed Feed Ck55 N HW P10 Cutting part geometry: κr = 70° εr = 90° rε = 0.8 mm Cutting path 800 1000 v = 160 m/min = 0.25 mm vc f γ0 = 6° α0 = 5° lS = 0° Fig. 2.2 Influence of passive force on dimensional accuracy design criterion when large numbers of pieces must be manufactured with the high- est possible level of productivity. Variation in manufacturing batches occur, when it can not be guaranteed that all active elements work securely during the process being at its performance limits. If, for example, cutting edges are randomly failed during a cutting process because of cutting edge fractures or layer failures, this can have an immediate, significant on the process capability. Another example of critical process conditions is when the quantities of heat entering the workpiece at high process performances cause thermal strain to induce an increased variation of geometrical characteristics. These examples reveal that measuring and testing procedures in manufacturing are necessary both to guarantee the quality of the manufactured part and to start and develop processes. In general, several manufacturing steps are necessary to manufacture a part. Manufacturing progresses result from a manufacturing chain or a manufacturing sequence. With every manufacturing step, characteristic changes (geometry, surface, peripheral surface zone) are left behind on the part. Thus a manufacturing history develops (Fig. 2.4). The output properties of the part following a certain manufac- turing step in turn become the input factors for the processing steps which follow. There can also be a significant interaction between the current step in the process and previous changes. 6 2 Metrology and Workpiece Quality s 3s Process capability indices cp = 0,71 cpk = 0,71 cp = 2,50 cpk = 1,00 cp = 1,67 cpk = 1,33 cp = 5,00 cpk = 5,00 LTL 10 15 20UTL NV x - LTL x x Mean value of the random sample UTL: Upper tolerance limit Estimation of the spread of the totality LTL: Lower tolerance limit Mean deviation of the random sample NV: Nominal Value σ : s : x : Minimum proximity to process limit Half process spread =cpk = Tolerance band Process spread =cp = UTL - LTL 2 ( 3·σ ) xx _ _ _ _ _ _ _ _ _ _ _ _ _ _ ^ ^ _ _ |x - NV|min 3 σ^ ^ = 6s T _ Fig. 2.3 Process capability indices Lu Ll Lu Ll Machining center Grinding machine tool k1a c2b knx Turning milling Hardening Hard machining Assembling Forging, cold extrusion Enveloping cut deviation Texture Lu Ll Anisotropism Lu Ll Lu,l Upper and lower limit c1a k2b cnX k, c Damping and stiffness Machining center Geometry Fig. 2.4 Manufacturing history (Source: Getrag Ford) 2.1 Manufacturing Disturbances and Manufacturing History 7 Box part: Automobile-gearbox made of Mg-alloy AZ 91hp Standard tolerance IT 4 Requested cpk = 1.67 Manufacturing process: Primary shaping, machining Manufacturing dispersion: Affected by residual stress, chucking 0.008 0.01 Fig. 2.5 Representative case study – box part The hole in a transmission part shown in Fig. 2.5 could not be manufactured in a procedurally secure way with the required process capability index and specified. There can also be a significant interaction between the current step in the process and previous changes. The hole in a transmission part shown in Fig. 2.5 could not Work piece: Blisk (Blade integrated Disk) made of TiAl6V4 Tool: End milling cutter (D = 8 mm) Manufacturing process: Forming, 5-axis-milling Manufacturing dispersion: Process instability, chatter marks, long and slander tools Source: MTU stabil instabil stability boundD ep th o f c ut /m m Speed / min–1 Fig. 2.6 Stability bounds when milling a BLISK 8 2 Metrology and Workpiece Quality Manufacturing process: Forming, turning, drilling, broaching Manufacturing dispersion: Process anomaly, tool life decrease of the part Source: Rolls-Royce Work piece: Turbine disk made of Inconel718 Tool: VHM-drill (D = 8 mm)1000 10000 100000 1000000 Numbers of change of load K t xσ ap pl . / M Pa 50 µm Without anomaly Smeared material Low thermal influencing High thermal influencing Fig. 2.7 Surface damages when drilling with a worn drill be manufactured in a procedurally secure way with the required process capability index and the demanded productivity. This is due to released residual stresses which arised in the previous die-casting process. Figure 2.6 shows a part manufactured by milling with long, slender end mills. The milling process is only stable for certain combinations for cutting speed and depth of cut. When these areas are exceeded, rattling oscillations occur. These characteristic stability areas must be known; otherwise the process cannot be carried out at the performance limit. However, not only impermissible macro-geometrically or micro-geometrically recognizable changes may limit the process, but also impermissible changes in the peripheral surface zone. Figure 2.7 shows a turbine disk which was exposed to high mechanical and thermal stresses caused by machining the drill holes. These stresses damaged the peripheral surface zone in a way that significantly diminished the fatigue strength of the part. 2.2 Measuring and Testing Quality characteristics must be tested during the manufacturing due to the boundary manufacturing conditions mentioned above. This can be done by means either of samples or of a 100% test. A 100% characteristic check is prescribed for many safety-related parts. Though, a 100% test does not assure freedom of errors. 2.2 Measuring and Testing 9 Testing means determining whether the test sample exhibits the required char- acteristics, such as dimension, form and surface quality. This determination can be made in different ways, thus the distinction between subjective testing and objective testing. Subjective testing is performed by means of the sensory perception of the tester, e.g. visual and tactile tests. Examples of this are the evaluation of burr formations on the edges of parts and of shadings on polished surfaces. In objective testing, the tester is supported by testing equipment. There are two further methods which fall under this category; measuring and gauging. Measurement is the comparison of a characteristic with a measurement standard. The result is a measured value. Gauging is the comparison of the test object with a dimension or a form. The result is information regarding whether the specified requirements were satisfied or not (go or not-go). Testing equipment is subdivided into measuring instruments, gauges and aids. Measuring instruments and gauges are distinguished by material measures cor- responding to the measurand. Material measures can be of mechanical, electric, optical and electronic nature. Mechanical material measures may be, for example, distances between surfaces or angular positions of surfaces. Indicating measuring instruments have movable markers, divisions or counters. When using these devices, the measuredvalue reading can be either direct analogue or digital. In contrast to this, the gauge body corresponds merely to the dimension or the dimension and form of the required characteristic. Intermediate values cannot be defined. Table 2.1 provides a survey of the attainable accuracy values when using different manufacturing processes. Table 2.1 Survey of manufacturing qualities 16 Primary shaping Die forming (warm) Extrusion (cold) Turning Drilling Reaming Milling Grinding 1 2 3 4 5 6 7 98 10 11 12 13 14 15 Standard tolerance IT Deep drawing Erosion 2.2.1 Measurement Errors As a matter of principle, every measurement result is subject to error. Possible reasons for measurement errors are shown in the ISHIKAWA diagram in Fig. 2.8. The causes of measurement errors may lie in the measuring method, the measuring 10 2 Metrology and Workpiece Quality Measurement Measuring method Preparation Environment Temperature Humidity Air pressure Vibration Extraneous light Interference field Measuring personMeasuring deviceMeasured object Preliminary arrangements Cleanliness Protocol Calibration Unconsidered disturbances Aptitude Abbé principle error Testing deviation Aim of the measurement Measuring uncertainty Aptitude Measuring forces Assembling Aptitude Routine Evaluation Visual acuity Mistake Attention error Fig. 2.8 Causes for measuring errors by the measuring procedure instrument, the measured object, the person measuring, the preparation involved and the environment. In order to achieve a high measurement accuracy, it is necessary to take the abovementioned influences into consideration and, where applicable, to minimize them, compensate them, or at least to estimate them in terms of their magnitude. It can principally be distinguished between systematic and random disturbances in measurement procedures, as well [DIN1319a]. 2.2.2 Macro- and Microgeometry of Components 2.2.2.1 Structural Deviations With regards to components, the distinction is often made between macro- geometrical parameters and the surface quality. Macro-geometrical parameters refer to deviations of dimension, form and position. The surface quality is defined by roughness parameters. The transitions between these categories are not always clearly definable. DIN 4760 offers a general system for organizing structural devi- ations (Fig. 2.9). Therefore it is necessary to define the term “surfaces” at the beginning. The real surface (primary surface; see DIN EN ISO 4287) is the sur- face actually present on the part. The actual surface is the metrologically registered surface. It may differ from the real surface, since every measuring method can only approximate the real surface. A geometrically ideal surface is assumed in designs 2.2 Measuring and Testing 11 Superposition of structural deviations 1st up to 4th Order 5th Order: textural structure 6th Order: lattice structures of the material 4th Order: scores, scales (roughness) 3rd Order: grooves (roughness) 2nd Order: waviness 1st Order: form deviations Structural deviations (in superelevated representation) Not easily representable Fig. 2.9 Structural deviations, acc. to DIN 4760 and forms the basis of tolerances. In Fig. 2.9 six orders of structural deviations are defined on the basis of these observations. Structural deviations of the 1st order (see also the following sections) are fre- quently the result of systematic errors. With regards to waviness, i.e. the structural deviations of the 2nd order, one cannot clearly define whether they are caused by systematic or random influences. The unbalance of a rotating tool and any peri- odical oscillations caused by it are forced, while sudden rattling oscillations are self-starting. In general, fundamentally different actions must be implemented in order to exclude any systematic or random causes of error. Structural deviations of the 3rd order also occur regularly. They are to be attributed to the penetration between tool and workpiece and are often determined by means of penetration calculations. Examples of these are kinematic roughness associated with turning, surface marks created in peripheral milling and generated cut deviations created in hobbing. In such cases, the structural deviations can be influenced in a targeted way by means of generation kinematics and tool design. The higher orders of struc- tural deviation are primarily random in their occurrence. Examples of structural deviations of the 4th order include chip formation processes and removal processes. Roughness of the 5th order is rendered visible by structural properties on the surface. This can play a significant role in the high-precision machining of metallic optical mirrors. Thus in high-precision turning of multicrystalline metals, grain boundaries may become visible because the individual crystals exhibit varying orientations and therefore varying stiffnesses. In this case, anisotropism of the grains becomes visible on the surface. 12 2 Metrology and Workpiece Quality In general, all the structural deviations on a real surface are superposed. Filters are employed to separate roughness and waviness in a measurement process [DIN EN ISO 4287]. The following sections will treat macrogeometrical deviations of structure, form and position, as well as the corresponding measurement technology. Section 2.4 and the following sections describe the metrological recording of higher- order structural deviations. 2.2.2.2 Form Deviations Form deviations refer to deviations from a specified ideal geometrical property, such as straightness, evenness, roundness or cylindric form [DIN EN ISO1101, VDI2601]. The following will introduce some examples of form errors and their causes (Fig. 2.10). • A cause for deviations from the cylindric form of a workpiece can be the incorrect alignment of the workpiece on the machine tool with respect to the tool. • Another cause for form deviations is the continuous alteration over time of the tool geometry caused by wear. • Thermal displacements of the workpieces, tools and machine tools can also lead to form deviations. • Deviations from cylinder form can also arise when the workpiece deflects because of a radial strain. This can happen, for example, e.g. when turning long, slender parts when the workpiece is not supported. • Roundness errors can develop through the incorrect clamping of the workpieces on the machine tool. 2.2.2.3 Position Deviations Position deviations are deviations of the position of a geometrical element with respect to a reference, such as an edge, circulation line or axis of the predetermined position. In general, the position of two surfaces or axes in relation to each other is indicated by simple length or angle specifications. Fig. 2.10 Deviations from circularity and cylinder form 2.3 Length Testing Devices 13 Fig. 2.11 Deviations from concentricity, straightness and parallelism Position deviations as shown in Fig. 2.11 may arise, for example, through incorrect clamping or defective clamping devices. 2.3 Length Testing Devices 2.3.1 Material Measures A material measure in length measurement technology represents lengths or angles by means of fixed distances or angles between surfaces or lines. Setting standards are material measures. The material measures used most frequently are gauges. The most important and most precise material measures in length measurement technology are parallel gauge blocks. They consist of two plane-parallel measuring surfaces made of hardened steel or cemented carbide. Parallel gauge blocks are used in prismatic and cylindric forms. Gauge blocks are composed of grades. A standard set contains 5 grades each containing 9 blocks, from which almost any dimensions can be assembled (see Fig.2.12). The measuring surfaces are superfinished and even enough to allow, after careful cleaning of the measuring surfaces, individual gauge blocks to be joined together so that they adhere. Fig. 2.12 Gauge blocks (Source: Mahr) 2.3.2 Gauges A gauge measures dimensions or forms generally according to limit dimensions [DIN2257]. It can be distinguished between inspection gauges, limit gauges and form gauges (Fig. 2.13). 14 2 Metrology and Workpiece Quality 21,5 G o G u Fig. 2.13 Types of gauges: inspection gauges, form gauges, limit gauges Square profile Go side Not go side Multitooth profile Go side Not go side Go side Not go side Shaft Go side Not go side Drill hole Fig. 2.14 Different types of limit gauges Inspection gauges are parts of a gauge set for which the measure is assembled from the combination of gauges. Examples are the combination of parallel gauge blocks and the setting of feeler gauges. Form gauges allow for the testing of profiles using the light-slit method. They include angles, radius gauges and thread gauges. Limit gauges function according to Taylor’s principle: The go gauge must be designed in such a way that the dimension and form of the workpiece can be inspected when combined with the gauge. Not-go gauges are only used to inspect single dimensions. Limit gauges used most frequently are calliper gauges, limit plug gauges, gaug- ing rings and thread gauges (Fig. 2.14). Gauges are the simplest testing equipment used in industrial manufacturing. 2.3.3 Indicating Measuring Instruments Indicating measuring instruments consist of a material measure and a display mech- anism. The indicating range is the range of measured values that can be displayed on a measuring instrument. The measuring range is the part of the indicating range for which display deviations lie within specified or agreed limits. The suppression range of a measuring instrument is the range which must be exceeded in order that 2.3 Length Testing Devices 15 the instrument can begin to display values. The hysteresis of a measuring instrument equals the difference of the display values determined by measuring from different directions. The hysteresis of a measuring instrument is often not constant, which means that only a certain lower limit is indicated. The reversal error is principally a systematic error. It can be compensated. The sensitivity of a measuring instru- ment is the ratio of an observable change on the measuring instrument display to the causative parameter. Using length measuring instruments, the sensitivity is defined as the ratio of the range of the indicating element (e.g. the indicator) and the range of the measuring element (e.g. the spindle or measuring arm). Conversion between the measurement range and the display may be based on different physical prin- ciples. The most frequently used conversion elements are mechanical, electrical, pneumatic, optical and electronic conversion elements. 2.3.3.1 Instruments with Mechanical Converters Instruments with mechanical converters utilize mechanical or optical indicating elements. In length measurement technology, the most often used measuring instru- ments function on the basis of mechanical converters, e.g. threads, racks, gearwheels and blade segments (Fig. 2.15). With mechanical callipers with sliding glideways as the conversion element, the material measure is mounted on the bar on which the display, i.e. the slider, is moved. Mechanical callipers have two different scales which can be read off against each other by the observer. The scale on the slider is called a vernier (Fig. 2.15). In the case of micrometers, highly precise threads are used as converters and as a material measure. The system comprises a measuring spindle running in a sleeve, whose forward face is designed as the measuring surface and whose back end car- ries a ground thread as material measure. Typical thread pitches are 0.5 and 1 mm. As seen with callipers, two different scales are read off against each other. One scale is mounted on the sleeve, the other on the scale drum. In order to avoid influencing Fixed measuring jaw Moveable measuring jaw Clamp Bar Vernier Linear scale Measuring ambos Measuring spindle Scale sleeve Thimble Coupler Fig. 2.15 Setup of callipers and micrometers 16 2 Metrology and Workpiece Quality Arm with blade segment Rack Pinion Prestressed spring Plug gauge Fig. 2.16 Setup of dial gauges and dial comparator the measurements through large fluctuations in the measuring force, the latter is lim- ited to 5–10 N by means of a coupler (ratchet coupling). Micrometers are designed both as outside micrometers for external dimensions and as inside micrometers for internal dimensions (Fig. 2.15). Dial gauges are length measuring instruments equipped with racks and gear- wheels as conversion elements which allow a larger view of the path of the plug gauge. The material measure lies in the gear mechanism, the conversion element which leads to measurement reversal errors due to anisotropic friction and potential tolerance. Needle positions greater than 360◦ are possible (Fig. 2.16). Dial comparators are the most precise mechanical length measuring instruments. They are equipped, unlike dial gauges, with a gear mechanism as lever arm system, gear segment and pinion as conversion elements. Thereby, the movement of the plug gauge is transmitted to the needle. The design only allows needle positions smaller than 360◦ (Fig. 2.16). In principle, all the instruments with mechanical conversion elements described here can be equipped with frictionless optical indicator elements in order to improve precision. Given constant conversion behaviour, the more precise indications the measuring instrument should display, the longer the indicator must be. However, since there is only a limited amount of space in the instruments and, above all, since the inertia of the indicator can lead to distorted measurement results when the measurement range is small, optical indicator elements are used. The principle is basically this: a beam of light is directed to the material measure and, according to the position of the material measure, this beam is reflected in a different direction. The optical indicator then displays the measurement range of the material measure without friction and inertia. Further potential for increasing precision can be exploited by means of a fine graduation of the scale which can no longer be observed with the naked eye, thus necessitating optical magnifying aids in the form of microscopes. By means of the microscope, a mechanism consisting of an objective and an ocular, a magnifica- tion of a real image by the objective can be viewed with the ocular. In this way, a remagnified virtual image of the object is created. The total magnification through 2.3 Length Testing Devices 17 a microscope is the product of the objective and ocular magnifications. The scale graduation can be applied in the ocular directly or by means of an ocular plate. Microscopes including measuring oculars are called measuring microscopes. 2.3.3.2 Instruments with Electrical Converters These instruments are used to determine changes in the measurand caused by alter- ations of electrical properties, such as resistance, inductance and capacity. The turns of a coil, the distance between plates of a condensator and the resistance of an electrical conductor can all serve as material measure. Inductance, for example, is altered by changing the immersion depth of an iron core; the capacity of a plate capacitor is a function of the plate distance (Fig. 2.17). C ˙ s UB UA = UA = Bridge-output voltage UB = Bridge-supply voltage C = Capacity s = Measurement range o = Electric constant r = Dielectric constantA = Surface area d = Distance Position encoder Sensor Position encoder Output to measuring amplifier L1 L2 s R4 UA UB R3 d C = r˙ Ao ˙ ε ε ε ε Fig. 2.17 Capacitive and inductive measuring principles 18 2 Metrology and Workpiece Quality Inductive position encoder Fig. 2.18 Inductive working sensor in real execution An alteration of the ohmic resistance can be effected by changing the conductor length and/or by a cross-sectional variation [Hoff04, Grot05]. Figure 2.18 shows a real execution for multi-point measuring with inductive working sensors. 2.3.3.3 Instruments with Optical Converters These length measuring instruments exploit the wave property of light. The wave- length of light is used as the material measure. Figure 2.19 shows the functional principle of a laser interferometer. Mirror Laser Detector Wedge prism of the measuring beam Measuring path Polarizing beam splitter Displacement Wedge prism of the reference beam R ef er en ce p at h Interference of measuring und reference beam Fig. 2.19 Longimetry with laser interferometer 2.3 Length Testing Devices 19 ϕ2 ϕ3 λ3 λ1 λ2 Time Am pl . l Am pl . Time Am pl . Time TimeA m pl . Interference of two coherent light waves out of phase (destructive interference) Monochromatic light Am pl . Time Interference of two coherent light waves with the same phase length (Addition of illuminance) λ: Wavelength ϕ : Phase difference Light mixture of different wavelengths Monochromatic and coherent light λ ≠ const. ϕ ≠ 0 λ = const. λ = const.ϕ ≠ 0 ϕ = 0 ϕ2 ϕ3 λ λ Fig. 2.20 Optical measuring principle, interference A light source emits coherent, monochromatic light whose beam is split into a reference beam and a measuring beam at a polarizing beam splitter. These beams are reflected on a respective wedge prism and combined again through superposition. Finally, the combined beam is detected and evaluated. If the wedge prism of the measuring beam is shifted, interferences occur because of the difference of the opti- cal paths of the two partial beams after combining them. These are fluctuations in light intensity via eliminating and amplifying light. Integral multiples of the wave- lengths lead to an amplification, phase differences of 180 degrees to an elimination of light (Fig. 2.20). The number of interference lines is directly related to the path being measured. Since the wavelength of the light is a function of temperature and also air pressure and humidity, these influences are compensated within the device. The advantages of such systems lie in their large measuring range and especially in their contactless measurements. 2.3.3.4 Instruments with Pneumatic Converters These instruments use pressure and flow rates as material measures (Figs. 2.21 and 2.22). This measuring principle can be used for both tactile and contactless measure- ment (Fig. 2.22). There are two types of such measuring instruments: high-pressure and low- pressure instruments. High-pressure instruments work with an operating pressure greater than 0.5 bar, low-pressure instruments with an operating pressure lower than 20 2 Metrology and Workpiece Quality 1 2 3 4 s Volume measuring method 1. Air filter 2. Pressure control 3. Flowmeter 4. Measuring nozzle 1 2 h 6 3 4 5 s Velocity measuring method 1. Air filter 2. Pressure control 3. Venturi-nozzle 4. Flow of valve 5. Measuring nozzle 6. Differential pressure manometer Fig. 2.21 Measuring principle of pneumatic distance measurement Air inlet Valve Follower Work piece Guide body Measuring nozzles Drill hole Tactile measurement Contactless measurement Fig. 2.22 Pneumatic sensor 0.1 bar. The pressure range between 0.1 and 0.5 bar is outside the operating range of the instrument [DIN2271a]. Figure 2.23 shows the functional principle of contactless pneumatic measure- ment. The left side shows an external measurement, the right side an internal measurement. If the measuring rod is designed in a way that both measuring nozzles 2.4 Surface Inspection 21 Measuring nozzle ∅dm h Annulus pa pa ps Work piece surface Measuring nozzle Test sample Fig. 2.23 Functional principles and examples for pneumatic measurement work within the linear range of the characteristic diagram, then an exact centring in the hole is unnecessary, since the air currents of the two nozzles are added and the sum represent the measure for the total gap width. Since the type of hole measure- ment described is a two-point measurement, deviations from hole roundness and diameter can be determined by turning the rod or the workpiece. The measuring rods are often specially adjusted to the measurement of a spe- cific workpiece. Therefore, for economical reasons, pneumatic measurement is used predominately in serial production, especially if a 100% test is required. The advantages of contactless pneumatic measurement lie in the self-cleansing effect of the measuring device (i.e. the workpieces do not generally have to be cleansed of oil, dirt or micro-chips) and in the quickness of the measuring process. 2.3.3.5 Electronic Measuring Instruments These devices work with photoelectric sensors, by which light-dark fields of a gauge are converted into electric signals. The material measure is realised through the light-dark fields. Impulse gauges and code gauges are preferably used as path mea- surement systems. To be precise, it is a mechanical guidance system whose positions are detected and indicated optoelectronically. This path measurement system is also executed with callipers, dial gauges and dial comparators. It is also realized in coordinate measuring devices and machine tools. To control measuring axes and to evaluate data, an exact control system and effective software are required which can influence the quality of the measuring result and the applicability of the data [Pfei01]. The measurement of freeform surfaces and tooth-flank topographies on spur gears and bevel gears with coordinate measuring devices is currently state of the art (Fig. 2.24). 2.4 Surface Inspection The task of characterizing a technical surface consists in attaining a complete topological record of its three-dimensional geometry and describing it. Often, in order to simplify the measuring process, only parameters for surface roughness along a single measured length are registered (one-dimensional parameters). This 22 2 Metrology and Workpiece Quality Fig. 2.24 3-D coordinate measuring machines procedure is frequently followed in practice and is sufficient in many cases. For cer- tain applications, e.g. in optics or for characterizing grinding wheel surfaces, more comprehensive, multi-dimensional surface descriptions must be used. However, the following will exclusively treat one-dimensional parameters. 2.4.1 Surface Parameters In most of the procedures used in industrial surface inspection technology, only structural deviations of the second or higher orders are analyzed and measured on surface sections. These sections must be statistically representative for the entire surface [DIN2257]. The surface can be detected by means of surface sections or the bearing surface (Fig. 2.25) [DIN4760]. Profile sections are sections which are oriented to the surface normally, tangentially or at other angles. First, a profile section will be used to illustrate some of the basic terms of surface inspection technology (Fig. 2.26). With respect to a profile, the distinction is made between the test length Lt of the surface section being metrologically detected and Tangential cross sectionProfile α Profile Cross section parallel to the tangentialcross section Diagonal crosssection Vertical cross sections Fig. 2.25 Registration of structural deviations by surface cuts 2.4 Surface Inspection 23 Ra Z (x) Measured length L Zt 1 L1 L2 L3 L4 L5 L6 Zp 1 Zv 1 Zv 2 Zp 6 x Fig. 2.26 Fundamental terms of surface inspection technology the measured length L, which is used for evaluation (L < Lt) [Grot05]. The detected profile (actual profile) of a surface depends on the measuring procedure and the filter used, thus it only represents an approximate image of the actual surface. The refer- ence profile shifted within the measured length perpendicularly to the geometrically ideal profile is defined as the middle profile. This is oriented in such a way that the surface areas above and below the middle profile line are equally large (Fig. 2.26). By using different measuring procedures and depending on which filter is used, different profiles can be determined [DIN EN ISO 4287]. These are the P-Profile (primary profile), the R-Profile (roughness profile) and the W-Profile (waviness profile) (Fig. 2.27). Grenzwellenlänge: λ = 0,75 mm 1 µm 250 µm 1 µm 250 µm 1 µm 250 µm W-Profil (Welligkeit) R-Profil (Rauheit) Without wave filter High-pass filter Low-pass filter W-Profile (waviness) R-Profile (roughness) Cutoff wavelength: λ = 0,75 mm 250 µm 1 µm 250 µm 1 µm 250 µm 1 µm P-Profile (waviness and roughness) Manufacturing technology: Short-stroke honing Average roughness: Ra = 0.75 Scanning system: HAT 25/6 Scanning path: 10 mm Fig. 2.27 Separation of waviness and roughness by wave filter 24 2 Metrology and Workpiece Quality The examples given below refer to the R-Profile (roughness) (Fig. 2.26). According to DIN EN ISO 4287, the following roughness parameters can be distinguished: • The height of the highest profile point Rp: value of the y-coordinate Z(x) of the highest profile point of the middle profile line within the sampling length Li. • The depth of the deepest profile valley Rv: value of the y-coordinate Z(x) of the deepest point of the profile of the middle profile line within the sampling length Li. • The total height of the profile Rt: the sum of the highest profile point and the depth of the deepest profile valley within the measured length L. • The greatest height of the profile Rz: the sum of the height of the highest pro- file point Rp and the depth of the deepest profile valley Rv within a sampling length Li. • The mean roughness value Ra: the arithmetic mean of the values of the y-coordinates Z(x) within a sampling length Li. Ra = 1L L∫ 0 |Z(x)| dx (2.1) Horizontal parameters (distance parameters) are also designated as bearing lengths. They are determined by means of tangential sections. Forming a ratio of of the summed single bearing lengths and dividing by the measured length yields the relative bearing length (material ratio) in a specified section depth c. By creating sections at different depths c, the bearing ratio curve – also called the ABBOTT-FIRESTONE curve – can be determined (Fig. 2.28). The bearing ratio of the roughness profile Rmr(c) is calculated as follows: Rmr(c) = ∑ Xi L (2.2) Measuring length L c 10060200 Rmr (c ) / % x1 x2 x3 x4 x5 x6 x7 x8 x9 x10 x Z(x) Fig. 2.28 Bearing ratio curve of the profile, acc. to DIN EN ISO 4287 2.4 Surface Inspection 25 The bearing ratio can be calculated on the basis of the primary profile (Pm), the roughness profile (Rm) and the waviness profile (Wm). Using the average roughness, Table 2.2 provides an overview of the surface roughness values which can be achieved with different manufacturing processes. With respect to general specifications on achievable surface values, one must consider the fact that it is not necessarily possible to deduce the manufacturing pro- cess when using one-dimensional parameters for describing the surface [Abou76]. Due to the characteristic engagement conditions between the workpiece and the tool one would also have to specify, for each surface parameter, which manufacturing process is to be used to create that parameter. This problem is somewhat alleviated if multiple one-dimensional surface parameters are used instead of just one when describing the manufactured surface or if surface reference standards are available (Figs. 2.29 and 2.30). Table 2.2 Achievable average roughness 10 00 Primary shaping 0. 1 0. 25 0. 4 1 2 .5 4 1610 25 40 0 25 0 Achievable average roughness Rz / µm 0. 04 16 0 30 0 63 0 Die forming Extrusion Turning Drilling Reaming MillingMilling Grinding Erosion Rough and finish turned Planed Honed Grinded Fig. 2.29 Surface quality for several manufacturing operations 26 2 Metrology and Workpiece Quality Flat lapping Reaming Flat grinding Horizontal milling Face milling Cylindrical turning R ou gh ne ss R t (µ m) Ar ith m . a ve ra ge ro u gh ne ss R a (µm ) 10 3. 0 0. 55 0. 05 0. 1 0. 2 0. 4 0. 8 1. 6 2. 5 8. 0 4. 0 16 32 50N 7 N 6 N 5 N 4 N 3 N 2 N 10 N 9 N 8 N 7 N 6 N 5 R ou gh ne ss m ar kl IS O R 1 30 2– 19 71 Su rfa ce m ar k D IN 1 40 Ar ith m . a ve ra ge ro u gh ne ss R a (µm ) 1 2. 5 6. 3 3. 2 0. 8 0. 4 R ou gh ne ss R t (µ m) 6, 0 1. 0 1. 6 1. 6 Fig. 2.30 Surface reference standard (Source: Rupert) 2.4.2 Subjective Surface Inspection In some cases, a visual inspection can determine whether the processed surface meets the specified requirements. A testing device frequently used in the work- shop is the straight edge, which is used to check the evenness of a surface using the light-slit method. In workshop operations, spotting straight edges or spotting plates are used to detect form deviations or contact patterns on the workpiece surface (Fig. 2.31). Impression methods using lacquers have been developed for surfaces which are difficult to access (e.g. drill holes, internal surfaces). The lacquer is applied onto the Spotting straight edge Spotting medium Work piece Grey gleaming areas (bearing points) Light areas (lowest points) Black areas (spotting medium) Spotting plate Fig. 2.31 Surface inspection by spotting 2.4 Surface Inspection 27 test surface and pulled off after drying. The contact patterns attained on the lacquer film thus attained can then be evaluated. A frequent use of spotting is detecting contact patterns in quality testing and in the assembly of gear teeth (especially bevel gear teeth). Applying spotting paste and then rolling the teeth under light strain causes the bearing points on the tooth flanks to become visible. These bearing points can then be compared to the reference contact pattern. Nowadays in individual cases machine-tool guiding elements also become scraped, therefore, spotting is used to judge the surface. 2.4.3 Surface Measurement All the physical principles mentioned in the context of length measurement technol- ogy are also fundamentally applicable to surface measurements. Since mechanical and optical measuring methods have proven to be the most effective in this field, the following discussion will limit itself to these methods. 2.4.3.1 Mechanical Measuring Methods Devices for surface measurement which function on the basis of a mechanical functional principle are generally referred to as stylus instruments. Mechanical mea- suring methods are classified as either scanning methods or sensing methods. In the scanning method, a contact stylus descends upon the surfaceto be tested at a speci- fied frequency. The surface is guided under the needle with a constant feed rate. The path of the contact stylus can be visualized mechanically, optically, electrically or electronically. The contact stylus can either be raised to a fixed level (the WOXEN principle) or raised by a fixed amount from the respective point of impact to the surface (differential tactile procedure) (Fig. 2.32). In the differential tactile procedure, the impact energy of the contact stylus is lower in comparison to the WOXEN principle and exhibits marginal dispersion. As a result, the penetration depth of the needle remains constant, the measuring accuracy being thus higher than in the case of the WOXEN principle. In the case of instruments functioning according to the sensing method, the contact stylus is guided continu- ously over the surface. The needle rises and falls in line with the profile pattern Scanning method Sensing method Woxen principle Differential tactile procedure Differential tactile procedure Fig. 2.32 Mechanical measuring methods 28 2 Metrology and Workpiece Quality Caliper Caliper slide Table Plane of reference system Caliper slide Caliper Skid Oscillating scanning system Caliper Scanning arm Skid Semi-rigid System Fig. 2.33 Different surface scanning systems (Fig. 2.32). The lifting motion is indicated relative to a reference point defined in the device or to a reference level. Here too, mechanical, electric, optical and electronic converters are used. Sensing profile methods are the most widespread in practice. Independently of the design type of the contact stylus instruments used, three system designs are distinguished (Fig. 2.33). Plane of Reference System In this system, the scanning unit is guided on a reference surface (plane, cylinder) which corresponds to the ideally geometrical surface of the test sample and is ori- ented along the surface to be measured (Fig. 2.33). Aside from errors arising due to the calliper geometry, this scanning system provides a faithful transmission of the roughness and waviness values of the test sample. When measuring small or very large surfaces, however, the handling of this scanning system can frequently become unwieldy. An alternative is the reference surface contact system. Here, the work- piece is conveyed on very precisely guided slides in a horizontal direction beneath the firmly anchored scanning system. Besides roughness, the macrostructure of a surface can also be detected in certain areas. Semi-Rigid System In semi-rigid systems, the scanning unit, which contains the contact stylus, is guided on the skid gliding on the surface to be measured (Fig. 2.33). This system has the advantage that it requires little space and is thus suitable for measuring small or hard-to-access surfaces. A disadvantage is that the system requires an orientation to the surface to be measured which can cause parts of the profile to be transmitted in a distorted manner. Oscillating Scanning System Two glide skids guide the scanning unit of the oscillating scanning system (Fig. 2.33). The latter is oriented towards the surface to be measured and is thus 2.4 Surface Inspection 29 comfortable to operate. However, it requires more space than the single skid system and can therefore not be used for small or hard-to-access surfaces. The distortions caused by long-wave profile sections are smaller than those in half-rigid systems, because the skids are flat and farther apart. Nevertheless the waviness must be filtered out in many cases [Henz68]. Usually, the magnification gauges for x- and y-coordinates are selected in a highly varying way in profile records. This is necessary because the measuring lengths (abscissa) lie in the mm region and roughness parameters are represented on the ordinate which lie in the μm region. The optical impression of the profile record is thus strongly distorted in comparison to reality. The contact styluses used in con- tact stylus instruments often have an apex radius of 2 μm. They function with a bearing strength of 0.5 N, which can result in considerable surface pressures (up to 6000 N/mm2), which possibly cause alteration of the test surface. On the other hand, excessively large contact stylus radii distort the result; they act like mechan- ical filters. Thus the optimal conditions must be determined on the basis of the material of the test sample and documented in their entirety in the measurement report. 2.4.3.2 Optical Measuring Methods White-Light Interferometer This technology differs from length measuring technology both in that it employs white light, i.e. light with the entire wavelength spectrum, and in that it does not just use one beam, as with laser interferometers, but rather an entire bundle. A reflected- light microscope is used to display an image of a section of the test object on a detector (e.g. CCD camera). By using different interference lenses, a beam splitter can be used to superimpose a highly accurate reference surface with the image of the test object on the same scale. The interferences which are then created can be detected and evaluated (Fig. 2.34). The topography of the test object creates a spatial modulation of the light intensity in the interference image. Depending on the surface to be measured, two different measuring modes are used: one to characterize very flat surfaces with an average roughness value Ra < 1 nm and one for all other surfaces. Steps and roughnesses of up to several millimetres high can be displayed using this technology. Fringe Projection The fringe projection method functions according to the triangulation procedure, in which equidistant stripe patterns are observed and evaluated at a certain angle, i.e. the triangulation angle. The stripe patterns on the test object are detected and evalu- ated from a certain position, with the projected stripes following the arbitrary form of the test surface. These stripes appear from the observer’s standpoint to be “inter- ferences”, though they only appear this way because the location of the projection 30 2 Metrology and Workpiece Quality Lenses Light Detector Displacement Interference of measuring and reference beam Te st o bje ct z x Reference mirror D is pl ac em en t Fig. 2.34 Principle of a white-light interferometer (two-beam interferometer) surface points varies in relation to that of the projector. The stripe patterns then are evaluated interferometrically on the basis of fluctuations in light intensity. The most important geometrical values on which this method is based are: • the real distance of the projected stripes • the stripe distance registered from the position of observation • the triangulation angle Fringe projection is used, for example, to judge surfaces bent over a large area, such as those found in deep-drawing tools and on deep-drawn parts. The advantages of this method are a high measurement speed and a spatial or laminar scanning. A disadvantage is that the test objects may not be transparent or reflective. 