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padronização aula1 Tiluação do boráx com o HCl titulacao do NaOH com HCl vi vf delta v m borax n borax n HCl [HCL] [HCL]m vi vf delta v V HCl [NaOH] [NaOH]m 2.10 24.30 22.20 0.3805 0.0009977188 0.001995 0.0898845721 0.0898475407 1.10 10.80 9.70 10.00 0.09263 0.09200 0.50 23.00 22.50 0.3867 0.0010139759 0.002028 0.0901311937 2.20 12.00 9.80 10.00 0.09168 13.40 24.60 11.20 0.1912 0.0005013504 0.001003 0.0895268562 7.20 17.00 9.80 10.00 0.09168 titulaçao do acetato de etilo Preparacao da sol de HCl vi vf delta v toma HCl n HCl inicial n HCl excesso n NaOh neutralizado n acetato reagiu V acetato [acetato] [acetato]m MM borax 381.37 Vf n HCl m HCl puro m sol mãe V sol mãe pureza 4.00 11.40 7.40 10.00 0.0008985 0.0006808 0.0002177 0.0009782 10.00 0.09782 0.09936 ro 1.19 Kg/L 250.0 0.02500 0.9115 2.604 0.002188 35% 11.40 19.30 7.90 0.0007268 0.0001717 0.0010242 0.10242 MM Hcl 36.458 14.70 22.10 7.40 0.0006808 0.0002177 0.0009782 0.09782 C HCl 0.1 M padronização aula 2 Tiluação do boráx com o HCl titulacao do NaOH com HCl vi vf delta v m borax n borax n HCl [HCL] [HCL]m vi vf delta v V HCl [NaOH] [NaOH]m 3.30 13.60 10.30 0.1903 0.0004990 0.0009980 0.09689 0.09693 2.60 12.90 10.30 10.00 0.09411 0.09411 13.60 23.90 10.30 0.1908 0.0005003 0.0010006031 0.09715 12.90 23.20 10.30 10.00 0.09411 12.20 22.60 10.40 0.1919 0.0005032 0.0010063718 0.09677 MM borax 381.37 Preparacao da sol de HCl T 25.8 ro 1.19 Kg/L Vf n HCl m HCl puro m sol mãe V sol mãe pureza MM Hcl 36.458 400.0 0.04000 1.458 4.167 0.0035013685 35% C HCl 0.1 M padronização aula 3 [HCL]m titulacao do NaOH com HCl 0.0969346008 vi vf delta v V HCl [NaOH] [NaOH]m T 22.9 0.80 11.10 10.30 10.00 0.09411 0.09411 23.1 7.30 17.60 10.30 10.00 0.09411 20.1 19 [HCL]m titulacao do NaOH com HCl 0.0969346008 vi vf delta v V HCl [NaOH] [NaOH]m T 16.2 3.00 13.90 10.90 10.00 0.08893 0.08893 18.2 12.10 23.00 10.90 10.00 0.08893 padronização aula 4 [HCL]m titulacao do NaOH com HCl T 13.8 0.0969346008 vi vf delta v V HCl [NaOH] [NaOH]m 2.30 13.30 11.00 10.00 0.08812 0.08853 10.10 21.00 10.90 10.00 0.08893 Ensaio 1 T=26 T 25.8 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 12 9.70 0.0471 0 0.0496790087 0 0 15 9.66 0.0466 0.00891 0.049259766 0.0084390324 0.0004485799 16 9.63 0.0463 0.0156 0.0489453339 0.0147683066 0.0007899231 18 9.60 0.0460 0.0223 0.0486309018 0.0210975809 0.0011355615 20 9.56 0.0456 0.0312 0.048211659 0.0295366132 0.0016032357 22 9.52 0.0452 0.0401 0.0477924163 0.0379756456 0.0020788905 25 9.45 0.0444 0.0557 0.0470587415 0.0527439522 0.0029311137 28 9.40 0.0439 0.0668 0.046534688 0.0632927426 0.0035558357 30 9.36 0.0435 0.0757 0.0461154452 0.071731775 0.0040655471 34 9.30 0.0429 0.0891 0.0454865811 0.0843903235 0.0048472265 35 9.27 0.0426 0.0958 0.045172149 0.0907195978 0.0052459924 39 9.20 0.0418 0.1114 0.0444384742 0.1054879044 0.0061977485 43 9.13 0.0411 0.1269 0.0437047994 0.120256211 0.007180508 46 9.07 0.0405 0.1403 0.0430759352 0.1329147595 0.0080487143 48 9.04 0.0401 0.1470 0.0427615031 0.1392440338 0.0084921026 53 8.96 [NaOH] 0.09412 limitante 0.0393 0.1648 0.0419230176 0.1561220985 0.0097059814 55 8.92 [AcEt] 0.09936 0.0389 0.1737 0.0415037749 0.1645611308 0.0103307389 61 8.83 V NaOH (mL)-A 100.0 0.0379 0.1938 0.0405604786 0.1835489536 0.0117821571 66 8.75 V Acetato de etilo (mL)-B 100.0 0.0371 0.2116 0.0397219931 0.2004270183 0.0131282937 71 8.67 CA0(mol/L) 0.04706 0.0363 0.2294 0.0388835076 0.217305083 0.0145305583 79 8.56 CB0(mol/L) 0.04968 0.0351 0.2539 0.03773059 0.240512422 0.01655696 83 8.51 θ 1.056 0.0346 0.2650 0.0372065366 0.2510612124 0.0175181303 89 8.43 K0 9.70 9.01 0.0337 0.2829 0.036368051 0.2679392771 0.019111583 95 8.35 K∞ 5.21 0.0329 0.3007 0.0355295655 0.2848173418 0.0207775282 102 8.27 0.0321 0.3185 0.03469108 0.3016954066 0.0225210307 108 8.20 k 0.1024051576 0.0313 0.3341 0.0339574051 0.3164637132 0.024114565 116 8.11 0.0304 0.3541 0.0330141089 0.335451536 0.0262634414 123 8.03 0.0296 0.3719 0.0321756234 0.3523296007 0.0282751403 132 7.95 0.0287 0.3898 0.0313371379 0.3692076654 0.0303901245 143 7.86 0.0278 0.4098 0.0303938417 0.3881954881 0.0329031451 152 7.78 0.0269 0.4276 0.0295553562 0.4050735529 0.0352658414 163 7.69 0.0260 0.4477 0.0286120599 0.4240613756 0.0380820983 174 7.60 0.0250 0.4677 0.0276687637 0.4430491984 0.0410816462 186 7.51 0.0241 0.4878 0.0267254675 0.4620370212 0.0442829957 194 7.46 0.0236 0.4989 0.0262014141 0.4725858117 0.0461563665 208 7.36 0.0225 0.5212 0.0251533072 0.4936833925 0.0501256767 223 7.27 0.0216 0.5412 0.0242100109 0.5126712153 0.053976815 233 7.21 0.0210 0.5546 0.0235811468 0.5253297639 0.0567064161 245 7.14 0.0202 0.5702 0.022847472 0.5400980705 0.060070598 261 7.06 0.0194 0.5880 0.0220089864 0.5569761352 0.0641746655 280 6.97 0.0184 0.6080 0.0210656902 0.575963958 0.0691595568 302 6.87 0.0174 0.6303 0.0200175833 0.5970615388 0.075215807 325 6.78 0.0165 0.6503 0.0190742871 0.6160493616 0.0811993623 349 6.69 0.0155 0.6704 0.0181309909 0.6350371844 0.0877642065 370 6.59 0.0145 0.6927 0.017082884 0.6561347653 0.0958493445 412 6.49 0.0134 0.7149 0.0160347771 0.6772323462 0.1049133852 447 6.40 0.0125 0.7350 0.0150914809 0.696220169 0.1140637509 476 6.33 0.0117 0.7506 0.014357806 0.7109884756 0.1219445626 522 6.23 0.0107 0.7728 0.0133096991 0.7320860565 0.1345796945 553 6.17 0.0101 0.7862 0.012680835 0.744744605 0.1430731581 596 6.09 0.00922 0.8040 0.0118423495 0.7616226697 0.1556674345 663 5.99 0.00818 0.8263 0.0107942426 0.7827202506 0.1738789625 721 5.91 0.00734 0.8441 0.009955757 0.7995983153 0.1909063756 790 5.83 0.00650 0.8619 0.0091172715 0.81647638 0.2106978883 11.68 14.58 16.18 17.78 19.68 21.68 25.28 27.89 29.99 33.78 34.58 38.79 42.97 46 47.69 52.55 54.79 60.67 65.69 71.069999999999993 78.989999999999995 82.58 88.68 95.17 101.79 107.89 115.78 123.4 131.58000000000001 143.34 152.25 163.28 173.78 186.07 193.55 208.47 222.99 233.27 245.29 261.08 279.60000000000002 301.99 324.58 349.3 370 411.88 446.7 475.89 522.07000000000005 552.69000000000005 596.29999999999995 662.9 721 790 9.6999999999999993 9.66 9.6300000000000008 9.6 9.56 9.52 9.4499999999999993 9.4 9.36 9.3000000000000007 9.27 9.1999999999999993 9.1300000000000008 9.07 9.0399999999999991 8.9600000000000009 8.92 8.83 8.75 8.67 8.56 8.51 8.43 8.35 8.27 8.1999999999999993 8.11 8.0299999999999994 7.95 7.86 7.78 7.69 7.6 7.51 7.46 7.36 7.27 7.21 7.14 7.06 6.97 6.87 6.78 6.69 6.59 6.49 6.4 6.33 6.23 6.17 6.09 5.99 5.91 5.83 Tempo (s) Condutividade molar (ms) 11.68 14.58 16.18 17.78 19.68 21.68 25.28 27.89 29.99 33.78 34.58 38.79 42.97 46 47.69 52.55 54.79 60.67 65.69 71.069999999999993 78.989999999999995 82.58 88.68 95.17 101.79 107.89 115.78 123.4 131.58000000000001 143.34 152.25 163.28 173.78 186.07 193.55 208.47 222.99 233.27 245.29 261.08 279.60000000000002 301.99 324.58 349.3 370 411.88 446 .7 475.89 522.07000000000005 552.69000000000005 596.29999999999995 662.9 721 790 4.7059999999999998E-2 4.6640757238307358E-2 4.6326325167037871E-2 4.6011893095768377E-2 4.5592650334075731E-2 4.517340757238307E-2 4.443973273942093E-2 4.391567928730513E-2 4.349643652561247E-2 4.2867572383073503E-2 4.2553140311804009E-2 4.1819465478841869E-2 4.1085790645879749E-2 4.0456926503340762E-2 4.0142494432071268E-23.9304008908685982E-2 3.8884766146993321E-2 3.7941469933184861E-2 3.7102984409799554E-2 3.6264498886414254E-2 3.5111581291759474E-2 3.4587527839643653E-2 3.3749042316258353E-2 3.2910556792873052E-2 3.2072071269487752E-2 3.1338396436525605E-2 3.0395100222717145E-2 2.9556614699331844E-2 2.8718129175946554E-2 2.7 77483296213809 1E-2 2.693634743875279E-2 2.5993051224944327E-2 2.5049755011135856E-2 2.4106458797327392E-2 2.3582405345211586E-2 2.2534298440979962E-2 2.1591002227171488E-2 2.0962138084632518E-2 2.0228463251670378E-2 1.9389977728285077E-2 1.8446681514476614E-2 1.7398574610244993E-2 1.645527839643653E-2 1.5511982182628068E-2 1.4463875278396437E-2 1.3415768374164815E-2 1.2472472160356353E-2 1.1738797327394211E-2 1.0690690423162589E-2 1.0061826280623609E-2 9.2233407572383068E-3 8.1752338530066849E-3 7.3367483296213837E-3 6.4982628062360817E-3 Tempo (s) [NaOH] (mol/L) 11.68 14.58 16.18 17.78 19.68 21.68 25.28 27.89 29.99 33.78 34.58 38.79 42.97 46 47.69 52.55 54.79 60.67 65.69 71.069999999999993 78.989999999999995 82.58 88.68 95.17 101.79 107.89 115.78 123.4 131.58000000000001 143.34 152.25 163.28 173.78 186.07 193.55 208.47 222.99 233.27 245.29 261.08 279.60000000000002 301.99 324.58 349.3 370 411.88 446.7 475.89 522.07000000000005 552.69000000000005 596.29999999999995 662.9 721 790 0 4.4857993051810214E-4 