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Hyperspectral applications in economic geology – Case Study: Alteration at the Olympic Dam IOCG-U Deposit Mauger, A.J., Ehrig, K., Kontonikas-Charos, A., Ciobanu, C.L. & Cook, N.J. 29 June 2016, AESC2016, Adelaide www.minerals.statedevelopment.sa.gov.au AJES Special Monograph Hyperspectral Applications • What is the attraction of the term “hyperspectral”? • Origins in Remote Sensing – bands • The more, and narrower, the “bands” the closer the digital record approximates an analogue signal • Usually considered to be > 100 bands What are we referring to with “hyperspectral”? • Specifically the mineralogical response to reflected radiation • VIS-NIR 300-1300 nm • SWIR 1300-2500 nm • TIR 6000-14500 nm • Instrumentation (a selection) – Hyperion – HyMap – HyLogger – Corescan – Terracore • This presentation will focus on HyLogger What has been the impact of hyperspectral? • Greater confidence in material identification – not just discrimination • Improved modelling of data corrections/calibration • All scales of observation – Satellite – Airborne – Laboratory – Portable Transition from Remote Sensing to Spectroscopy • Objective to have accurate, repeatable, unambiguous mineral identification and quantification from mixed spectra. • What are the applications of spectroscopy in the geological exploration-discovery- exploitation-recovery cycle? What have been the game changers? • PIMA study by CSIRO (AMIRA P435, 1999) identified white mica and chlorite chemistry as key vectors to mineralization • CSIRO/AMIRA Project P685: HyLogger Prototype 2002 • NCRIS/Auscope: Every Australian State Geological Survey equipped with HyLogger 2 (VSWIR) 2009 • Thermal Infrared attached: HyLogger 3 (VSWIR-TIR) 2011 Not just hyperspectral…. …but almost continuous recording at the cm scale • Why is this important? • Because mineralogy just became an Exploration tool. • HyLogger provides detailed datasets • HyLogger provides more than the best geologist can see • HyLogger enhances the geologist’s ability to describe and interpret • HyLogger provides consistent and quantitative information at the scale of mineralogy • Mineral Systems focus on minerals HyLogger 3-3 Quick recap: • Visible – Thermal Infrared semi-automated core scanner • Interprets minerals responsive to the measured wavelengths of reflected radiation • Can scan 500m diamond core per day – spectra every cm • Provides a high resolution image of the core • Alteration mineralogy is a key focus … Applications in Economic Geology • For the purposes of this presentation the focus will be on South Australian examples • Cu, Au, U, Pb, Zn, Ag have been the main commodities of interest in SA • The Copper Strategy South Australia’s Copper Strategy outlines the plan to triple the State’s copper production to 1 million tonnes per year within the next two decades and ensure the South Australian community benefits from this increase. Copper Gold Current Cu-Au Deposits & HyLogger OD HyLogger & Mineral Systems • Early identification of spectral vectors • Focus on the Olympic Domain (Cu, Au, U) • Establish the application of chlorite and sericite chemical gradients in IOCG-U systems • Development of TIR spectral vectors • Quintessential example – Olympic Dam itself Olympic Dam • Refer to Monday!! • World’s largest endowment of contained metal • 20,000 m of core in a 14 km cross section • Au, Cu, Ag, U – highly economic • What can HyLogger tell us that BHP Billiton don’t already know? Location of Olympic Dam In relation to Gawler Silicic Large Igneous Province After McPhie et al Location • 14 km • 30 Drill holes • 20,000 m Roxby Downs Olympic Dam RD 6750 00E 66300 00N Roxby Downs Granite Olympic Dam Breccia Complex biotite ‘out’ altered, weakly brecciated RDG Fe ~5% N Resource outline 6800 00E 66250 00N 66350 00N * dykes projected to -350mRL Gairdner dykes undiff mafic dykes sediment: hm-qtz sediment: mafic sediment: hm conglomerate volcanic breccia Fe (>20%) hem-rich bx Fe (5-20%) gr- to hem-rich bx Fe (<5%) RDG drill hole collars (this study) Simplified Geological Map (at - 350mRL) 0 1 2 km RD2488 RD2499 RD451 RD302 RD2773 RD2786A RD2923 