Koretsky - Apendice A y B

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639
APPENDIX A
Physical Property Data
 ► A.1 CRITICAL CONSTANTS, ACENTRIC FACTORS, AND ANTOINE COEFFICIENTS:1
 The Antoine equation is of the form: ln 1Psat 3bar 4 2 5 A 2 B
T 3K 4 1 C
TABLE A.1.1 Organic compounds
Formula Name MW3g/mol4 Tc 3K 4 Pc 3bar 4 v A B C Tmin Tmix
CH2O Formaldehyde 30.026 408 65.86 0.253 9.8573 2204.13 230.15 185 271
CH4 Methane 16.042 190.6 46.00 0.008 8.6041 897.84 27.16 93 120
CH4O Methanol 32.042 512.6 80.96 0.559 11.9673 3626.55 234.29 257 364
C2H4 Acetylene 26.038 308.3 61.40 0.184 9.7279 1637.14 219.77 194 202
C2H3N Acetonitrile 41.052 548 48.33 0.321 9.6672 2945.47 249.15 260 390
C2H4 Ethylene 28.053 282.4 50.36 0.085 8.9166 1347.01 218.15 120 182
C2H4O Acetaldehyde 44.053 461 55.73 0.303 9.6279 2465.15 237.15 210 320
C2H4O Ethylene oxide 44.053 469 71.94 0.200 10.1198 2567.61 229.01 300 310
C2H4O2 Acetic acid 60.052 594.4 57.86 0.454 10.1878 3405.57 256.34 290 430
C2H6 Ethane 30.069 305.4 48.74 0.099 9.0435 1511.42 217.16 130 199
C2H6O Ethanol 46.068 516.2 63.83 0.635 12.2917 3803.98 241.68 270 369
C3H6 Propylene 42.080 365.0 46.20 0.148 9.0825 1807.53 226.15 160 240
C3H6O Acetone 58.079 508.1 47.01 0.309 10.0311 2940.46 235.93 241 350
C3H8 Propane 44.096 370.0 42.44 0.152 9.1058 1872.46 225.16 164 249
C3H8O 1-Propanol 60.095 536.7 51.68 0.624 10.9237 3166.38 280.15 285 400
C4H6 1,3-Butadiene 54.090 425 43.27 0.195 9.1525 2142.66 234.30 215 290
C4H8 cis-2-Butene 56.106 435.6 42.05 0.202 9.1969 2210.71 236.15 200 305
C4H8 trans-2-Butene 56.106 428.6 41.04 0.214 9.1975 2212.32 233.15 200 300
C4H8O2 Ethyl acetate 88.105 523.2 38.30 0.363 9.5314 2790.50 257.15 260 385
C4H10 n-Butane 58.122 425.2 37.90 0.193 9.0580 2154.90 234.42 195 290
C4H10 Isobutane 58.122 408.1 36.48 0.176 8.9179 2032.76 233.15 187 280
C4H10O n-Butanol 74.122 562.9 44.18 0.590 10.5958 3137.02 294.43 288 404
C5H10 1-Pentene 70.133 464.7 40.53 0.245 9.1444 2405.96 239.63 220 325
C5H12 n-Pentane 72.149 469.6 33.74 0.251 9.2131 2477.07 239.94 220 330
C6H6 Benzene 78.112 562.1 48.94 0.212 9.2806 2788.51 252.36 280 377
C6H6O Phenol 94.111 694.2 61.30 0.440 9.8077 3490.89 298.59 345 481
C6H7N Aniline 93.127 699 53.09 0.382 10.0546 3857.52 273.15 340 500
C6H12 Cyclohexane 84.159 553.4 40.73 0.213 9.1325 2766.63 250.50 280 380
C6H12 1-Hexene 84.159 504.0 31.71 0.285 9.1887 2654.81 247.30 240 360
C6H14 n-Hexane 86.175 507.4 29.69 0.296 9.2164 2697.55 248.78 245 370
(Continued)