7.8992308736581867E-4 1.135561534513378E-3 1.6032357111816786E-3 2.0788905114851571E-3 2.9311137001709659E-3 3.555835677612158E-3 4.0655470657817456E-3 4.8472264872717495E-3 5.2459923888450721E-3 6.1977485145947482E-3 7.1805079595050562E-3 8.0487142581099035E-3 8.4921026360272253E-3 9.705981425411488E-3 1.0330738893959045E-2 1.1782157118770247E-2 1.3128293743092002E-2 1.4530558329630253E-2 1.6556960004547941E-2 1.7518130341930602E-2 1.9111582953813818E-2 2.0777528213494736E-2 2.2521030726221344E-2 2.4114565010433481E-2 2.6263441376995555E-2 2.8275140311951028E-2 3.0390124533847547E-2 3.2903145059853679E-2 3.526584140607987E-2 3.8082098281041948E-2 4.1081646183999031E-2 4.4282995660888357E-2 4.6156366546372889E-2 5.0125676702954321E-2 5.3976815023563003E-2 5.670641606224474E-2 6.00705980315306E-2 6.4174665531672365E-2 6.9159556800408847E-2 7.5215807030243956E-2 8.1199362256222554E-2 8.7764206499926153E-2 9.5849344456430355E-2 0.1049133851585896 0.11406375091504302 0.12194456255039597 0.13457969447815857 0.1430731580662673 0.15566743451095424 0.17387896252844076 0.1909063756439785 0.21069788827225178 Tempo (s) Ln((θ-XB)/(θ(1-XB))) Ensaio 2 T=26 12/13/22 16:18 T 26 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 13 9.48 0.0421 0.04784689 0.0475610661 0.0426325452 0.0048412437 16 9.44 0.0417 0.05742 0.0471374776 0.0511590542 0.0058587139 19 9.4 0.0413 0.0670 0.0467138891 0.0596855633 0.006893574 21 9.36 0.0409 0.0766 0.0462903006 0.0682120723 0.0079462741 24 9.32 0.0405 0.0861 0.0458667121 0.0767385813 0.0090172801 26 9.27 0.0399 0.0981 0.0453372264 0.0873967176 0.0103825167 29 9.22 0.0394 0.1100 0.0448077408 0.0980548539 0.0117780911 32 9.17 0.0389 0.1220 0.0442782551 0.1087129902 0.0132050273 35 9.12 0.0383 0.1340 0.0437487695 0.1193711265 0.0146643959 39 9.07 0.0378 0.1459 0.0432192838 0.1300292628 0.0161573169 42 9.02 0.0373 0.1579 0.0426897982 0.1406873991 0.0176849627 46 8.95 0.0365 0.1746 0.0419485183 0.1556087899 0.019884353 51 8.88 0.0358 0.1914 0.0412072384 0.1705301807 0.0221577831 56 8.81 0.0351 0.2081 0.0404659585 0.1854515716 0.0245090621 60 8.74 0.0343 0.2249 0.0397246786 0.2003729624 0.026942265 66 8.67 [NaOH] 0.08853 limitante 0.0336 0.2416 0.0389833987 0.2152943532 0.0294617571 71 8.6 [AcEt] 0.09936 0.0328 0.2584 0.0382421188 0.230215744 0.0320722197 76 8.53 V NaOH (mL)-A 100.0 0.0321 0.2751 0.0375008389 0.2451371348 0.0347786798 82 8.46 V Acetato de etilo (mL)-B 100.0 0.0313 0.2919 0.036759559 0.2600585256 0.0375865424 89 8.39 CA0(mol/L) 0.044265 0.0306 0.3086 0.036018279 0.2749799165 0.0405016268 95 8.32 CB0(mol/L) 0.04968 0.0299 0.3254 0.0352769991 0.2899013073 0.0435302074 102 8.25 θ 1.122 0.0291 0.3421 0.0345357192 0.3048226981 0.0466790588 108 8.18 K0 9.68 9.01 0.0284 0.3589 0.0337944393 0.3197440889 0.049955507 116 8.1 K∞ 5.5 0.0275 0.3780 0.0329472623 0.336797107 0.0538664691 123 8.03 0.0268 0.3947 0.0322059824 0.3517184978 0.0574439253 133 7.95 k 0.0799038241 0.0259 0.4139 0.0313588054 0.3687715159 0.0617227059 144 7.87 0.0251 0.4330 0.0305116283 0.3858245339 0.0662193199 155 7.79 0.0243 0.4522 0.0296644513 0.402877552 0.0709508857 166 7.71 0.0234 0.4713 0.0288172743 0.4199305701 0.0759363693 176 7.63 0.0226 0.4904 0.0279700972 0.4369835882 0.0811968412 190 7.55 0.0217 0.5096 0.0271229202 0.4540366062 0.0867557775 203 7.47 0.0209 0.5287 0.0262757432 0.4710896243 0.0926394145 217 7.39 0.0200 0.5478 0.0254285661 0.4881426424 0.0988771685 232 7.31 0.0192 0.5670 0.0245813891 0.5051956605 0.1055021342 247 7.23 0.0183 0.5861 0.0237342121 0.5222486785 0.112551681 265 7.15 0.0175 0.6053 0.022887035 0.5393016966 0.1200681694 284 7.07 0.0166 0.6244 0.022039858 0.5563547147 0.1280998169 304 6.99 0.0158 0.6435 0.021192681 0.5734077328 0.136701752 327 6.91 0.0149 0.6627 0.0203455039 0.5904607508 0.1459373057 351 6.83 0.0141 0.6818 0.0194983269 0.6075137689 0.1558796049 376 6.75 0.0132 0.7010 0.0186511499 0.624566787 0.1666135552 405 6.67 0.0124 0.7201 0.0178039728 0.6416198051 0.1782383289 438 6.59 0.0115 0.7392 0.0169567958 0.6586728231 0.1908705162 472 6.51 0.0107 0.7584 0.0161096188 0.6757258412 0.2046481567 509 6.43 0.0098 0.7775 0.0152624417 0.6927788593 0.2197359555 558 6.35 0.0090 0.7967 0.0144152647 0.7098318773 0.2363321141 606 6.27 0.0082 0.8158 0.0135680877 0.7268848954 0.2546773969 664 6.19 0.0073 0.8349 0.0127209106 0.7439379135 0.2750673464 738 6.11 0.0065 0.8541 0.0118737336 0.7609909316 0.2978690168 956 5.93 0.0046 0.8971 0.0099675853 0.7993602222 0.360594449 1086 5.85 0.00371 0.9163 0.0091204082 0.8164132403 0.3951689029 1270 5.77 0.00286 0.9354 0.0082732312 0.8334662584 0.4352963299 1527 5.69 0.00201 0.9545 0.0074260542 0.8505192765 0.482473129 13 16 19 21 24 26 29 32 35 39 42 46 51 56 60 66 71 76 82 89 95 102 108 116 123 133 144 155 166 176 190 203 217 232 247 265 284 304 327 351 376 405 438 472 509 558 606 664 738 956 1086 1270 1527 9.48 9.44 9.4 9.36 9.32 9.27 9.2200000000000006 9.17 9.1199999999999992 9.07 9.02 8.9499999999999993 8.8800000000000008 8.81 8.74 8.67 8.6 8.5299999999999994 8.4600000000000009 8.39 8.32 8.25 8.18 8.1 8.0299999999999994 7.95 7.87 7.79 7.71 7.63 7.55 7.47 7.39 7.31 7.23 7.15 7.07 6.99 6.91 6.83 6.75 6.67 6.59 6.51 6.43 6.35 6.27 6.19 6.11 5.93 5.85 5.77 5.69 Tempo (s) Condutividade molar (ms) 13 16 19 21 24 26 29 32 35 39 42 46 51 56 60 66 71 76 82 89 95 102 108 116 123 133 144 155 166 176 190 203 217 232 247 265 284 304 327 351 376 405 438 472 509 558 606 664 738 956 1086 1270 1527 4.214705 7416267952E-2 4.1723468899521526E-2 4.1299880382775121E-2 4.0876291866028702E-2 4.0452703349282297E-2 3.9923217703349279E-2 3.9393732057416274E-2 3.8864246411483255E-2 3.833476076555023E-2 3.7805275119617225E-2 3.7275789473684207E-2 3.6534509569377989E-2 3.5793229665071778E-2 3.5051949760765561E-2 3.4310669856459336E-2 3.3569389952153111E-2 3.2828110047846887E-2 3.2086830143540662E-2 3.1345550239234458E-2 3.0604270334928237E-2 2.9862990430622013E-2 2.9121710526315792E-2 2.838043062200957E-2 2.7533253588516743E-2 2.6791973684210522E-2 2.5944796650717708E-2 2.509761961722488E-2 2.4250442583732056E-2 2.3403265550239236E-22.2556088516746411E-2 2.1708911483253587E-2 2.0861734449760763E-2 2.0014557416267943E-2 1.9167380382775115E-2 1.8320203349282301E-2 1.7473026315789477E-2 1.66258 49282296653E-2 1.5778672248803832E-2 1.4931495215311006E-2 1.4084318181818184E-2 1.3237141148325358E-2 1.2389964114832536E-2 1.1542787081339712E-2 1.0695610047846887E-2 9.8484330143540633E-3 9.0012559808612409E-3 8.1540789473684167E-3 7.306901913875603E-3 6.4597248803827789E-3 4.5535765550239211E-3 3.7063995215310969E-3 2.8592224880382732E-3 2.0120454545454586E-3 Tempo (s) [NaOH] (mol/L) 13 16 19 21 24 26 29 32 35 39 42 46 51 56 60 66 71 76 82 89 95 102 108 116 123 133 144 155 166 176 190 203 217 232 247 265 284 304 327 351 376 405 438 472 509 558 606 4.8412436830997671E-3 5.8587139410656098E-3 6.8935739881324292E-3 7.9462740541341795E-3 9.0172800665195337E-3 1.038251671651616E-2 1.1778091123169378E-2 1.3205027284534928E-2 1.4664395872691704E-2 1.6157316927485729E-2 1.7684962739291942E-2 1.9884352958862084E-2 2.2157783105261716E-2 2.4509062071845132E-2 2.6942265014008971E-2 2.9461757070286202E-2 3.207221966997386E-2 3.4778679763031152E-2 3.7586542358827184E-2 4.0501626820006964E-2 4.3530207428014202E-2 4.6679058819825904E-2 4.9955506993790533E-2 5.3866469140218767E-2 5.7443925262617601E-2 6.1722705949241487E-2 6.6219319917626987E-2 7.0950885697742258E-2 7.5936369306533802E-2 8.1196841197417866E-2 8.6755777465147468E-2 9.2639414492655281E-2 9.8877168480365596E-2 0.10550213419652681 0.11255168104131884 0.12006816941963809 0.12809981687291325 0.13670175199848889 0.14593730569481628 0.15587960487485164 0.1 6661355518290699 0.17823832893470234 0.19087051623150647 0.2046481567035543 0.21973595550779312 0.23633211412276817 0.25467739693808505 Tempo (s) Ln((θ-XB)/(θ(1-XB))) Ensaio 1 T=24 T 22.9 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 10.98 9.16 0.0455822705 0.0314009662 0.0482012792 0.0297455506 0.001614915 11.88 9.13 0.045241256 0.038647343 0.0478602648 0.0366099085 0.0020013628 14.48 9.09 0.04478657 0.0483091787 0.0474055788 0.0457623856 0.0025250369 17.58 9.04 0.0442182126 0.0603864734 0.0468372213 0.057202982 0.0031935288 21.48 8.98 0.0435361836 0.0748792271 0.0461551923 0.0709316976 0.0040168369 22.08 8.97 0.0434225121 0.077294686 0.0460415208 0.0732198169 0.0041563591 24.88 8.93 0.0429678261 0.0869565217 0.0455868348 0.082372294 0.0047212072 28.18 8.88 0.0423994686 0.0990338164 0.0450184773 0.0938128904 0.0054428482 31.68 8.83 0.0418311111 0.1111111111 0.0444501198 