2.5 Inspection of the Workpiece Rim The functional behaviour and applicability of a component depend not only on its macrogeometry and surface roughness, but also from the physical properties of the material both on the interior and near the surface. While the inspection of material properties properly belongs to the field of materials science and materials testing and thus cannot be treated here in further detail, the following will discuss some of the properties of technical surfaces and of layers near the surface (i.e. the rim zone) and methods used to measure rim zone properties. Technical surfaces can be categorized according to types of load into the following groups: 2.5 Inspection of the Workpiece Rim 31 • external surfacesof technical products of all types, i.e. visible surfaces, covering surfaces, indicating surfaces, etc. They are generally mechanically unstrained, but are exposed to climatic or environmental stresses. • surfaces subjected to heat, radiation or electrical currents, such as insulating sur- faces, electrical contacts, or the like. Such surfaces are referred to as thermally stressed, radiation stressed or electrically stressed surfaces. • surfaces which come into contact with fluids or gases. On the one hand, a corrosive stress may be predominant, or a flow stress with cavitation and ero- sion processes may occur in the case of flowing media. Also, surface boundary currents may be influenced via microstructures (ribblets). • surfaces in mechanical contact with moved counter bodies. This strain is referred to as tribological stress. These stresses are found, for example, in typical machine elements, such as bearings, couplings, brakes, gear-teeth, etc. With this type of stress, different kinds of wear may occur. • optical surfaces used to form and conduct electromagnetic waves. Optical surfaces are produced with mirrors and transparent components. The basic beam-conducting and forming principles are reflection, refraction and diffraction. • biologically stressed surfaces exposed to the effect of microorganisms. 2.5.1 Surface Layers The properties of technical surfaces relevant to component behaviour are determined through the entirety of the physical and chemical properties of the surface layer. These properties include textural structure, hardness, strength and residual stresses in the rim zone near the surface. The surface rim zones of technical bodies are created through machining processes. A part of the energy used to create the surface always flows into the workpiece and is either stored or causes change processes in the base material. Thus every machining process also causes a change of the surface rim zone vis-à-vis the base material. Whether these changes affect the functionality of the workpiece must be tested and confirmed in individual cases. The distinction is frequently made between the external and the internal boundary layer. Figure 2.35 shows the structure of both boundary layers. The layers referred to here cannot be clearly defined; there are no fixed boundaries between them. For further reference, please refer to the following sources: [Schm36, Schl51, Czic03]. 2.5.1.1 The External Boundary Layer The external boundary layer is located between the surrounding atmosphere and the atoms of the base material embedded in the crystal lattice. It is generated via the reaction between the material and the atmosphere during and after machining. The external boundary layer encompasses the following individual layers: 32 2 Metrology and Workpiece Quality 1–10 nm 0.3–0.5 nm 10–100 µm Oxide film Adsorption layer Grease-/ oil film External boundary layer Internal boundary layer > 5 μm Matrix Plastic deformed and hardened Elastic und plastic deformed Elastic deformed Fig. 2.35 Layer structure of metallic surfaces, acc. to SCHMALTZ [Schm36] Reaction Layers/Oxide Film On the surface of metals which are either freshly machined or created through breakage can form thin reaction layers/oxide films. These layers may only have a thickness of 10–20 molecular layers. They may, for example, influence wetting capability or adhesive behaviour. Adsorption Layer After a short duration of time of being exposed to the air, the oxide layer is covered with an adsorbed layer of water and gas. This adsorption layer becomes considerably important, for example, in the context of electrical resistance when metallic contacts are present. Grease/Oil Film Coolants in particular cause a grease and oil film to deposit itself after machining on the adsorption layer. This film ranges from 10 μm to several 100 μm in thickness. A grease and oil film can still be detected even after cleansing. These films can exert considerable influence interface formation in further galvanic, adhesion, or PVD/CVD processing. 2.5.1.2 The Internal Boundary Layer The internal boundary layer is the layer of the machined workpiece bordering on the base material and thus possesses practically the same chemical composition as the 2.5 Inspection of the Workpiece Rim 33 Worn toolSharp-edged tool Cutting tool material: HC Material: C15 vc = 200 m/min f = 0.1 mm 50 µm 50 µm Fig. 2.36 Plastic deformation of the workpiece rim by drilling base material. The physical structure and the expansion of this layer in the direction of the workpiece interior depend both on the material used and the manufacturing operation used. The transition from the affected rim structure to the unaffected base structure is continuous. Figure 2.36 shows a model of the plastic deformation of the structure of case-hardened steel C15 after a drilling operation. Larger mechanical and ther- mal stresses caused by worn tools lead to clear modifications of the textural structure. In steel material processing, for example, given high enough temperatures and high cooling rates, a hardening zone may develop in the outermost surface layer. In the layers below this, annealing processes are possible due to the lower temperatures and cooling rates in these layers (Fig. 2.37). As shown in Fig. 2.37, a hardening zone has developed which has an extremely negative effect on the flank bearing strength. 2.5.2 Inspection of the Surface Rim Zone Since, in addition to surface geometry, the physical properties of the areas near the surface play an essential role, these properties must be tested, too. Therefore methods familiar in the field of materials testing are applied: • material analysis • structure and texture investigation • hardness testing • fracture mechanical testing • residual stress measurement Structural changes caused by increased thermal stresses of the rim zones near the surface can be determined in structure and texture investigations which are standardly used in materials science. This is done by metallographic preparations. Crack detection in rim zones of workpieces can be either destructive or non- destructive. A crack is a locally limited detachment of the material structure of small width but often considerable length and depth. The crack can arise through internal 34 2 Metrology and Workpiece Quality df dwLF RF Left flank Right flank Grinding burn with new hardening zone left flank 200 µmLF Pitting at the tip of a tooth 200 µmRF 400 500 700 900 1000 300 800 600 Vi ck er s ha rd ne ss / HV 0, 05 0 2 4 6 8 10 Distance from edge d / mm Left flank Fig. 2.37 Grinding burn during gear tooth grinding tensions or through external force effects. For further reference, please refer to the specified literature [Schu04]. 2.5.2.1 Residual Stresses Residual stresses are characteristic for the internal tension of a load-free workpiece. This tension results from inhomogeneous elastic and elastic-plastic deformations which are present without the influence of external forces and torques. For every component, there is a balance of all the internal forces and torques created by resid- ual stress. Residual stresses are subdivided into macro-residual stresses (type 1) and micro-residual stresses (types 2 and 3). Residual stresses caused by mechanical and thermal influences is treated in the chapters devoted to the relevant manufacturing operations. The basic formation mechanisms of thermally and mechanically induced residual stress are shown in Fig. 2.38. Residual stresses become significant in the context of dynamic stresses. The attempt is therefore often made to use manufacturing processes in finishing which create compressive residual stresses in the surface rim zone in order tominimize the probability of crack formation and crack growth. Such operations include, for 2.5 Inspection of the Workpiece Rim 35 Yielding point Stra in Rel eas e Deformation path Te ns ile (+) Co m pr es sio n(– ) St re ss Yielding point Plastic deformation sE– Compressive residual stress (mechanical caused) Temperature Cooling Heating High-temperature limit of elasticity High-temperature limit of elasticity Plastic deformation Tensile residual stress (thermal caused) Te ns ile (+ ) Co m pr es sio n (–) St re ss sE+ Fig. 2.38 Formation of residual stress example, finish and surface rolling as well as shot peening. In contrast, tensile residual stress is probable in electrical discharge machining, because of its ther- mal operating principle; in grinding and all manufacturing operations which use geometrically defined cutting edges, both mechanical and thermal load spectrums occur during processing, a prediction of the stress state is not easily possible. Methods of Analysis For all processes, the metrological definition of residual stresses occur indirectly through the measurement of strains, electromagnetic parameters or speed of sound. Below, the basic methods used in manufacturing technology will be explained. For further information on this topic, please refer to the specified sources [Peit92, Hauk87]. Mechanical Methods The mechanical methods of analysis include the borehole method and the toroidal core method. These are destructive methods which release residual stresses in the rim zone near the surface through the insertion of very small holes or ring grooves in this zone, which causes an altered stress state and thus strains, which can be measured with wire strain gauges, for example. The average residual surface tension can then be calculated from the strains in consideration of the material behaviour. By removing layers of the surface rim zone at different surface positions, dis- tributions of residual stresses can be defined up to the depth corresponding to the drill’s diameter. Since drilling or milling processes only cause reproducible strain changes at a depth of several hundredths of millimetres, this method cannot be used to determine residual surface stress with strong rim zone gradients. 36 2 Metrology and Workpiece Quality X-ray and Neutron Diffraction In research and practice methods are used which utilize the diffraction of monochro- matic X- or neutron radiation on the crystalline lattice structure of the material phases (Fig. 2.39). The BRAGG condition applies here: n · λ = 2 · a · sin � (2.3) Altered lattice distances a of the material phases can be calculated very accurately from the displacement of the diffraction lines, which in turn allow to draw con- clusions about residual stresses. The chosen measuring direction defines the stress components to be detected. This allows the definition of the entire stress tensor by measuring in multiple directions. In order to calculate residual stresses from strain measurements, the elastic properties of the material phases are used. In the case of many materials, their anisotropic behaviour can even be taken into consideration when measuring at the respective lattice levels. Figure 2.40 shows the customary device for measuring residual stresses (goniometer). Source of radiation ϑ ϑ ϑ λ a Detector Fig. 2.39 Principle of X-ray diffraction on crystalline lattice X-ray tube Detector Swivel table Specimen Rotating table Fig. 2.40 Goniometer 2.5 Inspection of the Workpiece Rim 37 Diffraction methods demand high requirements on measurement technology and on occupational safety (radiation protection). X-ray diffraction is used in practice to define residual stresses. In research, neutron sources can also be accessed at selected locations, with which it is possible to detect depth structures up to some millimeters without removing surface layers. The X-ray method has a depth of penetration which is limited to an extent depending on the absorption properties of the material and the wavelength used for the X-radiation. Given the usual measuring parameters, the average penetra- tion depths vary between approximately 1 μm for tungsten carbide and 5 μm for steel; significantly greater depths of penetration are possible for light metals. Residual stress depth profiles with great rim depths can be produced through the electrochemical removal of layers of the surface rim zone. Magnetic Methods Magnetic analysis methods use the influence of mechanical stresses on resetting in ferromagnetic materials. These changes can be measured by means of an exter- nally applied alternating magnetic field. The measurands are coercive field strength, superposition permeability, dynamic magnetostriction and magnetic and acoustic BARKHAUSEN noise. The simultaneous analysis of several magnetic parameters improves the evaluation of the quantitative measuring data. Magnetic methods are characterized by compact and easily manageable test set-ups. Depending on the material and the range of frequencies analyzed, surface rim zones can be gauged ranging from a few micrometers to over 1 mm. Disadvantegous is that these meth- ods they are limited to ferromagnetic materials and have to be calibrated to known material states. Acoustic Methods Residual stresses are generated through lattice strains of the material which result in an altered propagation of structure-borne sound. This acoustic-elastic effect can be used to analyze stresses by means of ultrasonic measurements. Such methods are based on the assumption that the sound velocity is proportional to the lattice strain. The applicational potential of these methods are limited above all by the material state. This is because microstructural errors and textures exert as great an influence on sound velocity as structural gradients. Chapter 3 Fundamentals of Cutting DIN 8580 defines machining as all process variants of the third main group “Cutting”, in which form is altered by means of reducing material cohesion. Deformation is achieved by means of a relative motion between the tool and the workpiece that brings about a transfer of energy [DIN8580]. In the standard, this basic classification is further refined in order to categorise machining procedures [DIN8589]. Machining is defined as follows: cutting, in which layers of material are mechanically separated from a workpiece in the form of chips by means of a cutting tool. According to DIN 8580, machining comprises Groups 3.2 (machining with geometrically defined cutting edges) and 3.3 (machin- ing with geometrically undefined cutting edges) in the manufacturing classification system. The first part of this compendium on manufacturing processes deals exclusively with process variants of Group 3.2. For this reason, the term “machining” will only be used in the sense of cutting with geometrically defined cutting edges. What all processes in the group of geometrically defined cutting edges have in common is that they use a tool, of which the cutting edge number, geometry and position to the workpiece are determined. Several concepts and terms are necessary to describe cutting part, which will be described in the following. 3.1 The Cutting Part – Concepts and Terms The concepts, designations and terms used to describe the geometry of the cutting part are set down in DIN 6581. The cutting part is the active part of the tool where the cutting wedges are located with the cutting edges. The idealized cutting wedge is made up of two faces: A rake face and a flank face, which cut in a line, cutting edge S. The angle between these two faces is designated as the wedge angle β. Figure 3.1 shows an idealized cutting wedge [DIN6581]. The rake face Aγ isthe face of the cutting edge where the chip runs off. The flank face Aα is the face on the cutting wedge, which is turned towards the new workpiece surface (the cut surface). These terms make it clear that the cutting wedge 39F. Klocke, Manufacturing Processes 1, RWTH edition, DOI 10.1007/978-3-642-11979-8_3, C© Springer-Verlag Berlin Heidelberg 2011 40 3 Fundamentals of Cutting Chip Tool Workpiece Trace of plane of flank face Aα Trace of plane of rake face Aγ Cutting speed vc Feed velocity vfEffective cutting speed ve Trace of plane of cutsurface β η ϕ Fig. 3.1 Description of the idealized cutting wedge (tool) should always be regarded in connection with the workpiece. This means that considerable importance should be attached to process kinematics. One model concept is often used for the sake of a simplified description of pro- cess kinematics, that of the selected cutting point. This model simplifies the actual kinematics by summarizing the spatial velocity fields in one point, the selected cut- ting point. At the selected cutting point, the velocity fields can be represented in a summarizing fashion by means of vectors. These vectors can be summarized in turn by vector addition in one total vector. Usually, the workpiece is assumed to be fixed; all motions are carried out by the tool. The resulting velocity vector is designated as the effective cutting speed ve. It can be divided into two components; the cutting velocity vc in the cutting direction and the feed velocity vf in the feed direction. To position the components of effective cutting speed clearly, two angles are defined: • The effective cutting speed angle η as the angle between the effective cutting direction and the direction of primary motion (see Fig. 3.1) • The feed motion angle ϕ as the angle between the feed direction and the direction of primary motion (see Fig. 3.1) Since there are no ideally sharp tools in practice, cutting edge rounding is taken into consideration (Fig. 3.2). In almost all cases the transition between flank and rake face is curved. This curvature is described by the cutting edge radius rß. Up to this point, the concepts have been explained using a simple cutting wedge formed by two faces. Generally, more complex tools are used, composed of several cutting wedges, in the simplest case of one major cutting wedge and one minor cutting face (Fig. 3.3). 3.1 The Cutting Part – Concepts and Terms 41 Tool Trace of plane of flank face Aα Trace of plane of rake face Aγ Chip Workpiece Cutting edge radius vc ve vf rβ β ϕη Fig. 3.2 Cutting edge with cutting edge radius Tool shank Direction of primary motion Direction of feed Major cutting edge S Major flank face Aα Minor flank face Minor cutting edge S′ Rake face Aγ Cutting edge A'α Fig. 3.3 Cutting edges and faces of the wedge, acc. to DIN 6581 Correspondingly, we speak of major and minor cutting edges. The major cutting edge S is always turned towards the cut surface, the minor cutting edge S′ towards the machined face [DIN6580]. If the selected cutting point is on the minor cutting edge, the concepts defined in the former are named accordingly and furnished with an apostrophe (′). The flat areas of the major and minor cutting edges are joined by the corner radius r� (Fig. 3.6). 42 3 Fundamentals of Cutting 3.2 Reference Systems In order to describe the location, position and direction of motion of a cutting wedge, reference systems are utilized in which characteristic planes are defined that are valid for all process variants. The two standardized reference systems are the tool-in-hand system and the tool- in-use system (Fig. 3.4). The tool-in-hand system was developed for tool design as well as for the production and testing of cutting tools. In the tool-in-hand system, the tool angle is measured without considering process kinematics. In actual cutting processes however, the effective angle deviates from the nominal tool angle under certain circumstances due to process kinematics (exception: the wedge angle). For this reason, a tool-in-use system is also defined (Fig. 3.4, right). The tool-in-hand system is a system, the reference plane of which is oriented orthogonally to the assumed cutting direction. In contrast, the reference plane of the tool-in-use system is oriented orthogonally to the effective direction. In both systems, all planes contain the selected cutting point. The reference systems are in agreement when the cutting direction corresponds to the effective direction. First, the tool-in-hand system will be considered (Figs. 3.4, left, and 3.5): • The basic plane, upon which all other planes are based, is the tool reference plane Pr. It contains the rotation axis (if present) and lies perpendicularly to the assumed cutting direction. P Pr Pf vc fv v Ppe Pre Pfe Direction of primary motion Effective cutting direction Direction of feed Assumed direction of primary motion Assumed direction of feed ep Fig. 3.4 Tool frame of reference (left) and tool-in-use system, acc. to DIN 6581 3.2 Reference Systems 43 Ps Pr Pn Assumed direction of primary motion Assumed direction of feed Po Fig. 3.5 Orientation in tool frame of reference Tool Trace of assumed working plane Pf Trace of tool cutting edge plane Ps Trace of tool back plane Pp Tool reference plane Pr Assumed direction of feed κr re Fig. 3.6 Position of tool cutting edge angle κ r • The cutting edge plane Ps runs tangentially to the cutting edge S and perpendic- ularly to the tool reference plane Pr. • The tool orthogonal plane Po is perpendicular to the tool cutting edge plane Ps. • The assumed working plane Pf is perpendicular to the tool reference plane Pr and parallel to the assumed feed direction. • The tool back plane Pp stands perpendicularly on the tool reference plane Pr and perpendicularly on the assumed working plane Pf. • The tool cutting edge normal plane Pn is perpendicular to the cutting edge S. The tool cutting edge normal plane Pn is identical to the effective cutting edge normal plane Pne, since it is not oriented to the tool reference plane but rather to the major cutting edge. The tool-in-use system is rotated towards the tool-in-hand system by the effective cutting speed angle η. In tool-in-use system, the same signs are used as in tool-in- hand system; they are followed however by an e, which stands for “effective”. 44 3 Fundamentals of Cutting In order to designate all tool and effective angles clearly, the same index is assigned to them that signifies the plane in which these angles are measured. For example, the tool orthogonal wedge angle βo is measured in the tool orthogonal plane Po, or the effective side rake angle γ fe is measured in the working plane Pfe. Information about three angles around the three rotatory axes in space is required in order to determine the orientation of the cutting edges or the positions in space of the rake and flank faces. For an optimal cutting process, certain orientations are responsible for three rotatory axes in space. In the following, these angles will be explained exemplarily in the tool-in-hand system: • the orientation angle around a rotation axis that stands orthogonally on the tool reference plane Pr: The tool cutting edge angle κ r between the tool cutting edge plane Ps and the assumed working plane Pf, measured in the tool reference plane Pr, is defined as the angle that determines the position of the major cutting edge S in the tool reference plane Pr. It is measured mathematically positively on the basis of the assumed working plane Pf (Fig. 3.6). • the orientation angle around a rotation axis that stands orthogonally on the tool cutting edge plane Ps: The tool cuttingedge inclination λs between the major cutting edge S and the tool reference plane Pr, measured in the tool cutting edge plane Ps, is defined as the angle that determines the position of the major cutting edge S in the tool cutting edge plane Ps (Fig. 3.7). • the orientation angle around a rotation axis that stands orthogonally on the tool cutting edge normal plane Pn: This rotation is executed by one of the tool angles αn or γ n, which are mea- sured in the tool cutting edge normal plane Pn. The tool normal rake angle γ n is customarily used as the orientation angle, as it has a large effect on the cutting process (Fig. 3.8). Tool Trace of assumed working plane Pf Tool-cutting edge plane Ps Major cutting edge S Trace of Tool reference plane Pr Assumed direction of primary motion λs Fig. 3.7 Position of cutting edge inclination λs 3.3 Basic Process Variants 45 Tool Trace of plane of flank face Aa Trace of plane of rake face Ag α n γn βn Trace of tool cutting edge plane Ps Cutting line of planes Pn and Pr Assumed direction of primary motion Assumed direction of feed Tool cutting edge normal plane Pn Fig. 3.8 Position of wedge in tool frame of reference It is measured mathematically positively between the tool rake face Aγ and the tool reference plane Pr in the tool cutting edge normal plane Pn. The tool normal wedge angle βn is always fixed on the tool and cannot be changed by tool rota- tion. The tool normal orthogonal clearance angle αn lies between the tool flank face Aα and the tool cutting edge plane Ps, measured in the tool cutting edge normal plane Pn. The angle between the flank face Aα and the tool cutting edge plane Ps, measured in the tool orthogonal plane Po, is designated as the tool orthogonal clearance angle αo. The angle between the rake face Aγ and the tool reference plane Pr is defined as the tool orthogonal rake angle γ o. The angle between the rake face Aγ and the flank face Aα is called the tool orthogonal angle βo. As rule, the clearance angle, wedge angle and rake angle – defined in the tool orthogonal plane Po, the assumed working plane Pf and the tool cutting edge normal plane Pn – must in total make a 90◦ angle. The kinematic factors of tool cutting edge angle κr, tool cutting edge inclination λs and tool normal rake angle γ n are important influencing parameters on the cutting process. For further information, see DIN 6582. 3.3 Basic Process Variants Despite the large number of cutting process variants, they can still all be subdivided into three main categories: • free, orthogonal cuts, • free, diagonal cuts and • bound, diagonal cuts. 46 3 Fundamentals of Cutting Workpiece Tool Chip λ s Workpiece Tool Chip vc vch vch vc Fig. 3.9 Free, orthogonal and free, diagonal cut The free, orthogonal cut is a special case, which can be brought about by the following marginal conditions: • Only the major cutting edge is being engaged (free). • The tool cutting edge angle κ r is 90◦ (orthogonal). • Tool cutting edge inclination λs is equal to 0◦ (orthogonal). Practically speaking, this cut can be executed, for example, by means of longitu- dinal face turning or cross cylindrical turning (see Sect. 9.1) allowing for the above marginal conditions (Fig. 3.9). The free, diagonal cut is more general and contains the free, orthogonal cut. The following marginal conditions must be realized in the case of the free, diagonal cut: • Only the major cutting edge is engaged (free). • The tool cutting edge angle κ r can take on values that are not equal to 90◦ (diagonal). • Arbitrary tool cutting edge inclinations λs are permissible (diagonal). As soon as one of the last two marginal conditions is fulfilled, it is a free, diagonal cut. Both conditions don’t have to be met simultaneously, although this can occur. The general case, the bound, diagonal cut (Fig. 3.10), contains all abovemen- tioned special cases and, in addition to the marginal conditions of the free, diagonal cut, also permits the engagement of the minor cutting edge (bound). All the basic process variants can be further extended by adding the following categories: • The uninterrupted cut and • the interrupted cut. The interrupted cut is the general variant among them, in which the cut takes place only intermittently. In the case of the uninterrupted cut, temporal interruption is infinitely small (the cut is continuous). Both process possibilities will be described 3.4 Chip Formation 47 Workpiece Tool Chip vch νc Fig. 3.10 Bound diagonal cut in great detail in later chapters (see Chaps. 9 and 10). In total, there are therefore six basic process variants. 3.4 Chip Formation At the beginning of the chip formation process, the cutting section penetrates the material, causing it to deform elastically and plastically. After the maximum per- missible material-dependent shear stress is exceeded, the material begins to flow. Contingent on a given cutting section geometry, the deformed material forms a chip, which runs off the rake face of the cutting section. The property of plastic deformability is not solely related to the material; it can also be brought about in a targeted way by altering the stress. The amount of stresses is influenced by the feed velocity vf, the cutting speed vc and the depth of cut ap. As far as process kinematics is concerned, the direction of cutting section stress is determined by defining the tool normal rake angle γ n, the tool cutting edge angle κ r and tool cutting edge inclination λs. In order to ensure chip formation, a minimum chip thickness and depth of cut must be exceeded (see Chap. 7 [Moll39, Djat52, Soko55, Bram61, Bram60]). 3.4.1 The Cutting Process By varying the direction and amount of stress, either tough or brittle material behaviour can be realized [Karm11, Böke14]. This has a large effect on chip for- mation. During cutting, the direction of a particular stress can be set by the process parameters tool normal rake angle, tool cutting edge angle and tool cutting edge inclination. The amount of the particular stress is influenced by the cutting para- meters cutting speed, feed velocity and depth of cut. To put it another way, the same material can be tough or brittle depending on the direction and amount of stress, 48 3 Fundamentals of Cutting Fig. 3.11 Model representation of deformation, acc. to Leopold [Leop00] independently of how it behaves at room temperature and under single-axis tensile loads (tension test). When cutting steel, one must bear in mind that brittle behaviour only occurs at very low temperatures. This is not the case when machining cast iron, glass and ceramics. There is brittle fracture behaviour for these materials even at high tem- peratures due to their material structures. The particular stress must therefore be optimally adjusted to the given material properties with process kinematics in both direction and amount. To clarify plastomechanical processes during chip formation, a grid is superim- posed on the workpiece (Fig. 3.11) so that material deformation during cutting can be observed (the visioplasticiy method) [Hast67, Chil71, Leop80, Leop00]. With this method, the chip formation process can be made visible, and with the help of this, chip formation models can be made. Finite element analysis is another possi- bility for modelling chip formation. The visioplasticity method can help to verify FE modellings, since it allows for a temporal and local definition of chip formation on the superimposed grid [Leop80]. Special marginal conditions exist during chip formation: both high rake face tem- peratures (about 770–1700◦C) as well as high deformation speeds (of an order of magnitude of 104/s). Figure 3.12 is a schematic representation of the chip formationprocess as sketched with the help of a photograph of chip initiation (right). In this representation, we can see a continuous plastic deformation that can be subdivided into four zones. The transition from the workpiece structure (a) to the chip structure (b) is made by simple shearing (shear zone). When cutting brit- tle materials, minor deformation on the shear plane can already lead to material detachment. If however the material has higher deformability, detachment first occurs in front of the cutting edge in zone (e). The tensile load under simultaneous perpendicularly 3.4 Chip Formation 49 Structure of the workpiece Cut surface Tool Flank face rake face Shear plane Structure of the chip c vch vc a Tool Shear zone 0,1 mm e d Cut surface b Fig. 3.12 Location of chip initiation active pressure leads, together with the high temperatures prevalent here, to strong deformations on the peripheries of the rake face (c) and cut surface (d). Sliding over the tool surfaces causes further plastic deformations to arise in the boundary layers. The “flow zone” (the non-etched white zone on the bottom of the chip), the deformation texture of which forms parallel to the rake face, gives the impression of a viscous flow process with an extremely high degree of deformation. The chip resulting from the described chip formation process is designated as a continuous chip. Other chip types include lamellar chips, segmented chips and discontinuous chips. Figure 3.13 shows a quantitative profile of normal and tangential stresses result- ing from the resultant force components acting on the rake face. These stresses – in conjunction with temperatures prevalent in the contact zone, which can amount to over 1000◦C in the continuous chip formation zone – lead to deformations with sheer strains ε¯ between 0.8 and 4.0 and sheer strain speeds ε¯˙ of up to 106/s. For the sake of comparison, Fig. 3.13 provides corresponding figures from the tension test. Cutting conditions under which cemented carbide tools operate result in deforma- tion and material heating durations in the order of magnitude of milliseconds; the heating velocities are theoretically around 106◦C/s [Opit70]. 3.4.2 Different Types of Chip Formation When chip formation has been ensured, it can occur in different ways. ERNST [Erns38, Erns41] has made a phenomenological classification of chip formation types. Continuous chip formation is characterized by an evenly deformed material 50 3 Fundamentals of Cutting vch d Flow area Tool Detail A vch vc T5 T4 T3 w Distribution of stress Cutting temperature: Chip flow velocity: Heating velocity: Average normal stress: Average shear stress: T1 ~ 1030 °C vch = 67 m/min 106 °C/s σn = 350 N/mm2 τ = 250 N/mm2 Shear strain Shear strain rate Tension test: ε ~ 0.2 Chipping: 0,8 < ε< 4.0 Tension test : ε~10–3 s–1 Chipping: ε ~ 104 s–1 Workpiece Material: C45E; Tool Material: HW-P20; ap = 2 mm; f = 0.25 mm; vc = 160 m/min σn σ τ τ − − Fig. 3.13 Conditions of the cutting process, acc. to KÖNIG [Köni67] chip structure, the cause of which is assumed to be in the temporally highly uniform friction conditions between the chip and the tool. Lamellar chip formation is characterized by an unevenly deformed material structure between the chip and the tool, the cause of which is explained by tem- porally highly altered friction conditions between the chip and the tool (stick-slip) or by dynamic stress transfer [Scha64]. Locally enhanced structural deformations, shear bands, can be recognized in the chip structure, that are characteristic of this type of chip formation. The frequencies of the vibrations caused by stick-slip are in the range of kilo- hertz and have small amplitudes. The high level of local structural deformation is 3.4 Chip Formation 51 explained by the fact that the thermally caused material softening is more dominant than its mechanical hardening. Research into these phenomena relies on the work of ZENER and HOLLOMON, who have described them and conceived the term “shear band”. Shear bands appear when machining high-strength materials with high lev- els of deformability. They are also especially frequent when machining with high cutting speeds [Hopp03]. If the stress condition in the shear zone exceeds the deformability of the mate- rial (shear strength), there is a detachment of material areas, which then fuse with each other again. This leads to the formation of segmented chips. This can be con- ceived of as a special case of lamellar chip formation in which highly localized deformations (shear bands) arise as well. In addition to vibrations, the entire system – consisting of the machine tool, tool, workpiece and fixtures – is influenced by further dynamic effects such as the regenenerative effect or directional coupling [Weck77]. The frequencies of these effects are much lower, in the area of a thousand hertz. In contrast to the higher- frequency chip formation dynamics, these vibrations do not so much influence chip formation in the sense of material deformation as much as chip formation from outside, since they are the cause of dynamic alterations in the nominal feed. SCHWERD has made microcinematographic experiments and suggested the con- cept of “discontinuous chip” [Schw36]. This process basically distinguishes itself from the other processes of chip formation by the fact that no plastic defor- mation occurs before fracture, but rather fracture takes place without plastic deformation. Discontinuous chips can be observed in the case of materials with very brittle properties, e.g. cast iron, stone, fibre-reinforced plastic or titanium alumnides. Figure 3.14 summarizes the principal chip types [Vier70]. • Continuous chips form when the material has sufficient deformability (εB > ε0), the microstructure is uniform in the cutting area, deformation does not cause embrittlement and chip formation is not impaired by vibrations. • Lamellar chips form when εB < ε0 < εF or the microstructure is not uniform or vibrations lead to variations in chip thickness. Lamellar chips can form with high feeds as well as with high cutting speeds. • Segmented chips consist of chip segments that are separated in the shear plane and fuse together again. The form when εF < ε0, whereby this is not only the case for brittle materials like cast iron but also can come about if deformation causes embrittlement in the microstructure. Segmented chips can also be formed at extremely low cutting speeds (vc = 1 − 3 m/ min). • Discontinuous chips most form when cutting brittle materials with uneven microstructures such as certain types of cast iron and stone. The chips are not detached, but are torn off the surface, often causing damage due to small breakings from the workpiece surface. Figure 3.15 gives a tool-oriented overview of the dynamic system of spheres of influence, all complexly overlapping and mutually retroactive, which brings about 52 3 Fundamentals of Cutting Continous chip1 Lamellar chip Segmented chip2 3 Discontious chip4 Range of lamellar-, segmented- and discontinous chip Range of continous chip Sh ea r s tre ng th τ 1 2 3 4 E B Elastic region Plastic region Yield range Sh ea r s tre ng th τ Degree of deformation ε ε 0 Strain ε ε0: Degree of deformation in the shear plane E: Elastic limit B: Breaking limit F: Fraction point F Fig. 3.14 Types of chip depending on material properties, acc. to VIEREGGE [Vier70] Mechanism of chip formation: • Continous chip formation • Lamellar chip formation • Segmented chip formation • Discontionous chip formation Range of temperature Material properties Range of velocity Tool geometry Friction and Deformation Toolwear Process parameter Fig. 3.15 Influence on chip formation the various types of chip formation. This system is heavily influenced by the velocity fields, the materials to be machined, tool geometry and process kinematics. This section will not deal with low-frequency dynamic effects on the part of the machine tool. See the relevant literature for further information [Kron54, Opit70, Weck77, Alti00]. 3.4 Chip Formation 53 Tool reference plane Pr Quarz glass pane Buffed and etched Workpiece Hollow spindle Primary motion Feed motion Tool Fig. 3.16 Microcinematograpy One method with which chip formation is directly observable, is microcine- matography, the first application of which on the cutting process was already carried out by KURREIN and then later by KLOPSTOCK [Kurr05, Klop23, Klop26] (see Fig. 3.16). The development of this process has been advanced by several researchers in the course of time [Schw36, Merc45, Oxle59, Spaa71, Warn74]. In this process, chip formation is observed through a quartz glass pane while photos are taken or films are recorded successively in short intervals. One disadvantage of this procedure is the limitation to very low cutting speeds (vc = 1 cm/min). Nevertheless, the process has helped to explicate basic phenomena. Today there are high-speed cameras available that can capture 150,000 images per second. With such cameras, the phenomena can be made visible at the lower threshold at higher speeds or especially during micro-cutting. In order to be able to study chip formation more effectively, various methods have been developed for cut interruption. During the cutting process, chip roots are held “in statu nascendi”, providing information about chip formation after sub- sequent metallographic preparation. In the case of the equipment used today, the tool is suddenly accelerated out of the cut. The acceleration is brought about by a predetermined breaking point on the swivel device that breaks during the cutting process due to an impulse caused by an explosion [Lola49] (Fig. 3.17). Gente has recently developed a method in which the delay time and the masses moved can be reduced in comparison with the “explosion method” [Gent02] (see also Fig. 3.17). In this way, investigations into chip roots are also possible with higher cutting speeds. Other methods have been developed in which a chip root is produced in the workpiece by means of a predetermined breaking point (brittle fracture, Fig. 3.18) [Buda68]. The advantage is that that chip root is detached from the workpiece so that the effective area can be spared during the following metallographic preparation. 54 3 Fundamentals of Cutting Moment 1 Moment 2 Tool Sample Direction of primary motion Gun Moment 1 Moment 2 Baffle Tool Fig. 3.17 Interruption of cutting process, acc. to LOLADSE [Lola49] (left) and GENTE [Gent02] (right) Predetermined breaking point Buffed sheet steel with high Young’s modulus Sa m ple Tool Fig. 3.18 Interruption of cutting process by predetermined breaking point, acc. to BUDA [Buda68] 3.5 Kinematic Surface Roughness Calculations of interpenetration between the tool and the workpiece can provide key information about the cutting process, including the associated undeformed chip cross-sections in the case of changing engagement parameters (see also gear man- ufacture) or micro-geometrical surface parameters. The following shows by way of example the generation of surface quality for a simple external turning process. Since chip formation processes are ignored, we speak in this case of the generation of kinematic surface roughness. For this, the penetration of the workpiece by the tool is geometrically evaluated taking into consideration the kinematics in the tool reference plane Pr (Fig. 3.19). 