1 For a more complete set of compounds, consult ThermoSolver, the text software.
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640 ► Appendix A Physical Property Data
TABLE A.1.1 Continued
Formula Name MW3g/mol4 Tc 3K 4 Pc 3bar 4 v A B C Tmin Tmax
C7H8 Toluene 92.138 591.7 41.14 0.257 9.3935 3096.52 253.67 280 410
C7H14 1-Heptene 98.186 537.2 28.37 0.358 9.2692 2895.51 253.97 265 400
C7H16 n-Heptane 100.202 540.2 27.36 0.351 9.2535 2911.32 256.51 270 400
C8H8 Styrene 104.149 647.0 39.92 0.257 9.3991 3328.57 263.72 305 460
C8H10 o-Xylene 106.165 630.2 37.29 0.314 9.4954 3395.57 259.46 305 445
C8H10 m-Xylene 106.165 617.0 35.46 0.331 9.5188 3366.99 258.04 300 440
C8H10 p-Xylene 106.165 616.2 35.16 0.324 9.4761 3346.65 257.84 300 440
C8H10 Ethylbenzene 106.165 617.1 36.07 0.301 9.3993 3279.47 259.95 300 450
C8H16 1-Octene 112.213 566.6 26.24 0.386 9.3428 3116.52 260.39 288 420
C8H18 n-Octane 114.229 568.8 24.82 0.394 9.3224 3120.29 263.63 292 425
C9H20 n-Nonane 128.255 594.6 23.10 0.444 9.3469 3291.45 271.33 312 452
C10H8 Naphthalene 128.171 748.4 40.53 0.302 9.5224 3992.01 271.29 360 545
C10H22 n-Decane 142.282 617.6 21.08 0.490 9.3912 3456.80 278.67 330 476
TABLE A.1.2 Inorganic Compounds
Formula Name MW3g/mol4 Tc 3K 4 Pc 3bar 4 v A B C Tmin Tmax
Ar Argon 39.948 150.8 48.74 20.004 8.6128 700.51 25.84 81 94
BCl3 Boron trichloride 117.169 451.95 38.71 0.148 9.0985 2242.71 238.99 182 286
B2H6 Diborane 27.670 289.80 40.50 0.138 8.7074 1377.84 222.18 118 181
Br2 Bromine 159.808 584 103.35 0.132 9.2239 2582.32 251.56 259 354
CCl3F Trichlorofl uoromethane 137.367 471.2 44.08 0.188 9.2314 2401.61 236.3 240 300
CF4 Carbon tetrafl uoride 88.004 227.6 37.39 0.191 9.4341 1244.55 213.06 93 148
C2F6 Hexafl uoroethane 138.012 292.8 30.42 0.255 9.1646 1559.11 224.51 180 195
CHCl3 Chloroform 119.377 536.4 54.72 0.216 9.3530 2696.79 246.16 260 370
CO Carbon monoxide 28.010 132.9 34.96 0.049 7.7484 530.22 213.15 63 108
CO2 Carbon dioxide 44.010 304.2 73.76 0.225 15.9696 3103.39 20.16 154 204
CS2 Carbon disulfi de 76.143 552 79.03 0.115 9.3642 2690.85 231.62 228 342
Cl2 Chlorine 70.905 417 77.01 0.073 9.3408 1978.32 227.01 172 264
F2 Fluorine 37.997 144.3 52.18 0.048 9.0498 714.10 26.00 59 91
H2 Hydrogen 2.016 33.2 12.97 20.22 7.0131 164.90 3.19 14 25
HBr Hydrogen bromide 80.912 363.2 85.52 0.063 7.8485 1242.53 247.86 184 221
HCN Hydrogen cyanide 27.025 456.8 53.90 0.407 9.8936 2585.80 237.15 234 330
HCl Hydrogen chloride 36.461 324.6 83.09 0.12 9.8838 1714.25 214.45 137 200
H2O Water 18.015 647.3 220.48 0.344 11.6834 3816.44 246.13 284 441
H2S Hydrogen sulfi de 34.082 373.2 89.37 0.100 9.4838 1768.69 226.06 190 230
NH3 Ammonia 17.031 405.6 112.77 0.250 10.3279 2132.50 232.98 179 261
He Helium-4 4.003 5.19 2.27 20.387 5.6312 33.7329 1.79 3.7 4.3
HF Hydrogen fl uoride 20.006 461 64.85 0.372 11.0756 3404.49 15.06 206 313
Kr Krypton 83.800 209.4 55.02 20.002 8.6475 958.75 28.71 113 129
N2 Nitrogen 28.013 126.2 33.84 0.039 8.3340 588.72 26.60 54 90
NF3 Nitrogen trifl uoride 71.002 234 45.29 0.132 8.9905 1155.69 215.37 103 155
N2O Nitrous oxide 44.013 309.6 72.45 0.160 9.5069 1506.49 225.99 144 200
NO Nitric oxide 30.006 180 64.85 0.607 13.5112 1572.52 24.88 95 140