0.1052534868 0.0061824031 35.98 8.77 0.0411490821 0.1256038647 0.0437680908 0.1189822025 0.0070944689 39.48 8.71 0.0404670531 0.1400966184 0.0430860619 0.1327109182 0.0080345388 43.28 8.65 0.0397850242 0.154589372 0.0424040329 0.1464396338 0.009003923 48.48 8.59 0.0391029952 0.1690821256 0.0417220039 0.1601683495 0.0100040149 53.18 8.52 0.0383072947 0.1859903382 0.0409263034 0.1761851845 0.0112115839 59.28 8.45 0.0375115942 0.2028985507 0.0401306029 0.1922020194 0.0124654955 64.68 8.38 [NaOH] 0.09412 limitante 0.0367158937 0.2198067633 0.0393349024 0.2082188544 0.0137684706 70.98 8.3 [AcEt] 0.0993580174 0.0358065217 0.2391304348 0.0384255305 0.2265238086 0.015321443 77.08 8.23 V NaOH (mL)-A 100 0.0350108213 0.2560386473 0.03762983 0.2425406435 0.016739757 83.28 8.16 V Acetato de etilo (mL)-B 100 0.0342151208 0.2729468599 0.0368341295 0.2585574785 0.0182172079 89.68 8.09 CA0(mol/L) 0.04706 0.0334194203 0.2898550725 0.036038429 0.2745743135 0.0197575747 96.98 8.02 CB0(mol/L) 0.0496790087 0.0326237198 0.306763285 0.0352427285 0.2905911484 0.0213649655 104.18 7.95 θ 1.0556525438 0.0318280193 0.3236714976 0.034447028 0.3066079834 0.0230438545 113.98 7.87 K0 9.29 0.0309186473 0.3429951691 0.0335376561 0.3249129376 0.0250564159 123.58 7.79 K∞ 5.15 0.0300092754 0.3623188406 0.0326282841 0.3432178918 0.0271767739 132.78 7.71 0.0290999034 0.3816425121 0.0317189121 0.361522846 0.0294138328 141.68 7.64 k 0.0960286993 0.0283042029 0.3985507246 0.0309232116 0.377539681 0.031474756 151.98 7.56 0.0273948309 0.4178743961 0.0300138396 0.3958446352 0.0339582531 162.58 7.48 0.0264854589 0.4371980676 0.0291044676 0.4141495895 0.0365902039 175.88 7.39 0.0254624155 0.4589371981 0.0280814242 0.434742663 0.0397457601 189.68 7.3 0.024439372 0.4806763285 0.0270583807 0.4553357365 0.0431288528 203.48 7.22 0.02353 0.5 0.0261490087 0.4736406907 0.046347636 220.78 7.12 0.022393285 0.5241545894 0.0250122937 0.4965218835 0.0506838361 237.58 7.03 0.0213702415 0.5458937198 0.0239892503 0.517114957 0.0549195735 257.08 6.94 0.0203471981 0.5676328502 0.0229662068 0.5377080305 0.0595123586 276.48 6.85 0.0193241546 0.5893719807 0.0219431633 0.558301104 0.0645093788 298.68 6.76 0.0183011111 0.6111111111 0.0209201198 0.5788941775 0.0699665304 321.28 6.67 0.0172780676 0.6328502415 0.0198970763 0.599487251 0.0759505287 345.98 6.59 0.0163686957 0.652173913 0.0189877044 0.6177922053 0.0817764711 369.88 6.51 0.0154593237 0.6714975845 0.0180783324 0.6360971595 0.0881495308 400.68 6.42 0.0144362802 0.693236715 0.0170552889 0.656690233 0.0960747023 435.48 6.33 0.0134132367 0.7149758454 0.0160322454 0.6772833065 0.1049366081 468.78 6.25 0.0125038647 0.7342995169 0.0151228734 0.6955882607 0.1137422885 508.88 6.17 0.0115944928 0.7536231884 0.0142135015 0.713893215 0.1235825565 556.78 6.08 0.0105714493 0.7753623188 0.013190458 0.7344862885 0.1361333343 614.98 5.99 0.0095484058 0.7971014493 0.0121674145 0.755079362 0.1505979256 677.68 5.9 0.0085253623 0.8188405797 0.011144371 0.7756724355 0.1674521331 740.68 5.82 0.0076159903 0.8381642512 0.0102349991 0.7939773897 0.1849588426 826.18 5.73 0.0065929469 0.8599033816 0.0092119556 0.8145704632 0.208303404 917.68 5.65 0.0056835749 0.8792270531 0.0083025836 0.8328754175 0.2332732002 10.98 11.88 14.48 17.579999999999998 21.48 22.08 24.88 28.18 31.68 35.979999999999997 39.479999999999997 43.28 48.48 53.18 59.28 64.680000000000007 70.98 77.08 83.28 89.68 96.98 104.18 113.98 123.58 132.78 141.68 151.97999999999999 162.58000000000001 175.88 189.68 203.48 220.78 237.58 257.08 276.48 298.68 321.27999999999997 345.98 369.88 400.68 435.48 468.78 508.88 556.78 614.98 677.68 740.68 826.18 917.68 9.16 9.1300000000000008 9.09 9.0399999999999991 8.98 8.9700000000000006 8.93 8.8800000000000008 8.83 8.77 8.7100000000000009 8.65 8.59 8.52 8.4499999999999993 8.3800000000000008 8.3000000000000007 8.23 8.16 8.09 8.02 7.95 7.87 7.79 7.71 7.64 7.56 7.48 7.39 7.3 7.22 7.12 7.03 6.94 6.85 6.76 6.67 6.59 6.51 6.42 6.33 6.25 6.17 6.08 5.99 5.9 5.82 5.73 5.65 Tempo (s) Condutividade molar (ms) 10.98 11.88 14.48 17.579999999999998 21.48 22.08 24.88 28.18 31.68 35.979999999999997 39.479999999999997 43.28 48.48 53.18 59.28 64.680000000000007 70.98 77.08 83.28 89.68 96.98 104.18 113.98 123.58 132.78 141.68 151.97999999999999 162.58000000000001 175.88 189.68 203.48 220.78 237.58 257.08 276.48 298.68 321.27999999999997 345.98 369.88 400.68 435.48 468.78 508.88 556.78 614.98 677.68 740.68 826.18 917.68 4.5582270531400973E-2 4.5241256038647357E-2 4.4786570048309181E-2 4.4218212560386466E-2 4.3536183574879241E-2 4.3422512077294702E-2 4.2967826086956519E-2 4.2399468599033832E-2 4.1831111111111118E-2 4.1149082125603871E-2 4.0467053140096632E-2 3.9785024154589378E-2 3.9102995169082132E-2 3.830729468599034E-2 3.7511594202898547E-2 3.6715893719806776E-2 3.5806521739130445E-2 3.5010821256038653E-2 3.4215120772946861E-2 3.3419420289855076E-2 3.2623719806763284E-2 3.1828019323671498E-2 3.0918647342995174E-2 3.000927536231884E-22.9099903381642516E-2 2.8304202898550724E-2 2.7394830917874397E-2 2.6485458937198073E-2 2.5462415458937196E-2 2.4439371980676326E-2 2.3529999999999999E-2 2.239328502415459E-2 2.1370241545893724E-2 2.0347198067632855E-2 1.9324154589371978E- 2 1.830 1111111111108E-2 1.7278067632850242E-2 1.6368695652173911E-2 1.5459323671497582E-2 1.4436280193236712E-2 1.3413236714975844E-2 1.2503864734299517E-2 1.1594492753623186E-2 1.0571449275362318E-2 9.5484057971014502E-3 8.5253623188405823E-3 7.6159903381642522E-3 6.5929468599033843E-3 5.6835748792270543E-3 Tempo (s) [NaOH] (mol/L) 10.98 11.88 14.48 17.579999999999998 21.48 22.08 24.88 28.18 31.68 35.979999999999997 39.479999999999997 43.28 48.48 53.18 59.28 64.680000000000007 70.98 77.08 83.28 89.68 96.98 104.18 113.98 123.58 132.78 141.68 151.97999999999999 162.58000000000001 175.88 189.68 203.48 220.78 237.58 257.08 276.48 298.68 321.27999999999997 345.98 369.88 400.68 435.48 468.78 508.88 556.78 614.98 677.68 740.68 826.18 917.68 1.6149150050768727E-3 2.0013628155537443E-3 2.5250368808497131E-3 3.1935288212333029E-3 4.0168368786318237E-3 4.1563591419129268E-3 4.7212072 414686652E-3 5.4428482129842744E-3 6.1824030647230927E-3 7.0944688936255794E-3 8.0345387633605041E-3 9.0039229709212749E-3 1.0004014881180717E-2 1.1211583868921692E-2 1.2465495468541301E-2 1.3768470636359257E-2 1.5321442992033666E-2 1.6739757025058213E-2 1.8217207903104781E-2 1.975757467406079E-2 2.1364965542172907E-2 2.30438545209369E-2 2.5056415891511738E-2 2.7176773906124739E-2 2.941383275565872E-2 3.1474756027299648E-2 3.3958253101997855E-2 3.6590203898492504E-2 3.9745760107489224E-2 4.3128852833134002E-2 4.6347635983439349E-2 5.0683836113649211E-2 5.4919573490789457E-2 5.9512358628083663E-2 6.4509378752298424E-2 6.996653036781128E-2 7.5950528723305613E-2 8.1776471133357079E-2 8.8149530825244307E-2 9.6 074702275765173E-2 0.10493660806422379 0.11374228847360637 0.12358255650186629 0.13613333430844998 0.15059792563172861 0.16745213307995069 0.18495884258463946 0.20830340402435471 0.23327320016068906 Tempo (s) Ln((θ-XB)/(θ(1-XB))) Ensaio 2 T=24 T 23.1 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 11.7 9.16 0.0455786925 0.0314769976 0.0481977012 0.0298175737 0.0016189421 15.9 9.12 0.0451229056 0.0411622276 0.0477419143 0.0389922118 0.0021367362 19.1 9.08 0.0446671186 0.0508474576 0.0472861274 0.0481668499 0.0026642365 21.4 9.04 0.0442113317 0.0605326877 0.0468303404 0.057341488 0.0032017186 23.7 9 0.0437555448 0.0702179177 0.0463745535 0.0665161261 0.0037494685 27.4 8.95 0.0431858111 0.0823244552 0.0458048199 0.0779844237 0.0044490488 31.1 8.89 0.0425021308 0.0968523002 0.0451211395 0.0917463808 0.005311192 34.6 8.84 0.0419323971 0.1089588378 0.0445514058 0.1032146784 0.006049267 38.5 8.78 0.0412487167 0.1234866828 0.0438677254 0.1169766355 0.0069595128 43.8 8.71 0.0404510896 0.1404358354 0.0430700983 0.1330322521 0.0080568878 48.8 8.64 0.0396534625 0.1573849879 0.0422724712 0.1490878687 0.0091944032 54 8.57 0.0388558354 0.1743341404 0.0414748441 0.1651434854 0.010374303 58.9 8.5 0.0380582082 0.191283293 0.0406772169 0.181199102 0.0115990021 60.5 8.43 0.0372605811 0.2082324455 0.0398795898 0.1972547186 0.0128711022 70.3 8.36 0.036462954 0.2251815981 0.0390819627 0.2133103353 0.0141934107 76.2 8.29 [NaOH] 0.09412 limitante 0.0356653269 0.2421307506 0.0382843356 0.2293659519 0.0155689612 83.2 8.21 [AcEt] 0.0993580174 0.034753753 0.2615012107 0.0373727617 0.2477152281 0.017210437 89.9 8.14 V NaOH (mL)-A 100 0.0339561259 0.2784503632 0.0365751346 0.2637708447 0.0187114876 96.2 8.07 V Acetato de etilo (mL)-B 100 0.0331584988 0.2953995157 