3.6 Mechanical and Thermal Strain on the Cutting Section 55 Area of validity: f < 2 · r cos(κ r + r – 90°) and κ r + r < 180° z x M1 M2 r r ε r –Rt f f/2 4 f 2 r ε 2 −Rt −= Rt ε8 ⋅ r f 2= or κ r Rtfε ε ε ε ε Fig. 3.19 Geometric ratio of engagement in the cutting process 3.6 Mechanical and Thermal Strain on the Cutting Section The resultant force F, represented here in the turning process as an example, can be decomposed into the components cutting force Fc, feed force Ff and passive force Fp (Fig. 3.20). Currently, these resultant force components are usually detected metrologically with the help of piezoelectric force sensors. vc Fc Primary motion (Workpiece) Direction of feed (Tool) F : Resultant force Fc : Cutting force Ff : Feed force Fp : Passive force Fa : Active force FD : Thrust force Fz Fa FD Fp Ffvf ve vc : Cutting speed vf : Feed velocity ve : Effective cutting speed Fig. 3.20 Resultant force and its components in the cutting process, acc. to DIN 6584 56 3 Fundamentals of Cutting h hch vch ToolWorkpiece Fc vc Shear plane Sectional view A-A Fc Cutting force Ff Feed force Fp Passive force Ffp Resultant of Ff and Fp FκN Normal force of major cutting edge FκT Tangential force of major cutting edge FγN Normal force of rake face FγT Tangential force of rake face FΦN Normal force of shear plane FΦT Tangential force of shear plane FcγN Resultant of FγT and FγN, or FΦT and FΦN Ff FfpFp vfhA A FκN FκT Fγ N FΦN FΦT Fκ N Fγ T Fcγ N h Undeformed chip thickness hch Chip thickness vc Cutting speed vch Chip speed αoe Tool orthogonal clearance β β oe Wedge angle γ oe Tool orthogonal rake angle κ re Working cutting edge angle λ se Working cutting edge inclination Shear angle γoe oe λse = 0° κre α oe Φ Φ Fig. 3.21 Components of resultant force in working plane of reference (top) and working plane (below) The analysis of forces derived for the orthogonal cut by Merchant [Merc45, Merc45a] is the basis for determining the forces acting on the tool cutting edge (Fig. 3.21). Assuming an ideally sharp cutting edge and neglecting flank face wear, the tan- gential force Fγ T and the normal force Fγ N acting on the tool can be calculated from the force components. The following applies as long as the inclination is λs = 0◦ and the influence of the minor cutting edge is slight: Fγ N = Fc cos γo − (Ff sin κr + Fp cos κr) sin γo (3.1) Fγ T = Fc sin γo + (Ff sin κr + Fp cos κr) cos γo (3.2) 3.6 Mechanical and Thermal Strain on the Cutting Section 57 where the bracket term in Eqs. (3.1) and (3.2) corresponds to the normal force of the major cutting edge FκN (Fig. 3.21). Because of the (in most cases) small dif- ference between the angles in the tool-in-hand system and the tool-in-use system, calculations are made within the tool-in-hand system for the sake of simplicity. For the case γo = 0◦, the cutting force Fc and the feed force Ff act perpen- dicularly/tangentially to the rake face. In contrast to Merchant’s original work, a neutral tool orthogonal rake angle (γo = 0◦) was selected, and the forces were shown with the effective cutting direction on the tool cutting edge. Designation of the acting forces and their signs is derived from the standards ISO 3002/4 and DIN 6584. As Fig. 3.22 clarifies for the simplest case of an orthogonal cross section with a neutral tool orthogonal rake angle, the cutting and feed forces on the worn tool are composed not only of the normal force of the rake face Fγ N and the tangential force of the rake face Fγ T but also of the tangential force of the flank face FαT and the normal force of the flank face FαN. The friction coefficient, which can be calculated from the cut and feed forces, thus contains not only rake angle friction but also forces acting on the flank face caused for example by elastic deformationof the workpiece surface and by tool wear [Klau65]. As research has shown, the normal force of the flank face amounts to about 40% of the feed force and thus to F ΦN F a = F z Fc Ff F Φ T Chip Toolvf vc FγN FγT VB FαT FαN Cutting edge acc to: Merchant |Fc | = |FγN |+ |FαT | |Ff | = |FγT |+ |FαN| True for: γo = 0°, κ r = 90°, VB > 0 h Φ Fig. 3.22 In the cutting process the mechanical strain of the cutting edge results from normal and tangential forces and their components acting on rake and flank face, acc. to MERCHANT [Merc45, Merc45a] 58 3 Fundamentals of Cutting about 66% of the rake face component in the feed direction [Spaa67, Lutz68]. A percentage of approximately 10% of the cutting force Fc was ascertained for the tangential force of the flank face. The average normal and tangential stresses originating from the resultant force components acting on the rake face are between 350 and 400 N/mm2 or between 250 and 350 N/mm2 when machining construction steel [Köni72]. Materials that are difficult to cut result in values of 1100 N/mm2. Their profile is qualitatively reproduced in Fig. 3.13. The size and direction of the resultant force are strongly influenced by the cutting parameters and cutting section geometries used. Figure 3.23 shows the dependence of the static components of the resultant cutting force Fc, Ff and Fp on the feed f, cutting speed vc, depth of cut ap and the tool cutting edge angle κ r qualitatively in a linear coordinate system. The extremes in the profiles of the resultant force components over cutting speed can be ascribed to growth of built up-edge. The reduction of forces with increasing cutting speed is caused by the reduction of material strength at higher temperatures. The components of the resultant force increase proportionally over the depth of cut ap. Yet this is only valid if the depth of cut is larger than the corner radius of the tool. The profile of feed force Ff and passive force Fp over the tool cutting edge angle κ r results from the geometric position of the cutting edge with respect to the workpiece axis, since with a larger cutting edge angle the resultant force component aimed in the feed direction increases, and its maximum is reached at κr = 90◦. If the tool cutting edge angle is increased, the undeformed chip thickness h increases proportionally to the reduction of the width of undeformed chip b. Since cutting Cutting force Fc Feed force Ff Passive force Fp Feed f Cu tti ng fo rc e co m po ne nt s Fc Ff Fp Cutting speed vc Cu tti ng fo rc e co m po ne nt s Tool cutting edge angle κr Fc Ff Fp Cu tti ng fo rc e co m po ne nt s Depth of cut ap Fc Ff Fp Cu tti ng fo rc e co m po ne nt s Fig. 3.23 Components of resultant force depending on feed, cutting velocity, tool cutting edge angle, and depth of cut (qualitative) 3.6 Mechanical and Thermal Strain on the Cutting Section 59 Influencing variables Change of cutting force components per degree angle variation Cutting force Fc Feed force Ff passive force Fp Tool orthogonal rake angle Tool cutting edge inclination Tool orthogonal rake angle Tool cutting edge inclination D ec re as in g In cr e a si ng 1.5 % 5.0 % 4.0 % 1.5 % 1.5 % 10.0 % 1.5 % 5.0 % 4.0 % 1.5 % 1.5 % 10.0 % Fig. 3.24 Influence of cutting edge and rake angle on the components of the resultant force force Fc is proportional over depth of cut ap(=ˆ width of undeformed chip b) but increases degressively over feed (=ˆ undeformed chip thickness h), a light reduction of Fc with increasing κr is the outcome of both changes. Figure 3.24 provides some standard values for how the components of the resul- tant force change if the tool orthogonal rake angle or the cutting edge inclination is varied. This information can vary greatly however and should only be seen as reference values. Changing the tool orthogonal clearance angle in the range of 3 ≤ αo ≤ 12◦ has no mentionable effects on the resultant force components. Changing the corner radius also does not have a significant effect on the forces as long as the condition 2r ≤ ap is met. Tool wear (see Sect. 3.7) is another variable that influences resultant forces. Varying effects on the components of the resultant force can be observed depending on the type of wear. Crater wear, resulting in a larger positive tool orthogonal rake angle, generally leads of a reduction of cutting forces. On the other hand, these forces increase when flank face wear is dominant since the friction surface between the workpiece and the flank face becomes larger. Quantitative determinations concerning force increase with increasing tool wear can only be approximated due to the large number of influ- encing parameters. The following reference values can be assumed approximately for force increase up to a width of flank wear land of VB = 0.5 mm: About 90% for the feed force Ff, about 100% for the passive force Fp and about 20% for the cutting force Fc. Several specific characteristic values can be distinguished for calculating the components of the resultant force. These component forces are directly proportional to the width of undeformed chip b. To identify empirical laws, it is usually advis- able to relate the measurement to already known, linearly dependent magnitudes in 60 3 Fundamentals of Cutting Undeformed chip thickness h / mm mc 1 1 –mc = 0.7265 45° 1 0.1 0.2 0.4 0.6 0.8 1.0 2.0 200 400 600 800 1000 2000 Cu tti ng fo rc e F c W id th o f u nd ef or m ed c hi p b = F c ’ / (N /m m) Fc' = kc1.1 ⋅h1–mc kc1.1 = 1740 N/mm2 Fig. 3.25 Graphical determination of characteristic values kc1.1 and (1–mc) order to minimize the number of variables going into the physical law. In this case, we form the quotient Fc′ from the cutting force Fc and the width of undeformed chip b. If we now plot the values thus found over undeformed chip thickness h in a double logarithmic plot, the measurement points arrange themselves in a straight line (Fig. 3.25). The corresponding linear equation log(Fc/b) = log(kc1.1) + (1 − mc) · log h (3.3) can be converted into the KIENZLE Equation Fc′ = kc1.1 · h(1−mc) (3.4) The specific cutting force kc1.1 is the cutting force required to detach a chip of undeformed chip width b = 1 mm and undeformed chip thickness h = 1 mm. The exponent (1–mc) designates the gradient of the straight line Fc′ = f (h) in the double logarithmic system. To determine kc1.1 and (1–mc), cutting experiments are carried out for the combi- nation of workpiece material and cutting tool material under investigation. In these experiments, the relevant cutting forces are measured with constant cutting speed, depth of cut and cutting section geometry and plotted in accordance with Fig. 3.25. The required specific cutting force characteristic parameter kc1.1 is determined by 3.6 Mechanical and Thermal Strain on the Cutting Section 61 extrapolating the undeformed chip thickness to h = 1 mm. The tangent of the angle between the straight line and the x-axis is the desired gradient value (1–mc). Corresponding equations and characteristic values can be defined for resultant force components Ff and Fp: F’f = kf1.1 · h(1−mf) (3.5) Fp′ = kp1.1 · h(1−mp) (3.6) The values determined in this way are however only valid for undeformed chip thicknesses of h > 0.1 mm. Values for kc and (1–m) can be found in [Köni82]. According to DIN 6584, the energy for cutting is the result of the product of the paths to be travelled or paths travelled and the components of the resultant force act- ing in their direction.Correspondingly the powers arising during the cutting process result from the product of the speed components and the components of the result force acting in their direction. Cutting energy Wc and cutting power Pc: Wc = lc · Fc (3.7) Pc = vc · Fc (3.8) Feed energy Wf and feed power Pf: Wf = lf · Ff (3.9) Pf = vf · Ff (3.10) Effective energy We and effective power Pe are understood as the sum of all corresponding cut and feed amounts: We = Wc + Wf (3.11) Pe = Pc + Pf (3.12) Due to the relatively low feed speeds and feed paths, feed energy/power dur- ing turning amounts to only about 0.03–3% of the corresponding cutting energy or cutting power. For this reason, we can assume We ≈ Wc and Pe ≈ Pc for most cases. Figure 3.26 provides an overview of the segmentation of the total active energy into shear, cutting and friction energy as a function of the undeformed chip thickness [Vier70]. The illustration shows that the amounts of the different types of energy depend on the undeformed chip thickness, whereby shear energy has the largest share for most undeformed chip thicknesses. The mechanical work used in cutting is almost completely converted into thermal energy. Since the heat centres are identical with the deformation centres, the shear 62 3 Fundamentals of Cutting Width of undeformed chip: h / mm Material: 55NiCrMoV6 Tensile strength: Rm = 800 N/mm2 Cutting speed: vc = 100 m/min Width of undeformed chip: b = 4.25 mm Tool orthogonal clearance: αο = 5° γο = 10° Tool orthogonal rake angle: 0 200 400 600 1.0 100 300 500 700 0 Friction of flank face and cutting energy Friction of rakeface Total energy Shear energy Effective energy We We = Fe ·Ie Deformation energy Friction energy Shear energy Cutting energy Friction of flank face Friction of rake face Latent energy and heat Pa th le ng th d ue to p rim ar y m o tio n Ef fe ct iv e en er gy W e / (m ·da N/ m) 0.2 0.4 0.6 0.8 Fig. 3.26 Segmentation of effective energy in cutting process depending on chip thickness, acc. to VIEREGGE [Vier59, Vier70] zone and the friction zones on the tool come into consideration as heat sources. As Fig. 3.13 shows, the degree of deformation on the bottom of the chip is much higher in the flow zone than in the shear zone, so one can expect the highest tem- peratures between the chip and the tool. Since the thickness of the flow zone is very small in comparison with the shear zone however, these higher temperatures should not also be equated with a high energy conversion. The illustration in Fig. 3.27 left gives information about heat that is absorbed/dissipated by the workpiece, chip and tool. Most of the heat is dissipated by the chip. Most of the mechanical energy (in this case 75% and generally more than 50%) is converted in the shear zone. The heat arising in the individual develop- ment locations is dissipated by thermal conduction, radiation and convection to the environment. As a result of this heat balance, corresponding temperature fields form in the workpiece and tool that change until equilibrium between added and removed heat is achieved. The right side of the figure shows such a temperature field. If we consider one material particle in the cutting zone, its temperautre will be at least equal to that of a particle in the shear zone. As it glides further into the contact zone, the material is intensively heated on the chip bottom side and the tool on the rake face, because the energy required to overcome friction between the chip 3.6 Mechanical and Thermal Strain on the Cutting Section 63 600 700 650 600 400 450 500 300 310 380 oC 130 80 500 30 Workpiece Chip Tool 5% 2% 18% 75% For steel Material: Steel Flow stress: kf = 850 N/mm2 Tool material: HW-P20 Cutting speed: vc = 60 m/min Width of undeformed chip: h = 0.32 mm Tool orthogonal rake angle: γo = 10o Fig. 3.27 Distribution of heat and temperature in workpiece, chip, and tool in the process of steel cutting, acc. to KRONENBERG [Kron54] and VIEREGGE [Vier59] and the rake face is almost completely converted into heat. Since this process only takes place in boundary layers of the chip and cutting tool material it heats up the rake and chip bottom side all the more strongly the less time is available for heat dissipation due to the higher cutting speeds. The maximum temperature does not appear directly on the cutting edge, but rather at a certain distance from it on the rake face depending on the cutting conditions. Determining the temperatures arising during cutting has long been the subject of intensive research [Gott25, Lang49, Schm53, Küst54, Vier55, Küst56, Axer55]. Already in 1956, KÜSTERS demonstrated temperatures of over 1000◦C on the rake face when cutting steel with cemented carbide [Küst56]. Later investigations have qualitatively confirmed these results again and again [Cass94, Denk90, Ehme70a, Lenz66, Laus88, Beye72, Dama90, LoCa94]. The level of the temperatures acting on the cutting section depends on the machined material, the cutting tool material, the selected cutting conditions, tool wear and the cooling medium. Figure 3.28 pro- vides an impression of the order of magnitude of the mean cutting temperatures to be expected on the rake face as a function of cutting speed for various cutting tool materials. In the vc = 20–50 m/min range, the temperature profile is non-linear in the double logarithmic coordinate system. The reason for this is the the growth of built up-edge arising in this cutting speed range (see Sect. 3.7.2), which interferes with direct heat conduction. In comparison to the rake face, temperatures on the flank face are generally low (Fig. 3.29) [Denk90, Ehme70a, Axer55, Laus88, Beye72, Dama90]. The size of the temperature difference between the rake face and the flank face, about 200–300◦C 64 3 Fundamentals of Cutting Tool material: HW–P10, P30 High speed steel HS12–1–4–5 Material: C53E Geometry of cutting section: 6° 6° 0° 70° 84° 0.8 mm Cross section of undeformed chip: ap · f = 3 x 0.25 mm2 Cutting time: tc = 15 s 300 350 400 450 500 550 600 650 700 750 800 850 900 950 1000 1050 1150 10 16 25 40 63 100 250 x x x x x x HW-P1 HW-P30 HS12–1–4–5 End of growth of– build–up edge Cutting speed vc / (m/min) 1100 Te m pe ra tu re o f r ak e fa ce ϑ / ° C α o γ o κ r ε r r ελs Fig. 3.28 Mean rake face temperature when cutting with cemented carbide tools according to [Ehme70a], is strongly co- determined by the position of the contact zone on the rake face. The closer the rake face moves towards the cutting edge, the more the temperatures prevalent on the rake and flank faces conform. This means that temperatures are very high on the flank face as well, especially during finishing operations with high cutting speeds and small feeds. According to the information provided by the literature [Ehme70a, Vier53, Schm53, Küst54, Vier55, Küst56, Axer55, Beye72], temperatures of over 800◦C can be found on the flank face depending on the selected marginal conditions when cutting with cemented carbide tools. There are various methods and devices available for temperature measurement during the cutting process (Fig. 3.30) [Lowa67], which vary according to technique, experimental setup and measurement position. The only metrological techniques that come into question for measuring temperature during the cutting process are time-resolution measurement techniques, since the cutting process duration (and thus the achievement of a thermally stationary state) is too short for other methods 3.6Mechanical and Thermal Strain on the Cutting Section 65 0 1 2 3 4 1 2 1200°C 800°C 600°C 500°C 400 °C Weld Isolation of silicon varnish CrNi-Wire ∅ 0.07 mm mVCompensating resistance Ni-tube ∅ 0.13−0.20 Example for the distribution of temperature inside the cutting edge Material: 30Mn4 Cutting tool material: HW-P10 Cutting speed: vc = 180 m/min Cross section of undeformed chip: ap·f = 3 ·0.74 mm2 Cutting wedge geometry 45° 90° γo αo λs κγ ε r rε Bevel width: 0.5 mm 45° to cutting edge0° 4° 0° 1000°C Fig. 3.29 Measurement of temperature with embedded thermocouple on cemented carbide, acc. to Küsters [Küst56] 2. Measurement with thermo-colours 1. Caloric heat measurement 3. Thermo-electric measurement 4. Radiation- measurement 2.1. Coat of paint at an uninvolved surface of the tool 2.2. Coat of paint at the inner surface of a splitted tool 4.1. Radiation pyrometer 3.1. One-chisel method 3.2. Two-chisel- method 3.3. Assembly of a complete thermocouple 3.4. Assembly of an isolated wire as themocouple Temperature measurment during machining 4.3. Measurement of infrared radiation with PDS-cell 4.2. Infrared photo- thermometry Fig. 3.30 Temperature measurement in cutting processes 66 3 Fundamentals of Cutting (e.g. coating with temperature-sensitive colours or powders with constant melting points). Of the processes introduced in Fig. 3.30, the one and two-chisel methods, temperature measurement with thermocouples, pyrometers and photo thermometry are of technical interest. GOTTWEIN developed the one-chisel method as the first direct method for mea- suring temperature and then, in cooperation with REICHEL, the two-chisel method [Gott25, Herb26, Vier70]. Both methods are based upon the principle of a thermo- couple. Both tool and workpiece form the heat soldering joints, while the tool clamp is the cold soldering joint. The workpiece and the tool must be clamped in isola- tion, since the thermoelectric voltage arising in the contact zone between the cutting insert and the chip would otherwise be dismantled through the machine in a short circuit. Contact between the passing chip and the workpiece outside of the contact zone must therefore also be avoided. Both methods require electrically conductive materials and cutting tool materials. In the case of the two-chisel method, cutting tool materials with varying thermoelectric properties must be used. The greatest dis- advantage of the single-chisel method is the protracted and elaborate process needed to calibrate the thermocouple which must be carried out again for every cutting tool material and workpiece material combination. This process can detect temperatures of up to 1200◦C. Temperature measurement with thermocouples is among the most common tech- niques today. Installing a thermocouple into the tool or workpiece allows for a point-wise determination of the temperature field (Fig. 3.29). The thermocouples included are classified as encapsulated thermocouples, sheathed thermocouples and single filament thermocouples. Thermocouples can be applied in blind holes in the tool [Küst56, Qure66, Abra97] or in the workpiece [Osul02]. Temporal res- olution is influenced by the response time of the thermocouple and heat transfer between the thermocouple and the device under test. These techniques generally have low temporal resolution. Also problematic is the contact heat transfer resis- tance between the surface under test and the thermocouple due to the roughness of the bore. This causes a difference in temperature between the measurement surface and the thermocouple. In the case of sheathed thermocouples with isolated mea- suring points, there is also the distance between the thermocouple surface and the internal measurement point. Due to the extremely high temperature gradients with short test times characteristic of cutting processes, this can lead to much lower mea- surements. The maximum values dominant in the friction zones cannot be measured in this way. Thermal compounds are used to improve heat transfer between the ther- mocouple and the surface. Another disadvantage is that direct contact between the thermocouple and the test object is necessary and that the holes used to position the thermocouples can significantly affect the distribution of temperature. The most important techniques in radiation measurement, which determines tem- perature by measuring the heat radiation emitted from a surface, are pyrometry and thermography. Pyrometry is the contact-free determination of absolute temperature by measuring the inherent radiation of a body without spatial scanning of the object field. Thermography provides a pictorial representation of temperature distribu- tion. Radiation techniques have decisive advantages compared with thermoelectric 3.6 Mechanical and Thermal Strain on the Cutting Section 67 methods: the time resolution is much higher (whereby pyrometers are principally faster than infrared cameras), and they are also contact-free. One significant problem when measuring for an exact absolute temperature with a radiation method is the dependence of the radiation emitted on the grade of emission of the surface. Since the emission grade is the function of many factors like temperature, wavelength, angular position, material and surface condition, calibrat- ing the measurement device for a particular surface is very difficult. The precision of total radiation and broadband partial radiation pyrometers are especially influenced by factors that alter the spectral grade of emission of the surface. In cutting, effects such as surface roughness and oxidation influence the grade of emission of different surfaces greatly. To limit the influence of the grade of emission on measured tem- peratures, narrow-band partial radiation, two-colour and multi-colour pyrometers have been developed. The two-colour pyrometer (Fig. 3.31) has the advantage that the spectral grades of emission ε1 and ε2 of the surface need not be known. Since the two selected wavelengths lie directly next to each other, ελ1 ∼ ελ2. An error in measurement will only result if both wavelengths λ1 and λ2 differ greatly. Further advantages of this principle are that the measured temperature is independent of signal dampening, due to dust for example, so long as both signals are dampened equally. Moreover, the temperature of objects that are smaller than the optical field of vision can be measured without error [Müll85]. Thermography with infrared cameras can be used as an alternative to pyrometri- cal measurements. The advantage to this is the pictoral representation of temperature information. Commercial cameras usually work with long wavelengths and large broad-bands, which makes it possible to measure lower temperatures but which also has a negative effect on the attainable accuracy. Scanning cameras that work with a single detector are too slow for fast processes. Some high-speed infrared cameras Insert Workpiece Chip Point of measurement Lens Dichroic beam-splitter Photodiode Amplifier IR-filter Glass fiber (∅ = 0.42 mm) Characteristics • Measurement of two discrete wavelength bands 1 = 1.7 µm, and 2 = 2 µm which are set into ratio • High temporal resolution (approx. 2 µs) • Independence from grade of emission (no calibration required) • Large range of temperature measurement (250–1200 °C) • Contact free measurement λ λ Fig. 3.31 Build-up of a two-colour pyrometer in principle, acc. to MÜLLER [Müll85] 68 3 Fundamentals of Cutting offer integration times in the range of microseconds, making it possible to capture fast processes without motion blur. One major problem in the metrological determination of cutting tempera- tures, besides poor accessibility, is the limitedlocal resolution of the available measurement techniques as well as the small range (only a few micrometers) within which the maximum temperatures arise. Local temperatures in the boundary layer between the cutting tool material and the sliding chip also cannot be captured with existing measurement methods. Promising attempts to determine thermal tool load more accurately than previously have been made with sensors in thin-film technol- ogy, which are applied to tool contact zones and determine temperature distribution within the contact zones during the machining process [Zieb95, Töns95, Kloc97]. This technology is however not yet suitable for cutting processes with high wear. Another highly promising method for determining temperatures in the boundary layers between the material and the cutting tool material is the implantation of a window made of diamond in the tool contact zone. Heat radiation emitted from the chip bottom side passes through the window via a mirror integrated into the chisel holder and reaches an infrared camera [Müll96]. A direct comparison of the temperatures measured by various authors is only rarely possible, since experimental conditions generally deviate from each other. There are numerous parameters that may have an effect on temperature: the type of cutting process, materials, cutting tool materials, possible coatings of the cutting tool materials, the use of cutting fluids and cutting parameters such as feed, cut- ting speed, depth of cut and cutting section geometry. Moreover, the measurement position is also crucial as well as metrological parameters like local or temporal res- olution. The duration of the cutting process and the measurement time must also be taken into consideration. Cutting speed clearly has the greatest influence on the maximum temperatures that arise in the contact zone between the chip and the tool. In the case of the basic process, most measurements indicate an apparent rise in temperature at low to average cutting speeds, while at high speeds there is an approximately constant temperature level. 3.6.1 Influence of the Geometry of the Cutting Section Depending on the cutting task at hand, we can select from a diverse array of cutting section geometries. Geometry selection depends on • the cutting tool material, • material, • cutting parameters and • tool geometry. Typical tool angles in steel cutting are given in Fig. 3.32. Determining the tool angle always involves a compromise that can only do approximate justice to various requirements. Figure 3.33 shows how a change in cutting section geometry influences cutting parameters. 3.6 Mechanical and Thermal Strain on the Cutting Section 69 Geometry of cutting section Cutting tool material Tool orthogonal rake angle Tool orthogonal clearance Cutting edge inclination λs κ r ε r Cutting edge angle Tool included angle Corner radius rε High speed steel (HSS) Cemented carbide –6° to +20° –6° to +15° –6° to +6° 10° to 100° 60° to 120° 0.4 to 2 mm 6° to 8° 6° to 12° αογο Fig. 3.32 Tool angle for machining of steel Lower minimum chip thickness Increasing stability of cutting section Improved chip formation Improved surface Reduced cutting force Decreasing wear Decreasing wear Increasing stability of cutting section Increased stability of cutting section Chamfer of the rake face Decreasing wear Decreasing chatter, Decreasing cutting force o = –10° to +20° αo = 6° to 12° κ r = 10° to 100° rε = 0.4 to 2 mm Decreasing chatter, Decreasing cutting force Increasing surface quality Controlled chip flow Increasing of passive forces, Increasing stability of cutting section s = –6° to +6° + – +– γ λ Fig. 3.33 Influence of cutting edge geometry on characteristic machining values 3.6.1.1 Tool Orthogonal Clearance αo Wear on the flank face (denoted by the width of flank wear land VB) is mostly determined by the size of the tool orthogonal clearance. If it is large, the cutting section is weakened in two respects: a heat build-up can ensue in the tool that can possibly lead to impaired or loss of hot hardness; also, if the wedge angle is too small, this increases the danger of breaking on the cutting edge. If αo → 0◦, surface 70 3 Fundamentals of Cutting wear increases because pressure weldings appear on the contact areas of the friction partners to a greater extent. 3.6.1.2 Tool Orthogonal Rake Angle γ o, Wedge Angle βo The tool orthogonal rake angle γo can, in contrast to αo, be either positive or neg- ative. It is responsible for the detachment of the material to be cut. The size of the tool orthogonal rake angle γo affects the stability of the wedge; highly positive tool orthogonal rake angles can thus lead to tool breakage as a result of cutting section weakening. The primary advantages of a positive tool orthogonal rake angle are the low cutting and feed forces as well as a usually improved workpiece surface qual- ity. However, a chip flow that is supported by a positive tool orthogonal rake angle often has insufficient chip breakage (tendency towards the formation of continuous chips). Negative tool orthogonal rake angles increase cutting edge stability (used for example for planing and machining workpieces with apertures, rolling skin or cast skin). The thereby increased deformation of the passing chip and the large cutting forces result in a high temperature load on the cutting section. Increased crater wear appears on the rake face, which can lead to a decreased tool service life. Together with the wedge angle βo, the tool orthogonal rake angle γo and the tool orthogonal clearance form a right angle αo (Fig. 3.8). 3.6.1.3 Tool Included Angle εr Due to the tool stability that is desired under extreme cutting conditions, the tool included angle εr should be as large as possible. Small tool included angles are required especially for copier and NC machining. The possible range is limited by specifying the position of the major cutting edge and by making sure that the angle between the minor cutting edge and the feed direction is at least 2◦ in order to avoid subsequent shaving of the minor cutting edge on the workpiece. 3.6.1.4 Cutting Edge Angle κr At constant feed and depth of cut, the width of undeformed chip b increases with decreasing κ r. This causes the specific cutting edge wear to sink, so small cutting edge angles are used especially to machine high strength materials in order to keep tool load and wear low. On the other hand, the passive force Fp rises with decreasing κ r, increasing the danger of clattering vibrations due to growing instability of the cutting process. 3.6.1.5 Cutting Edge Inclination λs A negative cutting edge inclination can stabilize the cutting process to a large extent since the lead of the tool does not take place on the cutting edge but rather towards the middle of the cutting edge. This results in an improved load profile, so that the danger of cutting edge breakage due to local overloading is reduced. First cuts that have minimal loads are of particular importance especially in the case of interrupted 3.7 Wear 71 cross sections (e.g. in milling or planing) as well as in the machining of cast iron and forged parts (workpieces with transverse drill holes, shrinkage cavities). Negative cutting edge inclinations induce large passive forces, which must be absorbed by the machine tools (stiffness perpendicular to the main spindle!). The cutting edge inclination also influences the direction of chip flow. A nega- tive cutting edge inclination can result in the chip getting diverted to the workpiece surface, decreasing the surface quality. 3.6.1.6 Corner Radius rε The cornerradius to be selected depends on the feed f and the depth of cut ap. Together with the selected feed, it influences the attainable workpiece sur- face quality to a great extent (see Sect. 7.2.3), whereby the following relation is approximately true: Rt = f 2 8rε (3.13) Large corner radii improve the surface quality and cutting stability. Small corner radii have the advantage of a smaller clattering tendency due to smaller passive forces. 3.7 Wear During the cutting process, deformation, separation and friction processes take place in the area of the cutting edge. The cutting tool materials used are subject to an extremely complex load collective characterized by high compressive stresses, high cutting speeds and high temperatures. Using cutting parameters common in practice, cutting tools reach the end of their service life because of continuously increasing wear on both rake and flank faces. This is explained as the progressive loss of material from the surface of a solid body, brought about by mechanical causes, i.e. contact and relative motion of a solid, liquid or gaseous counter body. 3.7.1 Wear Mechanisms The main mechanisms that cause wear are adhesion, abrasion, tribochemical reactions and surface disruption (Fig. 3.34). 3.7.1.1 Abrasion Abrasion occurs when rough areas of the counter body or particles present as inter- mediate material or also as counter bodies penetrate into the surface of the cutting tool material and simultaneously make a tangential motion, producing scores and 72 3 Fundamentals of Cutting Adhesion Abrasion Tribochemical reaction Surface damage Fig. 3.34 Schematic illustration of the four main mechanisms of wear, acc. to ZUM GAHR [ZumG92] Micro-plowing Micro-cutting Microcracks Fig. 3.35 Types of material damages caused by abrasive parts, acc. to ZUM GAHR [ZumG87] micro-cutting. The various forms of abrasion are designated as groove, fluid ero- sion, mill, notch or blast wear. Often, the term “groove wear” is used synonymously with the term “abrasive wear” [Habi80, Czic06]. In the case of groove wear, hard areas of roughness or hard particles penetrate into the surface of the stressed material, creating scores or grooves by a sliding movement. Wear can be caused by a rough, compact counter body (counter body grooving) or by loose particles in the case of sliding load (particle grooving). The process of material damage can be subdivided into micro-plowing, micro- cutting and microcracks (Fig. 3.35). Micro-plowing and micro-cutting are the predominant wear processes in the case of ductile materials. In the case of micro- plowing, the material is plastically deformed within the wear groove and pushed towards the groove edges. In the ideal case, no material is removed. This can how- ever occur if the material is repeatedly pushed to the groove edges due to the simultaneous effect of many abrasive particles or due to multiple effect of a sin- gle particle, and the material finally fails due to fatigue. Ideal micro-cutting leads to material removal in the form of a chip, the volume of which is equal to the volume of the wear groove created. In the case of brittle materials, microcracks also arise. Material particles are hereby generated by means of cracking and crack growth in the stressed surface. The volume of the wear particle created in micro-cracking is much larger than that of the continuous wear groove [ZumG87, ZumG92, Habi80]. 3.7 Wear 73 3.7.1.2 Adhesion Adhesion is defined as the formation of bonds between certain molecules [Erin90, ZumG87]. As a wear mechanism this process is understood as one in which atomic bonds (e.g. in the form of micro-welds) are formed in the contact zone between the material and the cutting tool material. These bonds are then deformed, reinforced and sheared off during a tangential motion of the friction partners. The process of adhesion (i.e. the formation of micro-welds between two fric- tion partners) can come about by atomic interaction (chemical adhesion) between the partners, such as thermally induced diffusion processes, electron exchange or electric polarisation. It can also result from mechanical snagging (mechanical adhe- sion) of the workpiece material, which has plastically become extremely deformable under high temperatures, with the cutting tool material [Tell93]. By means of adhesion, particles can be transferred from one wear partner to the other. If this transfer is the primary cause of wear, it is sometimes referred to as adhesive wear, although other wear mechanisms are usually also involved in the formation of loose wear particles [Habi80]. Adhesion is a pairing property that depends on the characteristics of the base and counter bodies. Whether a material has the propensity to adhesion can only be answered with reference to the material of the counter body, with which it may either form strong, weak or no adhesion bonds at all [Habi80]. The strength of an adhesion bond is described by the adhesion coefficient. This is defined as the quotient of the normal force FN with which two solid bodies in relative motion are pressed against each other and the opposing force FA that must be applied to undo the bond formed by adhesion [Habi80, Andr59, Siko63]. The propensity of solid bodies to form adhesion bonds can be evaluated with the help of their surface energy. Contact angle measurement is one method for ascertaining the surface energy of solid bodies. [Bobz00] describes a measurement process that makes it possible to compare the surface energies of coating systems with respect to their polar and dispersive parts. Since it is the polar energy share that is primarily responsible for the propensity of a solid body to adhesion, the surface energy of cutting tools (i.e. especially that of the coating system) should have as little polar energy as possible in order to minimize that propensity [Bobz00, Kloc05]. During chip formation, new material surfaces are generated that, without adsorp- tion or reaction boundary layers in statu nascendi, come in a chemically highly active state into contact with the tool surface under high pressures and temperatures, approaching that surface on the atomic level. Plastic deformation processes lead to the formation of large real contact areas. The cutting process thus provides very good opportunity for the appearance of adhesively caused interactions [Bömc89, Neis94, Erin90]. 3.7.1.3 Tribooxidation The term “tribooxidation” refers to chemical reactions of the cutting material and the material with components of the intermediate material or the surrounding medium as a result of activation caused by friction. Tribooxidation changes the properties 74 3 Fundamentals of Cutting of the external boundary layer. Reaction products can be formed that are either removed with the chip or remain stuck to the cutting tool material as a coating. Wear can be increased or reduced by this. Whether tribooxidation increases the amount of wear essentially depends on the hardness of the reaction products formed in comparison with the hardness of the cutting material. A decrease is especially possible when the reaction layers prevent direct metallic contact between the base and counter bodies, limiting the effect of adhesion [Erin90, Habi80, Tell93]. 3.7.1.4 Diffusion Diffusion is the thermally activated change of position of individual atoms [Horn67]. This involves a temperature-dependent physicochemical process in which the wear resistance of the cutting tool material can be reduced by foreign substances diffusing with it or its own components diffusing away from it. The diffusion of atoms from the tribologically loaded areas of the tribopartners leads on the one hand to a direct loss of material, which is usually very small but can still certainly be mea- sured as a quantity of wear; however, much more serious is the potentialreduction of the wear resistance of cutting tools by the diffusion of certain alloying elements. Diffusion of essential alloying elements can lead to decreased hardness and thus to reduced resistance of the cutting tool material to abrasion [Neis94, Erin90, Habi80]. The high pressures and temperatures in the contact zones characteristic of the cutting process provide an ideal setting for diffusion processes between the material and cutting tool material. Diffusion processes appear especially when high cutting speeds are used, thereby leading to high temperatures in the contact zone. In the area of the contact zone, the cutting tool material and the material approach each other on the atomic level. Furthermore, there is a difference in concentration due to the differing compositions of the material and the cutting tool material which also is preserved in the material because of the constantly added chip [Neis94, Erin90]. 3.7.1.5 Surface Damage Surface damage occurs as a result of tribological alternating stresses. In the stresses surface areas, alternating mechanical stresses lead to structural changes, fatigue, cracking, crack growth and even to separation of wear particles [Habi80]. As opposed to abrasion, in which wear particles can be formed by a single stress process, surface damage is usually preceded by a longer incubation period during which no measurable wear occurs. In this period, the formation of wear particles by means of structural changes as well as cranking and crack growth is prepared [Habi80]. 3.7.2 Causes of Wear Friction processes in tool contact zones are comparable to those of dry friction in a vacuum. Together with extraordinarily high mechanical and thermal stresses, the tool is generally worn out quickly [Rabi65, Krag71, Opit70a, Opit70b]. 3.7 Wear 75 To ta l w ea r Cutting temperature (cutting velocity; feed et al.) Adhesion High temp. oxidation Diffusive wear Abrasion Fig. 3.36 Causes of wear in cutting processes According to current information, the following separate causes can be given for the collective term “wear” (Fig. 3.36): • mechanical wear (abrasion), • the shearing off of adhered material • damage to the cutting edge due to mechanical and thermal overstress, • diffusion, • scaling. These processes overlap to a large extent and are only partially separable from each other with respect both to their cause and to their effect on wear [Opit67, Köni65, Ehme70b, Ehme70c]. 