Index_1992_The-Chemical-Bond

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I n d e x 
A 
Ab initio calculations, 154, 219, 226, 236 
Absolute rate theory, 116,168 
Activation energy, 120-121 
A-DNA, 33-34, 36-37, 65, 79-80, 93, 95 
Alkali halides, 263-264 
α helix, 7 ,36 ,48-49 , 51, 58-59, 91, 97, 
177 
Amino acids, structure determination, 
7-8 
Antibodies, 91 
Arrhenius equation, 114-115, 149, 223 
Arrhenius, Svante, 114, 149 
Atomic radii, 6-7 
Atom transfer reactions, 180-190 
Β 
Bacteriophage, 46-49 
Base pairs, 38-45, 52, 95 
B-DNA, 33-35, 38, 49-50, 61-62, 79-80, 
93, 95 
Bernstein, Richard, 181, 223-269, 
304-305 
Berry, R. Stephen, 263 
Bersohn, Richard, 233, 255 
β sheet, 47-48, 64-65, 90, 97 
Bimolecular reactions, 230-232, 
240-244, 256-262, 268-269 
Bohr, Niels, 106 
Bond energy bond order (BEBO) method, 
152 
Bragg equation, 4 
Bragg, William H., 4-5, 103 
Bragg, W. Lawrence, 4-6, 103 
Branching, microscopic and macroscopic, 
158-160, 162-164 
Brooks, Philip R., 243, 246 
Bunker, Donald, 181, 232 
Burdick, Lalor, 5 
c 
Catabolite-activating protein (CAP), 48, 
55 
Chaperone effect, 120-121 
Chemical bond, nature of, 3-16, 99-109 
Child, Mark S., 263 
Chlorine—oxygen reaction, 121-124 
Chlorophyll, 140 
Clonal selection theory, 91 
CIO radical, 121-125 
Collision theory, 116 
Complementarity, 91, 97 
Computers, 8-10 
Configuration interaction, 204 
Corey, Robert B., 7 
Cotton, F. Α., 28 
309 
310 INDEX 
Crick, Francis, 36, 87-98, 290-292 
Crim, F. Fleming, 237 
Cro protein, 47-50 
Crossed-beam experiments, 234-235, 
243, 257, 262 
Crystals, structure determination, 4-16 
Csanâdy, Agnes, 12-13 
Curl, Robert F., 243, 246 
D 
Davidson, Norman, 120 
Deisenhofer, Johan, 141 
Delbruck, Max, 97 
Dickinson, Roscoe G., 5-6, 100-102, 104 
Dimensional scaling, 204-219 
Dixon, Richard N., 236 
DNA, recognition, 46-56 
Double helix, 32-43, 82-83, 177 
Durant, James, 133-134, 144 
Ε 
Egami, T., 15 
Electron-diffraction photographs, 14—15 
Electronegativity, 177, 180-190 
Electronically excited states, 124-129 
Electronic structure, 175-220 
Emission spectroscopy, 245 
Endonuclease RI-DNA complex, 47, 
63-65 
Enzyme action, 91 
Evans, M. G., 115, 120, 157 
Evolutionary time, 97 
Ewald, P. P., 3 
Eyring, Henry, 115, 154, 157, 177, 228 
F 
Femtochemistry, 223-269 
Femtosecond era, 133-138 
Flash photolysis, 117-119, 121, 127, 
129-134, 141, 143, 147, 227, 265 
Franklin, Rosalind, 95 
Free radicals, 116-117, 119-122, 124, 
128 
Frontier orbital, 183-184 
G 
Gallagher, Alan, 244 
General Chemistry, 87, 93, 176 
Glucocorticoid receptor, 61-63 
Glucocorticoid response elements, 61, 63 
Goldschmidt, V. M., 7 
Grice, Roger, 263 
Grooves, major and minor, 34-42, 52-60, 
65, 68, 79-80, 82 
Group velocity compensation, 252 
H 
Half-collision process, 233-236 
Harding, Larry, 259 
Harpooning, 180, 182, 188 
Hartree-Fock approximation, 204-205, 
209 
Heitler-London theory, 115 
Helix-turn-helix motif, 46-57, 60-62, 65 
Heller, Eric J., 246 