0.0357775075 0.2798264613 0.020277065 103.4 8 CA0(mol/L) 0.04706 0.0323608717 0.3123486683 0.0349798804 0.295882078 0.0219114234 110.8 7.93 CB0(mol/L) 0.0496790087 0.0315632446 0.3292978208 0.0341822533 0.3119376946 0.0236191995 120.1 7.86 θ 1.0556525438 0.0307656174 0.3462469734 0.0333846261 0.3279933112 0.0254054568 128.1 7.79 K0 9.29 0.0299679903 0.3631961259 0.032586999 0.3440489279 0.0272757356 135.1 7.73 K∞ 5.16 0.0292843099 0.3777239709 0.0319033186 0.357810885 0.0289502946 144.9 7.66 0.0284866828 0.3946731235 0.0311056915 0.3738665016 0.0309931823 151.3 7.6 k 0.0965632527 0.0278030024 0.4092009685 0.0304220111 0.3876284587 0.0328259359 160.9 7.53 0.0270053753 0.4261501211 0.029624384 0.4036840754 0.0350664973 169.4 7.47 0.0263216949 0.4406779661 0.0289407036 0.4174460325 0.0370809865 177.8 7.41 0.0256380145 0.4552058111 0.0282570232 0.4312079896 0.0391886087 187.1 7.35 0.0249543341 0.4697336562 0.0275733429 0.4449699467 0.0413959802 198.5 7.28 0.024156707 0.4866828087 0.0267757157 0.4610255633 0.0441070423 210.7 7.21 0.0233590799 0.5036319613 0.0259780886 0.47708118 0.0469765663 222.5 7.14 0.0225614528 0.5205811138 0.0251804615 0.4931367966 0.0500188767 233.9 7.08 0.0218777724 0.5351089588 0.0244967811 0.5068987537 0.0527762498 245.8 7.02 0.021194092 0.5496368039 0.0238131007 0.5206607108 0.0556837059 261.1 6.95 0.0203964649 0.5665859564 0.0230154736 0.5367163275 0.0592823276 273.9 6.89 0.0197127845 0.5811138015 0.0223317932 0.5504782846 0.062560174 287.7 6.83 0.0190291041 0.5956416465 0.0216481128 0.5642402417 0.0660333155 304.2 6.76 0.018231477 0.612590799 0.0208504857 0.5802958583 0.0703562999 321.9 6.69 0.0174338499 0.6295399516 0.0200528586 0.596351475 0.075002306 347.9 6.6 0.0164083293 0.6513317191 0.019027338 0.6169944107 0.0815116864 374.7 6.51 0.0153828087 0.6731234867 0.0180018174 0.6376373463 0.0887131728 409.4 6.41 0.0142433414 0.6973365617 0.0168623501 0.6605739415 0.0976695097 442.1 6.32 0.0132178208 0.7191283293 0.0158368295 0.6812168772 0.1067498971 477.5 6.24 0.012306247 0.7384987893 0.0149252557 0.6995661533 0.1157866851 519.9 6.14 0.0111667797 0.7627118644 0.0137857884 0.7225027485 0.1286220954 571.9 6.05 0.0101412591 0.784503632 0.0127602678 0.7431456842 0.1419582595 622.7 5.96 0.0091157385 0.8062953995 0.0117347472 0.7637886199 0.1574014965 680.7 5.87 0.0080902179 0.8280871671 0.0107092266 0.7844315555 0.175496376 747.7 5.78 0.0070646973 0.8498789346 0.009683706 0.8050744912 0.1969938792 827.1 5.69 0.0060391768 0.8716707022 0.0086581855 0.8257174269 0.2229601028 902.4 5.61 0.0051276029 0.8910411622 0.0077466116 0.844066703 0.2510433499 11.7 15.9 19.100000000000001 21.4 23.7 27.4 31.1 34.6 38.5 43.8 48.8 54 58.9 60.5 70.3 76.2 83.2 89.9 96.2 103.4 110.8 120.1 128.1 135.1 144.9 151.30000000000001 160.9 169.4 177.8 187.1 198.5 210.7 222.5 233.9 245.8 261.10000000000002 273.89999999999998 287.7 304.2 321.89999999999998 347.9 374.7 409.4 442.1 477.5 519.9 571.9 622.70000000000005 680.7 747.7 1.6189421263938793E-3 2.13673624348615 07E-3 2.6642365378891242E-3 3.2017185842511059E-3 3.749468491866346E-3 4.4490488439863788E-3 5.3111920376517404E-3 6.0492669528790502E-3 6.9595127870655249E-3 8.0568878404904103E-3 9.1944031776106088E-3 1.0374303011536504E-2 1.1599002090080603E-2 1.2871102213979625E-2 1.4193410713775815E-2 1.5568961161889631E-2 1.7210436983432779E-2 1.871148761414293E-2 2.0277064996875697E-2 2.1911423363682243E-2 2.3619199516190834E-2 2.5405456841843501E-2 2.727573555378358E-2 2.8950294568471629E-2 3.0993182279715491E-2 3.2825935861081373E-2 3.5066497310147653E-2 3.7080986539172356E-2 3.9188608705750333E-2 4.1395980178680722E-2 4.4107042282296012E-2 4.6976566328680344E-2 5.0018876677106194E-2 5.2776249825289903E-2 5.5683705892694751E-2 5.928232762244813E-2 6.2560173982575865E-2 6.6033315538951809E-27.0356299939831848E-2 7.500230604290474E-2 8.1511686427297558E-2 8.8713172757989428E-2 9.7669509672236435E-2 0.10674989706522869 0.11578668512452518 0.12862209535522828 0.14195825948631943 0.15740149646346932 0.17549637601374138 tempo (s) Ln((θ-XB)/(θ(1-XB))) 11.7 15.9 19.100000000000001 21.4 23.7 27.4 31.1 34.6 38.5 43.8 48.8 54 58.9 60.5 70.3 76.2 83.2 89.9 96.2 103.4 110.8 120.1 128.1 135.1 144.9 151.30000000000001 160.9 169.4 177.8 187.1 198.5 210.7 222.5 233.9 245.8 261.10000000000002 273.89999999999998 287.7 304.2 321.89999999999998 347.9 374.7 409.4 442.1 477.5 519.9 571.9 622.70000000000005 680.7 747.7 827.1 902.4 9.16 9.1199999999999992 9.08 9.0399999999999991 9 8.9499999999999993 8.89 8.84 8.7799999999999994 8.7100000000000009 8.64 8.57 8.5 8.43 8.36 8.2899999999999991 8.2100000000000009 8.14 8.07 8 7.93 7.86 7.79 7.73 7.66 7.6 7.53 7.47 7.41 7.35 7.28 7.21 7.14 7.08 7.02 6.95 6.89 6.83 6.76 6.69 6.6 6.51 6.41 6.32 6.24 6.14 6.05 5.96 5.87 5.78 5.69 5.61 Tempo (s) Condutividade molar (ms) 11.7 15.9 19.100000000000001 21.4 23.7 27.4 31.1 34.6 38.5 43.8 48.8 54 58.9 60.5 70.3 76.2 83.2 89.9 96.2 103.4 110.8 120.1 128.1 135.1 144.9 151.30000000000001 160.9 169.4 177.8 187.1 198.5 210.7 222.5 233.9 245.8 261.10000000000002 273.89999999999998 287.7 304.2 321.89999999999998 347.9 374.7 409.4 442.1 477.5 519.9 571.9 622.7 0000000000005 680.7 747.7 827.1 902.4 4.5578692493946742E-2 4.5122905569007263E-2 4.4667118644067805E-2 4.4211331719128326E-2 4.3755544794188868E-2 4.3185811138014528E-2 4.2502130750605341E-2 4.1932397094431001E-2 4.1248716707021793E-2 4.0451089588377745E-2 3.9653462469733669E-2 3.8855835351089593E-2 3.8058208232445524E-2 3.7260581113801455E-2 3.6462953995157379E-2 3.5665326876513311E-2 3.4753753026634401E-2 3.3956125907990325E-2 3.3158498789346257E-2 3.2360871670702188E-2 3.1563244552058112E-2 3.076561743341405E-2 2.9967990314769977E-2 2.928430992736078E-2 2.8486682808716711E-2 2.7803002421307507E-2 2.7005375302663448E-2 2.632169491525424E-2 2.5638014527845043E-2 2.4954334140435835E-2 2.4156707021791773E-2 2.3359079903 1477E-2 2.2561452784503631E-2 2.1877772397094434E-2 2.1194092009685229E-2 2.0396464891041167E-2 1.971278450363196E-2 1.9029104116222762E-2 1.823147699757869E-2 1.7433849878934631E-2 1.6408329297820823E-2 1.538280871670702E-2 1.4243341404358355E-2 1.3217820823244556E-2 1.2306246973365621E-2 1.1166779661016946E-2 1.0141259079903146E-2 9.1157384987893449E-3 8.0902179176755469E-3 7.0646973365617463E-3 6.0391767554479458E-3 5.1276029055690106E-3 Tempo (s) [NaOH] (mol/L) Ensaio 1 T=21 T 20.2 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 1/CA 11 8.79 0.04706 0 0.0496790087 0 0 -3.0563318957 17 8.75 0.0465206304 0.0114613181 0.0491396391 0.0108570932 0.0005784861 -3.0678594009 21 8.70 0.0458464183 0.0257879656 0.0484654271 0.0244284597 0.0013192117 -3.0824582003 25 8.66 0.0453070487 0.0372492837 0.0479260574 0.0352855529 0.0019263881 -3.0942926579 29 8.61 0.0446328367 0.0515759312 0.0472518454 0.0488569194 0.0027043125 -3.1092854425 33 8.56 0.0439586246 0.0659025788 0.0465776334 0.0624282859 0.0035041267 -3.1245064365 36 8.52 0.043419255 0.0773638968 0.0460382637 0.0732853791 0.0041603668 -3.1368522723 42 8.46 0.0426102006 0.0945558739 0.0452292093 0.0895710189 0.0051732281 -3.1556616043 47 8.40 0.0418011461 0.111747851 0.0444201548 0.1058566587 0.0062219037 -3.1748315204 52 8.35 0.0411269341 0.1260744986 0.0437459428 0.1194280252 0.0071245497 -3.1910920413 57 8.29 0.0403178797 0.1432664756 0.0429368884 0.135713665 0.0082440109 -3.2109602445 63 8.23 0.0395088252 0.1604584527 0.0421278339 0.1519993048 0.0094051454 -3.2312312089 69 8.17 0.0386997708 0.1776504298 0.0413187795 0.1682849445 0.0106103249 -3.2519216021 76 8.10 0.0377558739 0.1977077364 0.0403748826 0.1872848576 0.0120754561 -3.2766142147 84 8.02 0.0366771347 0.2206303725 0.0392961434 0.208999044 0.0138332428 -3.3056017516 93 7.95 [NaOH] 0.09412 limitante 0.0357332378 0.2406876791 0.0383522465 0.2279989571 0.0154496917 -3.3316739919 102 7.87 [AcEt] 0.0993580174 0.0346544986 0.2636103152 0.0372735073 0.2497131435 0.0173938446 -3.362327733 113 7.79 V NaOH (mL)-A 100 0.0335757593 0.2865329513 0.036194768 0.2714273299 0.0194497674 -3.3939509214 122 7.72 V Acetato de etilo (mL)-B 100 0.0326318625 0.3065902579 0.0352508712 0.290427243 0.0213481625 -3.4224660917 133 7.64 CA0(mol/L) 0.04706 0.0315531232 0.329512894 0.0341721319 0.3121414294 0.0236413631 -3.4560827025 141 7.58 CB0(mol/L) 0.0496790087 0.0307440688 0.3467048711 0.0333630775 0.3284270692 0.0254548538 -3.4820581889 151 7.51 θ 1.0556525438 0.0298001719 0.3667621777 0.0324191806 0.3474269823 0.0276804945 -3.5132411164 160 7.45 K0 8.79 0.0289911175 0.3839541547 0.0316101262 0.3637126221 0.0296897195 -3.5407657898 171 7.38 K∞ 5.3 0.0280472206 