3.7.2.1 Mechanical Wear (Abrasion) Mechanical wear or abrasive wear occurs at both low and high cutting speeds. Groove wear in the form of counter body or particle grooving can be seen as the dominant form of wear in this category. In the case of counter body grooving, tri- bological stress on the cutting tool material is based on the abrasive effect of hard particles fixed on the contact surface of the workpiece or the chip. These particles can originate from the workpiece material (oxides, carbides, nitrides) or be trans- ferred by adhesion from the cutting tool material to the workpiece or chip bottom side. In the case of particle grooving, loose particles are the cause of wear. These can arise directly from abrasion (micro-cutting, microcracks) or from surface dis- ruption. However, these may also be adhesion particles or products of tribooxidation removed by abrasion or surface fatigue. Due to the high pressures and temperatures that predominate in the contact zones on both rake and flank faces, we must presume that the loose particles generated are pressed into the softer counter bodies flowing by them, contributing to further wear by counter body grooving. 76 3 Fundamentals of Cutting Due to abrasion or surface disruption on the cutting edge or in the contact zones on the rake and flank faces, cutting tool material particles that have broken away from the cutting tool material flow over the rake or flank face under high pressure. This can cause further wear by micro-cutting or microcracks. This process, also called “self-wear” [Ehme70a], is of particular importance especially with respect to the formation and development of flank face wear. 3.7.2.2 Shearing-Off of Adhered Material Particles (Adhesion) In the case of micro-welds being sheared off, material separation can occur in the boundary layer, within one or within both bodies. The term adhesive wear is used as soon as material is separated in the cutting tool material. Adhesion is also responsi- ble for the formation and growth of built-up edges, in which material is transferred from the material to be cut to the cutting tool [Erin90, Habi80, ZumG87]. Ferritic and austenitic steel materials have a high propensity to adhesion with the cutting tool material. The reason for this is above all the high plastic deformability of these materials. The high ductility of ferritic materials is based above all on their relatively low strength, in the case of austenitic steel materials on their face-centred cubic crystal lattice. Tungsten carbide, the basis of hardness and wear resistance in conventional WC- Co cemented carbides, has a hexagonal crystal structure. On the other hand, the crystal lattice of the binding metal cobalt is face-centred cubic above 690 K, which is favourable for adhesive processes. The titanium-based coating systems commonly deposited on cemented carbides also have face-centred cubic structures, resulting in a strong tendency to adhesion when machining austenitic steels. The types of wear resulting from this strong adhesive tendency can range from material bonding on the rake and flank faces to de-coating of coated tools in the area of the contact zone. Built-up edges are highly reinforced layers of the machined material that take over the function of the tool cutting edge as bondings on the tool. This is made pos- sible by the property of certain materials to harden during plastic deformation. The material adhering to the cutting edge is deformed by chip pressure, making it very hard. This makes it possible for it to take over the function of a chip-removing tool. Depending on the cutting conditions, built-up edge particles slip periodically between the flank face and the cutting surface. In the case of high hardness and removal frequencies up to about 1.5 kHz, these particles lead to increased flank face wear and considerably deteriorate the surface quality of the workpiece (Fig. 3.37). Since the chip is diverted with the built-up edge and not the rake face, crater wear is usually negligible. Figure 3.38 shows a wear-cutting speed function (VB-vc graph). According to it, flank face wear does not increase with cutting speed continuously, but has at least two distinct extremes [Opit64]. Wear first reaches a maximum at the cutting speed at which the built-up edges reach their largest dimensions. A wear minimum appears at the cutting speed at which no more built-up edges form. Flank face wear decreases after exceeding the maximum, despite higher cutting speeds. This can be ascribed to the fact that reinforcement of the built-up edge 3.7 Wear 77 1 2 3 4 Fig. 3.37 Scheme of the periodic growth of build-up edge W id th o f f la nk w ea r l an d VB / m m Cutting speed vc / (m/min) 100 0,24 0,20 0,16 0,12 0,08 0,04 0 1 2 3 5 10 20 30 50 Material: C53E Cutting mat.: HW-P30 Cross section of undeformed chip: ap· f = 2 · 0.315 mm2 –4°8° 10° 90° 60° 1mm re Geometry of cutting wedge: Cutting time tc = 30 min vc = 30 m/min vc = 20 m/min αo γo ε rκ rλs Fig. 3.38 Wear on flank face and growth of build-up edge begins to decrease as a result of recrystallization processes. It becomes unstable and no longer migrates partially between the cut surface and the flank face, but as a whole across the rake face. The position of the maxima and minima of the VB-vc graphis contingent on temperature. It is shifted to lower cutting speeds by any kind of measures taken 78 3 Fundamentals of Cutting to increase the cutting temperature (e.g. higher feed, smaller tool orthogonal rake angle, higher material strength). Measures to reduce the cutting temperature (e.g. cooling) shift the extremes accordingly to higher cutting speeds [Opit69, Peke74]. 3.7.2.3 Mechanical and Thermal Overstress Damage to the cutting edge, such as breaking, parallel cracks, comb cracks or plastic deformation, is the consequence of mechanical or thermal overstress. Cutting Edge Chipping Large cutting forces lead easily to breaking on the cutting edge (cutting edge chip- ping) or corner if the wedge angle or tool included angles of the tool are too small or the cutting tool material used is too brittle. In the case of such breaking, the profile of the fracture surface is determined by the direction of the cutting force [Köni75]. Cut interruptions can also lead to breaking, especially when tough materials are being cut, the chips of which tend to stick. Small amounts of breaking occur when the workpieces contain hard non-metallic inclusions that originate during deoxidation of the steel [Opit64a, Opit66, Opit62]. Sintered oxides and more wear-resistant types of cemented carbide are sensitive to this type of local overstress, especially in the case of manufacturing processes with relatively small cross-sections of undeformed chip (e.g. reaming or shaving). Distinct breaking of cutting tool material on the major and/or minor cutting edge can also be caused by chips striking against the cutting edge or during the rotation of shaft sections because of chip jamming between the cutting insert and the work- piece. Breakage of the cutting edge can occur both on the top and bottom sides of the insert. Parallel Cracks In the case of interrupted cuts (e.g. milling), the cutting tool material is subject to strong mechanical alternating stress. This dynamic pressure threshold load can lead to fatigue failure. Quick consecutive cutting force changes lead, especially in the case of milling with cemented carbide tools, to parallel cracks (Fig. 3.39). The quickly alternating stress in the formation of lamellar chips can also lead to parallel crack formation if a critical stress cycle is exceeded [Domk74, Beck69], e.g. when cutting titanium materials. Comb Cracks Comb cracks are a form of damage to the cutting edge as a result of thermal alternating stresses (Fig. 3.39). Such stresses originate mainly while working with interrupted cuts. During tool engagement, the cutting edge quickly heats up to high temperatures. It cools down after the tool exits the workpiece. The difference between the highest and the lowest temperature depends, among other things, on the material, cutting 3.7 Wear 79 Heating during cutting process –y Temperature Stress Tensile + 0 – Compressive Temperature Tensile + 0 – Compressive Stress Cooling Directio n of pa rallel cracks Di re ct io n of pr im ar y m ot io n Direction of comb cracks Rake face Flank face VB KM 42CrMo4+QT Comb and parallel cracks Comb cracks vc = 275 m/min GJS70 vc = 200 m/min Fig. 3.39 Comb and parallel crack formation in milling, acc. to VIEREGGE [Vier59] conditions and the ratio of the paths covered in the material and in the air. In the case of interrupted cuts, the use of cutting fluids is particularly important with respect to the size of the temperature difference because it has a much larger quenching effect than air. Cooling is advantageous to the formation of comb cracks in the case of cemented carbides and ceramic cutting tool materials. The profile of the comb cracks is aligned with that of the isotherms of the temperature field in the cutting part. The comb cracks arising in the cutting part during milling or also in short-cycle turning are generally temperature change cracks. These should be distinguished from thermoshock cracks such as develop during turning or milling while using cutting fluid. Thermoshock cracks are formed by a nonrecurring steep temperature change, while temperature change cracks form only gradually in the cutting part in the course of the cutting edge engagement. While in the case of thermoshock the thermally caused tensile strain arising in the contact zone exceeds the strength of the cutting tool material and leads directly to cracking, the stresses leading to the formation of temperature change cracks are below the strength of the cutting tool material. The development of temperature change cracks thus requires several periodic temperature changes as a rule. 80 3 Fundamentals of Cutting Due to the high energy level thermoshock cracks propagate with greater speed. Crack growth is largely transcrystalline. Depending on the stress level, they can acquire very large depths in the cutting tool material (> 1 mm), thus leading to considerable weakening of the cutting edge [Gers98]. Temperature change cracks can be observed in both wet and dry cuts. Besides the amount of thermal load, the cutting cycle and the number of cutting cycles play a decisive role in their formation. The use of cutting fluids leads to a strong reduction of the amount of cutting cycles required for cracking [Gers98]. Depending on the bending stress which the cutting edge is subject to during the cutting process and which are superimposed over thermally induced stresses, the cracks become larger with increasing numbers of cutting cycles. With a corre- sponding output length, they can relatively quickly achieve a critical size leading to fracture. As a result of the notching effect coming from the crack, they can also become the source of further cracks [Gers98]. Plastic Deformation Plastic deformation of the cutting edge arises when the thermomechanical stress effecting the tool cutting edge exceeds the deformation resistance of the cutting tool material. The influencing parameters are the strength of the material to be cut, the cutting parameters, the geometry of the insert and, on the part of the cutting tool material, its high temperature properties like hardness, compressive strength and creep behaviour. Cutting edges made of tool steel or high speed steel deform the stronger the smaller the difference is between the temperature of the cutting edge and the anneal- ing temperature of the cutting tool material. Plastic deformations also appear in the case of cemented carbides and cermet, however only at higher temperatures (cutting speeds) and under higher forces as is the case for tool or high speed steels. Cemented carbides deform more the more binder phase there is, usually cobalt. Plastic deformation of the cutting edge results in a considerable increase in wear and can lead to sudden disruption of the tool by cracking and shearing off of the cut- ting edge. It thus limits above all the cross-section of undeformed chip and cutting speeds applicable in rough turning. 3.7.2.4 Diffusion In the case of heat wear resistant cemented carbide tools, diffusion wear must be expected at high cutting speeds and mutual solubility of the partners. Tool steel and high speed steel already become soft at temperatures at which diffusion can hardly manifest itself (e.g. about 600◦C for high speed steel). When cutting with uncoated cemented carbide substrates, the following reactions can occur (Fig. 3.40): • diffusion of Fe into the binder phase Co, • diffusion of Co into the steel, whereby Fe and Co form a gapless series of mixed crystals, 3.7 Wear 81 WC: Dissolution into: Fe3W3C; (FeW)6C; (FeW)23C6 (Ti, Ta, Nb, W) C Co-W-C-mixedcrystal ChipTool Fe C Co X6CrNiMoTi17−12−2 0 10 20 30 40 50 M as s pe rc en t % 55µm W CoFe, Cr, Ni Fe W, Co 0 MaterialCutting material Cemented carbide WC-Co Fig. 3.40 Presentation of the diffusion phenomena in cemented carbide tools • dissolution of tungsten carbide to form mixed and double carbides in the form of Fe3W3C, (FeW)6C and (FeW)23C6. The carbon released during the dissolution of tungsten carbide migrates in the direction of lesser concentration, i.e. into the steel. The diffusion of carbon passes into the cobalt phase. The maximum solubility of carbon in cobalt is about 0.7% at 1200◦C. In the presence of Fe the solubility is increased to 1.5–2%. The diffusing iron thus introduces two reactions, both of which accelerate dissolution. It lends itself to the formation of iron mixed carbides and increases the reception of carbon in cobalt, which is in turn the prerequisite for the dissolution of tungsten carbide. The diffusion processes that are possible between cemented carbide and steel materials can be shown very effectively with the help of annealing tests. To this pur- pose, cemented carbide-material pairs were annealed at a temperature of 1100◦C, a pressure of 12.6 MPa and a holding time of 2 h in a protective gas atmosphere of argon. Then the samples that were fused together on the contact surface were separated on an abrasive cut-off machine perpendicularly to the contact level, and 82 3 Fundamentals of Cutting after these sample halves were grinded and buffed, the distribution of elements was analysed with a microprobe perpendicularly to the contact surface cutting tool material/material. As the quantitative line scans in Fig. 3.40 show, diffusion phenomena take place under the selected annealing parameters between the uncoated cemented carbide and the austenitic steel material here selected. On the side of the steel material, there is a diffusion of iron, chrome and nickel into the cutting tool material. In the opposite direction (i.e. from the cutting material into the material) tungsten and cobalt diffuse. The dissolution of tungsten carbide, the bearer of hardness and wear resistance, caused by the diffusion of iron into the cemented carbide leads to a weakening of the structure and lowers the resistance of the cemented carbide substrate against abrasion. The consequence of this is the formation of distinct crater wear (Fig. 3.41). Since diffusion phenomena depend on temperature, the cutting speed influences on an elementary level the speed with which crater wear develops. Uncoated cemented carbides can thus only be used at relatively low cutting speeds (vc < 100 m/ min). The cemented carbide substrate also has a serious effect on crater formation. Mixed carbides on the basis of titanium and tantalum/niobium have, in comparison to WC, a much higher chemical stability towards iron. Mixed carbides reduce the diffusion of iron into the cobalt binder phase, thus increasing the resistance of the cutting tool material to crater wear and increasing its heat wear resistance quite substantially. The most effective way to reduce crater wear is coating the cemented carbide substrate. Cemented carbide layers seal the substrate surface. This prevents direct contact between the substrate and the material, thus reducing or suppressing diffu- sion phenomena. As the line scans of annealing tests in Fig. 3.42 show, diffusion processes between the cemented carbide substrate and the material can by all means still occur in the case of TiN or TiCN layers. In contrast, no more diffusion takes place in the case of the coated cemented carbide with Al2O3 as an intermediate layer. The aluminium oxide layer thus functions as a diffusion barrier. The elements iron, nickel and chrome are found in the ZrN surface layer, while tungsten and cobalt are in the TiN boundary layer (Fig. 3.42). In the aluminium oxide intermediate layer Coated cemented carbide, tc = 20 minUncoated cemented carbide, tc = 40s vc = 120 m/min, f = 0.32 mm, ap = 2 mm vc = 200 m/min, f = 0.2 mm, ap = 2 mm Material: X6CrNiMoTi17–12–2 Fig. 3.41 Formation of crater wear on an uncoated and a coated cemented carbide, acc. to GERSCHWILER [Gers04] 3.7 Wear 83 W Co Fe Cr Ni X6CrNiMoTi 17-12-2 WC-7,5Co- 6,8MK TiN Ti (C,N) Al2O3 ZrN X6CrNiMoTi17-12-2WC-7,5Co- 6,8MK Ti(C,N) TiNTiN Cr Ni W Co Fe Fig. 3.42 Verification of the diffusion phenomena between coated cemented carbide and steel dependant on the coating system on the basis of annealing tests the traceable amount of these elements is reduced to 0 mass-%. There is above all no indication that iron, chrome, tungsten or cobalt have diffused through the Al2O3 intermediate layer on the opposite side of that layer. The observation that, excluding air or water, electrically isolated oxide layers function as diffusion barriers on cemented carbides as opposed to semiconducting nitride or carbon nitride layers can be explained as follows. In electrically isolating oxides like Al2O3 or HfO2, only ion diffusion is possible, no migration of elec- trons or holes. The result of this is that “component diffusion” becomes impossible. “Component” refers to an atom or iron, which theoretically can be split into an ion and an electron. For reasons of electron neutrality, the iron atom cannot “release” its electrons outside the layer and then migrate through the layer as an ion. The consequence is that these oxide layers act as barriers as long as there is no way for electrons to get around it, and the transport of oxygen ions is also slow enough (in oxides this transport is empirically slower than cation transport by several orders of magnitude.) In semiconductive or conductive layers however, electrons can migrate through the layer together with the ions, leading finally to the iron element migrat- ing through the layer to alloy with the substrate. Conversely, conveyance of Co or W into the chip is also possible. Diffusive transport is already possible at the tempera- tures prevalent on the tool during machining of > 800◦C. The diffusion coefficients are indeed still small, but the necessary diffusion paths are very short. While diffusion of iron through the cemented carbide layer into the cemented carbide substrate is indeed possible in the case of cemented carbides coated with TiN and TiCN, this diffusion is not as significant as is the case for uncoated sub- strates. As opposed to uncoated cemented carbides, the coat provides the substrate 84 3 Fundamentals of Cutting with additional protection from the abrasive action of the flowing chip. Especially because they are much harder than the substrate, cemented carbide layers help to reduce abrasive wear to a significant extent. Cemented carbide layers thereby ensure the high performance level of coated tools and allow for much higher cutting speeds when cutting steel materials in comparison with uncoated cemented carbides (Fig. 3.41). But as soon as the hard material layer in the contact zone of the rake face has been rubbed off and the substrate exposed, diffusion processes now once again taking place between the substrate and the chip contribute, together with the abrasive effect of the chip on the substrate, to an acceleration of crater wear. 3.7.2.5 Scaling If we examine a tool after cutting, we can recognize several annealing colours near the contact zones, indicating scaling (oxidation) of the cutting tool material. Scaling varies in importance depending on the cutting tool material alloy and cutting temper- ature (Fig. 3.43). Cemented carbides already begin scaling at 700–800◦C, whereby Annealing time / h In cr ea se in m as s / % HW-K10 HW-P25 HW-P10 HT-P05 20 15 10 5 0 1 2 3 4 5 HT-P10 HT-P20 Atmosphere: air Temperature: 1000 °C Annealing temperature: 500 °C Annealing time: 3h exp. to air HW-K10 HW-K10 HW-P25 HW-P10 HT-P10 Annealing temperature: 1000 °C; Annealing time:3 h exp. to air Fig. 3.43 Gain of weight during the annealing process in air dependant on the used cutting tool material 3.7 Wear 85 Flank face Oxidation zones Rake faceOxidation Cutting tool material: HW-P30 Cutting velocity: Cutting time: Feed: Depth of cut: Material: C53E vc = 125 m/min tc = 20 min f = 0.25 mm ap = 3 mm Fig. 3.44 Oxidation zones at a cemented carbide turning tool those made of pure tungsten carbide and cobalt oxidize more than those alloyed with titanium carbide or other carbides [Kief65]. Even under the usual cutting conditions, an oxide film is formed on WC tools in the area of the cutting edge under the effect of the cutting temperatures and atmo- spheric oxygen. This film covers the areas to which atmospheric oxygen has free access, i.e. the ends of the contact zones on the flank face, minor flank face and rake face (Fig. 3.44). The destructive effect of oxidation on the structure of cemented carbide can be observed especially clearly on the minor flank face. A complex tungsten- cobalt-iron oxide is formed that, as a result of its larger molar volume compared with cemented carbide, develops in a wart-like fashion and can lead to corner breaking [Köni75]. Scaling is of no practical importance for tool steels and high speed steels since their heat resistance is exceeded before their surfaces are oxidized more strongly. 3.7.3 Forms and Dimensions of Wear Wear phenomena that are generated on the cutting part during cutting vary greatly depending on the type and duration of stress. Figure 3.45 shows wear forms that occur primarily on turning tools. The cutting part is worn on the rake face (crater wear) as well as on the major and minor flank faces (flank face wear) (Fig. 3.46). Depending on the cutting parameters and the combination of workpiece and cutting tool material, flank face wear tends to be strongest on the edge of the contact zone on the major and minor cutting edge of the tool, which continues on the rake face. Such “notch wear” is caused by the abrupt transitions of mechanical and thermal stress prevalent on the end of the contact area, the abrasive character of the sharp 86 3 Fundamentals of Cutting Notch wear on minor cutting edge Cratering on rake face Plastic deformation of corner of cutting edge to the point of breaking Layer flaking beneath width of flank wear land Layer flaking due to plastic deformation of cutting edge Notch wear on flank face Wear on flank and minor flank face Delamination on cutting edge beyond contact zone Smeared material, partly overlapping the cutting edge in a palisade-like manner Spalling of cutting edge due to chip impact or clamped chips Spalling of cutting edge along major cutting edge Notch wear on rake face Fig. 3.45 Characteristic wear forms at the cutting part during the turning process Cutting tool material: Ceramic Material: Nickel-based alloy Cutting parameters: vc = 220 m/min f = 0.16 mm tc = 2.3 min ap = 0.3 mm Insert geometry: RCGX090700T00515 Cutting tool material: Cermet Material: 42CrMo4+QT Cutting parameters: vc = 400 m/min f = 0.1 mm tc = 12 min ap = 0.5 mm Insert geometry: SPGN120308 Cutting tool material: PCBN Material: Nickel-based alloy Cutting parameters: vc = 300 m/min f = 0.16 mm tc = 1.6 min ap = 0.3 mm Insert geometry: VBMW160412 Notch wear on: Minor cutting edge Major cutting edge Fig. 3.46 Examples for the formation of crater wear, flank face wear and notch wear dependent on the used cutting tool material and the machined material 3.8 Cutting Theory 87 KB: Crater width KM: Distance betw. crater centers KT: Crater depth SVα: Displacement of cutting edge toward flank face SVγ: Displacement of cutting edge toward rake face Wear notches on minor cutting edge Sectional view A-A A crater Wear notches on major cutting edge b Width of flank wear land VB VB B m a x. C B N b/4V B C VB B SV α A rε VB N A KT KB KM Plane PsSVα SV γ Fig. 3.47 Wear forms and measured quantities at the cutting part, acc. to DIN ISO 3685 chip edge or the feed comb and the tool edge as well as direct contact with the atmosphere (Fig. 3.46). Figure 3.47 is a schematic representation of the dimensions of wear. In particular, we distinguish the width of flank wear land VB, the displacement of cutting edge toward flank face SVα and rake face SVγ , crater depth KT and the crater centre distance KM from which the crater ratio K = KT/KM is formed. 3.8 Cutting Theory 3.8.1 Shear Plane Theory The model representation of the shear plane is based on ideal cutting conditions. Required are: • ideally sharp cutting edges, • cutting edges that are not subject to wear, • the representation of mechanical loads as substitute forces and • ideal plastic material behaviour. 88 3 Fundamentals of Cutting Trace of cutting edge plane Ps Trace of tool reference plane Pr Tool Po ≡ Pf ≡ Pn Selected point of cutting edge Workpiece Trace of shear plane PΦ y z h γn hch Φ Fig. 3.48 Model representation of the shear plane The chip formation theory derived from this model (shear plane theory) assumes that deformation takes place on only one plane, the shear plane. By definition, the shear plane passes through the selected point of cutting edge just like the tool-in- hand and tool-in-use reference system (Fig. 3.48). In the following the shear plane P� will be considered in the tool-in-hand refer- ence system. This is a plane which is inclined toward the cutting edge plane Ps by the shear angle F. The requirements made on process kinematics are fulfilled when: • tool cutting edge angle κr = 90◦ • tool inclination λs = 0◦ We are thus assuming a free, orthogonal cut. The shear plane model has the advantage of making complicated cutting processes highly comprehensible. If the effects of the corner radius and minor cutting edge are negligible in com- parison with that of the major cutting edge, the theory of the shear plane can also be used for the bound cut. With the shear angle we can macroscopically consider material and cutting tool material properties as well as thermal loads and friction conditions which pre- dominate during contact of the chip with the rake face. Moreover, the shear angle establishes the relation between undeformed chip thickness h and chip thickness hch. hch = cos (� − γn) sin� · h (3.14) 3.8 Cutting Theory 89 By means of the shear angle we can now calculate the surface area of the shear area A� in the shear plane: A� = b · h sin� (3.15) The ratio of undeformed to deformed magnitudes is designated in forming tech- nology as deformation. If the material is compressed and only the change in height is described, the term degree of compression is also used. This concerns volume consistency. In cutting theory, the term chip compression λh is used analogously [Krys39]. λh = hchh = cos (� − γn) sin� (3.16) The shear angle � is a purely theoretical quantity and should not be confused with the actual slip direction of the material, even if the shear surface and slip surface are nearly identical under certain marginal conditions. In conclusion, to show that the theory of the shear plane makes it possible to calculate various quantities with complicated relations, three classical applications of shear plane theory will be described. 3.8.1.1 Calculation of Chip Speed From simple trigonometric relations (law of sine) in the velocity plan, MERCHANT calculated the chip speed vch with the help of the shear angle F (Fig. 3.49) [Merc45]. | vch| = sin� cos (γn − �) · | vc| (3.17) Trace of cutting edge plane Ps Trace of tool refernce plane Pr Tool Po ≡ Pf ≡ Pn Selectedpoint of cutting edge Workpiece Trace of shear plane PΦ Φ y z h γn hch vch vc vΦ Fig. 3.49 Velocity plan, acc. to MERCHANT [Merc45] 90 3 Fundamentals of Cutting The continuity equation can also be used to calculate chip speed vch. The idea behind this is that a mass flow flows through a control surface, in this case the shear surface. Assuming that the density of the material is not altered by mechanical and thermal load, we obtain: m˙ = const. ⇒ | vc| · A = | vch| · Ach (3.18) From which follows: | vch| = hhch · | vc| = 1 λh · | vc| (3.19) 3.8.1.2 Calculation of Resultant Force It is assumed that the shear angle is a function of the shear stress in the shear plane, which will be shown in the following steps. In the first place we have: τ� = | F�| A� (3.20) The component of the resultant force in the shear plane, the shear force F�, can be represented by the resulting resultant force Fz. With the help of the angle relations in the circle of THALES we obtain according to Fig. 3.50: | F�| = | Fz| · cos (� + ρ − γn) (3.21) Trace of cutting edge plane Ps Trace of tool reference plane Pr Po ≡ Pf ≡ Pn Trace of shear plane PΦ y z γn Tool FΦn Fz FΦ Fγ Fγn Fc Ff Φ ρ − γn Fig. 3.50 Circle of THALES for the force diagram, acc. to MERCHANT 3.8 Cutting Theory 91 The amount of resultant force can now be calculated from Eqs. (3.20) and (3.21): | Fz| = τ� sin� · cos (� + ρ − γn) · b · h (3.22) The functional relations of the values of the resultant force components cutting force and feed force can be taken from the circle of Thales (Fig. 3.50). | Fc| = | Fz| · cos (ρ − γn) (3.23) | Ff| = | Fz| · sin (ρ − γn) (3.24) If we now insert Eq. (3.22) into Eqs. (3.23) and (3.24), the following is valid for the values of the resultant force components: | Fc| = cos (ρ − γn) · τ� sin� · cos (� + ρ − γn) · b · h (3.25) | Ff| = sin (ρ − γn) · τ� sin� · cos (� + ρ − γn) · b · h (3.26) 3.8.1.3 Calculation of the Shear Angle KRYSTOF developed a model for the simple calculation of the shear angle [Krys39]. He made the following assumptions: • The theory of the shear plane is valid. • The maximum shear stress leads to material collapse. In the main axial system, maximum shear stresses occur at an angle of 45◦. For calculations of the cutting process, the position of the main axial system is assumed to be approximately in the direction of the resulting contact stress (Fig. 3.51). For purposes of simplicity, the principle stress is not represented by the stress tensor but simply by vector addition. In this case, the friction angle approximates the orientation of the main axial system. The function relation between the shear angle, the tool orthogonal rake angle and the friction angle can be derived from Fig. 3.51. The following is valid for the shear angle: � = π 4 − (ρ − γn) (3.27) MERCHANT has suggested a possibility of calculating the shear angle that makes the following assumptions [Merc45, Merc45a]: • The theory of the shear plane is valid. • The position of the shear plane is determined by the minimum of cutting energy. The value of cutting force can be read off the circle of THALES in Fig. 3.50: 92 3 Fundamentals of Cutting Trace of shear plane PΦ Trace of cutting edge plane Ps Trace of tool reference plane Pr Po ≡ Pf ≡ Pn Tool Fz 1 τΦ Fγ Fγn 3 4 − ρ π γn Φ Fig. 3.51 Principle of the maximum shear stress, acc. to KRYSTOF [Krys39] | Fc| = cos (ρ − γn) cos (� + ρ − γn) · b · h sin� · τ� (3.28) The necessary and the sufficient conditions for calculating the position of the energy minimum are nec.: ∂Ec ∂� = 0 suff.: ∂ 2Ec ∂� �= 0 (3.29) Since the cutting energy is calculated as the product of the cutting force and the cutting path, and the cutting path is not a function of the shear angle, we can simplify to: nec.: lc · ∂| Fc| ∂� = 0 suff.: ∂ 2| Fc| ∂� �= 0 (3.30) From which follows for the shear angle: � = π 4 − 1 2 · (ρ − γn) (3.31) 3.8.2 Application of Plasticity Theory to Cutting HUCKS and OPITZ developed a shear angle equation by applying MOHR’s slip the- ory to the orthogonal cutting process [Huck51, Opit53, Mohr06]. As opposed to the models of KRYSTOF and MERCHANT, this theory makes it possible to take a material-specific slip angle into consideration instead of an idealized 45◦. It should 3.8 Cutting Theory 93 y ρ yFE zFE 3 γn Φ3 1 σ y yMT zMT Tool Po ≡ Pf ≡ Pn Sli p d ire cti on Slip direction τzy Trace of tool reference plane Pr Trace of cutting edge plane Ps ≡ Pp Trace of shear plane PΦ 1,3: Principle normal stress directions ϕ ω τzy τyz τyz σ y Φ1 Fig. 3.52 Surface element at the cutting part, acc. to HUCKS [Huck51] again be pointed out that the previously known shear angle need not necessarily be equal to the angle given by the actual position of the slip surface, since the direction of the shear plane was previously only purely geometrically determined by ideal considerations. In this case the directional angle of the slip surface towards the tool cutting edge plane is designated as the shear angle �. First a square surface element is considered on the rake face that experiences both shear and compressive stresses from the tool (Fig. 3.52). The shear stresses also appear on all remaining faces of the quadratic element as a result of the law of equality of shear stress. Due to the unhindered flow of the chip over the face there is a very small amount of compressive stress in this direc- tion, which will be neglected in the following. There are therefore two compressive stresses and four shear stresses on the surface element under consideration. If we now determine the principle normal stress with the help of MOHR’s stress circle, we establish the validity of the following equation: ω = 1 2 arctan(2 · μ) (3.32) The angle between the rake face and the principle stress direction is thus deter- mined by the friction coefficient between the rake face and the chip. This relation makes it clear, for example, why different cutting speeds yield different shear angles. The friction coefficient is dependent on the cutting speed and consequently alters the principle stress direction. The slip direction on the other hand is inclined towards the principle stress directions by a materially dependent angle ϕ. This angle can be 94 3 Fundamentals of Cutting calculated from the compressive flow stress σD and the shear flow stress τF with the help of flow tests and MOHR’s stress circle: ϕ = 45 − 1 2 arcsin ( σD − 2τF σD ) (3.33) For an ideal plastic body which is approximately realized by steel at the yielding point, the flow plane is under 45◦ in relation to the principle stress direction, since there the shear stress is at a maximum [Huck51]. With this, we obtain the principle stress and slip directions shown in Fig. 3.52 relative to the rake face. With the help of the angles γ , ϕ, and ω, the slip angle �1 can now be calculated: �1 = ϕ − 12arctan(2μ) + γn (3.34) Slip angle �3 is in the still undeformed area, which is why only slip angle �1 (which is identical with the shear angle) is significant. The shear angle calculated here presumes an extrapolation of the stress conditions via the shear plane and the width of flank wear land as well as the formation of a continuous chip. This approx- imation was proven to be in accordance with experiments made on materials with envelope lines that are inclined and parallel to the σ -axis. HUCKS did not experiment with materials with bent envelope curve [Huck51]. With the help of the shear angle, the resultant forces can now also be calculated. To do this, the stressesthat are active in the shear plane are multiplied with shear plane surface, resulting in a normal and tangential force in the shear plane. We will in this context proceed without the derivation of HUCKS’s formulae. For steel, which has an envelope line that is parallel to the σ -axis, the following formulae for cutting and feed force result with width of undeformed chip b and chip thickness h according to HUCKS: Fc = τ0 · b · h · ⎡ ⎣ 1 2 √ μ2 + 14 + cot g(φ) ⎤ ⎦ (3.35) Ff = τ0 · b · h · ⎡ ⎣ cot g(φ) 2 √ μ2 + 14 − 1 ⎤ ⎦ (3.36) To sum up, we can say that the highly numerous experimental relations in chip formation depend only on a few numbers of materials and the friction coefficient. HUCKS’s work made the fundamentally new discovery that the stress field in the chip on the cutting edge depends, besides its intensity, only on the friction coefficient and the normal direction of the envelope line [Huck51]. Chapter 4 Cutting Tool Materials and Tools Tool change times, and with them both manufacturing times and tool, machine and labour costs, are affected by wear. Wear is affected in turn by the properties of the cutting tool materials. Development in the cutting tool material sector is therefore far from finished, but is constantly aiming both to improve cutting tool materials that are already established as well as to discover new materials for use in the manufacture of cutting tools. Cutting tool materials should have the following properties in order to do justice to the stresses placed on them: • hardness and pressure resistance, • bending strength and toughness, • edge strength, • inner bonding strength, • high temperature strength, • oxidation resistance, • small propensity to diffusion and adhesion, • abrasion resistance, • reproducible wear behaviour. Should we consider all these characteristics simultaneously, we are then faced with the requirement for the “ideal” cutting tool material (Fig. 4.1). However, there is no one cutting tool material that unifies all the required properties. One rea- son for this, for example, is the physical opposition of hardness and toughness. Developments in the cutting tool material sector are concentrating on optimizing and modifying chemical composition, manufacturing methods, geometry and coat- ing in order to broaden the areas of application of cutting tool materials and tools in accordance with the requirements of modern production. 4.1 Overview of Cutting Tool Materials The cutting tool materials used in cutting can be summarized as (Fig. 4.2): • tool steels, • cemented carbides, 95F. Klocke, Manufacturing Processes 1, RWTH edition, DOI 10.1007/978-3-642-11979-8_4, C© Springer-Verlag Berlin Heidelberg 2011 96 4 Cutting Tool Materials and Tools DP Ide al cu ttin g t oo l m ate ria l 1BN Cu tti ng s pe ed W ea r- re si st an ce a nd h ea t-r es is ta nc e 1 Considering the hardness 2 Considering the hardness and the temperature DP: 2 Durability and bending-strength Feed HSS Coated HSS Fine grain and submicron grain cemented carbide Al2O3 + TiC Coated cermet Coated cemented- carbide Si3N4 - ceramic Al2O3 - ceramic Cemented-carbide on tungsten-carbide-basis Cermet Fig. 4.1 Schematic classification of several cutting tool materials Cold work steels High speed steels WC-Co TiC/TiN - Co,Ni WC-(Ti,Ta,Nb)C-Co Oxide-ceramic Silicon-nitride-ceramic Mixed-ceramic Boron-nitride Diamond Tool steels Cemented carbide Cutting - ceramics Super-hard cutting tool materials Cutting tool materials for chipping with geometrical defined cutting edge Fig. 4.2 Classification of cutting tool materials for machining 4.1 Overview of Cutting Tool Materials 97 • cutting ceramics and • super-hard cutting tool materials made of boron nitride and diamond. The hardness and wear resistance of the cutting tool materials increases in this order. On the other hand, their bending strength decreases in this order. Tool steels include unalloyed and alloyed cold work tool steels as well as high speed steel. The term cemented carbide refers to conventional cemented carbides based on tungsten carbide as well as “cermets” based on titanium boron nitride. Ceramics is the generic term for cutting tool materials made of oxide, mixed and non-oxide ceramic. 4.1.1 Classification of Hard Cutting Tool Materials According to DIN ISO 513, the notation and application of hard cutting tool mate- rials of cemented carbide, ceramic, diamond and boron nitride are classified in accordance with Fig. 4.3. According to it, uncoated cemented carbides based on tungsten carbide with a WC grain size of ≥ 1 μm take the abbreviation HW and with grain sizes of < 1 μm the notation HF. “Cermets” – cemented carbides based on titanium boron nitride – are notated with HT, coated cemented carbides and coated cermets with HC. Corresponding abbreviations from Fig. 4.3 are valid for other hard cutting tool materials based on ceramic, diamond or boron nitride. The goal of DIN ISO 513, besides that of identifying cutting tool materials, is above all their assignment to materials, for which they are most suitable for cutting. Expanding earlier norms, DIN ISO 513 provides six main application groups and thus six classes of workpiece-materials, which are classified with the code letters P, M, K, N, S and H as well as by colour (Fig. 4.4). DIN ISO 513 thus maintains the established code letters P, M and K but now only designate with them the main application groups that comprise the material groups steel (P), stainless steel (M), and cast iron (K). The major machining group K included according to the old stan- dard not only cast iron materials but also a number of other materials. In DIN ISO 513, these now new major application groups were provided with the labels N for nonferrous metals, S for special alloys and H for hard materials. Every main application group is subdivided into particular application groups (Fig. 4.4). These are notated with a code letter for the main application group they belong to and with an index. The index refers to the toughness and wear resis- tance of the cutting tool material. The higher it is within each application group, the lower is the material’s wear resistance and the higher its toughness. The indices are merely reference numbers indicating a certain sequence. They provide no infor- mation about the extent of the wear resistance or the toughness of a cutting tool material. Manufacturers of cutting tool materials should assign their cutting tool materials to the appropriate application group, depending on wear resistance and toughness. Examples are HW-P10, HC-K20, and CA-K10. An application group thus contains comparable cutting tool materials of different manufacturers, although they may differ in wear behaviour and performance. It is also possible for a cutting tool material from one manufacturer to be categorized under multiple application groups if suitable to them. 98 4 Cutting Tool Materials and Tools Ceramic Code-letter Group of materials CA Oxide-ceramic, predominantly made from aluminium-oxide (Al2O3) CM Mixed-ceramic, based on aluminium-oxide (Al2O3), but also with other components than oxides CN Silicon-nitride-ceramic, predominantly made from silicon-nitride (Si3N4) Code-letter CC Cutting-ceramic like above,but coated 1) These cemented carbides are also called "Cermet" Cemented carbide Group of materials HW Uncoated cemented carbide, predominantly made from tungsten-carbide (WC) with a grain size = 1 µm HT 1) Uncoated cemented carbide, predominant titan-carbide (TiC) or titan-nitride (TiN) or both HC Cemented carbide like above, but coated HF Uncoated cemented carbide,predominantly made from tungsten-carbide (WC) with a grain size < 1 µm CR Cutting-ceramic, predominantly made of Aluminium-oxide (Al2O3), reinforced Diamond Diamond Code-letter Group of materials DP Polycrystalline diamond DM Monocrystalline diamond Boron-nitride Boron-nitride Code-letter Group of materials BL Cubiccrystalline boron-nitride with a low content of boron-nitride BH BC Cubiccrystalline boron-nitride with a high content of boron-nitride Cubiccrystalline boron-nitride like above, but coated Code-letter Diamond category DP Polycrystalline diamond DM Monocrystalline diamond Code-letter Boron-nitride category BL Cubiccrystalline boron-nitride with a low content of boron-nitride BH BC Cubiccrystalline boron-nitride with a high content of boron-nitride Cubiccrystalline boron-nitride like above, but coated Fig. 4.3 Notation of hard cutting tool materials for machining, acc. to DIN ISO 513 4.2 Tool Steels 99 P blue M K N S H yellow red green brown grey P01 P10 P20 P30 P40 P50 Steel: All kinds of steel and cast-steel,exept stainless steel witch austenitic structure P05 P15 P25 P35 P45 M01 M10 M20 M30 M40 Stainless steel: Stainless austenitic and austenitic-ferritic steel and cast-steel M05 M15 M25 M35 K01 K10 K20 K30 K40 Cast-iron: Cast-iron with flake– graphite, cast-iron with ductile graphite, annealed cast-iron K05 K15 K25 K35 N01 N10 N20 N30 Nonferrous metals: Aluminium and other nonferrous metals, non- metal materials N05 N15 N25 S01 S10 S20 S30 Specializations and titanium: Highly heat resisting special-alloys based on iron, nickel and cobalt, titanium and titanium based alloys S05 S15 S25 H01 H10 H20 H30 Hard materials: Hardened steel, hardened cast-iron-materials, cast- iron for chill-casting H05 H15 H25 Increasing cutting speed, increasing wear-resistance of the cutting tool materials Increasing feed, increasing durability of the cutting tool materials Main application group Application group Code-letter Code-color Workpiece-material Hard cutting tool materials Fig. 4.4 Application and classification of hard cutting tool materials, acc. to DIN ISO 513 4.2 Tool Steels DIN EN ISO 4957 defines tool steels as high-grade steels suited to machining and processing materials as well as handling and measuring workpieces. We distinguish between cold work steels, hot work steels and high speed steels. Cold and hot work steels are suited to purposes in which the surface temperature during engagement 100 4 Cutting Tool Materials and Tools is generally under 200◦C. High speed steels on the other hand can be applied at temperatures of up to 600◦C. Tools for both cutting and forming are made out of cold work steels and high speed steels. Hot work steels are used primarily for forming tools such as forging dies, pressure casting dies or tools for forging machines and extrusion presses. 