Hemoglobin, 18-20, 22-26, 95-96 
Herman, Zelek S., 11 
Herschbach, Dudley R., 175-220, 224, 
230,240, 263, 298-299 
Herzberg, G., 119 
Hirschfelder, Joseph O., 228 
Hochstrasser, Robin, 262 
Homeobox, 56 
Homeodomain, 56-57 
Houston, Paul L., 233 
Hybridization, 177 
Hybridized rotational states, 190-203 
Hydrogen bond, 18, 88 
pairs, 43-46, 52-53 
significance in physiology, 17-29 
Watson-Crick, 34 
I 
ICN dissociation, 135-137, 249-250, 
254-255, 262 
Imre, Dan G., 255 
Infrared chemiluminescence, 156, 166, 
177, 182-183, 186 
Instanton path, 216-218 
INDEX 311 
Intermediates, reaction, 116-117 
Intermetallics, structural chemistry, 8-9, 
103-104, 109 
Introduction to Quantum Mechanics, 176 
Itano, Harvey, 95 
J 
Johnston, Harold, 151-152, 176 
Κ 
Karplus, Martin, 175, 181, 204, 232 
Kasha, Michael, 124, 127 
Kinsey, James L., 246 
Klemperer, William, 258 
Klug, David, 133-134, 144 
Kupperman, Axon, 262 
L 
Langmuir, Irving, 5, 100, 207 
Langmuir vibrations, 207, 219 
Lasers, 129,132-133, 223-269 
Laue equations, 3 
Laue, Max von, 3 ,102, 108 
Lee, Yuan T., 182, 224 
Leone, Stephen R., 233-236 
Leucine zipper, 65 
Levine, Raphael D., 262 
Levy, Donald H., 253 
Lewis, G. N., 5, 100, 105, 124, 151, 153, 
176-177, 207, 209 
Lewis structure, 207, 211-212, 218-219 
Lindemann, F. Α., 114 
Lipscomb, Bill, 175 
Lock and key, 89 
Loeser, John, 208-209 
London, Fritz, 153-154 
Lovelock, James, 123 
M 
Marcus, Rudolph Α., 237, 265 
Mathieu equation, 198 
McClure, Donald, 124 
Messenger RNA, 66, 68 
Metals, structural chemistry, 8, 103,109 
Metiu, Horia I., 265 
Michel, Hartmut, 141 
Michelson interferometry, 254 
Microsecond regime, 113-129 
Miller, William H., 214, 237, 279 
Molecular beam experiments, 156,177, 
179-181, 183, 194-195, 224, 228, 
251-253, 256-257 
Molecular biology, 87-98 
Molecular clock, 96-97 
Molecular recognition, 31-83 
Monte Carlo calculations, 181, 232 
Moore, C. Bradley, 237 
Mukamel, Shaul, 262 
Myoglobin, 21-23 
Ν 
Nanosecond era, 129-132 
Nature of the Chemical Bond, The, 8, 
17-18, 26, 87, 109, 113, 151, 176 
Nernst chain reaction, 114 
Norrish, Ronald G. W., 117, 227 
Noyes, Arthur Α., 5, 100-101, 106 
Nucleic acids, 31-83 
Ο 
Oriented molecules, 190-203, 259-262 
Ozone decomposition, 123-125 
ρ 
Palindromic sequences, 48-52 
Pancreatic trypsin inhibitor, 26-27 
Patterson, A. L., 7 
Patterson diagram, 7-8 
Pauling, Linus, 3-16, 94, 99-109, 
175-179, 282-283 
antibodies, 91 
hemoglobin and myoglobin, 20, 22, 95 
hydrogen bond, 18, 20 
molecular biology, 87-98 
orbital hybridization, 200 
protein structure, 32, 46, 90-93, 179 
312 INDEX 
reaction dynamics, 151-152 
resonance, 153, 204-205, 210, 218-219 
Pauling, Peter J., 11 
Pendular molecules, 190-203 
Peptides, structure determination, 7-8 
Perutz, Max F., 17-29, 284-285 
Phase problem, 93, 193 
Photochemistry, 124-129, 265 
Photodissociation, 182-184, 249-250, 264 
Photofragmentation, 224-225, 232-239, 
242, 247, 259-262 
Photosynthesis, 138-147 
Photosystems, 143-146 