0.4040114613 0.0306662293 0.3827125352 0.0321622621 -3.5738657382 182 7.31 0.0271033238 0.4240687679 0.0297223325 0.4017124483 0.0347851555 -3.6080989098 196 7.23 k 0.0878958512 0.0260245845 0.446991404 0.0286435932 0.4234266347 0.0379850893 -3.648713629 211 7.15 0.0249458453 0.4699140401 0.027564854 0.4451408211 0.0414240447 -3.6910479928 228 7.07 0.023867106 0.4928366762 0.0264861147 0.4668550075 0.0451298644 -3.7352540853 244 6.99 0.0227883668 0.5157593123 0.0254073755 0.4885691938 0.0491348941 -3.781505103 258 6.92 0.0218444699 0.5358166189 0.0244634786 0.5075691069 0.0529142997 -3.8238074827 278 6.84 0.0207657307 0.558739255 0.0233847394 0.5292832933 0.0575874219 -3.8744512155 301 6.75 0.019552149 0.5845272206 0.0221711577 0.553711753 0.0633580285 -3.9346700755 322 6.67 0.0184734097 0.6074498567 0.0210924185 0.5754259394 0.0690125284 -3.9914228921 348 6.59 0.0173946705 0.6303724928 0.0200136792 0.5971401258 0.0752394799 -4.0515914135 372 6.51 0.0163159312 0.6532951289 0.0189349399 0.6188543122 0.0821305906 -4.1156132723 397 6.44 0.0153720344 0.6733524355 0.0179910431 0.6378542253 0.0887929005 -4.1752053695 436 6.35 0.0141584527 0.6991404011 0.0167774614 0.662282685 0.0983819858 -4.2574434677 475 6.26 0.0129448711 0.7249283668 0.0155638798 0.6867111447 0.1093530954 -4.3470556264 520 6.17 0.0117312894 0.7507163324 0.0143502981 0.7111396044 0.1220290379 -4.4454956992 570 6.08 0.0105177077 0.776504298 0.0131367164 0.7355680641 0.1368419724 -4.5546949912 621 6.00 0.0094389685 0.7994269341 0.0120579772 0.7572822505 0.1522769659 -4.6629085758 682 5.92 0.0083602292 0.8223495702 0.0109792379 0.7789964369 0.1704373189 -4.7842694328 755 5.83 0.0071466476 0.8481375358 0.0097656563 0.8034248966 0.1951283771 -4.9411119043 833 5.75 0.0060679083 0.8710601719 0.008686917 0.8251390829 0.2221592604 -5.1047413281 901 5.69 0.0052588539 0.888252149 0.0078778626 0.8414247227 0.2466515166 -5.2478421718 982 5.63 0.0044497994 0.9054441261 0.0070688081 0.8577103625 0.275951193 -5.4148962564 ERROR:#NUM! 10.6 17.3 21.4 24.6 29.1 33 36.1 42.1 46.6 51.956.9 62.7 68.7 75.599999999999994 84.3 92.6 102.4 113.1 121.8 132.6 141.1 150.6 159.80000000000001 170.9 182.3 195.8 210.7 227.6 243.9 258.2 278.3 300.8 321.89999999999998 347.6 372.4 397.1 436 475 520 570 621 682 755 832.8 901.3 982.3 4.7059999999999998E-2 4.6520630372492842E-2 4.5846418338108881E-2 4.5307048710601733E-2 4.4632836676217764E-2 4.3958624641833824E-2 4.3419255014326655E-2 4.2610200573065922E-2 4.1801146131805168E-2 4.1126934097421207E-2 4.0317879656160453E-2 3.9508825214899727E-2 3.8699770773638981E-2 3.7755873925501435E-2 3.667713467048711E-2 3.5733237822349578E-2 3.4654498567335254E-2 3.357575931232093E-2 3.2631862464183391E-2 3.1553123209169059E-2 3.074406876790832E-2 2.9800171919770774E-2 2.8991117478510037E-2 2.8047220630372498E-2 2.7103323782234959E-2 2.6024584527220639E-2 2.4945845272206314E-2 2.3867106017191986E-2 2.2788366762177659E-2 2.184446991404012E-2 2.0765730659025792E-2 1.9552148997134675E-2 1.8473409742120347E-2 1.739467048710602E-2 1.6315931232091695E-2 1.537203438395 4165E-2 1.4158452722063036E-2 1.2944871060171921E-2 1.1731289398280807E-2 1.051770773638969E-2 9.4389684813753622E-3 8.3602292263610344E-3 7.1466475644699186E-3 6.0679083094555908E-3 5.2588538681948502E-3 4.4497994269340991E-3 Tempo (s) [NaOH] (mol/L) 10.6 17.3 21.4 24.6 29.1 33 36.1 42.1 46.6 51.9 56.9 62.7 68.7 75.599999999999994 84.3 92.6 102.4 113.1 121.8 132.6 141.1 150.6 159.80000000000001 170.9 182.3 195.8 210.7 227.6 243.9 258.2 278.3 300.8 321.89999999999998 347.6 372.4 397.1 436 475 520 570 621 682 755 832.8 901.3 982.3 8.7899999999999991 8.75 8.6999999999999993 8.66 8.61 8.56 8.52 8.4600000000000009 8.4 8.35 8.2899999999999991 8.23 8.17 8.1 8.02 7.95 7.87 7.79 7.72 7.64 7.58 7.51 7.45 7.38 7.31 7.23 7.15 7.07 6.99 6.92 6.84 6.75 6.67 6.59 6.51 6.44 6.35 6.26 6.17 6.08 6 5.92 5.83 5.75 5.69 5.63 Tempo (s) Condutividade molar (ms) 10.6 17.3 21.4 24.6 29.1 33 36.1 42.1 46.6 51.9 56.9 62.7 68.7 75.599999999999994 84.3 92.6 102.4 113.1 121.8 132.6 141.1 150.6 159.80000000000001 170.9 182.3 195.8 210.7 227.6 243.9 258.2 278.3 300.8 321.89999999999998 347.6 372.4 397.1 436 475 520 570 621 682 755 832.8 0 0 5.7848609433230501E-4 1.3192116822321077E-3 1.9263881104033594E-3 2.7043125407515468E-3 3.5 041267108698025E-3 4.1603667804779691E-3 5.1732280736610835E-3 6.2219037254454468E-3 7.1245496675695005E-3 8.2440109491183182E-3 9.4051453757652091E-3 1.0610324900932167E-2 1.2075456139094691E-2 1.3833242801767599E-2 1.5449691720747798E-2 1.7393844569120274E-2 1.9449767371483326E-2 2.1348162470116751E-2 2.3641363091434445E-2 2.5454853836329207E-2 2.7680494547747736E-2 2.9689719527241188E-2 3.2162262067333754E-2 3.4785155465885086E-2 3.7985089288790151E-2 4.1424044689600148E-2 4.5129864364351728E-2 4.9134894072330113E-2 5.2914299667202701E-2 5.758742189747576E-2 6.3358028520195814E-2 6.9012528361901734E-2 7.523947990065856E-2 8.2130590558659636E-2 8.8792900538885486E-2 9.8381985825862481E-2 0.1093530954384067 0.12202903788236076 0.13684197240662968 0.15227696591435286 0.17043731892717084 0.19512837711288364 0.22215926041691045 tempo (s) Ln((θ-XB)/(θ(1-XB))) Ensaio 2 T=21 12/13/22 11:01 T 19 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 10.9 8.87 0.04706 0 0.0496790087 0 0 15.9 8.84 0.0466804839 0.0080645161 0.0492994926 0.007639366 0.0004057548 19.9 8.8 0.0461744624 0.0188172043 0.0487934711 0.0178251873 0.0009563165 23.5 8.76 0.0456684409 0.0295698925 0.0482874496 0.0280110086 0.0015181047 27.9 8.71 0.045035914 0.0430107527 0.0476549227 0.0407432852 0.0022366573 31.1 8.66 0.0444033871 0.0564516129 0.0470223958 0.0534755619 0.0029740043 35.6 8.61 0.0437708602 0.0698924731 0.0463898689 0.0662078385 0.0037308931 39.7 8.56 0.0431383333 0.0833333333 0.045757342 0.0789401151 0.0045081112 43.7 8.51 0.0425058065 0.0967741935 0.0451248152 0.0916723917 0.005306489 47.8 8.45 0.0417467742 0.1129032258 0.0443657829 0.1069511237 0.0062937106 53.3 8.4 0.0411142473 0.126344086 0.043733256 0.1196834003 0.0071417938 59.2 8.34 0.0403552151 0.1424731183 0.0429742238 0.1349621323 0.0081914516 63.2 8.29 0.0397226882 0.1559139785 0.0423416969 0.1476944089 0.0090940324 68.7 8.24 0.0390901613 0.1693548387 0.04170917 0.1604266856 0.0100231376 75.1 8.17 0.0382046237 0.188172043 0.0408236324 0.1782518728 0.0113707193 81.1 8.11 [NaOH] 0.09412 limitante 0.0374455914 0.2043010753 0.0400646001 0.1935306048 0.0125716714 86.5 8.06 [AcEt] 0.0993580174 0.0368130645 0.2177419355 0.0394320732 0.2062628814 0.0136066252 92.9 8 V NaOH (mL)-A 100 0.0360540323 0.2338709677 0.038673041 0.2215416134 0.0148917664 98.9 7.95 V Acetato de etilo (mL)-B 100 0.0354215054 0.247311828 0.0380405141 0.23427389 0.0160005659 106 7.89 CA0(mol/L) 0.04706 0.0346624731 0.2634408602 0.0372814818 0.249552622 0.0173790739 115.1 7.83 CB0(mol/L) 0.0496790087 0.0339034409 0.2795698925 0.0365224496 0.2648313539 0.0188128625 122.1 7.77 θ 1.0556525438 0.0331444086 0.2956989247 0.0357634173 0.2801100859 0.0203053263 128.1 7.72 K0 8.87 0.0325118817 0.3091397849 0.0351308904 0.2928423625 0.0215965125 134.9 7.67 K∞ 5.15 0.0318793548 0.3225806452 0.0344983636 0.3055746392 0.0229332887 142.5 7.61 0.0311203226 0.3387096774 0.0337393313 0.3208533711 0.0246010743 151.5 7.55 k 0.0881631279 0.0303612903 0.3548387097 0.032980299 0.3361321031 0.0263426556 162.6 7.47 0.0293492473 0.376344086 0.031968256 0.3565037457 0.0287882856 174.1 7.4 0.0284637097 0.3951612903 0.0310827184 0.374328933 0.0310535111 185.4 7.33 0.027578172 0.4139784946 0.0301971808 0.3921541203 0.0334460146 198.8 7.25 0.026566129 0.435483871 0.0291851377 0.4125257629 0.0363503818 213.2 7.17 0.025554086 0.4569892473 0.0281730947 0.4328974055 0.0394540744 226.2 7.1 0.0246685484 0.4758064516 0.0272875571 0.4507225928 0.0423499579 241.5 7.03 0.0237830108 0.4946236559 0.0264020195 0.4685477801 0.0454308793 254.5 6.97 0.0230239785 0.5107526882 0.0256429872 0.483826512 0.0482327783 267.7 6.91 0.0222649462 0.5268817204 0.0248839549 0.499105244 0.0511970505 282.2 6.85 0.021505914 0.5430107527 0.0241249227 0.5143839759 0.0543382459 296.8 6.79 0.0207468817 0.5591397849 0.0233658904 0.5296627079 0.0576727084 312.3 6.73 0.0199878495 0.5752688172 0.0226068582 0.5449414398 0.0612188611 338 6.64 0.0188493011 0.5994623656 0.0214683098 0.5678595378 0.0669813678 358.8 6.57 0.0179637634 0.6182795699 0.0205827722 0.5856847251 0.0718779033 380.6 6.5 0.0170782258 0.6370967742 0.0196972345 0.6035099123 0.0771875446 405.7 6.43 0.0161926882 0.6559139785 0.0188116969 0.6213350996 0.0829649582 440.6 6.35 0.0151806452 0.6774193548 