4.2.1 Cold Work Steels Cold work steels obtain their wear and toughness properties from heat treatment, consisting of heating to austenitizing temperature, quenching in an oil or water bath (a high cooling speed is necessary, martensite hardness) and tempering (with the goal of a partial loss of hardness in order to increase toughness). Cold work steels can be classified as unalloyed and alloyed steels (Fig. 4.5) [DIN EN ISO 4957, Wegs95]. Unalloyed tool steels (carbon steels) contain up to 1.25% C Unalloyed cold work steels Composition Examples Hammers, hatchets, axes, scissors, screwdrivers, bits Wood saws, hand saws, steel blades for segment- buzz saws Files, ductors, chisels, paper knifes Chisel of all kinds Files, ductors, chisels, Paper knifes Cutting-tools, shear-blades for cutting of steel, broaches, wood- working-tools 0.80 – 0.90 0.25 – 0.40 0.50 – 0.70 1.20 – 1.35 0.10 – 0.30 0.10 – 0.35 – 0.50 0.40 – 0.40 0.15 – 0.80 0.60 0.42 – 0.47 0.20 – 0.30 0.85 – 1.0 1.7 – 1.9 0.25 – 0.30 0.05 1.10 – 1.25 0.15 – 0.30 0.20 – 0.40 0.5 – 0.8 – – 0.07 – 0.12 0.15 – 0.45 2.0 – 2.25 0.10 – 0.40 11.0 – 12.0 – – – – 0.6 – 0.8 C45W 1.1730 C85W 1.1830 C125W 1.1563 45CrMoV7 1.2328 115CrV3 1.2210 X210CrW12 1.2436 Alloyed cold work steels Material grade Material number C Si Mn Cr Mo V W Fig. 4.5 Examples for alloyed and unalloyed cold work steels 4.2 Tool Steels 101 and small amounts of Si and Mn. Alloyed tool steels have about 1.25% C as well as up to 1.5% Cr, 1.2% W, 0.5% Mo and 1.2%V. The hardness and wear resistance of unalloyed tool steels depend on their marten- sitic structure. Wear resistance increases with hardness and carbon content; yet toughness decreases simultaneously and thus the material’s sensitivity during heat treatment and tool use becomes greater. All unalloyed tool steels are shell hardeners, i.e. they do not harden all the way through along the entire cross-section but only on the surface of the workpiece. The advantages of alloyed tool steels in contrast to unalloyed are the increase in wear resistance (addition of carbide-forming elements), retention of hardness and high temperature strength (chrome, tungsten, molybdenum, vanadium alloys) and in their higher hardness (carbon in solution). Moreover, the critical cooling speed is lower, allowing for improved hardenability. They can be used at cutting temper- atures of up to 200◦C. They are used above all in steel machining with low cutting parameters (reaming, thread die cutting) and to manufacture tools for repair work, since their cost is lower than high speed steel (HSS) tools because they have fewer alloy elements. Due to their low hot hardness, which limits the cutting speeds with which they can be used, cold work steels are used only rarely for metalworking on machine tools. Their area of application extends mainly to hand tools such as files, gouges, reamers or on saw blades for woodworking (Fig. 4.5). 4.2.2 High Speed Steels A new cutting tool material was introduced for the first time in the year 1900 at the world’s fair in Paris, with which TAYLOR could realize significantly high cutting speeds. The productivity of machining processes could thus be increased consid- erably. This new group of cutting tool materials was called “high speed steels” (HSS). High speed steels are high-alloyed steels containing tungsten, molybdenum, vanadium, cobalt and chrome as their main alloy elements. They have relatively high bending fracture strength and thus have favourable toughness properties. In contrast to cold work steels, their matrix is characterized by improved reten- tion of hardness, and they have higher hardness. Their hardness of about 60–67 HRC is preserved up to 600◦C in temperature. Due to both this and their machinability, they continue to have a broad range of application, especially for tools with sharp cutting edges and small wedge angles such as broaching tools, twist drills, thread- cutting tools, reamers, milling cutters and turning tools for grooving and parting-off operations as well as for finishing. While the hardness of high speed steels are affected by the hardness of the base material (martensite) and the number and distribution of the carbides, the alloy ele- ments dissolved in the matrix W, Mo, V and Co, which, partially precipitated as stable special carbides, are responsible for retention of hardness. Hardness and wear resistance are increased by the martensite tempered in the matrix and the embedded 102 4 Cutting Tool Materials and Tools carbides (especially Mo-W double carbides, Cr and V carbides). Carbideformation and hardening is promoted by additional alloying of chrome. 4.2.2.1 Classification of High Speed Steels High speed steels are denoted with the letters “HS” and the percents of alloy elements in the order W-Mo-V-Co (e.g. HS10-4-3-10). High speed steels are clas- sified according to their W and Mo content into four alloy and performance groups (Fig. 4.6) [DIN EN 10027a]. Group I includes the steels that contain high amounts of tungsten (18% W). The type containing Co HS18-1-2-5 has good retention of hardness. Tools made of this alloy are used for roughing high strength steels, cast irons that are difficult to machine, nonferrous metals and non-metallic materials. The material HS12-1-4-5 of the group with 12% W has excellent wear resistance due to its high V content. Its Co content also gives it high hot hardness and retention of hardness. This alloy is used in the production of turning tools and profile steels of all kinds, for finishing tools, high performance milling cutters and automatic tool machines. They are suitable for machining highly heat-treated Cr-Ni steels and non-ferrous metals. For conditioning of steel under... Composition Symbol W - Mo - V - Co < 850 N/mm2 > 850 N/mm2 Roughing Finishing 18% W HS18-0-1 HS18-1-2- + – – – – + – – 12% W HS12-1- 4 - 5 HS10-4 - 3 - 10 – – – – (+) (+) + + 6% W + 5% Mo HS6-5-2 – – – + – – – (+) + – + – 2% W + 9% Mo HS2-9-1 HS2-9-2 HS2-10-1-8 + – – – + – – – + – – – HS6-5-2- 5 HS6-5- 3 I II III IV 5 ...average load ...highest load Fig. 4.6 Alloy and performance groups of high speed steels 4.2 Tool Steels 103 The last two groups are represented primarily by steels containing tungsten and molybdenum. Molybdenum replaces tungsten from metallurgical points of view and is more effective at equal masses because it has an approximately twice as large volume percentage due to its lower density. Steels containing molybdenum are espe- cially tough. Types containing cobalt are used for machining with simple tools when robust stresses are expected (drills, turning, milling, planing and broaching tools, hobs). They are characterized by high toughness, temperature resistance and reten- tion of hardness. They are universally applicable for roughing and finishing tasks, especially for highly stressed milling tools. Steels of both of these groups that have low amounts of or no cobalt are used to manufacture tools of all kinds. The most important group are high speed steels with 6% tungsten and 5% molybdenum. Usually, the universal or standard type HS6-5-2 is used [Habe88]. As a result of its balanced alloy structure, its high toughness and good wear resistance, this alloy is very diverse. It is suitable for manufacturing machining tools for roughing or finishing such as twist drills, milling cutters of all types, tappers, reamers, broaches etc. The basic effect of alloy elements in high speed steels is summarized once more in abbreviated form in the following: • Tungsten: forms carbides; increases hot hardness, retention of hardness and wear resistance. • Molybdenum: forms carbides; improves hardening and toughness, increases hot hardness, retention of hardness and wear resistance, molybdenum can replace tungsten (has half its density!). • Vanadium: exists as the primary carbide VC and increases wear resistance (finishing). • Cobalt: shifts the limit of overheating sensitivity to higher temperatures, making it possible to achieve higher hardness temperatures. Most carbides are dissolved and the hot hardness increases. • Chrome: improves hardenability, participates in carbide formation. • Carbon: the source of hardness in the base material. Increases wear resistance because it forms carbides. 4.2.2.2 Areas of Application Figure 4.7 provides a list of the main applications of high speed steels [DIN EN ISO 4957, Wegs95]. As the amount of alloy elements increases, so does the effec- tiveness of these cutting tool materials with respect to improved wear resistance and lifetime. At the same time however, machinability becomes more difficult, which has negative consequences particularly when manufacturing complicated moulding tools. Generally, a higher amount of alloy elements means higher tool costs. The cost effectiveness of a manufacturing process is thus also determined by the choice of high speed steel. This use of high-alloyed high speed steels lends itself especially to the solu- tion of machining problems in which an increase in high temperature strength or 104 4 Cutting Tool Materials and Tools Steel grade name according DIN EN ISO 4957 HS6-5-2 HS6-5-3 HS6-5-2-5 HS10-4-3-10 HS2-9-2 HS2-9-1-8 Material no. 1.3343 1.3344 1.3243 1.3207 1.3348 1.3247 Main use Standard high speed steel for all cutting tools for rough turning or finish turning, taps and twist drills, milling cutters of all kinds, pull broaches, reamers, threading dies, counterboring drills, planing-tools, buzz saws Highly loaded taps and reamers, high speed milling cutters, broaching-tools, twist drills, cutting and shaving wheels High speed milling cutters, planing- and turning-tools of all kinds, highly loaded twist drills and taps, broaches, woodworking- and cold working-tools, roughing-tools with high durability All-purpose usage for roughing- and finishing-works, turning- and highly loaded milling cutters, automated works, woodworking-tools Milling cutter, reamers, broaching-tools End-milling cutter, turning-tools for automated works, twist drills, taps Fig. 4.7 Main applications of the most important high speed steels, acc. to DIN EN ISO 4957 toughness would have a great effect. High speed steels alloyed with cobalt (e.g. HS6-5-2-5, HS18-1-2-5) are ideal for machining tasks that place increased require- ments on the high temperature strength of the tools. Steels that contain vanadium in addition to cobalt, such as the qualities HS12-1-4-5 and HS10-4-3-10, are character- ized by improved wear properties at increased temperatures stresses and are suited to machining tasks that place the highest requirements on the wear resistance of the tools. 4.2.2.3 High Speed Steel Fabrication High speed steels can be fabricated using cast-metallurgical [Habe88] or powder- metallurgical methods [Duda86, Beis82]. A comparison of both fabrication methods is provided in Fig. 4.8. Despite attempts to develop alternative fabrication tech- niques, the cast-metallurgical fabrication of high speed steels remains the most economically important. 4.2 Tool Steels 105 Recast (ESU) Cast-metallurgical fabrication Powder-metallurgical fabrication Hot- deformation Housing Hot deformation Cold isostatic pressing Sintering ρ < 100 % Hot- deformation Sintering ρ = 100 % Soft- ening Water spray aerated powder GrindingHeat-treatment Machining Machining Machining Cavity- pressing Casting Gas spray aerated powder Melting Hot isostatic pressing Hot isostatic repressing Fig. 4.8 Production-sequence of the powder- and cast-metallurgical fabrication of high speed steels Cast-Metallurgical Fabrication After melting and casting (1550◦C) the steel in moulds, it is then subjected to block tempering (900◦C) (homogenization, Fig. 4.9). This is followed by a forging process (to break up the ledeburite and carbides) with a possible intermediate heating of the workpiece, as well as by rolling (1200◦C). Softening improves machinability. The softened condition is in most cases the post practical both for cutting and cold forming and offers the most favourable output structure for hardening. In order to avoid cracks or warpage during hardening, itis advisable to anneal the tools with a minimal amount of stress in order to reduce machining stresses before the last mechanical processing, especially in the case of tools that are irregular or difficult to mould. High speed steels require a highly complex hardening sequence due to the high amounts of different alloy elements. Conventionally produced high speed steels thus tend to segregate (demix) during the hardening phase, which is especially pro- nounced in the case of large cast blocks and high-alloyed steels. Such phenomena are usually causes of lifetime deviations in later tool use. Independently of previously applied measures such as improved melting pro- cess or seeding as well as improved design of the block format, electro slag remelting (ESR) can further improve the degree of purity and toughness of high speed steels. In this process, only a small part of the block is fluid during remelt- ing, not the whole block. In this way, macroscopic demixings such as carbide agglomerations can be reduced and slag inclusions removed. The disadvantage is the higher fabrication cost. 106 4 Cutting Tool Materials and Tools 0 200 400 600 800 1000 1200 1400 1600 M el tin g an d ca st in g Bl oc k tu rn in g Block tempering Forging Rolling Softening Te m pe ra tu re T / ° C Time t /h 1. An ne alin g 2. An ne alin g oil/air air Air Air AirIf heated in a vacuum furnace Annealing duration each approx 1–2 h Time t / h Sl ow o ve n co o l-d o w n Ba la n ci ng -te m pe ra tu re Qu enc hin g Wa rm ing up Au ste nit isa tio n AnnealingStr es s r elie f h ea t tre atm en t Pr e pa ra to ry w o rk Fi ni sh in g w o rk s 3. An ne alin g 1st preheating stage aprrox. 400 °C (in salt bath) D 3rd preheating stage 1050 °C E Hardening temperature ~1200 °C F Hot bath 500 bis 600 °C G 50–80 °C A B C D E F G Te m pe ra tu re T / ° C A 600 to 650 °C C 2nd preheating stage 850 °C B Hardening temp. [°C] 1280 1240 1240 1240 1230 Annealing, each 0.5–1 h 3 × 560 °C 2 × 570 °C 1 × 550 °C 2 × 570 °C 2 × 560 °C 2 × 540 °C Code = Grade HS18-1-2-5 HS10-4-3-10 HS12-1-4-5 HS12-1-4 HS6-5-2 Fig. 4.9 Cast-metallurgical fabrication and heat treatment of high speed steels 4.2 Tool Steels 107 The advantage of the ESR process is that the end structure is more even, has a small amount of segregations and a high degree of purity. The practical conse- quences of this are reduced warpage in both transverse and longitudinal directions during hardening and annealing due to the more homogeneous microstructure – an especially important aspect in the case of tools that are long or are premachined with a small stock allowance – as well as improved toughness resulting from the higher degree of purity and the generally more homogeneous structure. Powder-Metallurgical Fabrication The starting materials for powder-metallurgical fabrication of high speed steels is powder obtained by means of gas or water spray aeration of the molten mass (Fig. 4.8). Gas spray aerated powder is housed and undergoes hot isostatic pressing. After soft deformation, the semi-finished products are conventionally machined into tools. Water spray aerated powder undergoes a cold isostatic pressing after soften- ing, and then the semi-finished products are sintered in a vacuum furnace. Sintering is not performed until the full theoretical density is reached. Final pressing takes place later in a forging process downstream. On the other hand, mouldings such as indexable inserts are hardened in matrix presses. During sintering, the aim is to reach the full theoretical density. The sintering process can sometimes be followed by a hot isostatic repressing. Powder-metallurgically obtained high speed steels have become increasingly important in recent years. As opposed to cast-metallurgically fabricated high speed steels, they generally have a somewhat higher alloy content. PM steels are characterized by a homogeneous structure (no carbide segregation) with an even dis- tribution of fine carbides. Due to their structural composition, PM steels have better grindability and higher toughness. With respect to their efficiency as cutting tools, powder-metallurgically fabricated high speed steels vary to some degree. Numerous cutting experiments have shown that they are at least equal to conventional high speed steels with the same nominal composition. PM steels become advantageous under high mechanical stress resulting from greater feeds, especially when cutting tool materials that are difficult to machine, such as nickel-based and titanium alloys. Until now, powder-metallurgically fabricated high speed steels have no mate- rial indexes of their own. They are designated according to the company that manufactures them. To simplify their classification, the American nomenclature is often used, or the standard designation of the corresponding cast-metallurgically fabricated high speed steel is applied. 4.2.2.4 Heat Treatment of High Speed Steels HSS tools are subjected to heat treatment in order to give them their required hardness [Habe88]. First they are hardened (heating and maintaining an austenitisa- tion temperature followed by high-speed cooling) and then annealed several times. Figure 4.9 shows a time-temperature chart for the heat treatment of high speed steel HS6-5-2. 108 4 Cutting Tool Materials and Tools Due to their poor heat conductivity, high speed steels must be heated very slowly in order to avoid heating stresses and cracks. Warming up thus generally takes place in two or three preheating stages at 400, 850 and 1050◦C. After reaching the level of austenitisation, a temperature of 1150–1250◦C is held for hardening. The goal of austenitisation is to dissolve as many carbides as possible, whereby the dis- solution of the secondary carbides increase with a rising hardening temperature and extended holding times. On the other hand, coarseness must also be avoided. Depending on the critical quenching speed and on the shape and size of the work- pieces, quenching can take place in different media, including water, oil, hot baths (salt or metal molten baths) or gas. Gaseous media include air that is still or in motion, nitrogen or other gasses. Quenching intensity, which in the case of gasses is much lower than with liquid media, can be increased by raising the flow speed and pressure. After quenching, the microstructure of high speed steels consists of marten- site, residual austenite and carbides. The hardness of this structure is unsuitable for cutting tools; due to the high amount of residual austenite and the instability of the structure, it has insufficient wear resistance, is not dimensionally stable during use and exhibits an increased fracture tendency. The tools must therefore undergo annealing after hardening. High speed steels are annealed at temperatures of 540–580◦C, the temperature range of secondary hardness. This is defined as the increase in hardness at higher annealing temperatures after an initial decline in hardness from annealing at low temperatures. Under normal hardness and annealing conditions, this second increase in hardness leads to hardness values that are clearly higher than those existing after quenching. Figure 4.10 is a schematic depiction of the processes that occur dur- ing the annealing of high speed steels. The cutting tool material hardness resulting ~ 600 A S M A1 A2 M1 M 2 ~ 66 Annealing temperatureT /°C H ar dn es s/ HR C Fig. 4.10 Schematic illustration of cutting tool material hardnessresulting from the superposition of various effects during the annealing of high speed steel 4.2 Tool Steels 109 from the superimposition of various effects is plotted as the cumulative curve S as a function of the annealing temperature. As the annealing temperature increases, the hardness of martensite (M) decreases continuously (M1). The cause of this is precipitation of the carbon trapped in solu- tion and the associated reduction of crystal lattice tension. The precipitation of the carbides acts against this process, which leads to the decline in hardness observable during annealing at up to about 350◦C. Extremely finely distributed carbides pre- cipitate from the martensite (M) above 350◦C and from the residual austenite (A) above around 450◦C, causing another increase in hardness (M2/A1) due to precipi- tation hardening. As a result of carbide formation, the matrix becomes low in carbon and alloy elements, so that part of the residual austenite is converted to secondary martensite (A2) during cooling from annealing temperature. All three processes – carbide precipitation from the martensite, carbide precipitation from the residual austenite and the conversion of residual austenite into secondary martensite – lead to the increase in hardness known as the secondary hardness effect. The maximum of the hardness profile is shifted to higher temperatures (560◦C), and, if austeniti- sation occurs correctly, hardness can be higher after annealing than in the hardened state [Habe88]. Until now, heat treatment usually took place in salt baths. Their advantages are optimal heat transfer and the possibility of executing partial heat and surface treatments. The important disadvantages are the high costs involved in detoxify- ing the salts and the necessity of cleansing the workpieces of salt residue after treatment. The last few years have seen increasing amounts of heat treatments taking place in vacuum furnaces. The advantages of this method are above all its environmental friendliness as well as the clean and shiny workpiece surfaces it yields. Quenching the workpieces from hardening temperature is achieved by flooding them with nitro- gen at a pressure of 10 bar. The gas is circulated such that it flows at high speed through the batch and then through a heat exchanger for recooling. Components are quenched in this manner to 50◦C. 4.2.2.5 Surface Treatment The wear properties of HSS tools can be further improved by treating the surface by nitrating (enriching the surface layer with nitrogen by thermochemical treatment at temperatures of 500–580◦C), steam annealing (formation of a thin iron oxide layer on the tool surface in a steam atmosphere at about 500◦C), chrome-plating (deposit of a hard chrome layer with a thickness of 5–50 μm at temperatures of 50–70◦C) or coating (PVD coating with thin, highly wear-resistant hard material coats such as titanium nitride (TiN) or titanium aluminium nitride (Ti,Al)N. 4.2.2.6 HSS Indexable Inserts Indexable inserts made of high speed steel can be manufactured by precision cast- ing, by machining pre-products or directly using powder-metallurgical methods. 110 4 Cutting Tool Materials and Tools Profile milling cutter for rotors HS10-4-3-10 P20 - P30 Indexable inserts Material: rpm: Feed velocity.: X5CrNi13–4 n = 65 min–1 v f = 35 mm/min 345 Diameter D/mm 480 HSS Cemented carbide Cu tti ng sp e e d v c 70 m /m in 98 m /m in High temperature wear resistance Sufficiant ductility at low vc Requirements for the cutting tool material Fig. 4.11 Fit-for-purpose design of indexable inserts composed of high speed steel and cemented carbide (Source: Fette) While pre-products still require further machining, powder-metallurgical fabrica- tion of HSS indexable inserts for example exploit the cost-intensive alloy elements much more fully. Besides lower manufacturing costs and more efficient utilization of material, the most important advantage of sintered HSS indexable inserts is their increased flexibility in tool use due to the use of indexable insert technology. In the case of manufacturing processes such as milling or drilling, this technology allows us to fit tools with various fit-for purpose cutting tool materials (Fig. 4.11). Indexable inserts made of precision casting have so far gained no importance for steel machining [Bong91, Wähl86]. 4.3 Cemented Carbides Cemented carbides are composite materials. They are composed of the carbides of transition metals (fourth to sixth subgroup of the periodic system), which are embed- ded in a soft metallic binder phase made of cobalt and/or nickel. The carbides are on the boundary between metals and ceramics. They still have metallic properties (e.g. electrical conductivity), but they assigned to the non-oxide ceramics as “metallic hard materials” [Horn06, Salm83]. Additionally, cermets contain titanium nitride. Hard materials are the bearers of hardness and wear resistance. The binder phase is responsible for binder the brittle carbides and nitrides to a relatively solid body. 4.3 Cemented Carbides 111 The advantages of cemented carbides include good structural uniformity due to their powder-metallurgical fabrication, high hardness, pressure resistance and high- temperature wear resistance. At 1000◦C, cemented carbides have the same hardness as high speed steel at room temperature. It is also possible to manufacture types of cemented carbides with various properties by means of intentionally changing the amounts of hard material and binder [Sche88, Kola92]. 4.3.1 Historical Development In 1927, cemented carbides were first introduced as new high performance cutting tool materials at the Leipzig Trade Fair under the name WIDIA (Fig. 4.12). This was a revolutionary development at the time, opening up completely new dimensions in cutting technology. In contrast to the high speed steel tools used hitherto, cemented carbides allowed the use of twice or three times the cutting speed with the same cross-section of undeformed chip. The capacities of the machine tools of the time were far beneath the potential of the new cutting tools. Materials such as chilled cast iron, which had been very difficult to cut with HSS tools, could be machined easily with the new cutting tool material. Initially, WC-Co cemented carbides were used exclusively to machine cast iron materials. Due to the high amount of crater wear, these cemented carbides were not suited to machining long-chipping steel materi- als. This changed with the introduction of titanium carbide as an alloy component. With cemented carbides containing TiC, similar sensational cutting speed increases were made possible in steel machining as previously was the case when machining cast iron with WC-Co cemented carbides. This period also saw the development of the first cermet. Cemented carbides made for patent reasons without tungsten based on TiC and Mo2C with Nickel as the binder proved in many cases to be 1923 Patent for the fabrication of WC-Co-HM, K. Schröter 1927 Leipzig Trade Fair: 1st WC-Co-HM, producer Krupp, labeling WIDIA 1928 Carboloy (General Electric) 1931 WC-TiC-Co cemented carbide 1934 1937 1942 Titanit (Plansee), Böhlerit (Böhler) Coromant (Sandvik) 68/69 Implemention of coated cemented carbide 1970 Fine grain cemented carbide 1973 Spinodal - cemented carbide (1st Cermet with TiN) since 73/74 Accelerated developing of Cermets 1993 Submicron grain and nano crystalline cemented carbide TiC-Mo2C-Ni (1st generation of Cermets) producer Plansee, labeling Titanit S Fig. 4.12 Milestones in the development of cemented carbides 112 4 Cutting Tool Materials and Tools excessively fragile for the machinery of the time [Sche88, Kola92, Kola93, DRP23, ÖP31, Häus90, Spri95]. Further development of cemented carbides in the followingyears led to continu- ous improvement of their composition, production and cutting performance. The influence of carbide grain size on the properties of cemented carbides was rec- ognized early on. The relation, whereby cemented carbides can be increased in hardness only with a reduction in toughness, could be overcome with the devel- opment of fine grain cemented carbide. By reducing WC crystallite size to under 1 μm, both hardness and bending strength could be increased with the same amount of binder [Sche88, Kola93, Spri95]. The introduction of coated cemented carbides at the beginning of the 1970s was another great innovation. The combination of tough cemented carbide substrates with highly wear-resistant hard material coats led to an enormous increase in pos- sible cutting speeds and tool standing times. The CVD and PVD methods are the most important coating process variants today. Multi-layer coats on substrates with binder-rich rim zones or gradient structures are new developments [Sche88, Kola92, Gill95]. With the development in 1973 of “spinodal” cemented carbides, the first Cermet, which contained titanium nitride as a further hard material component, the basic form of today’s highly efficient cermet was created. Cermets are today among the high performance cutting tool materials that meet the demands of modern cutting technology excellently by allowing for the use of high cutting speeds with moderate feeds and realizing long standing times with a high level of reliability. This is due to their high chemical stability and high-temperature wear resistance, making these cutting tool materials especially interesting for cutting operations with high thermal stress on the cutting edge. 4.3.2 Cemented Carbide Production Cemented carbides are fabricated using various powder-metallurgical means (Fig. 4.13). Due to the great variety of shapes that cemented carbide components can assume, very different forming methods can be used. The most general dis- tinction is between direct and indirect fabrication, combined fabrication and special methods (injection moulding). The fabrication method used depends mainly on the geometry and quantity of the product to be manufactured [Sche88, Kola92]. About two thirds of all cemented carbide products are manufactured by direct fabrication, primarily indexable inserts. Complicated moulding in small quantities, such as pistons, screws, rolling rings or matrices are made indirectly, i.e. using additional machining steps such as cutting, drilling, turning or milling. The start- ing material is a cemented carbide in a pre-sintered or cold-isostatically pressed condition, the consistency of which is still chalky [Sche88, Kola92]. The individual components of the cemented carbide are weighed out as powder to a batch and homogenized in mixers. In the wet grinding following this, the grind- ing fluid (alcohols, acetone, hexan) should protect the powder from oxidation during 4.3 Cemented Carbides 113 Vacuum drying, screening HM-powder Cold isostatic compression Machining Pressing additives Spray drying Granulation HM-modelling material Extrusion HM-injection moulding material Injection moulding Vacuum drying dispersing Vacuum drying dispersing Debindering Sintering Debindering Sintering/ HIP Debindering Sintering HIP Grinded mouldings for wear protection Thick beams Profiles Drills, milling cutter Indexable inserts Mining tools Small bearing parts Short beams Beams, profiles d < 22 mm Drills with integrated coolant bore Small mass products with complex geometry Tungsten- carbide WC Auxiliary metal Co, Ni Alloying elements TiC, (Ta,Nb)C, Mo2C, VC, Cr3C2 Blending, wet grinding, wet-sieving HM - Granulate Semi-finished products beams, profiles Finished products Coating Plasticising Cold isostatic compression Powder compaction Grinding, separating Fig. 4.13 Fabrication sequences for the production of workpieces made of cemented carbide (Source: Widia) grinding and guarantee optimal dispersal of all the components in the suspension. After the grinding process is finished, the powder mix is prepared in accordance with the subsequent shaping method. To produce indexable inserts, the powder is trans- formed into granulate in order to assure good flow properties and a suitable granulate size for compression into matrices. The granulate is produced with the help of spray drying or granulation processes. Shaping the indexable inserts is achieved by compressing the granulate in matrix presses. The matrix press method allows for short cycle times and is thus especially suited to producing large quantities [Kola92, Daub95]. Within the fabrication sequence, sintering process is probably the most important operation, since it is here that the component obtains the mechanical and technolog- ical properties that are essential for its functional capability. In principle, sintering is defined as a thermally activated material transport in which the compressed, loosely bonded powder material (pressed part, green compact) is increasingly com- pressed due to diffusion-controlled place-shifting processes (surface diffusion, grain 114 4 Cutting Tool Materials and Tools boundary diffusion, volume diffusion). It is decisive for fabricating cemented car- bides that not the entire alloy system is converted to a molten state, but rather (as it is called in professional jargon) sintered with liquid phase [Sche88, Kola92]. Molten baths first appear at about 1300◦C. Tungsten carbide dissolves increas- ingly in the molten bath. At a sintering temperature of about 1400◦C, the entire binder phase, composed of cobalt and tungsten carbide, is molten. The liquid phase wets the carbide, penetrates into all the pores and causes the hard material particles to glide together under the influence of surface tension into the smallest space. This particle rearrangement and re-precipitation process leads to tight packing with mini- mal surface energy. Depending on the green density and sintering parameters, linear shrinkage can reach 20%. As the mass cools from sintering temperatures, tung- sten carbide precipitates again from the liquid binder phase. Up to a temperature of 700◦C, a further thermally activated material transport of tungsten and carbon takes place in accordance with the solubility of WC in Co. Atoms of the hard material phase still dissolved after solidification in the binder phase stabilize the cobalt-rich binder phase in the cubic crystalline crystal lattice structure until room temperature; otherwise the cobalt converts into hexagonal form below 417◦C [Sche88, Kola92]. 4.3.3 Components of Cemented Carbides and Their Properties • WC: Mono tungsten carbide is the most important hard material phase in techni- cal sintered cemented carbides. WC is soluble in Co, resulting in the high inner bonding and edge strength of WC-Co cemented carbides. WC is also even more wear-resistant than TiC and TaC. The applicable cutting speed is limited at higher temperatures due to its tendency to dissolution and diffusion. • TiC: Titanium carbide has a low tendency to diffusion. The consequence of this is that TiC cemented carbides have considerable high-temperature wear resistance but little bonding and edge strength. Cemented carbides high in TiC are therefore brittle and fragile. Their use is preferred when cutting steel materials with high cutting speeds. TiC can join with WC to make a composite carbide. • TaC: In small amounts, tantalum carbide has a grain-refining effect, thus improv- ing toughness and edge strength; the inner bonding strength does not decrease as sharply as is the case for TiC. • NbC: NbC has a similar effect as TaC. Both carbides appear as a mixed crystal (Ta, Nb)C in cemented carbides. • TiN: Titanium nitride is the property-determiningcomponent in all modern cer- mets. TiN in steel is even less soluble and is thus more resistant to diffusion than titanium carbide. Nitrogen causes an increase in wear resistance. In addi- tion, grain growth is inhibited. Cermets containing nitrogen have as a rule a very fine-grained structure. In a solid state, TiC and TiN are completely mixable. The physical properties of cermets are based on those of titanium carbon nitride. • Co: Cobalt is still unrivalled as a binder metal for cemented carbides based on tungsten carbide. This is due to the high level of solubility of WC in cobalt and 4.3 Cemented Carbides 115 to the good wettability of tungsten carbide crystals by the molten WC-Co binder phase [Sche88]. • Ni: due to the improved wettability of hard materials, nickel is used as a binder for cermets. But since nickel is more easy to deform than cobalt, cobalt is also added with nickel as a binder in cermets today in order to improve their high temperature properties. The properties of the cemented carbide substrate are of key importance with respect to the wear resistance and efficiency of uncoated and coated cemented car- bides. Cemented carbides should have high hot hardness and pressure resistance for the sake of increasing the resistance of the cutting edge to plastic deformation. They should however also have high bending strength and therefore sufficiently high toughness and resistance to cracking, crumbling and fracture. In general, tough cemented carbides are low in hardness and pressure resistance. These opposing cut- ting tool material properties are influenced decisively by the microstructure of the base material. The tendency is that fracture toughness increases with the cobalt con- tent and average grain size, while hardness and pressure resistance are decreased (Fig. 4.14). As the concentration of composite carbides goes up, fracture toughness is reduced. Tantalus carbide has a favourable effect on temperature change strength. Co-Concentration TiC TaC TaC TiC WC-Grain size Composite carbide concentration B en di ng st re ng th W ea r re si st an ce Cutting tool material attributes Co-Concentration: WC-Grain size: Composite carbide concentration: Co-Concentration: WC-Grain size: Composite carbide concentration: High wear resistance High ductility (Ti,Ta)CHa rd ne ss Pr es su re re si st an ce Fig. 4.14 Influencing factors for wear resistance of cemented carbides 116 4 Cutting Tool Materials and Tools This is exploited in many cases and, in the case of substrates for milling, the ratio TiC/TaC is modified in favour of tantalum carbide [Sche88, Schi89, Köni90]. The high material costs put a tight limit on the use TaC alloys however. 4.3.4 Microstructure In conventional cemented carbides based on WC, the tungsten carbide is usually in the form of prisms with triangular bases. As opposed to cemented carbides contain- ing larger amounts of cobalt, in which crystal growth is less hindered, this crystal form is less well developed in types that are fine-grained and low in cobalt. Cubic mixed crystals exist both in both cubical (with rounded edges) and nearly spherical shape (Fig. 4.15). The carbide skeleton is filled with the binder phase. The structure of cermet contains only rounded composite carbon nitrides. The core/shell structure of the hard materials is characteristic of their microstructure. The causes of this are demixing phenomena in the hard materials (spinodal demixing), mainly however the dissolution and re-precipitation processes taking place during liquid phase sintering. By selective solution, the Ni-Co molten bath is enriched with carbide components. Composite carbides precipitate as a rim zone around the remaining hard material grains when cooling down from sintering temperature [Mosk66, Rudy73, Kola89, Kief71, Leop87, Kola89a, Kola93a]. Schematic Hard material particles: WC (Ti, Ta, Nb, W) C Binder phase: Co-W-C- Mixed crystall Hard material particles: TiN (Ti, Ta, W) (C, N) (Ti, Ta, W, Mo) (C, N) (Ti, Ta, W, Mo) (C, N) Binder phase: Co, Ni (Ti, W, Mo) Ni3 (Ti, Al) Main component Schematic Cemented carbide HW-P10 Chart of reflected electrons Cermet HT-P15 Chart of reflected electrons Fig. 4.15 Microstructure of conventional cemented carbides and cermets 4.3 Cemented Carbides 117 The microstructure of the hard material particles is determined by the compo- nents contained in the original powder. The hard materials can exhibit widely varied textural structures depending on composition and grain size. If the initial powder consists of unalloyed binary hard material components, usually titanium nitride or titanium carbide are in the cores (dark cores). When prealloyed powders are used consisting of composite carbides or quaternary carbon nitrides, higher concentra- tions of molybdenum and/or tungsten are also found in the cores (light cores). The back scatter electron image in Fig. 4.15 shows this varying core/shell structure very clearly. The initial powder consists in this case of single carbides, compos- ite carbides and carbon nitrides. The hard material particles with the dark cores have Ti(C,N) in the centre, which is surrounded by a relatively titanium-rich com- posite carbon nitride (Ti,Ta,W)(C,N). The lighter (Ti,Ta,W,Mo)(C,N) shell consists primarily of a titanium-tungsten-molybdenum composite carbide containing a rela- tively large amount of tungsten and/or molybdenum. The hard material particles in the light core contain this composite carbide inside, surrounded by a titanium and nitrogen-rich shell. 4.3.5 Classification of Cemented Carbides Cemented carbide cutting tool materials can be subdivided into three groups. These are cemented carbides based on: • WC-Co, • WC-(Ti,Ta,Nb)C-Co and • TiC/TiN-Co,Ni. The term “cermet” is now used for cemented carbides based on TiC/TiN-Co,Ni. 4.3.5.1 WC-Co Cemented Carbides The cemented carbides of this group consist almost exclusively of hexagonal tung- sten monocarbide and the binder phase cobalt. They can contain up to 0.8 mass % VC and/or Cr3C2 and/or up to 2 mass % (Ta,Nb)C as doping additives to control structural fineness and consistency (Fig. 4.16). WC-Co cemented carbides are characterized by high abrasion resistance. Due to the strong diffusion tendency of tungsten carbide, they are not suitable for machin- ing soft steel materials. They are mostly used for short-chipping materials, cast iron materials, non-ferrous metals and non-metals, high temperature materials as well as in stone and wood processing (Fig. 4.4). According to previous terminology, WC-Co cemented carbides were subdivided in accordance with the average WC grain size in the sintered microstructure into fine (0.8–1.3 μm), submicron (0.5–0.8 μm) and ultrafine (0.2–0.5 μm). Deviating from this, the standard DIN ISO 513 distinguishes only between cemented carbides with grain sizes ≥ 1 μm (HW) and those with grain sizes of < 1 μm (HF). 