NO2 Nitrogen dioxide 46.006 431.4 101.33 0.86 13.9122 4141.29 3.65 230 320
Ne Neon 20.180 44.4 27.56 0.00 7.3897 180.47 22.61 24 29
O2 Oxygen 31.999 154.6 50.46 0.021 8.7873 734.55 26.45 63 100
PH3 Phosphene 33.998 324.45 65.35 0.042 9.2700 1617.91 211.07 144 186
SF6 Sulfur hexafl uoride 146.056 318.7 37.59 0.286 12.7583 2524.78 211.16 159 220
SO2 Sulfur dioxide 64.065 430.8 78.83 0.251 10.1478 2302.35 235.97 195 280
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A.2 Heat Capacity Data ◄ 641
TABLE A.1.2 Continued
Formula Name MW3g/mol4 Tc 3K 4 Pc 3bar 4 v A B C Tmin Tmax
SO3 Sulfur trioxide 80.064 491.0 82.07 0.41 14.2201 3995.70 236.66 290 332
SiCl3H Trichlorosilane 135.452 479.0 41.7 0.203 9.7079 2694.02 227.00 275 305
SiCl4 Silicon tetrachloride 169.896 507.0 37.49 0.264 9.1817 2634.16 243.15 238 364
SiF4 Silicon tetrafl uoride 104.079 259.09 37.15 0.456 16.3709 2810.45 26.88 129 128
SiH4 Silane 32.117 269.69 48.43 0.089 9.7222 1620.99 5.35 94 162
WF6 Tungsten hexafl uoride 297.830 444.0 43.40 0.231 10.4899 2351.42 264.70 202 290
Sources: Mostly from R. C. Reid, J. M. Prausnitz, and T. K. Sherwood. The Properties of Gases and Liquids, 3rd ed. (New York: McGraw-Hill, 
1977). Also from: CRC Handbook of Chemistry and Physics (Boca Raiton, FL CRC Press, (various) years); P. J. Linstrom and W. G. Mallard, Eds., 
NIST Chemistry WebBook, NIST Standard Reference Database Number 69, June 2005, National Institute of Standards and Technology, 
Gaithersburg MD, 20899 (http://webbook.nist.gov/chemistry/fl uid).; C. L. Yaws, Handbook of Vapor Pressure (vol. 4) (Houston: Gulf Publishing, 1995).
 ►A.2 HEAT CAPACITY DATA
cp
R
5 A 1 BT 1 CT2 1 DT22 1 ET3 with T in 3K 4
TABLE A.2.1 Heat Capacity of Ideal gases: Organic Compounds
Formula Name A B 3 103 C 3 106 D 3 1025 E 3 109 Tmin Tmax Source
CH2O Formaldehyde 2.264 7.022 21.877 298 1500 1
CH4 Methane 1.702 9.081 22.164 298 1500 1
CH4O Methanol 2.211 12.216 23.45 298 1500 1
C2H2 Acetylene 6.132 1.952 21.299 298 1500 1
C2H4 Ethylene 1.424 14.394 24.392 298 1500 1
C2H4O Acetaldehyde 1.693 17.978 26.158 298 1000 1
C2H4O Ethylene oxide 20.385 23.463 29.296 298 1000 1
C2H6 Ethane 1.131 19.225 25.561 298 1500 1
C2H6O Ethanol 3.518 20.001 26.002 298 1500 1
C3H6 Propylene 1.637 22.706 26.915 298 1500 1
C3H8 Propane 1.213 28.785 28.824 298 1500 1
C4H6 l.3-Butadiene 2.734 26.786 28.882298 1500 1
C4H8 1-Butene 1.967 31.63 29.873 298 1500 1
C4H10 n-Butane 1.935 36.915 211.402 298 1500 1
C4H10 Isobutane 1.677 37.853 211.945 298 1500 1
C5H10 1-Pentene 2.691 39.753 212.447 298 1500 1
C5H12 n-Pentane 2.464 45.351 214.111 298 1500 1
C6H6 Benzene 20.206 39.064 213.301 298 1500 1
C6H12 Cyclohexane 23.876 63.249 220.928 298 1500 1
C6H12 1-Hexene 3.220 48.189 215.157 298 1500 1
C6H14 n-Hexane 3.025 53.722 216.791 298 1500 1
C7H8 Toluene 0.290 47.052 215.716 298 1500 1
C7H14 1-Heptene 3.768 56.588 217.847 298 1500 1
C7H16 n-Heptane 3.570 62.127 219.468 298 1500 1
C8H8 Styrene 2.050 50.192 216.662 298 1500 1
C8H10 Ethylbenzene 1.124 55.38 218.476 298 1500 1
C8H16 1-Octene 4.324 64.96 220.521 298 1500 1
C8H18 n-Octane 8.163 70.567 222.208 298 1500 1
Sources:
1. J. M. Smith, H. C. Van Ness, and M. M. Abbott, Introduction to Chemical Engineering Thermodynamics, 5th ed. (New York: McGraw-Hill, 1996).