RD2751 RD2347 RD2336 RD2326 RD480 RD2684 RD2568 RD2137 RD16/16W1 RD2151 RD2153 RD1603 RD1605 RD1604 RD1606 RD2162 RD16/16W1 RD76 RD252 RD33 RD49 RD2715 RD1614 inset -1400 -1000 -600 -200 ksp-ser ksp>ser -1400 -1000 -600 -200 ser (minor ksp) no ser hem-alt What minerals can be measured? • Not all minerals have a distinctive spectral response at the wavelengths HyLogger measures • SWIR – OH Bond predominantly, harmonics • TIR – Primary molecular vibrations What the HyLogger saw… SWIR 00 = Opal 01 = Dickite ‘ 02 = Kaolinite-PX 03 = Kaolinite-WX 04 = Nacrite 05 = Muscovite 06 = Paragonite 07 = Phengite 08 = Montmorillonite 09 = Nontronite 10 = Saponite 11 = Diaspore 12 = Gibbsite 13 = Prehnite 14 = Pyrophyllite 15 = Topaz 16 = Chlorite-Fe 17 = Chlorite-FeMg 18 = Chlorite-Mg 19 = Biotite 20 = Phlogopite 21 = Actinolite 22 = Hornblende 23 = Tremolite 24 = Riebeckite 25 = Serpentine 26 = Brucite 27 = Talc 28 = Epidote 29 = Zoisite 30 = Tourmaline 31 = Tourmaline-Fe 32 = Rubellite 33 = Ankerite 34 = Siderite 35 = Calcite 36 = Dolomite 37 = Magnesite 38 = Alunite-K 39 = Alunite-Na 40 = Alunite-NH 41 = Gypsum 42 = Jarosite 43 = Palygorskite 44 = Vegetation-Dry 45 = IsaWhite 46 = IsaYellow 47 = PlasticChipTray 48 = Teflon 49 = WhiteMarker 50 = Wood 51 = YellowMarker 52 = MuscoviticIllite 53 = ParagoniticIllite 54 = PhengiticIllite TIR 000 = Opal 001 = Quartz 002 = Anorthoclase 003 = Microcline 004 = Orthoclase 005 = Albite 006 = Anorthite 007 = Bytownite 008 = Labradorite 009 = Andesine 010 = Oligoclase 011 = Andradite 012 = Grossular 013 = Uvarovite 014 = Almandine 015 = Spessartine 016 = Augite 017 = Diopside 018 = Hedenbergite 019 = Enstatite 020 = Fayalite 021 = Forsterite 022 = Olivine 023 = Zircon 024 = Andalusite 025 = Cordierite 026 = Marialite 027 = Meionite 028 = Vesuvianite 029 = Analcime 030 = Chabazite 031 = Heulandite 032 = Laumontite 033 = Mesolite 034 = Natrolite 035 = Phillipsite 036 = Thomsonite 037 = Kaolinite 038 = Kaolinite-PX 039 = Illite 040 = Muscovite 041 = Paragonite 042 = Mont- morillonite 043 = Mont- morillonite-Na 044 = Nontronite 045 = Smectite-Fe 046 = Saponite 047 = Axinite 048 = Prehnite 049 = Pyrophyllite 050 = Topaz 051 = Chlorite 052 = Biotite 053 = Phlogopite 054 = Stilpnomelane 055 = Actinolite 056 = Amphibole- ML48 057 = Edenite 058 = Ferro- hornblende 059 = Hornblende 060 = Kaersutite 061 = Tschermakite 062 = Anthophyllite 063 = Gedrite 064 = Grunerite 065 = Holmquistite 066 = Mangano cummingtonite 067 = Arfvedsonite 068 = Glaucophane 069 = Riebeckite 070 = Antigorite 071 = Chrysotile072 = Lizardite 073 = Talc 074 = Clinozoisite 075 = Epidote 076 = Zoisite 077 = Tourmaline 078 = Cerussite 079 = Smithsonite 080 = Strontianite 081 = Witherite 082 = Azurite 083 = Malachite 084 = Ankerite 085 = Rhodochrosite 086 = Siderite 087 = Aragonite 088 = Calcite 089 = Dolomite 090 = Dolomite-Fe 091 = Magnesite 092 = Alunite-K 093 = Alunite-Na 094 = Barite 095 = Gypsum 096 = Jarosite 097 = Apatite 098 = Vonsenite 099 = Cassiterite 100 = Goethite 101 = Hematite 102 = Ilmenite 103 = Magnetite 104 = Chromite 105 = Gahnite 106 = Psilomelane 107 = Pyrolusite 108 = Rutile 109 = Palygorskite 163 substances 82 - OD Which wavelength region is best? What the HyLogger saw… 320 430 224 424 378 157 445 873 245 2084 380 85 374 602 319 531 328 457 318 693 327 376 306 391 306 583 295 623 TIR Summary Plots Showing approximate vertical relationships NE SW Feldspar Story • Absence of Albite (?) • HyLogger identified Plagioclase • Alkis revealed presence of Plagioclase • HyLogger maps Orthoclase and Microcline as distinct K-Feldspar species • Plotted the HyLogger results in a QAP diagram K-Feldspar in the TIR Orthoclase Microcline Mixtures compare slopes For the sake of modelling • Calculated single value per hole • Used “metres of mineral” as an approximation of abundance in a hole. • Wavelengths – used averages • Assays – used maximums Copper values Sericite and Chlorite Se ri ci te : D ec re as in g A l C h lo ri te : in cr ea si n g Fe K-Feldspar and Plagioclase Microcline Orthoclase Oligoclase Albite Feldspar Ratios O:M A:O QAP (modified) Biotite Out Distal Barren Core Ore Q – Quartz A – K-Feldspar P – Plagioclase From 1D to 2D • Next few slides depict cross sections derived from HyLogger data and presented in GoCAD • Blue is low number (wavelength or abundance). Red is a high number. Cu ppm Orthoclase Microcline Albite > An10 Scale: 3,000 m Illite Muscovite Phengite W2200 Scale: 3,000 m W2250 Fe-Chlorite Mg-Chlorite K/Al ratio Scale: 3,000 m Opportunities • Improve the sophistication of the quantification of mineralogy from TIR • Improve understanding of QAP (and similar tools) and limitations • Refine the TIR vectors • Undertake further transects to build 3D South Australian Experience • 2002 AMIRA Prototype – Emmie Bluff • Signature Holes – 2003 Hired Prototype – 1 month (1,000m/day) – 2005 Hired Prototype – 1 month • 2009 NCRIS/AuScope VSWIR HyLogger 2-3 • 2011 NCRIS/AuScope +TIR HyLogger 3-3 • 2016: 810 Openfile drillholes on SARIG/NVCL Projects • Significant scientific uptake • Cariewerloo Basin • Stuart Shelf IOCG-U – Olympic Dam – Emmie Bluff – Punt Hill – Hillside • Paris • DETCRC • Frome Embayment - U What has HyLogging revealed? • Every hole scanned delivers something new • 800 metre thick “monotonous red bed sandstone” is not monotonous at all. • Significant sections of Dickite, Kaolinite, Muscovite, Illite, Phengite and Paragonite whose geometry and spatial relationships required new thinking. Key Mineral Chemistry Gradients • Fe- Mg- content of Chlorite – A significant component of IOCG-U systems in the Olympic Domain • Al- content of White Mica – Muscovite, phengite, “paragonite” • Abundance gradients e.g. White Mica • K-Feldspar – Plagioclase - Quartz Future of Spectral Geology • One tray is a waste of time • One hole is interesting but really doesn’t do it • One section is a start • 3D model is where you want to be • Clusters of holes: where you start to appreciate the power of dense mineralogy Future of National Virtual Core Library • The HyLoggers were gifted to the States in order to effectively digitise their extensive drill core collections. • This work is only partly complete – there are at least 10 years more work in SA alone. • This task is ideally suited to HyLoggers. Acquisition speeds and data volumes are manageable. Current geological programs can be used to prioritise the work. • Internet is geared up to distribute the data efficiently • New knowledge is emerging from these repositories. Hyperspectral Technology… … has made its mark in the geological community. Surveys are providing free pre-competitive data. There is a growing desire to discover how it can assist exploration and deposit modelling. Current need for greater education – u-grad, post grad, professional development. Disclaimer www.minerals.statedevelopment.sa.gov.au The information contained in this presentation has been compiled by the Department of State Development (DSD) and originates from a variety of sources. Although all reasonable care has been taken in the preparation and compilation of the information, it has been provided in good faith for general information only and does not purport to be professional advice. No warranty, express or implied, is given as to the completeness, correctness, accuracy, reliability or currency of the materials. DSD and the Crown in the right of the State of South Australia does not accept responsibility for and will not be held liable to any recipient of the information for any loss or damage however caused (including negligence) which may be directly or indirectly suffered as a consequence of use of these materials. DSD reserves the right to update, amend or supplement the information from time to time at its discretion. HyLoggerTM is a trade mark of CSIRO <www.csiro.au/org/HyLoggingSystemsGroup.html> AuScope Ltd <www.auscope.org.au> is funded under the National Collaborative Research Infrastructure Strategy (NCRIS) an Australian Commonwealth Government Programme Contact www.minerals.statedevelopment.sa.gov.au Department of State Development Geological Survey of South Australia Level 4, 101 Grenfell Street Adelaide, South Australia 5000 GPO Box 320 Adelaide, South Australia 5001 T: +61 8 8463 3062 E: dsdreception@sa.gov.au
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