118 4 Cutting Tool Materials and Tools Cemented carbide Application group (DIN ISO 513) Grade WC-4Co WC-6Co WC-9Co WC-12Co Density (g/cm3) (ISO 3369) Hardness HV 30 (ISO 3878) Pressure resistance (cylinder test) (N/mm2) (ISO 4506) 5700 5400 5000 4500 Bending strength (N/mm2) (ISO 3327) Young’s modulus (103⋅N/mm2) (ISO 3312) Fracture toughness (N⋅m1/2/mm2) Poisson-constant Heat conductivity (W⋅m–1⋅K–1) Coefficient of thermal expansion (293–1073 K) (10–6⋅K–1) HW-K05 HW-K10 HW-K25 HW-K40 15.1 14.9 14.6 14.2 1730 1580 1420 1290 1600 2000 2350 2450 650 630 590 580 6.9 9.6 12.3 12.7 0.21 0.22 0.22 0.22 80 80 70 65 5.0 5.5 5.6 5.9 Fig. 4.16 Composition and attributes of conventional WC-Co cemented carbides, acc. to Kolaska [Kola92] Conventional Fine-Grain Cemented Carbides (HW) Conventionaluncoated WC-Co fine-grain cemented carbides (fine cemented car- bides) with an average grain diameter of 0.8–1.3 μm (acc. to DIN ISO 513 grain size ≥ 1 μm) are still widely used in cutting technology applications where high demands are placed on cutting edge sharpness and toughness, e.g. in steel milling, finishing, grooving and parting-off or in the manufacture of threads [Kola92]. Submicron and Ultrafine Cemented Carbides Submicron and ultrafine cemented carbides have until now been the terms used in literature and practice for WC-Co cemented carbides with an average WC grain diameter of 0.5–0.8 and 0.2–0.5 μm in the sintered microstructure. The small grain diameter gives there cemented carbides a special combination of attributes: reduc- ing the WC crystallite size below 1 μm with equal binder content leads both to increased hardness and bending strength (Fig. 4.17). This property makes submi- cron and ultrafine cemented carbides applicable to a wide variety of tasks [Kola92, Daub95, Köni90a, Köni93, Drey01, Gill01]. Valuable submicron and ultrafine cemented carbides are superior to conventional fine-grain cemented carbides in hardness, edge strength and toughness. Moreover, they have a small inclination to adhesion and to wear by diffusion. These attributes 4.3 Cemented Carbides 119 14 12 10 8 6 4 2 0 Turning of white iron (80 Shore) vc = 16 m/min f = 0.1 mm ap = 1.0 mm Indexable insert: SPGN 120308 Sharp-edged κ r = 75° To ol li fe T / m in Standard Fine grain Submicron grain Standard Fine grain WC-6Co-Cemented carbide Submicron grain (B ): B en din g s tre ng th N /m m 2 15 80 17 80 20 00 (H ) 43 00 (B ) 30 00 20 00 (H ): H ard ne ss H V3 0 Fig. 4.17 Microstructure and attributes of fine and submicron grain cemented carbides in comparison to standard K-class cemented carbides (Source: Widia) are necessary when hardened materials must be machined with finishing quality and the smallest machining allowances. Submicron and ultrafine cemented carbides are used whenever high toughness, high wear resistance and the highest edge strength is required of the cutting edge, e.g. for broaching, milling and shaping of heat treated and hardened steels, in cast iron machining and for machining fibre-reinforced plastics and non-ferrous metals [Kola92, Daub95, Köni90a, Köni93, Drey01, Gill01]. 4.3.5.2 WC-(Ti,Ta,Nb)C-Co Cemented Carbides The cemented carbides of this group contain, besides tungsten carbide, mixed carbides (MC) made of titanium, tantalum, niobium and/or zirconium carbide (Fig. 4.18). Compared with WC-Co cemented carbides, they are characterized by improved high-temperature properties. This is especially the case for hot hard- ness and high temperature strength, oxidation resistance and diffusion resistance to iron materials. Their main area of application is in machining long-chipping steels (Fig. 4.4). Due to the mixed carbide content, the cemented carbides of this group can be classified according to their use into two subgroups. Group A: Mixed carbide content >10–11 mass %. Due to their mixed carbide content, the cemented carbides of this group are characterized by a high level of 120 4 Cutting Tool Materials and Tools Cemented carbide Application group (DIN ISO 513) HW - - - - -- P10 HW P15 HW P25 HW P30 HW M10 HW M15 Composition (mass percentage) WC (Ti, Ta, Nb)C Co 31.0 60.0 9.0 25.5 64.5 10.0 17.3 72.7 10.0 10.0 78.5 11.5 9.5 84.5 6.0 11.0 82.5 6.5 Density (g/cm3) (ISO 3369) Hardness HV 30 (ISO 3878) 1560 1500 1490 1380 1700 1550 Pressure resistance (cylinder test) (N/mm2) (ISO 4506) 4500 5200 4600 4450 5950 5500 Bending strength (N/mm2) (ISO 3327) 1700 2000 2200 2250 1750 1900 Young’s modulus (103⋅N/mm2) (ISO 3312) 520 500 550 560 580 570 Fracture toughness (N⋅m1/2/mm2) 8.1 9.5 10.0 10.9 9.0 10.5 0.220.220.230.220.230.22Poisson constant Heat conductivity (W⋅m–1⋅K–1) 25 20 45 60 83 90 Coefficient of thermal expansion (293 K–1073 K) (10–6⋅K–1) 7.2 7.9 6.7 6.4 6.0 6.0 10.6 11.7 12.6 13.0 13.1 13.3 Fig. 4.18 Composition and attributes of WC-(Ti, Ta, Nb)C-Co cemented carbides, acc. to KOLASKA [Kola92] high-temperature wear resistance, a low tendency to diffusion with iron materials and low abrasion. They are utilized above all in steel and cast steel cutting, with the exception of rust and acid-resistant steels with austenitic microstructures. Group B: Mixed carbide content < 10–11 mass %. The cemented carbides assigned to this group have relatively good high-temperature wear resistance and abrasion resistance. They are especially suitable for cutting rust, acid and heat-resistant steels with austenitic structures as well as for alloyed or hard austenitic/ferritic cast iron materials. 4.3.5.3 TiC/TiN-Co,Ni Cemented Carbides (Cermets) Cemented carbides based on titanium carbide and titanium nitride with a Ni,Co binder phase are designated as cermets (formed from ceramic + metal). Present-day cermets are complex multi-material systems that can contain a number of additional elements such as tungsten, tantalum, niobium, molybdenum or complex carbides, from which intermetallic phases are formed during sintering. 4.3 Cemented Carbides 121 Cermet Application group (DIN ISO 513) HT - P05 HT - P20HT - P10 Composition (mass percentage) Carbon nitrides Additive nitrides Co/Ni 89.0 0.6 10.4 85.7 0.8 13.5 82.3 1.0 16.7 (ISO 3369) 6.1 7.0 7.0 (ISO 3878) 1650 1600 1450 (ISO 4506) 5000 4700 4600 (ISO 3327) 2000 2300 2500 (ISO 3312) 460 450 440 7.2 7.9 10.0 0.21 0.22 0.21 9.8 11.0 15.7 9.5 9.4 9.1 Density (g/cm−3) Hardness HV 30 Pressure resistance (cylinder test) (N/mm2) (N/mm2) Bending strength Young’s modulus (103⋅N/mm2) Fracture toughness (N⋅m1/2/mm2) Poisson constant Heat conductivity (W⋅m−1⋅K−1) Coefficient of thermal expansion (293 K–1073 K) (10−6⋅K−1) Fig. 4.19 Composition and attributes of cermets, acc. to KOLASKA [Kola92] The composition and some characteristic attributes of three typical cermet types is given in Fig. 4.19 [Kola92]. Compared to conventional cemented carbides, cermets are characterized by their lower density. Some essential differences to WC- based cemented carbides are their significantly smaller thermal conductivity coupled with their greater thermal expansion. Due to their lower heat conductivity, a larger portion of the cutting heat is dissipated with the chip, resulting in a lower total heating of the cutting insert. Near the contact zones however, the temperature gra- dient increases inside the cutting tool material. In association with the large thermal expansion coefficient, this leads to high tensile and pressure stresses in the cut- ting tool material. The result of this is that cermets react much more sensitively to temperature change than conventional cemented carbides. They thus have a strong tendency to form comb cracks, especially in interrupted-cut machining [Köni90a, Köni93, Kloc96]. Cermets are very hard, have a low tendency to diffusion and adhesion as well as a high level of high-temperature wear resistance. Due to their high edge strength, high resistance against abrasive wear and low adhesion, cermets are especially good for planing steels. Until now, cermets have been predominantly utilized to machine 122 4 Cutting Tool Materials and Tools Cu tti ng s pe ed v c /(m /m in) 0 0.1 0.2 0.3 0.4 Feed f /mm 0 100 200 300 400 500 Fine finishing ap < 0.5 mm Rough finishing ap < 3 mm Finishing ap < 2 mm Cutting time tc /min W id th o f f la nk w ea r l an d VB /m m 0.05 0.100.20 0.30 0.50 0.40 3 5 10 3020 Cermet Cemented carbide HW−P10 Material: Cutting conditions: Tool life quantity: 240 f = 0.3 mm Ce rm et Co at ed ce m en te d ca rb id e vc = 400 m/min f = 0–25 mm ap = 1–1.5 mm ap = 1–1.5 mm Tool life quantity: 150 C45E C45+N, Rm = 700 N/mm2 vc = 400 m/min, f = 0.1 mm, ap = 1 mm vc = 220 m/min Fig. 4.20 Field of application of cermets during turning steel (Source: Kennametal Widia, CeramTec) steels with high cutting speeds and small cross-sections of undeformed chip. The development of tougher cermet types has led to the expansion of their field of application to include more average roughing conditions (Fig. 4.20). Basic areas of application include both turning and milling. Cermets also are suitable for grooving and thread turning. The high wear resistance of the cutting edges, in association with the low diffusion tendency and high oxidation resistance, generally leads to better surface qualities than coated cemented carbides are capable of producing in planing and finishing. At the same time, due to these properties, they allow for higher cutting speeds in comparison with conventional cemented carbides. But they are also suitable for cutting speeds below 100 m/min. Tougher cermet types, corresponding to the range P15 to P25 of conventional cemented carbides based on WC-(Ti,Ta,Nb)C-Co, are used successfully in average rough turning operations and in milling (Fig. 4.21). Because of their clear tendency to 4.3 Cemented Carbides 123 Chamfering of gears Material: Tools: Coolant: Cutting speed (m/min) Tool life quantity (pieces) Tool costs per workpiece *Limited by the nmax of the maschine Material: Tool: Cutting cond.: Peripheral down-cut milling Cermet Cemented To ol li fe tr av el p at h l f / m 0 100 200 300 Cutting speed vc / (m/min) 100 % 70 % 25 % 200 300 600 HSS -TiN Cermet 260* 150 Cemented Carbide -TiN PVD 50 50CrV4, 250 – 300 HB End milling cutter, D = 8 mm, z = 3 fz = 0.025 mm ap = 8 mm, ae = 1 mm Dry cutting 16MnCr5 End milling cutter, D = 16 mm, (HSS -TiN) and D = 18 mm, (Cemented Carbide, Cermet-inserts) Emulsion carbide K25 Fig. 4.21 Milling with cermets (Source: VW-Kassel, Kennametal) form comb-type fractures, cermets should always be dry-milled [Drey97, Köni90a, Köni93, Kloc96]. 4.3.6 Uncoated Cemented Carbides and Cermets Uncoated conventional cemented carbides are still used consistently in cutting tech- nology whenever there are high demands placed in cutting edge sharpness and toughness properties, e.g. in steel milling, finishing, grooving and parting off opera- tions or in thread manufacture. They are however in direct competition with coated cemented carbides and cermets, which are replacing them in an increasing amount of applications. According to DIN ISO 513, uncoated cemented carbides based on tungsten carbide take the abbreviation HW and uncoated cermets the prefix HT (Fig. 4.3). 4.3.7 Function Gradient Cemented Carbides Function gradient cemented carbides are defined as materials, whose composition and/or microstructure differ in the rim zone and kernel area. The transition from the rim zone to the kernel area is continuous [Berg03]. 124 4 Cutting Tool Materials and Tools The goal in the development of function gradient cemented carbides was, and still is, to improve even further the wear resistance of coated indexable inserts (especially in the case of dynamic stress) by modifying the rim zone. Such modifications, e.g. via cobalt enrichening and mixed carbide depletion in a approx. 50 μm thick rim zone, both cracking and fracture sensitivity of the insert are reduced [Berg97]. Such measures are, however, only practical when applied to indexable inserts intended for larger cross-sections of undeformed chip and interrupted cuts. In planing oper- ations, the strength of cemented carbides is generally completely sufficient. In this case, a rim zone that takes over or supports the wear-reducing effect of the coating (mixed carbide enrichening) is advantageous [Berg97]. In the following, three types of function gradient cemented carbides will be introduced. 4.3.7.1 Cemented Carbides with Rim Zone Free of Mixed Carbides Gradient cemented carbides are understood as cemented carbides, the rim zone of which is free of hard and brittle (Ti, Ta, Nb)C mixed crystals (Fig. 4.22) and consists practically of nothing but tungsten carbide and cobalt up to a depth of about 50 μm. The cobalt content in the rim zone is higher than within. To reduce impact sensibility, a coarse WC grain is advantageous. Moreover, nitrides, which are less hard but more wear-resistant than cubic carbides or carbides of other transition metals (e.g. zirconium carbides) can also be contained in these rim zones. In this way, cemented carbide substrates with high hardness but very tough rim zones of lesser hardness and increased resistance against cracking can be produced. The fabrication of rim zones free of mixed carbides can take place in various ways. The basic principle behind it is the formation of a nitrogen gradient in the rim zone of the cemented carbides [Berg97]. In the most commonly used method, nitrogen is introduced into the initial cemented carbide mixture as TiN or Ti(C,N). The titanium nitride decomposes dur- ing the sintering process. The nitrogen dissolving in the liquid phase diffuses from the cutting tool material into the surrounding atmosphere. In this way, a nitrogen concentration gradient arises in the cemented carbide plate from the inside outwards. The result of this is the formation of a titanium activity gradient. Titanium diffuses into the interior and accumulates there on existing cubic mixed crystals. The same is valid for tantalum and niobium. The mixed carbides near the surface gradually dissolve. On the other hand, cobalt penetrates from inside towards the outside. The growth rate follows a parabolic temporal law. It increases with a rising nitrogen con- tent and decreases with a rising titanium content. An edge effect is characteristic of these processes, the end effect of which is that the zone free of mixed carbides is thinner on sharp edges than on even surfaces [Berg97]. Other method variants include nitrogen pressure treatment, in which the cemented carbide is subjected to a nitrogen treatment under increased pressure after sintering, and the creation of zones free of mixed carbides without nitrogen, in which the cemented carbide contains a defined excess of carbon and a certain sintering regime is adhered to during cooling [Berg97, Köni90, Yohe93]. 4.3 Cemented Carbides 125 Multilayer coating on gradiented rim zone P25 100% Tool life quantity 360 % Material = C25 vc = 200 m/min f = 0.15–0.3 mm ap = 0.5–1.5 mm Multilayer coating gradiented rim zone Hardness gradient 10 µm 1000 1200 1400 1600 Hardness HV Fig. 4.22 Influence of the rim zone on the tool life of CVD tools (Source: Sumitomo) The thickness of mixed-carbide-free rim zones produced in this fashion is up to 50 μm. The methods described can therefore only be used for indexable inserts that are already in their final shape after the sintering process. At best a minor cutting edge rounding can still be undertaken. Therefore, in the case of highly accurate milling inserts that are ground, such toughness-increasing measures are not used, although they would be highly desirable. In the case of turning operations with tools of the application groups P20–P40, indexable inserts with rim zones free of mixed carbides are widely used [Berg97]. As has been shown in practice, thus designed cemented carbides have signif- icant advantages in their wear behaviour compared with coated ones. Especiallywhen turning with interrupted cut, tools coated according to this design achieve significantly longer standing times. 126 4 Cutting Tool Materials and Tools 4.3.7.2 Gradient Cemented Carbides with External Ti(C,N) Enrichment The hallmark of these cemented carbides is an enrichment of nitrides and carbon nitrides on the surface. The substrates are first tightly sintered and then impinged with nitrogen. Diffusion of nitrogen into the rim zone leads to the formation and enrichment of carbon nitrides high in nitrogen on the surface, the composition of which becomes more rich in carbon with increasing depth. The thickness of the surface carbon nitride layer can be varied by changing the treatment time. This process of enriching the rim zone with Ti(C,N) is called coating the substrate during the sintering process. The thus “coated” cemented carbides are efficient alternatives to uncoated and conventionally coated tools. Cutting experiments with gradient cemented carbides with Ti(C,N)-rich rim zones showed clearly improved wear behaviour compared with uncoated cemented carbides. They can however also be conventionally coated. This guarantees that the coating adheres better, espe- cially when one succeeds in designing the coating and the rim zone such that neither are clearly delineable from each other after the coating process [Leng06, Leng04]. 4.3.7.3 Gradient Cemented Carbides with Internal Ti(C,N) Enrichment In this substrate variant, first a rim zone free of mixed carbides is produced. Then nitrogen pressure is altered at a relatively high temperature so that nitrogen dif- fuses into the interior through the mixed-carbide-free WC-Co rim zone. Diffusion of Ti through the WC-Co layer is, however, minimal. The rim zone functions as a membrane that permits the diffusion within of nitrogen but prevents the diffusion without of titanium. By means of this one-sided diffusion of nitrogen, a transition of the WC-Co zone to the base cemented carbide develops, i.e. a zone enriched with Ti(C,N) a few micrometers beneath the surface in the interior of the substrate. In milling experiments, inserts with internal Ti(C,N) enrichment exhibited excel- lent wear behaviour in comparison with TiAlN-coated standard inserts [Leng06, Leng04]. 4.3.8 Coated Cemented Carbides and Cermets Coating cemented carbides with thin, highly wear-resistant hard material coatings is one of the milestones in their continued development. Coated cemented carbides consist of a relative tough base body (e.g. P20, K20) on which is applied a 5–20 μm thick hard material coating made of carbides (e.g. titanium carbide, TiC), nitrides (e.g. titanium nitride, TiN), carbon nitrides (titanium carbon nitride, Ti(C,N)) and/or oxides (e.g. aluminium oxide, Al2O3). Although uncoated cermets are already rela- tively high in wear resistance, hard material coating also can further improve their wear performance and efficiency just as with the conventional cemented carbides. According to DIN ISO 513, coated cemented carbides and cermets have the prefix HC (e.g. HC-K20). 4.4 Coatings 127 4.4 Coatings Since about 1968, cemented carbides have been coated with hard materials in order to improve their wear resistance and thus also their performance capability. Today, the use of coated cemented carbides and high speed steels for machining various materials is state-of-the-art. The high efficiency of coated cemented carbides is made even more clear by the fact that in the meantime more than 80% of all cemented carbides used in cut- ting have a highly wear-resistant hard material coating. In turning, the percentage is about 95% and in milling about 60%. The primary function of the hard material layer is to inhibit contact between the material, thereby reducing tool wear, which is caused by adhesion, abrasion, diffusion and oxidation phenomena (Fig. 4.23). These processes are superimposed to a large extent and are only partially separable in their causes and in their effects on wear. But in general, besides abrasion at low cutting speeds, it is above all adhesion and, at high temperatures, diffusion and oxidation that determine wear on the tool. With their high hardness and chemical stability, several hard materials possess the required prerequisites for improving resistance effectively against crater, flank face and notch wear at both low and high cutting speeds. While the hard material layer improves wear resistance, lessens adhesion between the tool and the workpiece and acts as a diffusion barrier, the task of the substrate is to act as an effective support for the hard material layer and to provide the composite body (consisting of substrate and coating) with sufficient hot hardness and, in particular, toughness. The toughness attributes of a substrate are of decisive importance for applications with interrupted cut. Due to input and output impacts and associated mechanical and thermal stress variations, the toughness of the cutting edge is much more responsible Diffusion Oxidation Abrasion Delamination Adhesion Surface effects Volume effectsStrains Crack formation Crumbling Fractures Fig. 4.23 Wear phenomena at coated cutting tools 128 4 Cutting Tool Materials and Tools for its dimensional accuracy than wear resistance. For the interrupted cut, the com- posite material “coated cemented carbide” must first exhibit sufficient resistance to cracking, crumbling and fracture (Fig. 4.23). Only when these demands are met can, analogously to the interrupted cut, wear mechanisms like adhesion, abrasion, delaminations and – as long as the contact zone temperature and contact time are sufficient – oxidation and diffusion be effectively hindered. From this we can derive two requirements for coatings [Köni92]: • The hard material layer has to drastically reduce the effect of all (if possible) wear mechanisms involved in wear process. • The coating process may not reduce the inner bonding strength, i.e. especially the toughness of the substrate. 4.4.1 Coating Methods Coating cutting tools can be done chemically and physically. Method variants include • chemical vapour deposition (CVD) and • physical vapour deposition (PVD). Figure 4.24 shows an overview of technically established coating methods for the production of wear-resistant hard material layers. As can be seen, layer deposition lies within a specific pressure/temperature range for each method and includes some characteristic coating systems, which are given in bold in the illustration [Berg03]. 105 104 105 103 102 101 10–1 10–2 100 400 600 800 1000 1200 Coating temperature T /°C Pr es su re p /P a PA-CVD PVD MT-CVD CVD (Ti,Zr)(C,N) (Ti,Hf)(C,N) Hf(C,N) Zr(C,N) Ti(C,N) Al2O3 / ZrO2 / TiOx TiC TiN Ti(C,N) Al2O3 (Ti,Zr)(C,N) TiN Ti(C,N) Al2O3 TiN Ti(C,N) (Ti,Al)N (Ti,Al)(O,N) MoS2 WC/C Fig. 4.24 Comparision of pressure and temperature conditions of coating methods with charac- teristic coating systems (Source: Kennametal Widia) 4.4 Coatings 129 4.4.1.1 CVD Processes CVD processes are chemical reactions that take place in gaseous phase under rough vacuum conditions (103–105 Pa) and with the addition of thermal or radiant energy, forming technically useful solids (hard materials) as well as volatile products. The chemical reaction is determined by the laws of thermodynamics and thus by the partial pressure of the gaseous components and temperature. There are three types of CVD coating procedures: • HT-CVD (high temperature CVD, 900–1100◦C) • MT-CVD (medium temperature CVD, 700–900◦C) • PA-CVD (Plasma activated CVD, 450–650◦C) A broad palette of hard material coating systems can be synthesized with CVD methods. The most common coating materials are based on hard materials with pri- marily metallic bonds, such as TiC, Ti(C,N), TiN, heteropolar(ionic) bonds such as Al2O3, but also covalent bonds such as diamond [Damm04]. Figure 4.25 pro- vides an overview of the most common hard materials manufactured with the CVD process. Figure 4.25 provides a comparison of some essential physical characteristics with the properties of tungsten carbide, the main component of classical cemented carbides. WC- 6Co TiC TiN ZrC ZrN HfC HfN Crystal system fcc fcc fcc fcc fcc fcc Density (g/cm3) 14.9 4.93 5.44 6.46 7.35 12.30 13.94 Micro hardness HV0,05 1580 HV30 3100 2300 2800 1700 2600 1850 Young’s modulus (103⋅N /mm2) 590 451 570 348 495 352 530 Melting point (°C) 3070 2950 3420 2980 3700 3380 Coefficient of thermal expansion (10–6.K–1) 5.5 7.7 9.4 6.7 7.3 6.6 6.9 Thermal conductivity (W⋅cm–1⋅K–1) 80 33 29 38 21 29 22 Colour G re y M et al lic gr e y G ol d ye llo w M et al lic gr ey Li gh t ye llo w M et al lic gr ey G re e n ye llo w α-Al2O3 ZrO2 HfO2 rhombo- hedral mono- clinic mono- clinic 3.99 5.7 9.7 2300 1200 1100 380 200 2050 2700 8.0 7.7 5.6 6 (at 1000 °C) 0.6 (at 1000 °C) < 0.1 Un co lo re d W hi te G re y w hi te Fig. 4.25 Characteristics of hard materials for coatings in comparison to a cemented carbide of the application group HW-K10 (Source: Kennametal Widia) 130 4 Cutting Tool Materials and Tools Because the process is near equilibrium, thermally activated HT and MT-CVD methods can only be used to produce equilibrium phases. On the other hand, the low temperature PA-CVD process is also capable of producing metastable phases such as TiAlN. Among the most technically advanced methods is the deposition of coating systems with nanostructures. In this way, complexly doped hard material phases made of Al2O3 or superlattice structures made of TiN/TiB2 can be produced with a single coating layer thickness of 5 nm [Damm04]. The HT-CVD Process The high temperature CVD process (HT-CVD) is the classic CVD method for coating cemented carbides. With it, HM tools can be coated at temperatures of 900–1100◦C. High temperature coatings are characterized by a high level of adhe- sive strength on the substrate, which is produced by an easily reproducible material transfer between the surface of the substrate and the reactive periphery [Ever94]. In order to produce a TiC coating, titanium tetrachloride (TiCl4), for example, is vaporized and transferred with methane (CH4) to a reaction vessel, which can contain several thousand indexable inserts (Fig. 4.26). Titanium carbide is formed at temperatures of 900–1100◦C and a pressure below atmospheric pressure in a hydrogenous environment (H2) in a chemical reaction following this equation: CH4 H2 H2+TiCl4 Fluid TiCl4 Evaporator Gas exhaust Coating furnace Gas inlet H2 Fig. 4.26 Schematic illustration of a CVD coating unit (schematic) 4.4 Coatings 131 TiCl4 + CH4 + n H2 1000◦C −−−−−−−−→ 10 − 150 mbar TiC + 4HCl + n H2 (4.1) This process allows us to deposit hard materials like TiC, TiN, Ti(CxNy), (Ti,Hf)(C,N), (Zr/C,N), Al2O3, AlON and others as single coats or in different com- binations as multilayer coats. The coating material is formed by chemical reaction from the gaseous phase directly on the surface of the parts to be coated. The reac- tion products rinse the substrates so that no shading effects arise. Parts with complex geometries can thereby be coated thoroughly and consistently without difficulty. Cemented carbides that are coated with the classic high temperature CVD pro- cess are characterized by high wear resistance due to their relatively thick hard material coatings (up to 20 μm for turning and up to 6 μm in the case of milling). The high process temperature is problematic in the case of coating tool and heat- treated steels. In this case, coating must be followed by rehardening, making the material vulnerable to unacceptable warpage. A further disadvantage to the HT-CVD coating process is that the toughness of the coated cemented carbide body is reduced in comparison to the uncoated sub- strate. The causes for this loss of toughness in HT-CVD coating are extraordinarily complicated. They include on the one hand the properties of the substrate to be coated (chemical composition, crystalline structure, grain size, thermal expansion, bending and pressure strength, pre-treatment) and process control on the other hand (gas atmosphere, pressure conditions, temperature/time cycle). Furthermore, pro- cesses taking place during coating in the rim zone (formation of eta phases), residual stresses present in the substrate, transition zone (interface) and hard material layer as well as the microstructure, texture, thickness and adhesion of the applied coating are all mutually responsible for toughness reduction in HT-CVD coating. We will now consider more closely processes in the rim zone (eta phase formation), the “temperature/time cycle” in the coating process and coating thick- ness based on all the above factors, which offer us many starting points for the improvement of toughness in coated cemented carbides. During the high temperature CVD coating process, there is a danger of form- ing brittle phases in the interface. Cemented carbides of the first generation exhibited an additional approx. 3–5 μm thick brittle zone with an “eta phase” (W6Co6C, W3Co3C), caused by decarburization processes in the rim zone [Schi89]. Embrittlement from the eta phase has a negative influence on the toughness of coated cemented carbides. Figure 4.27 shows the time/temperature transformation chart for a cobalt alloy with 5% tungsten and 0.23% carbon. It shows typical coating temperatures and times for the HT-CVD, MT-CVD, PA-CVD and PVD methods. From this chart, we can see that in the classic HT-CVD and medium temperature CVD process the area of eta phase precipitation is passed through/tangent. In contrast, no changes in constitution are to be expected in the case of low temperature coating methods, as in the PA-CVD or PVD processes [Köni90]. 132 4 Cutting Tool Materials and Tools Eta'EtaWC Co3W 200 400 600 800 1000 1200 0.01 0.1 1.0 10 100 1000 Te m pe ra tu re T /° C Time t /h HT-CVD MT-CVD PA-CVD PVD Co-5W-0.23 C Fig. 4.27 TTT-chart of a cobalt alloy with typical temperature sequence of several coating processes (Source: Widia) The comparative examination of the bending strength of thin, variously coated WC-Co cemented carbides shows what effect coating temperature and coating thickness have on these toughness-relevant parameters (Fig. 4.28). With increasing coating thickness and coating temperature, bending strength is reduced. The effect is especially negative in cutting operations with interrupted cut, in which the tool is subject to dynamic stresses. In the case of milling therefore, cemented carbides with thinner hard material coatings (4–6 μm) than in turning are used. With these coating thicknesses, toughness loss is relatively low. Reduction of wear protection due to the reduced coating thickness must be expected. The logical consequence of these discoveries is that more and more coating methods have gained significance for coating cemented carbides in the past few years, which can be used at lower coating temperatures in comparison with the classic HT-CVD process. The MT-CVD Process By using acetonitrile (CH3-CN) instead of a methane (CH4)/ nitrogen (N2) gas mix- ture, it is possible to lower the coating temperature in comparison with the HT-CVD method by up to 200◦C [Chat86]. In the 700–900◦C temperature range, carbon 4.4 Coatings 133 Ch an ge s o f b en di ng st re n gt h / % 10 0 10 –10 –20 –30 –40 –50 –60 02 4 6 8 PA-CVD PVD 550 °C 700 °C 550 °C 700 °C CVD CVD 400 °C Coating thickness / µm 14,5 2,6 F TiN/Ti(C,N) TiN Fig. 4.28 Influence of coating method and coating thickness on the bending strength of coated cemented carbides (Source: Widia) nitride coatings of the elements Ti, Zr and Hf can be applied with high deposi- tion rates. As opposed to the conventional HT-CVD process, the MT-CVD method has the following advantages: • Thermal stress on the cutting tool material is lower due to the reduced coating temperature at simultaneously higher deposition rates. • The danger of decarburization and thus of embrittling eta phases is lower for cemented carbide substrates. • The coatings applied with the MT-CVD method exhibit lower tensile residual stresses compared with HT-CVD coatings. Trial results from the longitudinal turning test show the same qualitative depen- dence on cutting speed for MT-CVD coated cemented carbides as for the uncoated substrate (Fig. 4.29) [Köni92, VDI3324]. Both MT-CVD coated and PVD coated cemented carbides are clearly superior to uncoated cemented carbides in per- formance. In higher cutting speed ranges, the performance of the 3 μm thick 134 4 Cutting Tool Materials and Tools 100000 50000 10000 5000 1000 500 100 60 80 100 200 400300 N um be ro f i m pa ct s n Cutting speed vc / (m/min) Material: 42CrMo4+QT Rm = 980 N/mm2 Substrate: P30/40 SPUN120312 f = 0.2 mm ap = 2.5 mm MT-CVD Uncoated Arc-PVD Fig. 4.29 Influence of coating methods and cutting speed on the toughness behaviour of carbides in an interrupted longitudinal turning test Arc-PVD-TiN coating and the 6 μm thick MT-CVD-TiN-Ti(C,N)-TiN coating do not differ. The PVD coating tends to show advantages at low cutting speeds. It extends the range of applicable cutting speeds clearly to lower cutting speeds to a range that is also covered by coated HSS. At low cutting speeds, the cutting edges succumb to flank face wear and no longer to cracking and crumbling. The causes for the improved toughness are the unaffected properties of the substrate and the more favourable compressive residual stresses resulting from PVD coating of the cemented carbides [Köni90]. MT-CVD coated cemented carbides are used above all in milling. There are significant performance advantages compared with conventional coatings. The end of their standing times is no longer brought about by cutting edge crumbling, but in a reproducible way by a continuous wearing of the flank face. Their excellent toughness properties make these cemented carbides also ideal for milling with cut- ting fluids. Fewer comb cracks form and crack development is slower than it is the case with HT-CVD coatings. Transverse cracks and cutting tool material crum- bling occur later, resulting in longer tool standing times and higher machining quality. 4.4 Coatings 135 Residual Stresses in CVD Coating Systems As a rule, coatings deposited by means of the HT or MT-CVD process exhibit tensile residual stresses. This is, however, no longer exclusively true. In the meantime, there are also CVD systems with compressive residual stresses available. Tensile residual stresses originate when cooling from coating temperature to room temperature and result primarily from the difference of the thermal expan- sion coefficients between the substrate and the coating or, in the case of multilayers, between the individual coatings. In addition, stress-free annealing in the substrate cemented carbide always occurs at the coating temperatures typical for the CVD process, leading (as opposed to the low temperature PVD process) to a reduc- tion of the (compressive) residual stresses introduced, for example, during grinding [West00]. Coatings with compressive residual stresses, generally familiar in the case of PVD coatings, have the advantage that crack development is hindered in the hard material coating, and the fracture strength of the coating/substrate composite is largely maintained. Compressive residual stresses are therefore the most beneficial to performance in interrupted turning and in milling in general. Compressive residual stresses can also be produced when using the CVD method by a corresponding choice and arrangement of individual coating systems. One example is the coating sequence TiN-Ti(C,N)-Al2O3. The outside coating composed of Al2O3 has the smallest thermal expansion coefficient, the inside TiN coating the largest. After cooling from coating to room temperature, the Al2O3 coating exhibits a small amount of compressive residual stress. Considerable larger compressive residual stress is measured with the same coating sequence if it is supplemented externally with a further Zr(C,N) or Hf(C,N) coating (ratio C:N = 1:1) (Fig. 4.30). Hf(C,N) (MT - CVD) Strain Pressure 10 00 – 10 00 – 20 00 – 30 00 0 17 µ m CVD-Coating system PVD-Coating system – 10 00 – 20 00 – 30 00 0 Pressure TiAlN 4 µm – 40 00 Cemented carbide substrate Cemented carbide substrate Ti(C,N) (MT - CVD) Al2O3 Internal stress (N/mm2) Internal stress (N/mm2) Fig. 4.30 Influence of coating methods and coating structure on residual stresses in hard coating systems 136 4 Cutting Tool Materials and Tools To produce these multilayer systems, the classic high temperature CVD process is combined with the MT-CVD process, whereby the precipitation of the carbon nitride coatings takes place with the help of the medium temperature CVD process [Drey97, West00, Berg03, Berg05]. The Plasma Activated CVD Process In the PA-CVD process (“plasma assisted” or “plasma activated”) – also known in the literature as PE, “plasma enhanced” – precipitation of fine-grained hard material coatings takes place at the, in contrast to HT and MT-CVD methods, much lower coating temperatures of 450–650◦C. At these temperatures, the thermal energy alone is insufficient for introducing the chemical reaction needed to form the hard materials from the gaseous phase. For this reason, additional energy is added to the process by means of the pulsed plasma of a low pressure glow discharge. In this way, chemical reactions are made possible that, at thermodynamic equilibrium, are only possible at much higher temperatures [Tabe89, Köni89]. As in the HT-CVD process, coatings made of titanium nitride, titanium car- bide, titanium carbon nitride and aluminium oxide can be deposited individually in crystalline structure by changing the gas composition with individually or in an arbitrary sequence. Due to the non-equilibrium conditions during deposition, there is also a possibility of synthesizing metastable systems like (Ti,Al)N using PA-CVD [Lemm03]. The attributes of the cemented carbide remain largely unaffected by the low- ering of temperature during coating. The residual stresses are in the compressive range after coating. PA-CVD coated cemented carbides measure about 30% higher bending strengths than HT-CVD coated ones. The properties of PA-CVD coated cemented carbides have a positive effect on their performance when cutting strong steel materials in interrupted cut. The sensi- tivity of the composite to comb cracking and failure due to crumbling is much lower than it is the case for HT-CVD coated cutting tool materials. The application exam- ple “side milling” proves this (Fig. 4.31). As opposed to the uncoated substrate, the tool life travel path is slightly diminished after HT-CVD coating due to thermal influence on the substrate as well as tensile residual stresses in the hard material coating, while it is over 300% larger after PA-CVD coating. Modifying the Layer Structure The layer structure of many multilayer systems usually begins with a thin tita- nium nitride layer coating the substrate,followed by one or more titanium carbon nitride intermediate layers. The TiN surface layer functions as a diffusion barrier during coating and prevents brittle eta phases forming in the interface [Köni90]. The Ti(C,N) layers building upon the TiN surface layer can consist of one layer or several layers differing in stoichiometry. They act as a kind of “buffer” between the relatively soft and tough substrate and the much harder and more brittle carbides, nitrides or oxides of the coating. 4.4 Coatings 137 Cemented carbide P25 / TiN, PA-CVD-coated Side milling cutter Material: 60WCrV8, Cutting tool material: HW-P25 vc = 80 m/min fz = 0.08 mm ae = 42 mm ap = 6 mm Coating method To ol lif e tr a v e lp at h L f / m PA-CVDUncoated HT-CVD0 4 12 16 8 220 HB Fig. 4.31 Cutting edge durability of a PA-CVD-coated cemented carbide in side milling (Source: Widia) With increasing coating thickness, the wear resistance of the CVD-coated cemented carbides increases, but their bending strength and toughness is reduced. The toughness of the coating/substrate composite is affected not only by the thick- ness of the entire coating, but also to a large extent by the coating material and the thickness of the individual coating components. Figure 4.32 illustrates this using the example of a coating made of TiC and Al2O3. With a constant total coating thickness of 10 μm, the failure rate of the coated cutting tool material due to fracture clearly increases with the thickness of the Al2O3 layer [Naka88]. Due to its high chemical stability as a coating material, aluminium oxide does indeed have excellent resistance against crater wear, but it only has a small amount of thermal shock resistance and toughness. In order to reduce the brittleness of coating systems containing aluminium oxide, they are often designed in the form of fine lamellar, fine grained multilayer coatings (Fig. 4.32). Such multilayer coatings consist usually of a combination of TiN or Ti(C,N) with Al2O3 or, as in Fig. 4.32, with aluminium oxynitride (AlON). Coatings such as these can also be composed of a large number of individual layers, whereby each layer can be thinner than 0.2 μm. Total coating thicknesses, depending on the intended use, are around 5 μm in the case of milling and between 12–20 μm for turning. Using PA-CVD coating technology, we are now also capable of depositing nanolayer coatings. These are multilayer coatings with individual layers whose thickness is given in nanometres, not in micrometers (Fig. 4.33). In the case of coating systems 1 and 2 shown in Fig. 4.33, sixty 80 nm thick layers and thirty-six 50 nm thick layers are deposited on a top layer composed of titanium nitride. In 138 4 Cutting Tool Materials and Tools AlON TiN AlON TiN AlON TiN AlON TiN Transistion layers Substrate PVD PA-CVD CVDBe nd in g st re n gt h Coating thickness Occurance of failure / (%) (cutting edge breakage) Si n gl e la ye r th ic kn e s s Al 2O 3 / T iC CVD − coating Al2O3 / TiC Total coating thickness for all tools 10 µm 800 100302010 40 706050 90 6 µm / 4 µm 1 µm / 9 µm 4 µm / 6 µm 3 µm PVD CVD W ea rr e si st an ce Coating thickness Fig. 4.32 Fine lamellar multilayer coating (Source: Widia, Sumitomo) the case of the coating system TiN-AlN, there are as much as 2000 single layers of titanium and aluminium nitride of 9 nm thickness that are applied alternately. Lowering the thickness of the coating increases hardness, toughness and wear resistance. This effect is based, among other things, on the fact that coating materials below a certain thickness take on completely new properties. For example, AlN is, with a hardness of about 1200 HV0.05, relatively soft in comparison to hard materials like TiC, however it has a hardness of over 3000 HV0.05 when the coating thickness is below 10 nm. At high cutting speeds or during dry machining, demands on thermal resistance of the tool cutting edge are increased. Due to their low thermal conductivity, oxide coatings are especially suitable to meet these demands. As can be seen in Fig. 4.25, in addition to aluminium oxide, both zirconium oxide ZrO2 and hafnium oxide HfO2 have very low thermal conductivity. Since both oxides are insufficiently hard by themselves, they are combined with Al2O3 [West00]. This can be accomplished in the form of multilayer coating systems with single or multi-phase layers, whereby the latter – so-called composite coatings – are finely distributed in the Al2O3 base matrix of a further oxide, e.g. HfO2 oder ZrO2 (Fig. 4.34). In the case of the Al2O3/ZrO2/TiOx composite coatings shown in Fig. 4.34, the oxide layer, consisting of three components, is condensed from a gas mixture com- prising AlCl3, ZrCl4, TiCl4, CO2, H2, N2 and Ar. Al2O3 then exists as a κ-phase and ZrO2 as a phase mixture in tetragonal/monoclinical (coating temperature > 990◦C) 4.4 Coatings 139 Coating system: TiN-30x(TiCN-TiN) Coating thickness: 5.2 µm Single layer thickness: approx. 80 nm Coating system: TiN-18x(Al2O3-TiN) Coating thickness: 2 µm Single layer thickness: approx. 50 nm Coating system: 1000x(TiN-AlN) Coating thickness: 9 µm Single layer thickness: approx. 