2. P. J. Linstrom and W. G. Mallard, Eds., NIST Chemistry WebBook, NIST Standard Reference Database Number 69, June 2005, 
National Institute of Standards and Technology, Gaithersburg MD, 20899 (http://webbook.nist.gov/chemistry/fl uid).
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http://webbook.nist.gov/chemistry/fluid
642 ► Appendix A Physical Property Data
TABLE A.2.2 Heat Capacity of Ideal Gases: Inorganic Compounds
Formula Name A B 3 103 C 3 106 D 3 1025 E 3 109 Tmin Tmax Source
Air 3.355 0.575 20.016 298 2000 1
BCl3 Boron trichloride 4.245 16.539 218.969 20.176 8.031 298 700 2
9.882 0.078 20.018 23.374 0.001 700 6000 2
B2H6 Diborane 21.494 32.188 218.314 0.361 3.988 298 1200 2
19.440 1.351 20.262 244.224 0.018 1200 6000 2
Br2 Bromine 4.493 0.056 20.154 298 3000 1
CF4 Carbon tetrafl uoride 1.921 25.299 222.789 20.261 7.482 298 1000 2
12.776 0.129 20.027 210.032 0.002 1000 6000 2
CO Carbon monoxide 3.376 0.557 20.031 298 2500 1
CO2 Carbon dioxide 5.457 1.045 21.157 298 2000 1
CS2 Carbon disulfi de 6.311 0.805 20.906 298 1800 1
C2F6 Hexafl uoroethane 8.389 27.106 220.948 21.751 5.671 298 1400 2
21.284 0.123 20.023 213.447 0.001 1400 6000 2
Cl2 Chlorine 4.442 0.089 20.344 298 3000 1
H2 Hydrogen 3.249 0.422 0.083 298 3000 1
HBr Hydrogen bromide 3.815 21.648 2.809 20.035 21.084 298 1100 2
3.956 0.339 20.057 23.819 0.004 1100 6000 2
HCN Hydrogen cyanide 4.736 1.359 20.725 298 2500 1
HCl Hydrogen chloride 3.156 0.623 0.151 298 2000 1
HF Hydrogen fl uoride 3.622 20.390 0.345 20.030 0.055 298 1000 2
2.955 0.829 20.150 20.282 0.010 1000 6000 2
H2O Water 3.470 1.45 0.121 298 2000 1
H2S Hydrogen sulfi de 3.931 1.49 20.232 298 2300 1
N2 Nitrogen 3.280 0.593 0.04 298 2000 1
NH3 Ammonia 3.5778 3.02 20.186 298 1800 1
N2O Nitrous oxide 5.328 1.24 20.928 298 2000 1
NO Nitric oxide 3.387 0.629 0.014 298 2000 1
NO2 Nitrogen dioxide 4.982 1.195 20.792 298 2000 1
N2O4 Dinitrogen tetroxide 11.660 2.257 22.787 298 2000 1
O2 Oxygen 3.639 0.506 20.227 298 2000 1
PH3 Phosphene 1.431 10.160 24.576 0.348 0.685 298 1200 2
SF6 Sulfur hexafl uoride 7.085 30.736 230.343 21.935 10.676 298 1000 2
18.901 0.058 20.012 29.959 0.001 1000 6000 2
SO2 Sulfur dioxide 5.699 0.801 21.015 298 2000 1
SO3 Sulfur trioxide 8.06 1.056 22.028 298 2000 1
SiCl4 Tetrachlorosilane 12.700 0.255 20.069 21.744 0.006 298 6000 2
SiClH3 Chlorosilane 2.977 14.807 29.231 20.432 2.242 298 1100 2
11.954 0.572 20.114 217.303 0.008 1100 6000 2
SiCl2H2 Dichlorosi lane 6.026 10.145 26.014 20.959 1.328 298 1500 2
12.603 0.195 20.035 215.277 0.002 1500 6000 2
SiCl3H Trichlorosilane 7.732 10.262 28.671 20.908 2.818 298 1000 2
12.552 0.253 20.052 27.179 0.004 1000 6000 2
SiF4 Silicon tetrafl uoride 5.170 19.158 218.179 20.514 6.207 298 1000 2
12.903 0.057 20.012 26.482 0.001 1000 6000 2
SiH4 Silane 0.729 16.835 29.368 0.163 1.953 298 1300 2
12.010 0.511 20.097 224.525 0.006 1300 6000 2
WF6 Tungsten hexafl uoride 18.137 0.730 20.197 23.690 0.017 1000 6000 2
Sources:
1. J. M. Smith, H. C. Van Ness, and M. M. Abbott, Introduction to Chemical Engineering Thermodynamics, 5th ed. (New York: McGraw- Hill, 
1996).
