Exercício de Química Sintética e Organica Mista (803)

Prévia do material em texto

A-6. Pentane: three signals; 2-methylbutane: four signals; 2,2-dimethylpropane: two signals
A-7. 2,3-Dimethylbutane: (CH3)2CHCH(CH3)2
B-1. (d) B-2. (a) B-3. (b) B-4. (b)
B-5. (b) B-6. (a) B-7. (b) B-8. (a)
B-9. (c) B-10. (a) B-11. (c) B-12. (c)
B-13. (a) B-14. (a) B-15. (d )
CHAPTER 14
A-1. (a)
(b)
(c)
A-2. (a) (d )
(b) (e)
(c)
A-3. (a)
(b)
A-4. (a) (CH3CH2CH2)2CuLi (c) CH2I2, Zn(Cu)
(b) (CH3)2CHMgX
(X � Cl, Br, I)
and�
O
CH3CH2CH2CH CH3CH2CH2CH2MgX
(X � Cl, Br, I)
�CH3CH2CH2CH2CH
O
CH3CH2CH2MgX
(X � Cl, Br, I)
C6H5CH � �C6H5MgX(CH3)3CMgX and (CH3)3CCH
O O
(X � Cl, Br, I) (X � Cl, Br, I)
H3C CH2OH
H3C
CH3
Br Br
H
H
(CH3)2CHCH2D
CH2CH3HO
� CH3CH2OH(C6H5)2CCH3
OH
2C6H5CH2Li (C6H5CH2)2CuLi LiX� �CuX
(X � Cl, Br, I)
(CH3)3CBr Mg (CH3)3CMgBr�
2Li
LiX
(X � Cl, Br, I)
� LiX�
798 APPENDIX A