9 nm Hardness of coating: 3200HV0,05 Fig. 4.33 Nanolayer created by a PA-CVD coating process (Source: Kennametal Widia) or monoclinical form (coating temperature < 990◦C) depending on the coating tem- perature. In the fracture structure image, the ZrO2 particles can be recognized as finely distributed in the Al2O3 matrix. The highly fine-grained coating structure is originated by means of a small addition of titanium as doping agent. Doping layers made of Al2O3 with titanium or boron (or TiN layers with boron) leads to the formation of very fine-grained coating structures. In the CVD process, titanium is added to the gas mixture as TiCl4 and boron as BCl3. The doping prod- ucts TiOx und BxOy, well detectable in the EDX (energy dispersive X-ray) analysis but still not clearly identifiable as a phase, are effectively dissolved in the Al2O3 lat- tice. Due to their nanodispersive distribution, they have a positive effect on coating growth and the grain size of the hard materials forming the coating system [West01, Kloc01, Berg03]. Doping brings about higher deposition rates, makes it possible to reduce deposition temperature and clearly improves wear resistance at high thermal cutting edge loads (Fig. 4.35) [Kath03]. Aftertreatment Aftertreatment helps to improve further the performance characteristics of coat- ings, especially in the case of interrupted cut. For example, smoothing the surface of CVD-coated tool bodies by means of brushing, jet treatment or polishing is 140 4 Cutting Tool Materials and Tools 6 µm 0.5 µm 1 µm 1.5 µm (12–13 µm) Ti(C,N) (MT-CVD) Al2O3 /HfO2 /TiOx TiN HfO2 7 µm 5 µm (12–17 µm) Al2O3 /ZrO2 /TiOx Composite TiCN (MT-CVD) TiN 9.5 µm 9.5 µm (16–18 µm) Al2O3 with dispersed HfO2 TiCN (MT-CVD) TiN Fig. 4.34 Fracture structure of CVD-coated cemented carbides with modern coating-design (Source: Kennametal Widia) Single layers of TiN and Ti(C,N) endowed with boron Ti(C,N) TiN Single layers of Al2O3 and TiN endowed with titan and boron TiN MK reduced rim zone A B A B Fig. 4.35 Formation of microcrystalline layer structures via doping with titanium and boron (Source: Ceratizit) 4.4 Coatings 141 the common practice today for removing potential cracking sources. Since brush- ing only covers the cutting edge area, all-round smoothing with jet treatment is being given increasingly more preference. It is of particular importance that the jet treatment, in addition smoothing, alsocauses an alteration of the tensile residual stresses as a function of the treatment parameters. For example, the Al2O3 layer in the Al2O3/ZrO2/TiOx coating system has, after jet treatment, compressive residual stresses (–3.500 N/mm2) in place of tensile residual stresses (1000 N/mm2). Jet treatment not only improves the residual stress condition, but also reduces the range within which the wear and standing time of coated hard material indexable inserts are scattered [Berg03]. Modifying the Substrate Rim Zone In comparison to uncoated cemented carbides, CVD coatings lengthen standing times enormously. On the other hand, they also lower the toughness of indexable inserts, thereby also reducing their capacity to bear high stress peaks during cut interruptions [Köni90, Köni92]. The reason for this is assumed to be cracks, which spread from the hard tensile stressed material coating into the cemented carbide substrate. Attempts to improve the toughness and resistance of cemented carbides sub- strates to crack development without reducing their hot hardness led to the development of substrates with graded rim zone structures [Sche88, Köni90, Schw89]. The goal was to modify the rim zone of the cemented carbide such that crack development towards the centre of the indexable insert was hindered or sup- pressed. One possible solution are cemented carbides, the rim zones of which are largely lacking hard and brittle (Ti, Ta, Nb)C mixed crystals and consist practically of only tungsten carbide and cobalt up to a depth of approx. 50 μm (mixed carbide- free or reduced rimzone, Fig. 4.35). The coating and application of such cemented carbides is presently state of the art. Further developments in this area are aimed at establishing the basic properties of a coated cemented carbide body – hard outside and tough inside – already during sintering [Leng04]. This would also have positive effects on the following coating process. The fabrication of function-graded cemented carbides with rim zones lack- ing mixed carbides and with external or internal Ti(C,N) enrichment is described in more detail in Sect. 4.3.5. 4.4.1.2 PVD Coating The early 1980s saw the succession of the CVD process by the PVD process in vari- ous process variants (vacuum evaporation, Arc-PVD, sputtering). The initial benefit of these methods was the possibility of coating HSS tools with complex geometries. In the meantime, these processes are also being used for cemented carbide and cer- met coating. In addition, decorative layers, oxidation layers and corrosion layers can also be produced. 142 4 Cutting Tool Materials and Tools The fundamental differences between PVD coating and the classic HT-CVD pro- cess can be summarized as follows [Sche88, Schi89, Köni90, Rödh87, Knot89, Gühr89, VDI3198, VDI3824]: • The process temperature of 160–600◦C means relatively low temperature stress on the substrate materials, so that temperature-sensitive substrate materials can also be coated. • The bending strength of the substrate remains largely unaffected by the low coating temperature. • PVD coatings exhibit residual compressive stresses, which currently limit the possible layer thicknesses to 3–6 μm. Residual compressive stresses reduce the risk of fracture formation under shock lead and thermal cycling. • In the PVD process, workpieces that are to be coated require a very careful pretreatment of the surface and process control in order to guarantee sufficient adhesion of the coating. CVD coatings have better adhesion due to the effects of evaporation and diffusion. • Because of shadowing effects, consistent layer thicknesses can only be partially realized by means of very costly devices for rotating the parts to be coated. Inner contours are as a rule only coatable up to a depth/diameter ratio of 1, since the layer thickness is diminished with increasing depth. • High number of potential coating systems and substrate materials. • Besides stable coating systems such as TiN and Ti(C,N), multi-component metastable phases can also be deposited under the non-equilibrium conditions of physical vapour deposition. These phases often exhibit structures that do not exist under equilibrium conditions. An example of this is the coating system TiAlN. We can distinguish several different methods of PVD coating: • methods with thermal evaporation (vacuum evaporation) • methods with arc evaporation (arc-PVD) • methods with cathode evaporation (sputtering) Thermal Evaporation (Vacuum Evaporation) In vacuum evaporation, usually the coating material is evaporated in a crucible with a resistance heater or an electron beam gun (EB-PVD) in high vacuum at a pressure of 10–3–10–6 Pa (Fig. 4.36). The vapour atoms exhibit average free path lengths of up to several meters at these pressures. Therefore, they generally do not interact with each other and proceed straight to the substrate. Since the latter is considerably colder than the vapour, the particles condense on the substrate in accordance with the principle of water vapour. A columnar fine crystalline layer is formed [Möhw96]. Due to the straight path of the particles, the substrate material must be moved in the coating chamber in order to avoid shadowing effects and inconsistent coating thicknesses. Vacuum evaporation allows for high coating rates (coating thickness increase per unit time) and is used above all for optical applications, in mass pro- duction for large-scale metallization of films, plastic parts and paper as well as for coating turbine blades (EB-PVD) [Sche88, Rass96]. 4.4 Coatings 143 High vacuum coating plant evaporation by: - resistance heating or by - electron beam Vacuum pump Energy supply Evaporator Target Watercooled recipient Gas inlet Electron beam Fig. 4.36 PVD-Process – Vacuum evaporation, acc. to Möhwald [Möhw96] In order to form hard material coatings composed of carbides, nitrides or oxides, the substrate is reactively vapour-deposited with the help of a reaction gas (N2, CH2,. . .). [Haef87]. For example, from 2Ti + C2H2 the hard material layer 2TiC and the gas H2 are formed. In the case of simple reactive evaporation, bonding strength is relatively low due to the low particle energy of less than 2 eV. Arc Evaporation (Arc-PVD) In the arc-PVD method, the target material is vapour-deposited and ionised by means of an arc in high vacuum. The arc travels either randomly (random arc) or in a controlled fashion (steered arc) by means of the vaporizing source, usually con- nected as a cathode (Fig. 4.36). This method is distinguished by its high degree of ionisation of up to 90% and thus makes it possible to produce high quality coatings with thick structures and good adhesive properties. Due to the high energy density in the focal point of the arc, the material is explosively evaporated and propelled, but molten particles are also torn out at the same time. The liquid particles that are carried away are found again as drop- shaped defects (“droplets”) in the layer [Bran05]. These are undesirable because they adhere to the substrate insufficiently [Möhw96]. The appearance of droplets is 144 4 Cutting Tool Materials and Tools the main disadvantage of arc evaporation, and since the droplets can lead to pores in the coating, this method is not suited to depositing corrosion-resistant coatings [Möhw96]. Droplet emission can be partially reduced by optimizing the process parameters. Since evaporation by means of cathode arcs requires that the coating material is electrically conductive, no oxide coatings can be deposited with this method. One process variant is the LARC method (Lateral Rotating Arc Cathodes). The basis of this method are rotating, water-cooled arc cathodes [Damm04]. The mag- netic field is created by permanent magnets and coils that are shifted and steered vertically and radially.In contrast to conventional arc technology, fewer droplets are produced, resulting in smoother coatings [Csel03]. Cathode Evaporation (Sputtering) In a low-pressure plasma, an inert gas (e.g. argon) is ionized by applying high volt- age. The positively charged inert gas ions are propelled onto the target switched as a cathode (coating material) and knock out atoms, atomic groups and molecules of the coating material via impulse exchange [Rass96] (Fig. 4.37). Vacuum pump Additional magnetic system Evaporator (Target) Plasma-room Sputtering plant - without additional magnetic field: Diodes-Sputter-Source - with additional magnetic field: Magnetron-Sputter-Source Gas inlet -1...5 kV Target Electrode as additional ion source + Fig. 4.37 PVD-Process – Cathode evaporation (sputtering) 4.4 Coatings 145 As opposed to vacuum evaporation, sputtering requires a process gas (usually argon) as well as a high voltage source. After evacuating the recipient, the process gas is admitted at up to 0.1–1 Pa pressure. The average free path length of the parti- cles at this pressure amounts to a few millimetres. At a target voltage of –1 to –5 kV, a glow discharge plasma is created. The plasma burns between the target which acts as an anode and the substrate connected to the ground or the recipient wall, thus making it the anode. The plasma consists of ions, electrons and uncharged atoms [Möhw96]. This evaporation method is universally applicable, since the material is evapo- rated not thermally but by means of impulse transfer. Almost all substances [Haef87] and composites of very diverse melting substances can be evaporated, i.e. not only metallic, but also isolating layers as well as materials with high melting points can be deposited. If not only metals or metal alloys are to be deposited, but also carbides, nitrides, or oxides, this can be achieved with reactive sputtering. In this case, a reaction gas (e.g. N2, CH4, O2, H2, . . .) is injected in addition to the process gas. From this reaction gas are obtained the non-metallic components of the coating (e.g. TiN, TaC, Al2O3, . . .). As in the arc method, sputtering also involves the possibility of depositing metastable coatings (i.e. coatings that do not exist in equilibrium). Because the process conditions are far from equilibrium conditions, it is possible to freeze metastable composite phases due to their rapid condensation from the gaseous phase, thus synthesizing a completely new material type that is often superior to stable boundary systems [Leye04]. We differentiate between DC sputtering, in which the sputtering material is electrically conductive, and RF sputtering, in which there is a high-frequency AC field that is used for non-conductive materials. The use of direct current (DC) plasma, high-frequency (RF) plasma and the combined use thereof as well as a nearly unlimited number of possible coating materials making sputtering enormously flexible with respect to the development of application-specific com- ponent coatings [Rass96]. Although RF sputtering has important advantages when atomizing insolating materials, this technology is of lesser importance in the creation of wear-protection coatings due to the appreciably higher capital costs in comparison with DC sputtering and the significantly lower deposition rates [Lemm03]. The disadvantages of RF sputtering can be surmounted by using pulsed DC sputtering (MF: medium frequency sputtering, up to 50 kHz). The coat- ings produced with sputtering at low vapour-deposition rates have good adhesive properties. Magnetron Sputtering In comparison to pure diode sputtering, magnetron sputtering involves the arrange- ment of permanent magnets behind the target (Fig. 4.37), the magnetic field lines of which vertically penetrate the cathode plate and the target affixed onto it. Due to the overlapping of magnetic and electric fields, the electrons in the plasma are 146 4 Cutting Tool Materials and Tools directed on extended spiral-shaped paths. In this way, the probability of ionisation is increased as well as the deposition rate as the discharge voltage is reduced. It was the invention of magnetron sputtering that has first made possible an economic utilization of the sputtering effect for coating deposition and thus the commercial deposition of wear-protective layers by means of sputtering technology [Lemm03, Bobz00]. High-Ionisation Pulsing Rising interest in isolating, mostly oxidic wear-protection coatings and the necessity of increasing ion density in the area of the substrate in order to deposit layers of dense, optimized morphology have led to the development of pulsed DC plasmas. With this technology, not only coating systems usually reserved for RF technology can be deposited, but completely new coating systems can also be synthesized due to the extremely enhanced ion currents [Lemm03, Leye04]. Pulse technology makes it possible to deposit conductive and electrically isolat- ing layers in almost arbitrary stoichiometry as well as nano-structured single and multi-phased layers with new property combinations. Figure 4.38 shows a (Ti,Al)N coating created with conventional DC technol- ogy in comparison to one made with the help of pulse technology. One can clearly recognize the alteration of the coating micromorphology towards finer crystalline structure made possible with the increased plasma ionisation of pulse technology [Lemm03]. Pulse technology thus also creates the possibility of depositing crys- talline γ-Al2O3 at substrate temperatures of < 500◦C or producing (Ti,Al)N layers with a AlN content of up to 66 mol% (Fig. 4.39). The coating process with pulsed plasmas is also known as high ionisa- tion pulsing (H.I.PTM). We distinguish between three process variants: unipolar, asymmetrical bipolar and bipolar two-cathode magnetron sputtering [Lemm03, Erke05]. Fig. 4.38 Fracture pattern of (Ti,Al)N-layers on cemented carbide substrates, deposited with conventional DC-technique (left) and using bipolar-pulse-technique (right) (Source: CemeCon) 4.4 Coatings 147 900 800 700 600 500 400 300 200 100 TiN AlN xAlN T / ° C (Ti,Al)N+ (Al,Ti)N (Ti,Al)N (NaCl structure) (Al,Ti)N (wurtzite structure) 0,2 0,4 0,6 0,8 Fig. 4.39 Metastable phase diagram of the system TiN-AlN, acc. to Cremer [Crem98] Ion Plating With respect to process control, ion plating is defined as a variant of PVD coating, in which the condensing layer is altered by means of an additional electric field applied to the substrate. This method variant is independent of the type of process and physical principle involved in creating the metal vapour. The prerequisite is a sufficiently high number of ionised steam and process gas atoms. In ion plating, the substrate is coated with a negative voltage or “bias voltage”. The metal vapour is ionized by means of electrodes arranged in a gas space and electromagnetic fields. Part of the ionised particles are accelerated towards the sub- strate (Fig. 4.40). Ion plating thus involves surrounding the substrate with gas ions. By bombarding the growing layer with ion, coating properties such as density and residual stress are modified and adhesion to the substrate is improved. The resultant coatings are very adhesive and tight. All PVD methods in which a bias voltage is used to modify the coating are termed “ion plating” [Bobz05]. In order to produce carbides, nitrides or oxides for coating purposes, here too a reactive gas is fed into the chamber. This method is called reactive ion plating [Möhw96, Haef87]. Ion plating can also be utilized for purifying and activating the component surface prior to coating (also called etching) or for activation during coating [Rass96]. A variety of ion plating plant designs have emerged as practicable coatingvari- ants. For tool coating, arc ion plating (AIP) and ion plating with low-voltage arc discharge are among the process variants that have become the most significant in tool coating. 148 4 Cutting Tool Materials and Tools + 10...5000 V- Vacuum pump Magnets for stabilisation rather leading of the arc Vaporising via vacuum arc vaporiser: Contact ignition device Rotating arc plasma channel Fig. 4.40 PVD-Process–Ion plating, acc. to MÖHWALD [Möhw96] Arc Ion Plating (AIP) In the AIP process, the target material is vaporized and ionised by means of an arc in high vacuum. This method is characterized by the high degree of ionization of up to 90% and can thus be used to produce high quality coatings with dense structures and good adhesion. The pre-voltage applied to the substrate accelerates the ionised particles, which impact the substrate at high speed. Their energy is partially converted into heat, which can result in high coating temperatures (approx. 550◦C) in the substrates. Magnetron Sputter Ion Plating (MSIP) MSIP guarantees a stable plasma and high atomization rates [Bobz00]. Coatings deposited with MSIP exhibit very good mechanical and optical properties. Nearly all materials are depositable with this method. Since the ionisation degree of the atom- ized particles is under 5%, the substrates are heated to a much smaller degree than in the AIP process, so that plastics and materials with low annealing temperatures can also be successfully coated [Bobz00]. 4.4 Coatings 149 Low-Voltage Arc Coating Ion plating with low voltage arc discharge is characterized by a low acceleration voltage, with which an electron jet is created from a low-voltage arc discharge. This jet is directed towards the target (anode) in a water-cooled crucible. The vapour made of the coating material arising from the electron bombardment is about 50% ionised and, since the substrate is applied with a voltage of –200 V, directed towards the coating target. This method is ideal for depositing nitride or carbide layers by introducing the corresponding reactive vapours [Haef87]. No droplets are formed when ion plating with low-voltage arc discharge is used for coating. This method thus makes it possible to deposit very smooth layers (Rz = 0.1 μm) and is thus suitable for coating mirror-polished surfaces without the need for post-polishing. The Use of PVD-Coated Cemented Carbides at Low Cutting Speeds Broaching soft and hardened steels offers an impressive example for the cutting edge durability of PVD-coated cemented carbides at low cutting speeds [Köni92a]. Characteristic of the broaching process are the generally low applicable cutting speeds, usually 1–25 m/min depending on the broaching machine, cutting tool material and the target material. Built up edge formation is characteristic of machining relatively soft or tough steels at low cutting speeds. These lead to dimensional and shape inaccuracies as well as to reduced workpiece surface quality. One measure for reducing built up edge formation among others is the use of broaching oils. By using PVD-TiN-coated cemented carbides in place of uncoated ones, built up edge formation is almost completely suppressed due to lowered adhesion between the flowing chip and the cutting tool material in the entire cutting speed range under investigation of vc = 10–63 m/min (Fig. 4.41). Furthermore, the use of coolants – a constant ecological problem whose maintenance and disposal are ever costlier – is superfluous. 4.4.2 Specific Properties of Hard Material Coatings The most commonly utilized wear-protection coatings in metal machining com- mercially are TiN, TiC, Ti(C,N), Ti(Al,N), CrN and Al2O3. Besides these coating systems, those that are characterized by a low friction coefficient such as DLC (diamond-like carbon) and MoS2-coatings are successfully used for wear- protection. Due to the unsurpassed hardness of diamond, CVD diamond coatings are also being increasingly used [Lemm03]. Different coating systems can be deposited as monolayers (e.g. TiN, Ti(C,N), Ti(Al,N), (Ti,HF,Cr)N) or, to improve their wear-protective effect, combined as multilayers with single layer thicknesses in the micrometers (e.g. TiN-Ti(C,N)- Al2O3-TiN, (Ti,Al)N-WC/C). 150 4 Cutting Tool Materials and Tools vc = 63 m/min broaching oil vc = 63 m/min dry Material: 17CrNiMo6+FP Cutting tool material: HW6Co Chip thickness: h = 0.1 mm vc = 10 m/min dry vc = 63 m/min dry Uncoated PVD-TiN-coated Tool geometry: 5° αo γo λs rβ 9° 0° 35 μm 0.2 mm Fig. 4.41 Coating prevents formation of built up edges The primary goals of multilayer technology are not only to improve the tough- ness, hardness and wear resistance of the coating but also to increase the total thickness of the coating. The transitions that are formed between layers of different materials place limits on shifting, which leads to a large increase in strength, espe- cially in the case of coatings with very diverse Young’s modulus. For cracks that are growing in the coating, transitions between the individual layers signify barriers at which they are forced into energy-dissipating detours, slowing or even stopping fur- ther growth (Fig. 4.42). The multilayer structure leads, in comparison to an equally thick monolayer coating, to lower residual stresses. Multilayer coatings also make it possible to integrate layers with different properties within one coating system, thus combining the functionalities of diverse coating materials. Such specific coating functions include, for example, high thermal stability, high hot hardness or the low friction resistance of intermediate or cover layers [Krie01, Lugs03]. Larger layer thicknesses mean a larger coating volume that has to be worn. From this fact results the generally longer standing times as well. One further development in multilayer technology is the deposition of nanolay- ers or coatings with superlattice structures. These are coating systems consisting of a large number of extraordinarily thin layers, the thickness of which amounts to 4.4 Coatings 151 Coating with low internal residual stresses Nanocrystalline structures Crack growth along the boundary surfaces Crack growth is hindered . Balance between high residual compressive stresses (bad coating adhesion) and low blank (no obstruction of crack growth) ones Multilayer Coatings with high residual stresses Crack growth down to the substrate Crack growth along the grain boundaries Substrate Substrate Substrate Substrate . Ductility of the coating is as important as the hardness of the coating Fig. 4.42 Schematic diagram of the crack growth in hard coatings depending on structure and properties (Source: Oerlikon Balzers) only a few nanometres (Fig. 4.43). In contrast to conventional, usually columnar layers, coating materials deposited as nanolayers are characterized by their signifi- cantly higher hardness. As has already been explained in the context of the PA-CVD coating process, this is based on the fact that the hardness of a material increases sig- nificantly below a certain layer thickness. This increase in hardness is explained by the phenomenon that diminishing layer thicknesses have altered crystal lattices and thus Young’s modulus as well. For example, AlN has a hexagonal lattice structure at layer thicknesses > 10 nm and a cubic structure when the layer thickness is < 10 nm [Csel03a]. Another way to improve a coating’s properties is to produce so-called nanocom- posites. These are noncrystalline isotropic multiphase systems, in which two mutually insoluble phases (e.g. Al, Ti, Si) are deposited during the coating pro- cess on the tool surface. Examples of this are the embedment of nanocrystalline cubic TiN in an AlN matrix, of nanocrystalline TiAlN/AlCrN in an amorphous Si3N4 matrix[Csel04] or of nanocrystalline (Ti,Al)N into a matrix composed of (Al,Ti)N. The nanocomposites can be deposited as monolayer or multilayer coating systems. The boundary layers/grain boundaries in the nanolayer/nanocomposite lay- ers are energy-dissipating barriers to cracks. Cracking and the speed of crack growth are thereby reduced (Fig. 4.42). Both nanolayer and nanocomposite layers are thus characterized not only by extremely high hot hardness and high-temperature wear resistance but also by favorable toughness attributes. With respect to the structure of hard material coatings, we differentiate between monophase layers (e.g. TiN), multiphase layers (e.g. TiN + Ti2N) and graded layers, i.e. layers the chemical composition of which exhibits a gradient (e.g. (Ti,Al)N layers with an increasing Al content) [VDI3824]. 152 4 Cutting Tool Materials and Tools Graded layer Ti(C,N)-Ti(C,N) (Ti,Al)N-(Al,Ti)N Monolayer (TiN, Ti(C,N), (Ti,Al)N, etc.) Multilayer with functional intermediate layers (TiN-Ti(C,N)-Al2O3-TiN, TiN-Ti(C,N)-Al2O3-Zr(C,N), etc.) Nanolayer (Superlattice) thickness of one layer: a few atom layers to 100 nm (Ti,Hf)N-CrN Hard layer with shear-flexible cover (TiN + MoS2,(TiAl)N + WC/C, etc.) Hard layer + low-friction amorphous carbon layer (DLC-layer) (a-C, a-C:H, a-C:H:Me) Super hard layer (CVD-Diamant, Bornitrid) Nanocomposite (nc-TiN/a-AlN, nc-(Ti,Al)N/a-Si3N4) Fig. 4.43 Schematic diagram of the structure of current CVD and PVD layer systems The properties of hard material coatings are determined by their chemical composition and structure, which depends on the conditions of their deposition. Figures 4.25 and 4.44 show some characteristic values for layer properties for some exemplary hard material coating systems produced by PVD and CVD processes. By changing the deposition conditions, such properties as chemical composition, mor- phology, structure, texture, residual stresses and thus microhardness, the thermal expansion coefficient and oxidation resistance can be altered within certain lim- its. The data presented can thus only be considered as guides for possible areas of application. Besides the hard material coatings here presented and explained in more detail below, there is a number of other hard material layers used for tool coating that are not more fully described here. 4.4.2.1 Titanium Carbide Coatings (TiC) Coating tools with hard materials began with the deposition of TiC. Due to the high hardness realizable with titanium carbide (3100–3400 HV0.05), it provides more effective protection against abrasive wear than TiN. On the other hand, its tendency to diffusion is a bit higher than that of TiN and Al2O3 due to the relatively small enthalpy of formation. TiC′s resistance to flank face wear is thus higher than that of TiN, while its resistance to crater wear is lower. Its oxidation wear is also the low- est of the layers shown in Fig. 4.44. TiC coatings are chiefly applied using the CVD process. For the most part, TiC is used as a monolayer when abrasion is predominant or in multilayer coatings together with TiN, Ti(C,N) or Al2O3 [VDI 3824]. 4.4.2.2 Titanium Nitride (TiN) Since 1980, tools were already being coated with titanium nirtide. TiN is the most frequently employed hard material for coating cutting tools today. The coat- ing material is an intercalation compound composed of titanium and nitrogen. 4.4 Coatings 153 TiN TiCN TiC TiAlN PVD/CVD PVD/CVD CVDProduction process 2300 3000 3100 Coating thickness/µm 1 to 5 1 to 5 1 to 5 Microhardness/HV 0,05 1) > 450 > 350 > 350 +++ ++ + Oxidation temperature/°C 2) ++ +++ +++Resistance to abrasion ++ + + Resistance to wear due to diffusion (to steel) 3000 Resistance to wear due to adhesion (against steel) PVD 1 to 5 > 700 ++++ +++ +++ 1) For the microhardness, mean values are indicated. They are obtained from reported measured values resulting from different compositions, coating thicknesses and internal stresses. 2) The oxidation temperature is the temperature at which oxidation of the coating material begins, considerably affecting the characteristics of the coating. 3) Al2O3 is already an oxide. 4) Being poor conductors of heat, the coatings act as a thermal barrier to the heat produced during metal-cutting so that most of the heat can be removed through the chip. 5) As the aforementioned hard coatings themselves do not corrode, they protect the basis material from corrosion. (Leaks in hard coatings may lead to the development of local galvanic elements and to pitting corrosion). ++ ++ + ++ Thermal barrier effect 4) + + + Protection of basis material against corrosion 5) + CrN Al2O3 PVD 1900 1 to 10 > 600 + ++ ++ 2100 HV 0.1 CVD/PVD 1 to 5 – 3) +++++ ++ +++ ++ +++ ++ + Fig. 4.44 Quantities Characterising the coating and the coating performance, acc. to VDI 3824/1 Due to the high interaction between the metal and nitrogen atoms, this com- pound is highly stable. With an enthalpy of formation that is almost twice as high as that of TiC, TiN is thermodynamically more stable, and thus more diffu- sion resistant and less inclined to adhesion. Therefore, TiN’s resistance to crater wear is higher than that of TiC. TiN coatings are characterized by a high level of toughness. TiN can be deposited with both the CVD and PVD process. The characteristic colour of TiN is goldish yellow. Silver-hued TiN coatings consist of a phase com- posite of Ti2N and TiN, whereby the Ti2N phase is dominant. These coatings are harder but also more brittle than pure TiN layers. They are most commonly used when abrasive wear predominates [VDI 3824]. 154 4 Cutting Tool Materials and Tools 4.4.2.3 Titanium Carbonnitride Coatings (Ti(C,N)) TiC and TiN can be mixed at any ratio. The properties of titanium carbonnitride are adjustable by varying the C/N ratio. With increasing carbon content, the colour of the Ti(C,N) layers change from coppery to violet, bluish-grey to grey [VDI 3824]. Titanium carbonnitrides are used industrially both as hard materials in cemented carbides and as wear-resistant thin-films. Often Ti(C,N) coatings are multilayered, i.e. deposited with increasing carbon content in the direction of the coating surface. By integrating carbon atoms in place of nitrogen atoms into the titanium nitride crystal lattice, a considerable increase in hardness can be realized, which is positive for wear resistance but also increases brittleness [Sato78, Schi74, Berg90]. To com- pensate for this increase in brittleness, Ti(C,N) coatings are deposited as multilayers, so that residual stresses between the individual coating layers can be reduced. Ti(C,N) coatings are suited for machining steels with high tensile strength and thus for higher cutting temperatures. 4.4.2.4 Titanium Aluminium Nitride Coatings ((Ti,Al)N) The (Ti,Al)N coating system was developed in order to improve the oxidation resistance, hot hardness and wear-protection properties above the levels of previ- ously used coatings [Quin87, Knot87]. In comparison to TiN and Ti(C,N) coatings, (Ti,Al)N coatings have the highest oxidation resistance with a comparably high level of hardness. Since Ti(Al,N) is a metastable coating system, it can only be deposited with the PVD, PA-CVD or MT-CVD process. (Ti,Al)N coatings are a further development of TiN, whereby titanium is substi- tuted by aluminium by 20–60 at.-%. Depending on the composition, these layers range from brown (lower Al-content) to black-violet (higher Al-content) [VDI 3824]. Due to their high level of oxidation resistance and hot hardness, the preferred areas of application are dry machining, hard machining and HSC machining. The excellent wear resistance of (Ti,Al)N coatings is explained by the fact that, as opposed to stable compositephases, metastable layers decompose into stable bound- ary phases or form stable oxides in an oxidizing atmosphere as long as the energy required to convert into an equilibrium condition is added (e.g. as heat), as it is the case in dry machining or high-speed machining. In this context, the high oxi- dation resistance of (Ti,Al)N is derived from the fact that a thin aluminium oxide layer is formed on the coating surface which is constantly renewed during the cut- ting process, thus decelerating the progress of wear. With increasing Al-content, the oxidation resistance of the (Ti,Al)N coating is increased. Despite its much further improved oxidation resistance compared to TiN and Ti(C,N) coatings, this coat- ing also fails beyond approx. 800◦C. TiAlN coatings are deposited as monolayer, multilayer or gradient layers [Lemm03, Leye04, VDI 3824]. (Ti,Al)N is one of the most commonly used high-performance coating systems. Important measures being taken to further augment the cutting edge durability of (Ti,Al)N coatings include the development of nanolayers and increasing the con- tent of aluminium. The primary goal of these developments is to improve their hot 4.4 Coatings 155 hardness, wear resistance and oxidation resistance. In order to differentiate them from conventional (Ti,Al)N coatings, those with over 50% aluminium content are designated as (Al,Ti)N coatings. 4.4.2.5 Al-Cr-N Coatings Besides increasing the aluminium content another approach to further improving the oxidation resistance and high-temperature properties of (Ti,Al)N coating systems is adding small amounts of oxide formers such as Cr, Y or Si. One example for this direction in coating development is the Al-Cr-N coating system. In comparison to the conventional (Ti,Al)N coating, the (Al,Cr)N coating system has proved to have a higher resistance to abrasive wear as well as higher hot hardness and oxidation resistance [Gey04]. Its areas of application include the dry, HSC and hard machining of steel and non-ferrous metals by turning, drilling and milling [Gey04, Denk04]. 4.4.2.6 Aluminium Oxide Coatings (Al2O3) The exceptional resistance of Al2O3 against both abrasion and diffusion wear and its simultaneous insensitivity to oxidative wear, known from its use in cutting ceramics, has made Al2O3 an obvious candidate as a hard material for coating [Sche88]. Because it is very brittle, Al2O3 is generally not used in monolayer form, but only in combination with other hard materials in multilayer coatings. The electri- cally nonconductive Al2O3 layers could thusfar not be fabricated with the PVD, but only with the CVD process for technical reasons. The deposition of the thermody- namically stable high-temperature modification of aluminium oxide – α-Al2O3 – by means of CVD process has been established industrially for over two decades. Due to its excellent wear protection and high performance potential, attempts are being made to produce Al2O3 layers with the PVD process as well. A first step in this direction was the deposition of amorphous aluminium oxide (α-Al2O3) with the help of RF sputtering technology. Because of the low coating rates and consequently long process durations, this technique is proven to be uneconomical for coating cut- ting tools. With the help of the pulsed magnetron sputtering process, it has become possible to coat cutting tools with crystalline γ-Al2O3 layers at substrate temper- atures of 500–600◦C. γ-Al2O3 can be applied either as a monolayer or multilayer coating in combination with carbidic or nitridic intermediate layers [Hauz05]. 4.4.2.7 Amorphous Carbon Coatings The concept “amorphous carbon coatings” includes a number of coatings and coating systems. They are often referred to as “diamond-like carbon” or “DLC” coatings. These are carbon-based, highly cross-linked amorphous layers with dif- ferent amounts of sp2 (graphite bond) and sp3 bonds (diamond bonds) as well as various amounts of embedded hydrogen. In the case of Me-C:H layers, finely distributed metal carbides are also embedded. DLC coatings are manufactured by means of plasma-activated PVD and CVD techniques and deposited at coating temperatures ranging from room temperature to about 300◦C. Their typical layer 156 4 Cutting Tool Materials and Tools MeC:H a-C:H a-C Diamond PVD CVD PVDProduction process 800 to 1800 1500 to 3500 3000 to 7000 Coating thickness in µm 1 to 10 1 to 5 1 to 3 Microhardness in HV 0,05 1) 0.1 to 1.5 1 to 3 2 to 6Internal stresses in GPa 350 400 450Graphitisation temperaturein °C 2) + +++ ++++ Resistance to abrasion + +++ +++ Protection of bais material against corrosion 3) 10000 Resistance to wear due to adhesion (against steel) CVD 3 to 10 – > 600 ++++ +++ 1) For the microhardness, mean values are indicated. They are obtained from reported measured values resulting from different compositions, coating thicknesses and internal stresses. 2) The graphitising temperature is the temperature at which amorphous carbon begins to convert from a three-dimensional lattice into graphite, considerably affecting the characteristics of the coating. 3) As the aforementioned hard coatings themselves do not essentially corrode (except for MeC), they protect the basis material from corrosion. (Leaks in hard coatings may lead to the development of local galvanic elements and to pitting corrosion.) +++ +++ +++ (+++) with good cooling Fig. 4.45 Quanties Characteristing the coating and the coating performance, acc. to VDI 3824/1 thicknesses are 1–5 μm. Figure 4.45 shows some characteristic values for the layer properties of the most important carbon-based hard material layers producible with PVD and CVD available today [VDI 3824, VDI 2840]. In order to improve their adhesive strength, carbon layers are as a rule deposited on a hard material layer (e.g. CrN) as a top layer. Graded intermediate layers made of CrCN have proved favourable for this, in which case hardness and the Young’s modulus can be adjusted to the mechanical properties of the carbon top layer by successive exchange of nitrogen and carbon. This procedure makes it possible to obtain a largely continuous transition from the hard material layer to the carbon layer in order to optimize the bond between both coating systems [Leye04]. Amorphous carbon layers are characterized by extremely low friction coeffi- cients in the case of solid body friction, high wear resistance and low tendencies to adhesion. In cutting technology, these coatings are used above all on tools for dry machining NE metals (e.g. aluminium or magnesium) and in fine machin- ing with great success. Further areas of application are in machining graphite and fibre-reinforced plastics. 4.4 Coatings 157 The property profile of amorphous carbon layers can be purposefully influenced by process control and by integrating additional chemical elements. This poten- tial has led to a number of diverse types of carbon coatings in the last several years. In the following, the essential characteristics and properties of some selected amorphous carbon layers will be described in close detail. The classification, designation and characterization of the coatings are derived from VDI guideline 2840. According to VDI guideline 2840, amorphous carbon coatings can be subdivided into two groups, hydrogen-free and hydrogenous coatings. Since all carbon layers contain a certain amount of hydrogen even without adding hydrogen gas (e.g. from residual gasses), a limit of about 3 at.-% hydrogen is seen as the transition from hydrogen-free to hydrogenous carbon coatings. With increasing amounts of hydro- gen, the amount of interconnection between the carbon atoms decreases, leading to softer layers [VDI 3824, VDI 2840]. As wear-protection coatings on cutting tools, hydrogen-free carbon layers are used above all in the form of theamorphous carbon layer a-C and the tertraedic amorphous carbon layer ta-C. The atoms are arranged randomly in amorphous solid bodies. The only bonds are those between a few isolated atoms. If the sp2 bond is predominant in the amorphous carbon layer, it is softer, while it is harder if the amount of sp3 is higher. Depending on the deposition energy, the carbon atoms in the layer are predominantly arranged in one of the two hybrid states. At low deposition energies, the amount of sp2 bonds is higher, making the layers softer. These have the abbreviation “a-C”. With high deposition energies, sp3 hybridizations with a tetraedic arrangement predominate. The layers exhibit a high hardness level, and the compressive residual stresses are increased. Tetraedic amorphous carbon coatings have the designation “ta-C” [VDI 3824, VDI 2840]. Of all amorphous carbon coatings containing hydrogen, it is above all the non- modified layers that besides carbon contain only hydrogen, designated with “a-C:H” as well as modified carbon layers that are of any importance. The latter contain further elements in addition to hydrogen and are classified in accordance with VDI 2840 into the group of carbon layers containing metal and the group of hydrogenous amorphous carbon layers modified with non-metals [VDI 3824, VDI 2840]. The a-C:H coating system represent the origin of coating with amorphous hydro- carbon layers. In addition to carbon, it contains 10–30% hydrogen. The latter is derived from hydrocarbon gases like acetylene, which are employed in the fabrication process. If, during vacuum deposition, metals are additionally integrated, layers con- taining metal are produced. As opposed to a-C:H layers, these are electrically conductive and can be manufactured with a technically simpler and cost-efficient DC method. Of all amorphous carbon layers, these therefore have the broadest and deepest range of application. Amorphous carbon layers containing metal are also generally known as “a-C:Me” or “a-C:H:Me” (the abbreviation Me-C:H is also common), where “Me” stands for “metal”. Instead of the abbreviation “Me”, the integrated metals can also be named specifically, e.g. tungsten (a-C:W, a-C:H:W) oder titanium (a-C:Ti, a-C:H:Ti). The added metals form finely distributed carbides 158 4 Cutting Tool Materials and Tools with the carbon in the matrix. By integrating metal carbides, layer adhesion can be improved and the tribological properties of the coating can be affected [VDI 3824, VDI 2840]. Hydrogenous amorphous carbon layers modified with non-metals contain non- metallic elements such as silicon (Si), oxygen (O), nitrogen (N), fluorine (F) or boron (B), which partially also form carbides. By incorporating different non- metals, further improvements become possible. Silicon for example helps to increase temperature resistance. Moreover, different elements can be built into the layer at the same time. In this way, special layer properties like surface energy (adhesion tendency, wettability) can be altered. 