2. P. J. Linstrom and W. G. Mallard, Eds., NIST Chemistry WebBook, NIST Standard Reference Database Number 69, June 2005, 
National Institute of Standards and Technology, Gaithersburg MD, 20899 (http://webbook.nist.gov/chemistry/fl uid).
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A.3 Enthalpy and Gibbs Energy of Formation at 298 K and 1 Bar ◄ 643
TABLE A.2.3 Heat Capacity of Liquids and Solids
Formula Name Phase A B 3 103 D 3 1025 Source
CH4O Methanol L, cP 9.815 2
C2H6O Ethanol L, cP 13.592 2
C3H6O Acetone L 11.184 13.375 2
C5H12 Pentane L 18.691 5.254 3
C6H6 Benzene L 16.310 0.000 2
C6H14 Hexane L 23.695 2
Al Aluminum L 3.819 1
Al Aluminum S 2.486 1.490 1
Al2O3 Aluminum oxide S 23.154 4
C Graphite S 2.063 0.514 21.057 1
C Diamond S 0.782 4
Cu Copper L 3.950 4
Cu Copper S 2.723 1
Cu2O Cuprous oxide S, alpha 7.498 1
CuO Cupric oxide S 4.666 1
Fe Iron S, alpha 2.104 2.979 1
Fe3O4 Iron oxide S 11.012 24.260 1
GaAs Gallium arsenide S 5.438 0.730 1
Ni Nickel S 1.508 4.308 0.297 1
Si Silicon L 3.272 4
Si Silicon S 2.879 0.297 20.498 1
SiO2 Silicon dioxide S 5.647 4.127 21.359 1
SiCl3H Trichlorosilane L, cP 15.678 2
SiCl4 Tetrachlorosilane L, cP 16.117 2
H2O Water L, cP 9.069 2
H2O Water (ice) S, cP 4.196 5
H2SO4 Sulfuric acid L 16.731 1.875 3
HNO3 Nitric acid L, cP 13.315 2
NH3 Ammonia L 6.880 9.682 2
Sources:
1. O. Kubaschewski and C. B. Alcock, Metallurgical Thermochemistry, 5th ed. (New York: Peramon Press, 1979).
2. Milan Zabransky et al., Heat Capacity of Liquids (Washington, DC: American Chemical Society; Woodbury, NY: National Bureau of Standards,
1996).
3. Richard M. Felder and Ronald W. Rousseau, Elementary Principles of Chemical Processes, 3rd ed. (New York: Wiley, 2000).
4. M. W. Chase et al., JANAF Themochemical Tables, 4th ed. (Washington, DC: American Chemical Society; National Bureau of Standards, 1998).