0.0177996539 0.6417067422 0.0902241437 472.9 6.27 0.0141686022 0.6989247312 0.0167876109 0.6620783849 0.0982964486 506 6.2 0.0132830645 0.7177419355 0.0159020732 0.6799035721 0.1061399038 540.7 6.13 0.0123975269 0.7365591398 0.0150165356 0.6977287594 0.1148362084 584.6 6.05 0.0113854839 0.7580645161 0.0140044926 0.718100402 0.1260099199 634.1 5.97 0.0103734409 0.7795698925 0.0129924496 0.7384720446 0.1387707276 683.2 5.9 0.0094879032 0.7983870968 0.0121069119 0.7562972319 0.1515227822 757.5 5.81 0.0083493548 0.8225806452 0.0109683636 0.7792153299 0.170636737 826.7 5.73 0.0073373118 0.8440860215 0.0099563205 0.7995869725 0.1908940744 926.3 5.64 0.0061987634 0.8682795699 0.0088177722 0.8225050704 0.218570043 1024.6 5.57 0.0053132258 0.8870967742 0.0079322345 0.8403302577 0.2448692389 1124.1 5.5 0.0044276882 0.9059139785 0.0070466969 0.858155445 0.2768330191 10.9 15.919.899999999999999 23.5 27.9 31.1 35.6 39.700000000000003 43.7 47.8 53.3 59.2 63.2 68.7 75.099999999999994 81.099999999999994 86.5 92.9 98.9 106 115.1 122.1 128.1 134.9 142.5 151.5 162.6 174.1 185.4 198.8 213.2 226.2 241.5 254.5 267.7 282.2 296.8 312.3 338 358.8 380.6 405.7 440.6 472.9 506 540.70000000000005 584.6 634.1 683.2 757 .5 826.7 926.3 1024.5999999999999 1124.0999999999999 4.7059999999999998E-2 4.6680483870967744E-2 4.6174462365591411E-2 4.5668440860215057E-2 4.5035913978494636E-2 4.4403387096774202E-2 4.3770860215053761E-2 4.3138333333333348E-2 4.2505806451612907E-2 4.1746774193548386E-2 4.1114247311827966E-2 4.0355215053763445E-2 3.9722688172043004E-2 3.9090161290322591E-2 3.8204623655913983E-2 3.7445591397849462E-2 3.6813064516129042E-2 3.6054032258064521E-2 3.5421505376344094E-2 3.4662473118279566E-2 3.3903440860215059E-2 3.3144408602150538E-2 3.2511881720430111E-2 3.1879354838709677E-2 3.112032258064517E-2 3.0361290322580649E-2 2.9349247311827954E-2 2.8463709677419364E-2 2.757817204301076E-2 2.6566129032258065E-2 2.5554086021505378E-2 2.4668548387096 773E-2 2.3783010752688176E-2 2.3023978494623655E-2 2.2264946236559141E-2 2.150591397849462E-2 2.074688172043011E-2 1.9987849462365596E-2 1.8849301075268811E-2 1.7963763440860221E-2 1.7078225806451613E-2 1.6192688172043005E-2 1.5180645161290316E-2 1.4168602150537628E-2 1.3283064516129033E-2 1.2397526881720427E-2 1.1385483870967737E-2 1.037344086021505E-2 9.4879032258064541E-3 8.3493548387096692E-3 7.3373118279569912E-3 6.1987634408602081E-3 5.3132258064516134E-3 4.4276881720430074E-3 Tempo (s) [NaOH] (mol/L) 10.9 15.9 19.899999999999999 23.5 27.9 31.1 35.6 39.700000000000003 43.7 47.8 53.3 59.2 63.2 68.7 75.099999999999994 81.099999999999994 86.5 92.9 98.9 106 115.1 122.1 128.1 134.9 142.5 151.5 162.6 174.1 185.4 198.8 213.2 226.2 241.5 254.5 267.7 282.2 296.8 312.3 338 358.8 380.6 405.7 440.6 472.9 506 540.70000000000005 584.6 634.1 683.2 757.5 826.7 926.3 0 4.0575483030226252E-4 9.56316507738546 33E-4 1.5181047120785311E-3 2.236657283560354E-3 2.9740042836445559E-3 3.73089307143763E-3 4.5081111747392781E-3 5.306489026312991E-3 6.2937105644443559E-3 7.1417937882248712E-3 8.1914515732264288E-3 9.0940324356560635E-3 1.0023137586283344E-2 1.1370719347018327E-2 1.2571671401874417E-2 1.3606625151123812E-2 1.4891766404009077E-2 1.6000565907453301E-2 1.7379073942813947E-2 1.8812862453888045E-2 2.0305326304992891E-2 2.15965124688129E-2 2.2933288723230166E-2 2.4601074267073909E-2 2.6342655641305925E-2 2.8788285563249506E-2 3.1053511125303562E-2 3.3446014594329637E-2 3.6350381768157858E-2 3.9454074414741913E-2 4.2349957880970894E-2 4.5430879313250662E-2 4.8232778253719751E-2 5.119705046285962E-2 5.4 338245935117643E-2 5.7672708448807002E-2 6.1218861102202704E-2 6.6981367829024391E-2 7.1877903296245813E-2 7.7187544599279748E-2 8.2964958206830988E-2 9.0224143705725693E-2 9.8296448590758159E-2 0.10613990379012306 0.11483620844103733 0.12600991993873473 0.13877072756567693 0.15152278221998725 0.17063673696052872 0.19089407438656134 0.21857004297215826 tempo (s) Ln((θ-XB)/(θ(1-XB))) 10.9 15.9 19.899999999999999 23.5 27.9 31.1 35.6 39.700000000000003 43.7 47.8 53.3 59.2 63.2 68.7 75.099999999999994 81.099999999999994 86.5 92.9 98.9 106 115.1 122.1 128.1 134.9 142.5 151.5 162.6 174.1 185.4 198.8 213.2 226.2 241.5 254.5 267.7 282.2 296.8 312.3 338 358.8 380.6 405.7 440.6 472.9 506 540.70000000000005 584.6 634.1 683.2 757.5 826.7 926.3 1024.5999999999999 1124.0999999999999 8.8699999999999992 8.84 8.8000000000000007 8.76 8.7100000000000009 8.66 8.61 8.56 8.51 8.4499999999999993 8.4 8.34 8.2899999999999991 8.24 8.17 8.11 8.06 8 7.95 7.89 7.83 7.77 7.72 7.67 7.61 7.55 7.47 7.4 7.33 7.25 7.17 7.1 7.03 6.97 6.91 6.85 6.79 6.73 6.64 6.57 6.5 6.43 6.35 6.27 6.2 6.13 6.05 5.97 5.9 5.81 5.73 5.64 5.57 5.5 Tempo (s) Condutividade molar (ms) Ensaio 1 T=18 12/6/22 16:26 T 16.2 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 17.9 8.26 0.0409388834 0.0794044665 0.0461478921 0.071078645 0.0079910888 22.8 8.22 0.0404974938 0.0893300248 0.0457065025 0.0799634756 0.0090718808 27.1 8.18 0.0400561042 0.0992555831 0.0452651129 0.0888483063 0.0101725496 32 8.14 0.0396147146 0.1091811414 0.0448237234 0.0977331369 0.0112936494 36.5 8.09 0.0390629777 0.1215880893 0.0442719864 0.1088391752 0.0127246331 40.6 8.05 0.0386215881 0.1315136476 0.0438305968 0.1177240058 0.013893838 46.2 8 0.0380698511 0.1439205955 0.0432788598 0.1288300441 0.0153868926 51.5 7.95 0.0375181141 0.1563275434 0.0427271229 0.1399360824 0.0169161942 59.6 7.9 0.0369663772 0.1687344913 0.0421753859 0.1510421207 0.0184830808 65.2 7.84 0.0363042928 0.1836228288 0.0415133015 0.1643693666 0.0204149397 70.8 7.79 0.0357525558 0.1960297767 0.0409615645 0.1754754049 0.0220695584 77.9 7.73 0.0350904715 0.2109181141 0.0402994802 0.1888026508 0.0241111288 86.8 7.66 0.0343180397 0.2282878412 0.0395270484 0.2043511044 0.0265738495 93.6 7.6 0.0336559553 0.2431761787 0.038864964 0.2176783504 0.0287575879 100.8 7.54 0.032993871 0.2580645161 0.0382028797 0.2310055963 0.0310120095 110.3 7.47 [NaOH] 0.08894 limitante 0.0322214392 0.2754342432 0.0374304479 0.2465540499 0.0337361786 118.6 7.41 [AcEt] 0.0993580174 0.0315593548 0.2903225806 0.0367683636 0.2598812959 0.0361560489 129.2 7.34 V NaOH (mL)-A 100 0.0307869231 0.3076923077 0.0359959318 0.2754297495 0.0390839013 139.1 7.27 V Acetato de etilo (mL)-B 100 0.0300144913 0.3250620347 0.0352235 0.2909782031 0.042131049 148.6 7.21 CA0(mol/L) 0.04447 0.0293524069 0.3399503722 0.0345614157 0.304305449 0.0448434755 159.1 7.14 CB0(mol/L) 0.0496790087 0.0285799752 0.3573200993 0.0337889839 0.3198539026 0.0481324378 171.4 7.07 θ 1.1171353432 0.0278075434 0.3746898263 0.0330165521 0.3354023562 0.0515637433 183.2 7 K0 8.58 0.0270351117 0.3920595533 0.0322441204 0.3509508098 0.0551468588 197.1 6.92 K∞ 4.55 0.0261523325 0.41191067 0.0313613412 0.3687204711 0.0594410287 210.9 6.85 0.0253799007 0.429280397 0.0305889095 0.3842689247 0.0633854643 226.6 6.77 k 0.0520060562 0.0244971216 0.4491315136 0.0297061303 0.4020385859 0.068123952 244.8 6.69 0.0236143424 0.4689826303 0.0288233511 0.4198082472 0.0731282553 260.1 6.62 0.0228419107 0.4863523573 0.0280509194 0.4353567008 0.0777431515 279.7 6.54 0.0219591315 0.5062034739 0.0271681402 0.453126362 0.0833102293 300.2 6.46 0.0210763524 0.5260545906 0.0262853611 0.4708960233 0.0892172541 322.6 6.38 0.0201935732 0.5459057072 0.0254025819 0.4886656845 0.0954964576 346.4 6.3 0.019310794 0.5657568238 0.0245198028 0.5064353458 0.1021842947 369.3 6.23 0.0185383623 0.5831265509 0.023747371 0.5219837994 0.1084037647 395.7 6.15 0.0176555831 0.6029776675 0.0228645918 0.5397534606 0.1159739086 427.3 6.07 0.016772804 0.6228287841 0.0219818127 0.5575231219 0.1240881923 463 5.99 0.0158900248 0.6426799007 0.0210990335 0.5752927831 0.1328077702 501.4 5.9 0.0148968983 0.6650124069 0.020105907 0.5952836521 0.1434293052 540.5 5.82 0.0140141191 0.6848635236 0.0192231278 0.6130533133 0.1536844101 579.5 5.75 0.0132416873 0.7022332506 0.0184506961 0.6286017669 0.1633656317 624.7 5.67 0.0123589082 0.7220843672 0.0175679169 0.6463714282 0.1753419168 681.3 5.59 0.011476129 0.7419354839 0.0166851377 0.6641410894 0.1884205984 747.9 5.5 0.0104830025 0.7642679901 0.0156920112 0.6841319583 0.2046533291 816.6 5.42 0.0096002233 0.7841191067 0.014809232 0.7019016196 0.2206503041 897.8 5.34 0.0087174442 0.8039702233 0.0139264529 0.7196712808 0.2383739298 986.9 5.26 0.007834665 0.82382134 0.0130436737 0.7374409421 0.2581230029 17.89999999999999922.8 27.1 32 36.5 40.6 46.2 51.5 59.6 65.2 70.8 77.900000000000006 86.8 93.6 100.8 110.3 118.6 129.19999999999999 139.1 148.6 159.1 171.4 183.2 197.1 210.9 226.6 244.8 260.10000000000002 279.7 300.2 322.60000000000002 346.4 369.3 395.7 427.3 463 501.4 540.5 579.5 624.70000000000005 681.3 747.9 816.6 897. 