4.4.2.8 Self-Lubricating Coatings Self-lubricating coatings include coating systems which include graphite or molyb- denum disulfide (MoS2). On cutting tools, graphite and MoS2 coatings are applied as top layers on a supporting hard material layer, where they act as a solid lubricant. Graphite is deposited in combination with WC as a WC/C multilayer coating system consisting of several layers of WC and graphite. Graphite and MoS2 have similar crystal structures. It is characteristic of graphite that its C atoms are arranged in a plane resulting in a very high level of internal bond strength due to the small inter-atomic distance. There is a relatively large distance between the atom layers however, so the layers of atoms can be easily shifted against each other under the influence of external forces. MoS2 also has a lamellar structure. There is a very strong chemical bond between the Mo and S atoms forming each lamella. The bond between two neighbouring lamellae is made between the sulphur atoms. Due to the intermolecular van der Waals bonds between the sulphur atoms of two lamellae, these can be shifted towards one another very easily. These slip planes are responsible for the soft, lubricating effect of graphite and molybdenum sulphide. Both coating systems are used primarily for machining materials that tend to adhere strongly with the tool, for example in the case of dry machining aluminium wrought alloys. In the case of drilling, these layers decrease the friction between the chip and the tool because of their “lubricating” effect and thus help to improve chip removal. In the case of tapping, in which case the machining results are determined above all by crushing, friction and adhesion processes, these coating systems can bring about significant improvements in performance even without hard material intermediate layers. Because of their properties, both coating systems are gradually worn out during the cutting process (loss lubrication). Even if the layer appears optically to be worn, its effect is still partially demonstrable. This is explained by the fact that the coating material still exists in microscopically small recesses on the tool surface where it can still be effective. After a complete loss of the soft top layer, the further wear proper- ties of the tools is then determined by the properties of the supporting hard material system. 4.4 Coatings 159 4.4.2.9 Diamond Coatings (Crystalline Carbon Coatings) Coating tools with polycrystalline diamond has been available only since 1990 and is as such the most recent technique in diamond tool production. Diamond coat- ings are applied to tools made of cemented carbide or ceramics in a low-pressure diamond synthesis (a CVD process). The diamond layer consists of pure diamonds and does not have a binder phase. Industrial deposition temperatures are around 600–1000◦C. This coating technology makes it possible to manufacture even tools with complex geometries, such as curved surfaces, economically out of diamond [Leye95]. Application examples for this are drilling tools, end milling cutters and indexable inserts with chip form geometries. These tools are used in the machining of plastics, cemented carbide and ceramic green bodies, non-ferrous metals as well as in the machining of abrasive materials. Diamond-coated tools can not be used to machine steel and other ferrous materials since the diamond coating is easily worn due to the solubility of carbon in iron. We differentiate between thin diamond layers (sd = 1–40 μm) and thick diamond layers (sd = 0.3–2 mm). Thin diamond layers are used to coat components (tools, for example) directly. On the other hand, thick diamond layers are generally deposited on an auxiliary substrate and then detached from it again. Diamond plates produced in such manner are then used as free-standing diamond (e.g. as radiation windows) or mounted on supports, usually by means of vacuum soldering in order to produce tools or other components. Since this can no longer be referred to explicitly as a layer, we often no longer refer to it as a CVD diamond layer but as a CVD diamond [VDI 2840]. Several processes have been established for fabricating diamond coatings. The most important include the hot filament process (HF-CVD), the microwave process and the plasma jet process (DC arcjet). What all of these processes have in com- mon is the decomposition of carbonic gases (e.g. methane, acetylene or carbon monoxide) followed by a deposition of carbon on the substrate surface. The forma- tion of unwanted graphite must be avoided in the process. Atomic hydrogen plays a key role in the germ formation and growth of the diamond layers. In the case of the hot filament method, the best-known process used for depositing CVD thin diamond layers, the atomic hydrogen required for the process is produced by elec- tricallyheated filaments made of refractory metals (Ta, W or Re). Gas temperatures of over 2500◦C are necessary to initiate the required chemical reactions [Lemm04, VDI 2840]. The rim zone is of particular importance when coating cemented carbides. Cobalt, which forms the binder phase of the cemented carbide, reduces the germ formation of diamond on the substrate surface, accelerates graphite formation, and affects crystal growth and layer adhesion. Cemented carbide substrates must there- fore be subjected to pretreatment prior to coating, in which case we differentiate between physical and chemical pretreatment and the introduction of an intermedi- ate layer. The common process presently is a multi-stage pretreatment consisting of irradiation, chemical etching, purifying and seeding. The substrate is first purified and homogenized with microbeam treatment. In the subsequent chemical etching 160 4 Cutting Tool Materials and Tools process, the cobalt binder phase is removed from the rim zone of the cemented car- bide substrate. The depth to which the binder phase is removed depends on the back diffusion of cobalt during the coating process. Due to the high substrate temperature of 900◦C and long processing times, cobalt diffuses through the etched rim zone to the substrate surface during the diamond coating process. If the etching depth is too small, the cobalt that has diffused to the surface reacts with the diamond layer and leads to the separation of diamonds on the boundary surface. This lowers the adhesive strength of the diamond coating. If the etching depth is too large, the car- bide bonds in the binder phase are weakened, also lowering layer adhesion. The rough surface caused by etching serves mechanically to clamp the diamond layer to the cemented carbide substrate. Due to the extreme differences between the coating and substrate material (Young’s modulus and hardness) this mechanical clamping is of special importance with respect to the adhesive strength of the diamond layer. After etching, the substrates are again purified and seeded. In order that the diamond layer will develop, there must be diamond germs on the substrate surface that serve as starting crystals and from which the layer grows. Seeding can be performed, for example, by applying small diamond crystals with a diamond suspension [Gram04, VDI 2840, Lemm04]. Standard diamond layers have a microcrystalline structure (Fig. 4.46). The crystallites grow from the germs with varying speed depending on their crystal ori- entation. Slowly growing crystallites are covered by the faster-growing ones. With increasing layer thickness, the crystallites forming the surface become larger and larger, resulting in the typical appearance of a microcrystalline CVD diamond layer with sharp-edged crystal surfaces [VDI 2840]. If growth conditions are set such that new germs are constantly formed and large- scale growth of individual crystallites becomes impossible, crystallite size remains in the range of nanometres within the entire layer (Figs. 4.46 and 4.47).This is how “nanocrystalline” CVD layers are formed, which are much smoother compared to crystalline layers [VDI 2840]. Both layer types can also be combined in multilayer structures, uniting the pos- itive attributes of microcrystalline and nanocrystalline diamond layers [Uhlm05] (Figs. 4.46 and 4.47). This increases the fracture toughness of the entire system and contains the development of cracks, such that they can no longer easily reach the Microcrystalline (standard) Nanocrystalline (smooth) Multilayer (smooth) Microcrystallin Nanocrystalline Fig. 4.46 Growth model of diamond coatings, acc. to VDI 2840 and LEMMER [Lemm04] 4.5 Ceramic Cutting Tool Materials 161 Microcrystalline (standard) Nanocrystalline (smooth) Multilayer (smooth) Fig. 4.47 SEM photographs of CVD diamond coatings on a cemented carbide substrate [VDI 2840, Lemm04] interface between the first diamond layer and the substrate, potentially causing the entire surface to chip [Lemm04]. 4.4.3 Substrate Pretreatment Both CVD and particularly PVD coating processes place high demands on the sur- face conditions of the components that are to be coated. Even the smallest impurities on the surface of the substrate – be it residual cutting fluid or grease, water deposits, grinding and polishing agents, hardening salt residues or oxide deposits – can degas during the coating process, negatively influence that process and lead to coating adhesion problems. The pretreatment of the substrate therefore has a key role in creating high and reproducible coating quality [Lugs03, VDI3824]. In substrate pretreatment a distinction is drawn between mechanical pretreatment (grinding, deburring, microbeaming and polishing) and physicochemical pretreat- ment (coating-removal, ultrasound-supported purification). In order to optimize layer adhesion, the parts are subjected to a multi-staged ultrasound purification pro- cess before charging. In the coating plant, the parts are then first heated in a vacuum, whereby further impurities can evaporate. Then the tools are etched by means of argon ion bombardment in order to produce a purely metallic surface. Coating fol- lows directly thereafter. If the substrates still need to be stored temporarily before charging, this takes place in a drying closet in order to protect the substrate sur- faces from water deposits (from air moisture), rust film formation and skin contact [Lugs03, VDI3824, Gey03]. 4.5 Ceramic Cutting Tool Materials Ceramic materials include all non-metallic, inorganic solid materials. Essentially these are chemical compounds of metals with non-metallic elements of group III A to group VII A of the periodic system of elements. A distinction is made between oxidic and non-oxidic ceramics. The largest group of ceramics are the oxides. Non-oxidic ceramics are carbides, borides, nitrides and silicons. Some authors dif- ferentiate again between metallic hard materials (compounds between C, B, N or 162 4 Cutting Tool Materials and Tools S and Ti, Zr, Nb, Ta, W among others) and non-metallic hard materials such as diamond, SiC, Si3N4, B4C and BN. Characteristic properties of ceramic materials are compressive strength, high chemical resistance and high melting temperatures, which can be derived from the strong covalent and ionic bonds of the atoms [Salm83a, Horn06]. The following will describe more closely those ceramic materials that are used as cutting tool materials in cutting technology. Following the usage common in practice, we will differentiate between cutting ceramics (oxidic and non-oxidic ceramics) and superhard non-metallic cutting tool materials (diamond and boron nitride). 4.5.1 Cutting Ceramics Ceramics have applications in many areas of machining with geometrically defined cutting part geometries. Mentionable among these are the high-speed machining of cast iron materials, hard machining or nickel-based alloy machining. The use of ceramics in the mass production of brake disks, flywheels and like workpieces has become a matter of course. In the field of automotive technology, silicon nitride ceramics have been able to capture an important market share in the high-speed cutting of cast iron workpieces [Schn99]. Hard machining is a primary applica- tion area of mixed ceramics. “Whisker-strengthened” ceramics are often used in the area of engine construction for machining engine components made of nickel-based alloys. Whiskers are needle-shaped monocrystals with a small degree of misorien- tation in the lattice. Correspondingly, they have high mechanical strength (Rm up to 7000 N/mm2). Their length is about 20–30 μm, their diameter between 0.1 and 1 μm. The increased interest in ceramics in production is based not only on the excel- lent wear properties of ceramic cutting tool materials but most importantly on their toughnessproperties, which have been clearly increased in recent times. The brit- tle fracture attributes characteristic of ceramic materials, the wide variation of their strength properties and the resulting stochastically appearing tool fractures are as before the main causes limiting the use of these cutting tool materials in machining technology (in contrast to cemented carbides for example). New developments and improvements in ceramics have been concentrated there- fore on further augmentation of the toughness and dependability of these cutting tool materials in production. In the case of pure oxidic ceramics, research is focused on improving these prop- erties by increasing their zirconium oxide content, improving the distribution of these phases and by making the microstructure more consistent. In the case of mixed ceramics, finer-grain hard materials are used and titanium carbide is being par- tially substituted with titanium carbon nitride. Further measures include fibre and/or whisker reinforcement, reduction of the amount of glass phase at the grain bound- aries of non-oxidic ceramics as well as the formation of special microstructures [Kola86, Clau77, Schn99]. 4.5 Ceramic Cutting Tool Materials 163 Cutting ceramics Oxidic ceramics Non-oxidic ceramics Oxide ceramics Mixed ceramics Whisker- reinforced ceramics Silicon nitride ceramics Al2O3 Al2O3+ ZrO2 Al2O3 + TiC Al2O3 + ZrO2 + TiC Al2O3 + SiC-whisker β-Si3N4 β-Si3N4 + hard materials α-Sialon (α + β)-Sialon Fig. 4.48 Classification of cutting ceramics Ceramic cutting tool materials can be subdivided into oxidic and non-oxidic cutting ceramics (Fig. 4.48). Oxidic cutting ceramics include all cutting tool materials based on aluminium oxide (Al2O3). A distinction is made between oxide ceramics that only contain oxides (e.g. ZrO2) in addition to Al2O3, mixed ceramics, which in addition to Al2O3 also contains metallic hard materials (TiC/TiCN) and whisker-reinforced ceramics, in which SiC whiskers are integrated in the Al2O3 matrix. Figure 4.49 shows images of fractures of different cutting ceramics taken with a scanning electron microscope. It is typical of oxidic cutting ceramics that they do not have a visible binder phase such as cemented carbides (cobalt) have. One can recognize the globular grains of oxide ceramics, the extremely fine grains of mixed and whisker-reinforced ceramics as well as the SiC whiskers, which are only a few μm large in the detail magnification. Characteristic of non-oxidic ceramics based on Si3N4 is the needle-shaped formation of the crystals. In order to improve wear resistance, Si3N4 cutting ceramics can be coated with Al2O3 or with multilayer coating systems made of Al2O3 and TiN [Schn99]. Figure 4.50 shows some physical properties of commercially available ceramic cutting tool materials. Depending on their chemical composition, these ceramic types can have considerably diverse properties. 4.5.1.1 Cutting Ceramics Based on Al2O3 Oxide Ceramics White oxide ceramics are the traditional type of cutting ceramics. Ceramics based Al2O3 on were already introduced as cutting tool materials at the end of the 1930s [Kola86]. Inserts were made for a long time out of pure aluminium oxide. Due 164 4 Cutting Tool Materials and Tools Oxide ceramic (Al2O3 + ZrO2) Mixed ceramic (Al2O3 + TiC ) Silicon nitride ceramic (Si3N4 + MgO ) Coated silicon nitride ceramic (Si3N4 + Al2O3) Detail magnification (Al2O3 + SiC-Whisker ) Whisker-reinforced ceramic (Al2O3 + SiC-Whisker ) Fig. 4.49 Fractures of cutting ceramics Properties Oxide ceramic Al2O3 Whisker-reinf. Oxide ceramic Al2O3 Bending strength Compressive strength Young‘s modulus Vicker hardness ρDensity − - bB σdB +3.5% ZrO2 +15% ZrO2 +15%ZrO2 +20%SiC- Whisker 4.0 1730 700 5000 380 4.2 1750 800 4700 410 3.7 1900 900 - 390E Mixed ceramic Al2O3 Silicon nitride ceramic Si3N4 +10%ZrO2 +5%TiC +30% Ti(C,N) +10%Y2O3 4.1 1730 650 4800 390 4.3 1930 620 4800 400 3.3 1750 800 - g/cm3 N/mm2 N/mm2 103⋅N/mm2 α Fracture toughness Thermal conductivity Thermal expansion Melting point λ T 4.5 16.4 8 - 5.1 15 8 - 8.0 32 - - 4.2 14.7 8 - 4.5 20 8 - 7.0 3.4 - N⋅m1/2/mm2 W/m⋅K 10–6⋅K–1 °C KIC σ Fig. 4.50 Physical and mechanical properties of different cutting ceramics and their main components 4.5 Ceramic Cutting Tool Materials 165 to their brittleness and vulnerability to fracture, such inserts are no longer used in machining. The pure ceramics used today are dispersion material containing Al2O3 as well as about 3–15% of finely distributed zirconium dioxide to improve toughness. The toughness-enhancing effect of dispersed ZrO2 particles in an Al2O3 matrix is based on the phase transformation of zirconium dioxide. ZrO2, which exists in the form of a tetragonal lattice modification in the sintering temperature range (1400–1600◦C), transforms during cooling into its monoclinic low-temperature modification. The temperatures in which this transformation takes place depend on the size of the particles. The smaller the ZrO2 particles are, the lower the transforma- tion temperature. Since the transformation from the tetragonal to the monoclinical modification is associated with a volume expansion, various specific mechanisms of action can assert themselves depending on the size of the particles. The com- mon effect of all these mechanisms is that they ultimately absorb fracture energy. The speed of crack development is reduced by microcracking, crack branching, the stress-induced transformation of small ZrO2 particles as well as crack diversion. The result of this is that critical cracks only develop at a higher level of energy, which corresponds to an increase in fracture resistance and an improvement of ductility [Clau77, Clau84, Zieg86]. Mixed Ceramics Mixed ceramics (black ceramics) are dispersion materials based on Al2O3 that con- tain between 5 and 40% of non-oxidic components in the form of TiC or TiCN. The hard materials in the matrix form finely distributed phases, which limit the growth of aluminium oxide grains. Correspondingly, these ceramics have a very fine-grained structure, improved toughness properties and a high level of edge strength and wear resistance. Compared to pure ceramics, they are harder and have more favourable thermoshock properties due to their high level of thermal con- ductivity (Fig. 4.50). The toughness of these ceramics can be further improved by adding ZrO2. The development of mixed ceramics is progressing towards finer and finer- grained cutting tool materials with extremely homogeneous textural structures. As opposed to conventional cutting ceramics based on aluminium oxide and titanium carbon nitride with an average grain size of < 2 μm, the more advanced mixed ceramics have a submicron structure with grain sizes of < 1 μm. The finer-grained structure increases hardness and bending strength and consequentially the mechan- ical and thermal loadability, wear resistance and edge strength of ceramic inserts. Fine-grained mixed ceramics are used in hard-fine machining, e.g. for machin- ing hardened rolling bearing steels, for hard-fine turning case-hardened automotive components such as drive wheels, crown wheels, gearwheels or sliding sleeves with a Rockwell hardness of 54–62 HRC but also for planing and fine planing cast iron at very high speeds. In the case of hard turning, submicron mixed ceramics are competing with PCBN cutting tool materials in many areas of application as more economical alternatives due to their good cost-benefit ratio [Krel97, Schn99]. 166 4 CuttingTool Materials and Tools Whisker-Reinforced Cutting Ceramics Whisker-reinforced cutting ceramics are cutting tool materials based on Al2O3 with about 20–40% silicon carbide whiskers. The goal of whisker-reinforcement is to enhance the toughness properties of ceramic cutting tool materials. The increase in toughness gained by incorporating whiskers in oxidic ceramics is remarkable. Compared to mixed ceramics, whisker-reinforced types have up to 60% higher fracture toughness. The whiskers bring about a more consistent distribution of mechanical loads in the cutting tool material as well as a more rapid transport of heat from the thermally highly loaded cutting areas due to their improved heat con- ductivity. This results in improved fatigue limits and thermoshock resistance, so that whisker-reinforced cutting ceramics can also be used in wet cut processes. Fabrication of Oxidic Cutting Ceramics The starting materials of cutting ceramics, including pressing and sintering auxil- iaries, are metered according to an exact formula, homogenized in vibration mills and converted to a compressible powder with a high bulk material stability in a spray-dryer. Oxide ceramics, as well as mixed ceramics with small amounts of hard materials, are compressed at room temperature to inserts (cold pressing) and then sintered. The sintering temperature is about 1600◦C. Mixed ceramics with a high percent- age of hard material (> 10%) as well as whisker-reinforced ceramics have to be hot-pressed, i.e. pressing and sintering take place in one cycle. Due to the special equipment required for this (e.g. graphite moulds instead of cemented carbide ones), hot pressing is more cost-intensive than normal sintering. Furthermore, the number of manufacturable tool geometries is much more limited. Hot isostatic pressing can be used to subsequently compact sintered ceramic parts, thus reducing the poros- ity of the cutting tool material. One method variant is hot isostatic compacting of pre-sintered closed-pore mouldings in an installation. After sintering/hot pressing, the contact face, and in the case of precision inserts, the lateral surface and cutting edge chamfer are ground with diamond grinding discs [Kola86, Grew85]. Properties of Oxide Ceramic Cutting Tool Materials Because of their high hot hardness and chemical resistance, ceramic cutting tool materials based on Al2O3 are characterized by excellent wear properties. However, the highly favourable wear properties of oxide ceramic cutting tool materials is accompanied by their sensitivity to tensile, bending, impact and thermal shock stresses. As mentioned at the beginning of this chapter, current further develop- ment of oxide ceramic cutting tool materials has for this reason been concentrated on improving toughness and thermoshock properties without diminishing wear resistance. 4.5 Ceramic Cutting Tool Materials 167 The excellent wear resistance of oxidic cutting tool materials, particularly at high temperatures, is based among other things on their superior hardness and compres- sive strength compared to other cutting tool materials at high temperatures. For example, oxide ceramic cutting tool materials at 1000◦C are still harder than high speed steel at room temperature (Fig. 4.51). While the compressive strength of Al2O3 at room temperature roughly corre- sponds to that of cemented carbide, it is at 1100◦C still as great as that of steel at room temperature, while neither steel nor cemented carbide are resilient to pres- sure at 1100◦C. The high compressive strength of ceramics has been a primary reason for their being privileged as cutting tool materials. But because their band- ing fracture strength is relatively low, the use of oxide ceramics as the cutting tool material requires that the process kinematics be selected such that the cutting forces are effective as much as possible only in the form of compressive stresses [Kola86, Kola86a, Zieg86]. A further property which makes the use of ceramic cutting tool materials advan- tageous at high cutting speeds is Al2O3’s low level of creeping. In the case of cemented carbides, high temperature strength is limited by the property-determining cobalt phase at temperatures of 800–900◦C. At higher temperatures, creeping pro- cesses are introduced which are smaller by several orders of magnitude in the case of Al2O3. Diamond Boron nitride Mixed ceramic Al2O3 + TiC/TiCN Oxide ceramic Al2O3 Carbide HSSTool steel 0 5000 4000 3000 2000 1000 1250750500 1000250 H ar dn es s H V 10 Temperature T / K Fig. 4.51 Hot hardness of cutting tool materials (Source: CeramTec) 168 4 Cutting Tool Materials and Tools The high wear resistance of oxidic cutting tool materials can also be attributed to the good chemical resistance of Al2O3. Al2O3 is resistant to oxidation at the cutting temperature used in practice and has only a small amount of affinity to metallic materials. The most crucial disadvantage of ceramic cutting tool materials is their brittle- ness, i.e. lacking capacity to reduce stress peaks by means of plastic deformation. The cause of this is the low number of sliding systems in the crystal structures of ceramic materials. This results in high sensitivity to tensile stresses and low resistance to mechanical and thermal shock compared with metals. In the case of a sudden mechanical overload due to impulse-like stress, the cutting tool material is destroyed by brittle fracture. Because of insufficient ductility, cracks begin to form when the inner material cohesion is exceeded by external stress. If the crack reaches a critical size, unstable crack growth appears leading to fracture of the ceramic tool. The stress intensity factor KI is a parameter for judging the stress condition at the peak of a crack. Failure of the cutting tool material due to fracture occurs if the stress intensity factor reaches a critical value, crack toughness (fracture toughness) KIC. In comparison to other materials, the values of KIC are very low for ceramics (Fig. 4.50). Another important disadvantage of oxide ceramics are their relatively low resis- tance to temperature change. In the case of temperature changes of more than 200◦C, pure Al2O3 is destroyed. This can only be improved by alloying a component of superior resistance to temperature change. Due to their sensitivity to thermoshock, coolants should not be used in conjunc- tion with oxide ceramics when roughing and planing. Coolants should only be used to temper the workpiece, e.g. due to narrow workpiece tolerances. Low bending fracture strength and relatively high sensitivity to impact and temperature change stresses require a slanted entering and leaving cutting path, which is associated with delayed load of the cutting edge of the tool (Fig. 4.52). Due to their low edge strength, chamfered edges should stabilize the cutting edge. Areas of Application of Oxide Ceramic Cutting Tool Materials It must be stressed that, due to their extreme brittleness, a careful adjustment of cut- ting parameters to tool geometry is the prerequisite of a successful use of cutting ceramics. There is no room for error, since ceramics can be destroyed immediately in the form of fracture should the marginal conditions be unfavourable. Cutting ceramics are therefore almost exclusively used in mass production. This is justified by the reduction of processing times and the high cost of selecting and adjusting the cutting tool materials. The main area of application of oxide ceramic cutting tool materials is rough and finish turning of grey cast iron, case-hardened steels and heat-treated steels. However, pure oxide ceramics are being increasingly replaced by silicon nitride ceramics, especially in cast iron processing (Fig. 4.53). The increased popularity of dry machining however is opening up new areas ofapplication to oxide ceramics in the case of turning extrusion parts with a small machining allowance. 4.5 Ceramic Cutting Tool Materials 169 1. Chamfering 1. Chamfering and external turning 2. Face turning3. Face turning 2. Chamfering and internal turning 1. Clamping (external) Finished part 2. Clamping (internal) Fig. 4.52 Entering and exit tool path when turning with cutting ceramics (Source: Ford) Fine-grained mixed ceramics are used in hard-fine machining (e.g. for machining hardened rolling bearing steels) for fine turning case-hardened automotive com- ponents such as drive wheels, crown wheels, gearwheels or sliding sleeves with a Rockwell hardness of 54–62 HRC. They are also used for finish planing and fine planing cast iron at very high speeds. In the case of hard turning, submicron mixed ceramics are competing with PCBN cutting tool materials in many areas of application as more economical alternatives due to their good cost-benefit ratio [Krel97, Schn99]. Both types of cutting ceramics still however remain restricted with respect to the carbon content of the machined steels. For example, in the case of steels with a C content of under 0.35% adhesion occurs on the tool as well as chemical reactions which increase wear and generally make the process uneconomical. Whisker-reinforced oxide ceramics have been used with great success for turn- ing high temperature nickel-based alloys (Fig. 4.54). In contrast to otherwise used cutting tool materials (cemented carbide or HSS), it is possible to increase the cutting speed by a factor of 10 or more. In the case of rough and finish milling Inconel 718 with milling head face cutters, cutting speeds of 800–1000 m/min can be realized with cutting ceramics based on silicon nitride or whisker-reinforced aluminium oxide. As opposed to machining with cemented carbide tools, this rep- resents an increase in performance by factors of 25 or more [Momp93, Gers02, Krie02, Uhlm04]. 170 4 Cutting Tool Materials and Tools Al2O3-ceramic Si3N4-ceramic vc = 1000 m/min f = 0.5 mm ap = 3.0 mm vc = 600 m/min f = 0.35 mm ap = 3.0 mm 300 250 200 150 100 50 0 To ol lif e qu an tit y N non-chamfered chamfered non-chamfered chamfered Fig. 4.53 Influence of cutting ceramics and entering path on the tool life quantity in brake disc manufacturing (Source: CeramTec) Determinant tool life wear criteria Notch wear Flank wear VB VBVBN vc = 400 m/min f = 0.12 mm ap = 0.30 mm Inconel 718 Wet cut To ol li fe tr av el p at h L c / m 3000 Cemented carbide K10/20 Polycrystalline cubic boron nitride Cutting speed vc / (m/min) 600200100 300 1000 500 400 300 200 100 20 5030 40 Criteria of tool life: VB = 0.3 mm, VBN = 0.3 mm 400 2000 SiC-whisker reinforced cutting ceramics and SiAlON Fig. 4.54 Achievable tool life travel paths and applicable cutting speeds in finish turning Inconel 718 with uncoated cemented carbide, whisker-reinforced cutting ceramic, silicon nitride ceramic and PCBN 4.5 Ceramic Cutting Tool Materials 171 Chemical reactions and built-up edge formation when machining light metal alloys make Al2O3 cutting ceramics unsuitable for machining Al, Mg and Ti alloys. Cutting ceramics composed of thin ceramic tubules represent a new generation of ceramic cutting tool materials. In the case of these ceramics, first introduced at EMO 2005, the tool body is formed of small thin tubes consisting of a tough ceramic material and filled with a hard, wear-resistant ceramic material. The diameter and thickness of the tubes, as well as their orientation and filling, are variable. The tubes are arranged in a plane. The tool is formed with a large number of planes built on top of each other, where the tubes forming the individual planes can be parallel from plane to plane or can be arranged alternately at an angle of 45◦/90◦ to each other. In this way, the properties of the cutting tool material, such as toughness and wear resistance, can be modified and adjusted to the stresses of various machining tasks. Initial machining experiments in turning high-temperature nickel-based alloys as well as in machining hardened steel materials demonstrated the promising wear properties and performance of this new cutting ceramic [Haid05]. 4.5.1.2 Non-oxidic Cutting Ceramics Among the non-oxidic ceramics (carbides, nitrides, borides, silicides. . .), materi- als based on Si3N4 have been especially successful as cutting tool materials for machining purposes. Si3N4 cutting ceramics, in contrast to oxidic cutting ceram- ics, are characterized by increased toughness and improved thermoshock resistance (Fig. 4.50). Moreover, they have a higher hot hardness and high temperature strength. In machining processes involving grey cast iron, they make it possible to use the highest cutting values while maintaining the highest tool life spans and low failure rates. The high safety level of these cutting tool materials has been an especially important factor in the acceptance of Si3N4 cutting tool materials by manufacturers. The significantly higher fracture resistance compared to oxide and mixed ceram- ics is based on the needle-like shape of the hexagonal β-Si3N4 crystals as opposed to the globular Al2O3 grains. The non-directional growth of the needle-shaped crys- tals leads to a microstructure made up of mechanically interlinked components which provides the cutting tool materials with excellent strength properties. The low thermal expansion of Si3N4 ceramics compared with oxide and mixed ceramics is responsible among other things for its favourable thermoshock properties. However, in order to press silicon nitride ceramics completely, sintering auxiliaries (Y2O3, MgO, Al2O3) are required that form a glass phase and fill in the gaps between the crystals. This glass/binder phase has a negative influence on the high-temperature properties of silicon nitride ceramics. Besides sintering auxiliaries, Si3N4 cutting ceramics can also contain other addi- tives that affect their crystal structure or texture and thus their properties as well. Corresponding to their chemical composition and crystallographic structure, the silicon nitride ceramics available today can be subdivided into three groups: • I: β-Si3N4 + binder phase (Y2O3, MgO, Al2O3) • II a: α sialon (α–Si3N4 + Al2O3 + AlN) + binder phase (Y2O3) 172 4 Cutting Tool Materials and Tools • II b: (α + β) sialons (α Si3N4 + Al2O3 + AlN) + additive (e.g. ytterbium) + binder phase (Y2O3) • III: β silicon nitride + hard materials (e.g. TiN, ZrO2, SiC-whiskers) + binder phase The cutting tool materials from Groups I and II are fabricated by means of hot pressing, sintering, hot isostatic pressing or a combination of these methods. Most of the Si3N4 cutting tool materials available on the market today belong to Group I. The cutting tool materials from Group II are usually designated as sialons. Silicon nitride can receive up to 60% aluminium oxide in solid solution. Some nitrogen atoms are replaced in the process by oxygen atoms and silicon atoms by aluminium atoms. While the α sialon mixed crystals have a globular form, β sialon mixed crys- tals are stem-shaped. Including special additives makes it possible to stabilize the β sialons, thereby creating a cutting tool material the structure of which consists of both α and β mixed crystals. The amount of additives determines the amount of β sialons in the cutting tool material’s microstructure. In comparison to the cut- ting tool materials from Group I, sialons are harder, more chemically resistant and have an increased resistance to oxidation. The manufacturing method in this case is sintering, which can sometimes be followed by hot isostaticpressing. Group III can include Si3N4 cutting tool materials, the properties of which can be specifically altered by adding hard materials such as titanium nitride, titanium carbide, zirconium oxide or Sic whiskers. Areas of Application of Non-oxidic Cutting Ceramics The classic field of Si3N4 cutting tool materials is grey cast iron machining. In this case, usually the tougher silicon nitride ceramics of Group I are preferred, espe- cially in automated manufacture. Due to the high fracture toughness of these cutting tool materials, large feeds, high cutting speeds and thus large volume removal rates can be realized when machining cast iron materials in smooth and interrupted cut [Köni86, Köni87, Schn99]. For example, when turning automotive brake discs, using Si3N4 ceramics improves tool life quantity considerably compared with oxide ceramics (Fig. 4.53). Improved resistance to fracture makes it possible, as shown in Fig. 4.52, to omit workpiece chamfering as long as one forgoes maximal utilization of the cutting tool material. The main area of application of sialons is in turning nickel-based alloys under finishing or average roughing conditions (Fig. 4.54). They are therefore in direct competition with whisker-reinforced oxide ceramics. Like the latter, sialons can be used for machining nickel-based alloys at much higher cutting speeds than cemented carbide tools. They are also good for high-speed milling of nickel-based alloys with tools mounted with indexable inserts at cutting speeds of 800–1000 m/min. The wear resistance of silicon nitride ceramics is slightly lower than that of oxide ceramics. Silicon nitride cutting tool materials exhibit a strong affinity to iron and oxygen under machining conditions. They wear very quickly in the case of steel machining, so the use of these materials groups currently remains uneconomical. 4.5 Ceramic Cutting Tool Materials 173 Coating silicon nitride ceramics opens up further prospects for their use. The classic coating materials are TiN, TiC, TiCN and Al2O3, which are applied in dif- ferent combinations and layer thicknesses. A multilayer coating system consisting of aluminium oxide and titanium nitride remains the most popular. The service life of Si3N4 can be considerably increased by applying a wear and diffusion inhibiting coating, especially when machining cast iron with globular graphite (e.g. GJV40) [Schn99]. Coated silicon nitride ceramics are also suitable therefore for cases that had hitherto been reserved for cemented carbides. As opposed to cemented car- bides, they allow for higher cutting speeds and thus for shorter machining times and in many cases also for dry machining [Schn99]. 4.5.2 Superhard Non-metallic Cutting Tool Materials In machining technology, cutting tool materials based on diamond and boron nitride are designated as superhard and non-metallic. According to the definition, both are ceramic cutting tool materials, where diamond is assigned to monatomic, boron nitride to non-oxidic ceramics. 4.5.2.1 Diamond as a Cutting Tool Material Elemental carbon appears in the two crystal modifications graphite and diamond. Diamond solidifies in the cubic crystalline lattice system, in which the C atoms are bonded covalently and tetraedically. The extremely high bond and lattice energy is the reason why diamond is the hardest of all known materials. Diamond is equally superior to all other known hard materials with respect to thermal conductivity. Figure 4.55 shows the hardness and thermal conductivity of some materials that tend to be used as abrasives as well as different carbides, which are components of cemented carbide tools and permits a comparison with diamond. Classification of Diamond Cutting Tool Materials To classify diamond cutting tool materials, we differentiate between natural and syn- thetic diamond, which both can appear in monocrystalline or polycrystalline form. According to DIN ISO 513, the identification letters of polycrystalline diamond are DP while those of monocrystalline diamond are DM (Fig. 4.3). Following the usage common in practice and in the literature, we will also refer to polycrystalline diamond cutting tool materials with the abbreviation PCD. (a) Natural Diamond Natural diamond is only of importance for the purposes of cutting with geomet- rically defined cutting edges in its monocrystalline form. Although diamond also exists in nature in polycrystalline form (ballas, carbonado), these types of diamond are of lesser interest since the synthetic fabrication of polycrystalline diamond is more advantageous both economically as well as technologically. One significant property of monocrystalline diamond is the anisotropy (directional dependence) of mechanical properties such as hardness, strength 174 4 Cutting Tool Materials and Tools Hardness HV Thermal conductivityλRT / (W/m⋅K) Diamond cBN B4C SiC TiC 10001002500500010000 10000 α -Al2O3 Fig. 4.55 Hardness and thermal conductivity of diamonds in comparison to other hard materials or elastic modulus. While this directional dependence is compensated in the case of polycrystalline materials by the completely random distribution of the individual crystals, anisotropy remains in monocrystalline materials due to the aligned orientation of the crystal lattice. This also the cause of the cleavability of monocrystalline diamonds in four select cleavage directions. From this we can see that the position of the lattice directions must be known both for grinding monocrystalline diamond as well as for using it as a tool. While grinding must always take place in the direction of lowest hardness, monocrystalline diamond tools have to be oriented in the tool holder such that the cutting force points in the direction of a hardness maximum. (b) Synthetic Diamond The fabrication of synthetic diamonds takes place using a catalyst solution in a pressure and temperature range in which diamond forms a stable phase. By a careful selection of pressure and temperature, the crystal growth rate and dimen- sions of the crystals can be controlled within a range of a few micrometers to several millimetres and specific physical properties like purity or porosity can be influenced. Diamond synthesis results in monocrystalline diamond particles that are utilized in machining with geometrically defined cutting edges as synthetic monocrystalline diamond tool bodies or for further processing into polycrys- talline cutting parts. Fabrication and Designs of Diamond Tool Bodies (a) Monocrystalline Diamond Tools Monocrystalline diamond tool bodies are manufactured with both natural diamond and synthetic monocrystals [Heus96]. The most common cutting edge shapes of 4.5 Ceramic Cutting Tool Materials 175 Tool with round cutting edgeTool with one cutting edge κr ≈ 45° κ'r ≈ 2° κ'r ≈ 2° κr ≈ 18° Tool with facette shape 160° Fig. 4.56 Shapes of monocrystalline diamond tools monocrystalline diamond tools are shown in Fig. 4.56 [Wein69]. The tool with one cutting edge is used both for drilling as well as for external turning, whereby in the latter case a corner radius is ground onto it in order to improve the surface profile. By selecting a very small minor cutting edge lead angle κ ′r < 2◦, the minor cutting edge can be designed as a broad-tool cutting edge which takes on the function of further polishing the surface. Tool variants with round cutting edges have the advantage of having a very large useful cutting edge length, but due to the curvature of the cutting edge they have unfavourable chip formation conditions and relatively high passive forces. In the case of tool bodies with facette shapes, three to five cutting edges are ground on, whereby two neighbouring edges form an angle of about 160◦. The tool is adjusted so that the minor cutting edge has a very small lead angle as acts