5. K. Ranjevic, Handbook of Thermodynamic Tables and Charts (New York: McGraw-Hill, 1976).
 ►A.3 ENTHALPY AND GIBBS ENERGY OF FORMATION AT 298 K AND 1 BAR
TABLE A.3.1 Organic Compounds
Formula Name Phase Lhf,298o 3kJ/mol 4 Lgf,298o 3kJ/mol 4 Source
CH2O Formaldehyde G 2115.97 2109.99 1
CH4 Methane G 274.81 250.72 1
CH4O Methanol L 2238.73 2166.34 1
CH4O Methanol G 2200.66 2161.96 1
C2H2 Acetylene G 226.88 209.24 1
C2H3N Acetonitrile L 53.17 98.93 1
C2H3N Acetonitrile G 87.92 105.67 1
C2H4 Ethylene G 52.26 68.15 1
(Continued)
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644 ► Appendix A Physical Property Data
TABLE A.3.1 Continued
Formula Name Phase Lhf,298o 3kJ/mol 4 Lgf,298o 3kJ/mol 4 Source
C2H4Cl2 1,1-Dichloroethane L 2160.86 276.20 1
C2H4Cl2 1,1-Dichloroethane G 2130.00 273.14 1
C2H4O Acetaldehyde G 2166.47 2133.39 1
C2H4O Ethylene oxide L 277.46 211.43 1
C2H4O Ethylene oxide G 252.67 213.10 1
C2H4O2 Acetic acid L 2484.41 2389.62 1
C2H4O2 Acetic acid G 2435.13 2376.94 1
C2H6 Ethane G 284.68 232.84 1
C2H6O Ethanol L 2277.17 2174.25 1
C2H6O Ethanol G 2234.96 2168.39 1
C3H6 Propylene G 20.43 62.76 1
C3H6O Acetone L 2248.28 2155.50 1
C2H6O Acetone G 2217.71 2153.15 1
C3H6O Propylene oxide L 2120.75 226.75 1
C3H6O Propylene oxide G 292.82 225.79 1
C3H8 Propane G 2103.85 223.49 1
C3H8O 1-Propanol L 2304.76 2170.78 1
C3H8O 1-Propanol G 2257.70 2163.08 1
C4H6 1,3-Butadiene L 85.41 149.68 1
C4H6 1,3-Butadiene G 110.24 150.77 1
C4H8 1-Butene G 20.13 71.34 1
C4H8 cis-2-Butene G 26.99 65.90 1
C4H8 trans-2-Butene G 211.18 63.01 1
C4H8O2 Ethyl acetate L 2479.35 2332.93 1
C4H8O2 Ethyl acetate G 2443.21 2327.62 1
C4H10 n-Butane L 2147.75 215.07 1
C4H10 n-Butane G 2126.23 217.17 1
C4H10 Isobutane L 2158.55 221.98 1
C4H10 Isobutane G 2134.61 220.89 1
C4H10O n-Butanol L 2326.03 2161.19 1
C4H10O n-Butanol G 2274.61 2150.77 1
C5H10 1-Pentene L 246.72 78.25 1
C5H10 1-Pentene G 220.93 79.17 1
C5H12 n-Pentane L 2173.33 29.46 1
C5H12 n-Pentane G 2146.54 28.37 1
C6H6Benzene L 49.07 124.34 1
C6H6 Benzene G 82.98 129.75 1
C6H6O Phenol S 2165.13 250.45 1
C6H6O Phenol G 296.42 232.91 1
C6H7N Aniline L 31.11 149.18 1
C6H7N Aniline G 86.92 166.80 1
C6H12 Cyclohexane L 2156.34 26.89 1
C6H12 Cyclohexane G 2123.22 31.78 1
C6H12 1-Hexene L 272.43 83.44 1
C6H12 1-Hexene G 241.70 87.50 1
C6H14 n-Hexane L 2198.96 24.35 1
C6H14 n-Hexane G 2167.30 20.25 1
C7H8 Toluene L 12.02 113.84 1
C7H8 Toluene G 50.03 122.09 1
C7H14 1-Heptene L 298.01 88.84 1
C7H14 1-Heptene G 262.34 95.88 1
C7H16 n-Heptane L 2224.54 1.00 1
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A.3 Enthalpy and Gibbs Energy of Formation at 298 K and 1 Bar ◄ 645
TABLE A.3.1 Continued
Formula Name Phase Lhf,298o 3kJ/mol 4 Lgf,298o 3kJ/mol 4 Source
C7H16 n-Heptane G 2187.90 8.00 1
C8H10 o-Xylene L 224.45 110.53 1
C8H10 o-Xylene G 19.01 122.17 1
C8H10 m-Xylene L 225.41 107.73 1
C8H10 m-Xylene G 17.25 118.95 1
C8H10 p-Xylene L 224.45 110.03 1
C8H10 p-Xylene G 17.96 121.21 1
C8H10 Ethylbenzene L 212.48 119.78 1
C8H10 Ethylbenzene G 29.81 130.67 1
C8H16 1-Octene L 2123.59 94.16 1
C8H16 1-Octene G 282.98 104.29 1
C8H18 n-Octane L 2250.12 6.49 1
C8H18 n-Octane G 2208.59 16.41 1
C9H20 n-Nonane L 2275.66 11.76 1
C9H20 n-Nonane G 2229.19 24.83 1
C10H8 Naphthalene S 78.13 201.18 1
C10H8 Naphthalene G 151.06 223.74 1
C10H22 n-Decane L 2301.24 17.25 1
C10H22 n-Decane G 2249.83 33.24 1
Sources:
1. Daniel R. Stull, Edgar F. Westrum, and Gerard C. Sinke, The Chemical Thermodynamics of Organic Compounds, (New York: Wiley, 1969).