8 986.9 8.26 8.2200000000000006 8.18 8.14 8.09 8.0500000000000007 8 7.95 7.9 7.84 7.79 7.73 7.66 7.6 7.54 7.47 7.41 7.34 7.27 7.21 7.14 7.07 7 6.92 6.85 6.77 6.69 6.62 6.54 6.46 6.38 6.3 6.23 6.15 6.07 5.99 5.9 5.82 5.75 5.67 5.59 5.5 5.42 5.34 5.26 Tempo (s) Condutividade molar (ms) 17.899999999999999 22.8 27.1 32 36.5 40.6 46.2 51.5 59.6 65.2 70.8 77.900000000000006 86.8 93.6 100.8 110.3 118.6 129.19999999999999 139.1 148.6 159.1 171.4 183.2 197.1 210.9 226.6 244.8 260.10000000000002 279.7 300.2 322.60000000000002 346.4 369.3 395.7 427.3 463 501.4 540.5 579.5 624.70000000000005 681.3 747.9 816.6 897.8 7.9910888086759321E-3 9.0718807606331251E-3 1.0172549579200923E-2 1.1293649372675419E-2 1.2724633094280182 E-2 1.3893837959603699E-2 1.5386892616093037E-2 1.6916194215224972E-2 1.8483080784021253E-2 2.0414939730435858E-2 2.2069558399691696E-2 2.4111128763626626E-2 2.6573849483611377E-2 2.8757587859764653E-2 3.101200953545348E-2 3.3736178604728238E-2 3.6156048862852348E-2 3.9083901289621775E-2 4.2131049009974164E-2 4.4843475487789455E-2 4.8132437772000006E-2 5.1563743323393647E-2 5.5146858838663868E-2 5.9441028658298985E-2 6.3385464258623264E-2 6.8123952041752228E-2 7.3128255296616471E-2 7.7743151520102208E-2 8.331022925864924E-2 8.9217254116639E-2 9.5496457646217073E-2 0.10218429468249404 0.10840376474514182 0.11597390863077389 0.12408819225799157 0.13280777019621592 0.14342930521293359 0.1536844100620 5 0.16336563165881601 0.17534191675442976 0.18842059836824437 0.20465332907317083 0.22065030406063982 0.23837392984950836 tempo (s) Ln((θ-XB)/(θ(1-XB))) 17.899999999999999 22.8 27.1 32 36.5 40.6 46.2 51.5 59.6 65.2 70.8 77.900000000000006 86.8 93.6 100.8 110.3 118.6 129.19999999999999 139.1 148.6 159.1 171.4 183.2 197.1 210.9 226.6 244.8 260.10000000000002 279.7 300.2 322.60000000000002 346.4 369.3 395.7 427.3 463 501.4 540.5 579.5 624.70000000000005 681.3 747.9 816.6 897.8 986.9 4.0938883374689823E-2 4.0497493796526063E-2 4.0056104218362282E-2 3.9614714640198515E-2 3.9062977667493795E-2 3.8621588089330035E-2 3.8069851116625308E-2 3.7518114143920603E-2 3.6966377171215883E-2 3.6304292803970226E-2 3.5752555831265513E-2 3.5090471464019855E-2 3.4318039702233252E-2 3.3655955334987595E-2 3.2993870967741937E-2 3.2221439205955334E-2 3.1559354838709683E-2 3.0786923076923076E-2 3.0014491315136477E-2 2.9352406947890822E-2 2.8579975186104219E-2 2.7807543424317627E-2 2.7035111662531017E-2 2.6152332506203475E-2 2.5379900744416872E-2 2.4497121588089324E-2 2.3614342431761793E-2 2.284191066997519E-2 2.1959131513647645E-2 2.10763523573201E-2 2.0193573200992559E-2 1.9310794044665014E-2 1.8538362282878418E-2 1.7655583126550873E-2 1.6772803970223332E-2 1.5890024 813895787E-2 1.4896898263027302E-2 1.4014119106699757E-2 1.3241687344913154E-2 1.2358908188585609E-2 1.1476129032258064E-2 1.0483002481389581E-2 9.6002233250620361E-3 8.7174441687344912E-3 7.8346650124069463E-3 Tempo (s) [NaOH] (mol/L) Ensaio 2 T=18 12/6/22 16:57 T 18.2 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 16.5 8.34 0.0416687402 0.062992126 0.0468777489 0.0563871928 0.0062461408 22.9 8.3 0.0412018635 0.0734908136 0.0464108722 0.0657850583 0.0073563811 26.3 8.26 0.0407349869 0.0839895013 0.0459439956 0.0751829237 0.0084879166 30.1 8.22 0.0402681102 0.094488189 0.0454771189 0.0845807892 0.0096413666 34.6 8.17 0.0396845144 0.1076115486 0.0448935231 0.096328121 0.0111149794 39.5 8.12 0.0391009186 0.1207349081 0.0443099273 0.1080754529 0.0126251547 44.4 8.07 0.0385173228 0.1338582677 0.0437263315 0.1198227847 0.0141732722 50 8.01 0.0378170079 0.1496062992 0.0430260166 0.1339195829 0.0160831436 55.1 7.96 0.0372334121 0.1627296588 0.0424424208 0.1456669147 0.0177199438 61 7.91 0.0366498163 0.1758530184 0.041858825 0.1574142466 0.0193995969 69.3 7.84 0.0358327822 0.1942257218 0.0410417909 0.1738605111 0.0218263731 74.6 7.79 0.0352491864 0.2073490814 0.0404581951 0.185607843 0.0236160173 82.6 7.72 0.0344321522 0.2257217848 0.0396411609 0.2020541075 0.0262043728 88.7 7.67 0.0338485564 0.2388451444 0.0390575651 0.2138014394 0.0281151951 95 7.61 0.0331482415 0.2545931759 0.0383572502 0.2278982376 0.0304798731 102.9 7.55 [NaOH] 0.08894 limitante 0.0324479265 0.2703412073 0.0376569352 0.2419950358 0.0329266107 108.9 7.5 [AcEt] 0.0993580174 0.0318643307 0.2834645669 0.0370733394 0.2537423676 0.0350313756 118.1 7.43 V NaOH (mL)-A 100 0.0310472966 0.3018372703 0.0362563053 0.2701886322 0.0380839978 129.1 7.35 V Acetato de etilo (mL)-B 100 0.0301135433 0.3228346457 0.035322552 0.2889843631 0.0417333791 137.3 7.29 CA0(mol/L) 0.04447 0.0294132283 0.3385826772 0.0346222371 0.3030811613 0.0445902867 150 7.21 CB0(mol/L) 0.0496790087 0.0284794751 0.3595800525 0.0336884838 0.3218768922 0.0485706316 159.7 7.14 θ 1.1171353432 0.0276624409 0.3779527559 0.0328714497 0.3383231568 0.0522249571 171.4 7.07 K0 8.58 0.0268454068 0.3963254593 0.0320544155 0.3547694214 0.0560512342 183.1 7 K∞ 4.77 0.0260283727 0.4146981627 0.0312373814 0.371215686 0.060061922 194.4 6.93 0.0252113386 0.4330708661 0.0304203473 0.3876619505 0.064270716 205.6 6.87 k 0.0684391253 0.0245110236 0.4488188976 0.0297200323 0.4017587487 0.0680473273 218.2 6.8 0.0236939895 0.467191601 0.0289029982 0.4182050133 0.0726652576 230.2 6.74 0.0229936745 0.4829396325 0.0282026833 0.4323018115 0.0768181906 245.3 6.67 0.0221766404 0.501312336 0.0273856491 0.4487480761 0.0819081504 261.2 6.6 0.0213596063 0.5196850394 0.026568615 0.4651943406 0.0872829641 274.6 6.54 0.0206592913 0.5354330709 0.0258683001 0.4792911388 0.0921353025 291.8 6.47 0.0198422572 0.5538057743 0.0250512659 0.4957374034 0.0981068447 312.4 6.39 0.0189085039 0.5748031496 0.0241175126 0.5145331343 0.1053785753 337.9 6.3 0.0178580315 0.5984251969 0.0230670402 0.5356783316 0.1141918002 359.1 6.23 0.0170409974 0.6167979003 0.0222500061 0.5521245962 0.1215619955 382.6 6.15 0.0161072441 0.6377952756 0.0213162528 0.5709203271 0.1306024018 410.4 6.07 0.0151734908 0.6587926509 0.0203824995 0.5897160581 0.1403786989 449.9 5.98 0.0141230184 0.6824146982 0.0193320271 0.6108612554 0.1523745687 475.6 5.9 0.0131892651 0.7034120735 0.0183982738 0.6296569863 0.1640485737 518.1 5.81 0.0121387927 0.7270341207 0.0173478014 0.6508021836 0.1784940632 553.5 5.73 0.0112050394 0.7480314961 0.0164140481 0.6695979145 0.1926821407 601.4 5.64 0.0101545669 0.7716535433 0.0153635756 0.6907431118 0.2104196893 655.6 5.55 0.0091040945 0.7952755906 0.0143131032 0.7118883091 0.2303809419 701.8 5.48 0.0082870604 0.813648294 0.0134960691 0.7283345737 0.2477281135 755.7 5.41 0.0074700262 0.8320209974 0.012679035 0.7447808383 0.2669560575 814.3 5.34 0.0066529921 0.8503937008 0.0118620008 0.7612271028 0.2883923873 874.7 5.27 0.005835958 0.8687664042 0.0110449667 0.7776733674 0.3124466422 948.7 5.2 0.0050189239 0.8871391076 0.0102279326 0.794119632 0.3396380218 16.5 22.9 26.3 30.1 34.6 39.5 44.4 50 55.1 61 69.3 74.599999999999994 82.6 88.7 95 102.9 108.9 118.1 129.1 137.30000000000001 150 159.69999999999999 171.4 183.1 194.4 205.6 218.2 230.2 245.3 261.2 274.60000000000002 291.8 312.39999999999998 337.9 359.1 382.6 410 .4 449.9 475.6 518.1 553.5 601.4 655.6 701.8 755.7 814.3 874.7 948.7 8.34 8.3000000000000007 8.268.2200000000000006 8.17 8.1199999999999992 8.07 8.01 7.96 7.91 7.84 7.79 7.72 7.67 7.61 7.55 7.5 7.43 7.35 7.29 7.21 7.14 7.07 7 6.93 6.87 6.8 6.74 6.67 6.6 6.54 6.47 6.39 6.3 6.23 6.15 6.07 5.98 5.9 5.81 5.73 5.64 5.55 5.48 5.41 5.34 5.27 5.2 Tempo (s) Condutividade molar (ms) 16.5 22.9 26.3 30.1 34.6 39.5 44.4 50 55.1 61 69.3 74.599999999999994 82.6 88.7 95 102.9 108.9 118.1 129.1 137.30000000000001 150 159.69999999999999 171.4 183.1 194.4 205.6 218.2 230.2 245.3 261.2 274.60000000000002 291.8 312.39999999999998 337.9 359.1 382.6 410.4 449.9 475.6 518.1 553.5 601.4 655.6 701.8 755.7 814.3 874.7 94 8.7 4.1668740157480316E-2 4.1201863517060379E-2 4.0734986876640421E-2 4.0268110236220483E-2 3.9684514435695539E-2 3.9100918635170595E-2 3.8517322834645679E-2 3.7817007874015748E-2 3.7233412073490818E-2 3.6649816272965881E-2 3.5832782152230971E-2 3.5249186351706041E-2 3.4432152230971125E-2 3.3848556430446194E-2 3.3148241469816278E-2 3.2447926509186355E-2 3.1864330708661424E-2 3.1047296587926508E-2 3.0113543307086613E-2 2.9413228346456696E-2 2.8479475065616801E-2 2.7662440944881888E-2 2.6845406824146986E-2 2.6028372703412076E-2 2.5211338582677167E-2 2.4511023622047247E-2 2.3693989501312337E-2 2.2993674540682421E-2 2.2176640419947508E-2 2.1359606299212599E-2 2.0659291338582682E-2 1.984225721784777E-2 