Picosecond era, 132-133 
Pigment-protein complexes, 138-141 
Polanyi, John C , 149-171, 181-182, 186, 
224,232, 244, 300-301 
Polanyi, Michael, 115, 154, 157, 177, 180, 
228 
Poon, S. J., 15 
Porter, Lord George, 113-147, 227, 
294-296 
Potential curve crossing, 263 
Product angular distribution, 240-243 
Protein denaturation, 90 
Protein-nucleic acid complexes, 45—46, 
50-55, 64 
Proteins 
drug interactions with, 26 
nucleic acids and, 31-83 
stability, 18-21 
structure determination, 7, 23, 46, 
90-93 ,179 
Pulse compression, 252-253 
Pump-probe experiments, 117,132, 260 
Q 
Quantum mechanics, 106-108, 153, 192, 
194 
Quasicrystals, 10-16 
R 
Rate constant, 224 
Raymond, Albert, 6 
Reaction centers, 141-147 
Reaction dynamics, 150, 175-220,224-226 
Rebound reaction, 181-183 
Recognition site, 39-43 
Recombination reactions, 120-121 
Reisler, Hanna, 237, 258 
Repressor protein, 47-50 
Resonance, 153, 177, 204-205, 210, 
218-219 
Resonance integrals, 153 
Resonances, trapping, 262—265 
Restriction endonucleases, 63-64 
Rice, Stuart Α., 262 
Rich, Alexander, 31-83, 89, 286-288 
Rowland, F. Sherwood, 123 
Russell, Ken, 120 
S 
Saddle point, 227, 268-269 
Sato, S., 154 
Schatz, George C., 259, 279 
Schlag, Edward, 253 
Schomaker, Verner, 7-8 
Schrodinger equation, 166, 194, 206-207 
Schrodinger, Erwin, 106-107,152 
Schumacher, Ernst, 244 
Shank, Charles V., 133, 228, 252 
Shapiro, Moshe, 262 
Sickle cell anemia, 26, 95-97 
Simons, John P., 120, 236 
Smalley, Richard E., 253 
Smith, Ian W. M., 226 
Sodium iodide dissociation, 138 
Soep, Benoit, 258, 279 
Sommerfeld, Arnold, 3 ,105-108, 152 
State-to-state experiments, 226-227, 
233,237-241 
Stern, Otto, 177, 180, 198 
Stwalley, William C , 244 
Supersonic expansion, 194-195, 227 
Surface reactions, 169-170 
Synthetase recognition, 77-79 
τ 
Terenin, Alexander N., 233 
Thermodynamics, 177-178 
INDEX 313 
Three-vector correlation, 191-193 
Time-of-flight mass spectroscopy, 253 
Tolman, Richard C , 104-105 
Trajectory calculation, 228-229 
Transfer RNA, 65-82 
Transition state, 149-171,226-230, 
242-248, 268, 279 
Transition state spectroscopy, 135-138, 
167-169 
Transition state theory, 115-118 
Triangle plots, 155-156, 158-159 
Trihalides, 189-190 
Triplet states, 124-127, 132 
Troe, Jurgen, 237 
Truhlar, Donald G., 262, 279 
Tryptophan repressor, 55 
Tunneling, 204-219 
u 
Uncertainty principle, 147, 193, 200, 219, 
255, 268 
Unimolecular reactions, 230, 237, 
240-244, 254-255 
V 
Valence, 153 
Van der Waals precursor molecule, 
257-258 
Van't Hoff, J. H., 114 
w 
Watson, J. D. ,34, 89 
Wharton, Lennard, 253 
Wilkins, Maurice, 95 
Wilson, E. Bright, 175-176, 207 
Wilson, Kent R., 233 
Wittig, Curt, 237, 258 
Woodward-Hoffmann rules, 188 
X 
X-ray crystallography, 3-16, 88, 141-142 
X-ray diffraction, fiber, 33, 94-95 
Y 
Yeast phenylalanine transfer RNA, 34, 
67, 69-77 
Ζ 
Zare, Richard Ν., 233, 253, 278 
Z-DNA, 34, 37-38, 79-82 
Zewail, Ahmed, 135, 138, 223-269, 
302-303 
Zinc finger, 47, 53, 57-61, 82