TABLE A.3.2 Inorganic Compounds
Formula Name Phase Lhf,298o 3kJ/mol 4 Lgf,298o 3kJ/mol 4 Source
BCl3 Boron trichloride G 2402.96 2387.96 2
B2H6 Diborane G 35.61 86.77 2
BN Boron nitride S 2254.387 2228.501 2
B2O3 Boron oxide S 21271.94 21192.8 2
CCl3F Trichlorofl uoromethane G 2284.70 2245.51 1
CF4 Carbon tetrafl uoride G 2975.52 2889.03 1
C2F6 Hexafl uoroethane G 21343.06 21257.3 2
CHCl3 Chloroform L 2132.30 271.89 1
CHCl3 Chloroform G 2101.32 268.58 1
CHN Hydrogen cyanide G 130.63 120.20 1
CO Carbon monoxide G 2110.53 2137.17 2
CO2 Carbon dioxide G 2393.51 2394.36 2
CS2 Carbon disulfi de G 116.94 66.82 2
CaS Calcium sulfi de S 2473.2 2468.178 2
CaSO4 Calcium sulfate S 21434.11 21321.68 2
CaO Calcium oxide S 2635.09 2603.51 2
CuCl Copper chloride S 2155.65 2138.66 2
CuO Copper monoxide S 2156.06 2128.29 2
Cu2O Dicopper oxide S 2170.71 2147.88 2
CuS Copper sulfi de S 253.1 253.47 2
CuSO4 Copper sulfate S 2771.36 2662.08 2
Fe3C Triiron carbide S 25.104 20.029 2
(Continued)
bapp01.indd 645bapp01.indd 645 31/10/12 9:30 AM31/10/12 9:30 AM
646 ► Appendix A Physical Property Data
TABLE A.3.2 Continued
Formula Name Phase Lhf,298o 3kJ/mol 4 Lgf,298o 3kJ/mol 4 Source
Fe2O3 Hematite S 2824.25 2742.29 2
Fe2O4 Magnetite S 21118.38 21015.23 2
HBr Hydrogen bromide G 236.38 253.45 2
HCl Hydrogen chloride G 292.312 295.29 2
HF Hydrogen fl uoride G 2272.55 2274.65 2
HNO3 Nitric acid G 2134.31 273.96 2
H2O Water L 2285.83 2237.14 2
H2O Water G 2241.82 2228.57 2
H2S Hydrogen sulfi de G 220.5 233.33 2
H2SO4 Sulfuric acid L 2813.99 2689.89 2
H2SO4 Sulfuric acid G 2735.13 2653.37 2
NH3 Ammonia G 246.11 216.45 2
N2O Nitrous oxide G 82.05 104.17 2
NO Nitric oxide G 90.29 86.6 2
NO2 Nitrogen dioxide G 33.1 51.26 2
N2O4 Dinitrogen tetraoxide L 219.564 97.51 2
N2O4 Dinitrogen tetraoxide G 9.079 97.79 2
NaCl Sodium chloride S 2411.12 2384.02 2
NaF Sodium fl uoride S 2573.48 2545.08 2
NaOH Sodium hydroxide S 2425.93 2379.73 2
NaOH Sodium hydroxide G 2197.49 2200.19 2
O Oxygen G 249.17 231.74 2
PH3 Phosphene G 5.57 13.59 2
TaN Tantalum nitride S 2252.3 2226.58 2
TiC Titanium carbide S 2184.5 2180.84 2
TiN Titanium nitride S 2337.86 2309.16 2
SiC Silicon carbide S 273.22 270.85 2
SiCl2 Dichlorosilylene G 2168.61 2180.36 2
SiCl4 Silicon tetrachloride G 2662.75 2622.76 2
SiF4 Silicon tetrafl uoride G 21614.94 21572.7 2
SiCl3H Trichlorosilane G 2496.22 2464.9 3
SiCl2H2 Dichlorosilane G 2320.49 2294.9 3
SiH3Cl Chlorosilane G 2141.838 2119.29 3
SiH4 Silane G 34.31 56.82 2
Si3N4 Silicon nitride S 2744.75 2647.34 2
SiO2 Silicon dioxide, trigonal S 2910.86 2856.44 2
