Exercício de Química Sintética e Organica Mista (806)

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APPENDIX A 801
A-8. (a)
(b)
(c)
B-1. (e) B-2. (d ) B-3. (c) B-4. (c)
B-5. (b) B-6. (b) B-7. (a) B-8. (a)
B-9. (d ) B-10. (a) B-11. (b) B-12. (d )
B-13. (e) B-14. (a) B-15. (c)
CHAPTER 16
A-1. CH3OCH2CH2CH3
Methyl propyl ether
CH3OCH(CH3)2
Isopropyl methyl ether
CH3CH2OCH2CH3
Diethyl ether
A-2. (a) (d ) 
(b) (e) C6H5SCH2CH3
(c) ( f ) C6H5SCH2CH3
O�
�
C6H5CHCH2OH
I
C C
H3C H
OHH
HO
H3C
CH3
CH3
OH
SCH2CH3
C OCH3
CH3
H
CH3CH2
C6H5CH3 C6H5CH2Br C6H5CH2MgBr
NBS
peroxides, heat
C6H5CH2CH2CO2HC6H5CH2CH2CO2CH2CH3
C6H5CH2CH2CH2OH
K2Cr2O7
H�, H2O
heat
Mg
O
1.H2C CH2
2. H3O
�
CH3CH2OH
H�
Na2Cr2O7
H�, H2O
1. CH3CH2MgBr
2. H3O
�
CH
O
CCH2CH3
O
CHCH2CH3
OH
(CH3)2CHCHCH3
OH
(CH3)2CHCCH3
O
(CH3)2C CHCH3
PDC
CH2Cl2
1. B2H6
2. H2O2, HO