SiO2 Silicon dioxide, hexagonal S 2906.34 2757.11 2
SiO2 Silicon dioxide, cristobalite S 2902.53 2716.46 2
SiO2 Silicon dioxide L 2935.34 2551.67 2
SF6 Sulfur hexafl uoride G 21220.47 21116.5 2
SO2 Sulfur dioxide G 2296.813 2300.1 2
SO3 Sulfur trioxide G 2395.77 2371.02 2
WF6 Tungsten hexafl uoride G 21721.72 21632.29 2
ZnO Zinc oxide S 2350.46 2320.48 2
ZnS Zinc sulfi de, wurtzite S 2191.84 2190.14 2
ZnS Zinc sulfi de, sphalerite S 2205.18 2200.4 2
ZnSO4 Zinc sulfate S 2982.8 2871.45 2
Sources:
1. Daniel R. Stull, Edgar F. Westrum, and Gerard C. Sinke, The Chemical Thermodynamics of Organic Compounds (New York: Wiley, 1969).
2. Ihsan Barin, Thermochemical Data of Pure Substances, 3rd ed. (vol. I and II) (New York: VCH, 1995).
3. M. W. Chase et al., JANAF Thermochemical Tables, 3rd ed. (Washington, DC: American Chemical Society; (New York: National Bureau of
Standards, 1986).
bapp01.indd 646bapp01.indd 646 31/10/12 9:30 AM31/10/12 9:30 AM
►
647
APPENDIX B
Steam Tables 
 ► TABLE B.1: Saturated Water: Temperature Table [648]
 ► TABLE B.2: Saturated Water: Pressure Table [650]
 ► TABLE B.3: Saturated Water: Solid-Vapor [652]
 ► TABLE B.4: Superheated Water Vapor [653]
 ► TABLE B.5: Subcooled Liquid Water [659]
Symbols Used in the Steam Tables
 T Temperature °C
 P Pressure kPa or MPa
 v̂ Specifi c volume m3/kg
 û Specifi c internal energy kJ/kg
 ĥ Specifi c enthalpy kJ/kg
 ŝ Specifi c entropy kJ/kg K
Subscripts
 l Liquid in equilibrium with vapor
 s Solid in equilibrium with vapor
 v Vapor in equilibrium with liquid or solid
 lv Change by evaporation
 sv Change by sublimation
Source: New York: Wiley J. H. Keenan, F. G. Keys, P. G. Hill, and J. G. Moore, 
Steam Tables (1969), as used by G. J. Van Wylen, R. E. Sonntag, and C. Borgnakke, Fun-
damentals of Classical Thermodynamics, 4th ed., (New York: Wiley, 1994).
bapp02.indd 647bapp02.indd 647 31/10/12 9:42 AM31/10/12 9:42 AM
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bapp02.indd 648bapp02.indd 648 31/10/12 9:42 AM31/10/12 9:42 AM
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bapp02.indd 649bapp02.indd 649 31/10/12 9:42 AM31/10/12 9:42 AM
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bapp02.indd 651bapp02.indd 651 31/10/12 9:42 AM31/10/12 9:42 AM
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bapp02.indd 656bapp02.indd 656 31/10/12 9:42 AM31/10/12 9:42 AM
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Pa
T °C
v̂
m
3 /
kg
û
k J
/k
g
ĥ
kJ
/k
g
ŝ
k J
/k
g 
K
T °C
v̂
m
3 /
kg
û
k J
/k
g
ĥ
kJ
/k
g
ŝ
k J
/k
g 
K
T °C
v̂
m
3 /
kg
û
k J
/k
g