1.8908503937007874E-2 1.7858031496062993E-2 1.7040997375328094 E-2 1.6107244094488195E-2 1.5173490813648301E-2 1.4123018372703421E-2 1.3189265091863526E-2 1.2138792650918636E-2 1.1205039370078751E-2 1.0154566929133859E-2 9.1040944881889772E-3 8.2870603674540782E-3 7.4700262467191662E-3 6.6529921259842551E-3 5.8359580052493431E-3 5.0189238845144424E-3 Tempo (s) [NaOH] (mol/L) 16.5 22.9 26.3 30.1 34.6 39.5 44.4 50 55.1 61 69.3 74.599999999999994 82.6 88.7 95 102.9 108.9 118.1 129.1 137.30000000000001 150 159.69999999999999 171.4 183.1 194.4 205.6 218.2 230.2 245.3 261.2 274.60000000000002 291.8 312.39999999999998 337.9 359.1 382.6 410.4 449.9 475.6 518.1 553.5 601.4 655.6 701.8 755.7 814.3 874.7 948.7 6.2461408243731737E-3 7.356381099847431E-3 8.4879165592547726E-3 9.6413665658151675E-3 1.1114979370273226E-2 1.2625154691346663E-2 1.4173272165626439E-2 1.6083143634881159E-2 1.7719943796316594E-2 1.9399596932233452E-2 2.1826373144276136E-2 2.3616017303079266E-2 2.6204372818628384E-2 2.8115195118020981E-2 3.0479873050128035E-2 3.2926610673637426E-2 3.5031375579884866E-2 3.8083997755641266E-2 4.1733379051361763E-2 4.4590286658029318E-2 4.8570631604958843E-2 5.222495711508917E-2 5.6051234198235524E-2 6.0061921952376848E-2 6.4270716046848045E-2 6.8047327330344382E-2 7.2665257575240658E-2 7.6818190642529691E-2 8.1908150442032521E-2 8.7282964144905911E-2 9.2135302478234649E-2 9.8106844708886323E-2 0.1053785752595322 0.11419180015652672 0.12156199554759468 0.1306024017817637 7 0.1403786989340276 0.15237456871965174 0.16404857367774725 0.17849406321263048 0.19268214068812203 0.21041968932502916 0.23038094191824221 0.24772811352523175 0.26695605749416795 0.28839238729839123 0.31244664215209711 0.33963802181623248 tempo (s) Ln((θ-XB)/(θ(1-XB))) Ensaio 1 T=15 12/13/22 10:29 T 13.8 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 20.5 7.76 0.0389030026 0.1211340206 0.0443170113 0.1079328586 0.0130994946 27.2 7.72 0.0384466624 0.131443299 0.0438606711 0.1171186338 0.0143532149 31.7 7.68 0.0379903222 0.1417525773 0.0434043309 0.126304409 0.0156316779 38.5 7.63 0.0374198969 0.1546391753 0.0428339056 0.137786628 0.0172656828 43.5 7.59 0.0369635567 0.1649484536 0.0423775654 0.1469724032 0.0186025716 49.7 7.54 0.0363931314 0.1778350515 0.0418071402 0.1584546222 0.0203121182 55.3 7.49 0.0358227062 0.1907216495 0.0412367149 0.1699368412 0.0220659214 59.7 7.44 0.0352522809 0.2036082474 0.0406662896 0.1814190602 0.0238657249 66.9 7.38 0.0345677706 0.2190721649 0.0399817793 0.195197723 0.0260888029 68.4 7.33 0.0339973454 0.2319587629 0.0394113541 0.206679942 0.0279964134 71.5 7.27 0.0333128351 0.2474226804 0.0387268438 0.2204586048 0.0303546892 79.2 7.22 0.0327424098 0.2603092784 0.0381564185 0.2319408238 0.0323801099 89.4 7.17 0.0321719845 0.2731958763 0.0375859932 0.2434230428 0.0344627261 91.4 7.11 0.0314874742 0.2886597938 0.0369014829 0.2572017056 0.0370408404 120 7.04 0.0306888789 0.3067010309 0.0361028876 0.2732768122 0.0401632878 127.6 6.97 [NaOH] 0.08853 limitante 0.0298902835 0.324742268 0.0353042922 0.2893519188 0.0434166091 135.9 6.9 [AcEt] 0.0993580174 0.0290916881 0.3427835052 0.0345056969 0.3054270254 0.0468092268 140.5 6.84 V NaOH (mL)-A 100 0.0284071778 0.3582474227 0.0338211865 0.3192056882 0.0498349773 155.3 6.77 V Acetato de etilo (mL)-B 100 0.0276085825 0.3762886598 0.0330225912 0.3352807948 0.0535112198 163.6 6.71 CA0(mol/L) 0.044265 0.0269240722 0.3917525773 0.0323380809 0.3490594576 0.0567953517 165.8 6.65 CB0(mol/L) 0.0496790087 0.0262395619 0.4072164948 0.0316535706 0.3628381204 0.0602100661 167.8 6.59 θ 1.1223090187 0.0255550515 0.4226804124 0.0309690603 0.3766167832 0.0637633303 171.4 242.7 6.37 K0 8.23 0.0230451804 0.4793814433 0.0284591891 0.4271385468 0.0781250164 174.5 258.1 6.29 K∞ 4.35 0.0221325 0.5 0.0275465087 0.4455100972 0.0839374308 277.3 6.21 0.0212198196 0.5206185567 0.0266338283 0.4638816476 0.0901110903 304.5 6.13 k 0.04590 0.0203071392 0.5412371134 0.0257211479 0.482253198 0.0966808819 331.9 6.05 0.0193944588 0.5618556701 0.0248084675 0.5006247484 0.1036863526 367.9 5.97 0.0184817784 0.5824742268 0.0238957871 0.5189962988 0.1111725173 396.6 5.9 0.017683183 0.6005154639 0.0230971917 0.5350714054 0.1181575099 427.6 5.81 0.0166564175 0.6237113402 0.0220704262 0.5557393996 0.1278004513 464.1 5.73 0.0157437371 0.6443298969 0.0211577458 0.57411095 0.1370696076 499.7 5.65 0.0148310567 0.6649484536 0.0202450654 0.5924825004 0.1470775665 521.9 5.58 0.0140324613 0.6829896907 0.0194464701 0.608557607 0.1565129664 567.9 5.51 0.013233866 0.7010309278 0.0186478747 0.6246327136 0.166656712 622.6 5.44 0.0124352706 0.7190721649 0.0178492793 0.6407078202 0.1775922669 680 5.35 0.0114085052 0.7422680412 0.0168225139 0.6613758144 0.1929740571 778.8 5.27 0.0104958247 0.7628865979 0.0159098335 0.6797473648 0.2080814293 857.2 5.19 0.0095831443 0.7835051546 0.014997153 0.6981189152 0.2247603442 927.1 5.11 0.0086704639 0.8041237113 0.0140844726 0.7164904656 0.2432722056 1010.9 5.03 0.0077577835 0.824742268 0.0131717922 0.734862016 0.2639405005 1131.9 4.95 0.0068451031 0.8453608247 0.0122591118 0.7532335664 0.2871706377 1248 4.87 0.0059324227 0.8659793814 0.0113464314 0.7716051168 0.3134780214 1365 4.79 0.0050197423 0.8865979381 0.010433751 0.7899766672 0.3435287069 1524 4.71 0.0041070619 0.9072164948 0.0095210706 0.8083482176 0.3781998618 1690 4.67 0.0036507216 0.9175257732 0.0090647304 0.8175339928 0.3976218037 20.5 27.2 31.7 38.5 43.5 49.7 55.3 59.7 66.900000000000006 68.400000000000006 71.5 79.2 89.4 91.4 120 127.6 135.9 140.5 155.30000000000001 163.6 165.8 167.8 242.7 258.10000000000002 277.3 304.5 331.9 367.9 396.6 427.6 464.1 499.7 521.9 567.9 622.6 680 778.8 857.2 927.1 1010.9 1131.9000000000001 1248 1365 1524 1690 3. 890300257731958E-2 3.8446662371134012E-2 3.7990322164948444E-2 3.7419896907216491E-2 3.6963556701030922E-2 3.6393131443298969E-2 3.5822706185567009E-2 3.5252280927835056E-2 3.4567770618556697E-2 3.3997345360824736E-2 3.3312835051546384E-2 3.2742409793814431E-2 3.2171984536082471E-2 3.1487474226804125E-2 3.0688878865979381E-2 2.9890283505154637E-2 2.9091688144329896E-2 2.8407177835051544E-2 2.76085824742268E-2 2.6924072164948451E-2 2.6239561855670106E-22.555505154639175E-2 2.3045180412371136E-2 2.2132499999999999E-2 2.1219819587628863E-2 2.030713917525773E-2 1.9394458762886594E-2 1.8481778350515461E-2 1.7683182989690724E-2 1.6656417525773192E-2 1.5743737113402066E-2 1.4831056701030933E-2 1.4032461340206187E-2 1.3233865979381443E-2 1.2435270618556706E-2 1.1408505154639174E-2 1.0495824742268038E-2 9.5831443298969 136E-3 8.6704639175257791E-3 7.7577835051546445E-3 6.84510309278351E-3 5.9324226804123746E-3 5.0197422680412409E-3 4.1070618556701055E-3 3.6507216494845382E-3 Tempo (s) [NaOH] (mol/L) 20.5 27.2 31.7 38.5 43.5 49.7 55.3 59.7 66.900000000000006 68.400000000000006 71.5 79.2 89.4 91.4 120 127.6 135.9 140.5 155.30000000000001 163.6 165.8 167.8 242.7 258.10000000000002 277.3 304.5 331.9 367.9 396.6 427.6 464.1 499.7 521.9 567.9 622.6 680 778.8 857.2 927.1 1010.9 1131.9000000000001 1248 1365 1.3099494635712392E-2 1.4353214882811084E-2 1.563167793254051E-2 1.726568276748788E-2 1.8602571556791198E-2 2.0312118236765202E-2 2.2065921391928672E-2 2.3865724921014516E-2 2.6088802911355995E-2 2.799641340166658E-2 3.0354689244310777E-2 3.2380109867973121E-2 3.4462726089277057E-2 3.7040840405637133E-2 4.0163287834936896E-2 4.3416609082486748E-2 4.6809226769889481E-2 4.9834977266747196E-2 5.3511219832031567E-2 5.6795351721197589E-2 6.0210066073869209E-2 6.3763330279334951E-2 7.8125016367989672E-2 8.3937430772535473E-2 9.0111090306416092E-2 9.6680881939104638E-2 0.10368635256997265 0.1111725172919623 0.11815750987391437 0.12780045128082498 0.13706960761179868 0.14707756650986978 0.15651296642363749 0.1666567119580295 0.1775922668550878 0.19297405712407095 0.20808142933987389 0.22476034423282323 0.24327220557715284 0.2639 4050046092049 0.28717063767279088 0.31347802144173192 0.34352870685847886 tempo (s) Ln((θ-XB)/(θ(1-XB))) 20.5 27.2 31.7 38.5 43.5 49.7 55.3 59.7 66.900000000000006 68.400000000000006 71.5 79.2 89.4 91.4 120 127.6 135.9 140.5 155.30000000000001 163.6 165.8 167.8 242.7 258.10000000000002 277.3 304.5 331.9 367.9 396.6 427.6 464.1 499.7 521.9 567.9 622.6 680 778.8 857.2 927. 1 1010.9 1131.9000000000001 1248 1365 1524 1690 7.76 7.72 7.68 7.63 7.59 7.54 7.49 7.44 7.38 7.33 7.27 7.22 7.17 7.11 7.04 6.97 6.9 6.84 6.77 6.71 6.65 6.59 6.37 6.29 6.21 6.13 6.05 5.97 5.9 5.81 5.73 5.65 5.58 5.51 5.44 5.35 5.27 5.19 5.1100000000000003 5.03 4.95 4.87 4.79 4.71 4.67 Tempo (s) Condutividade molar (ms) Ensaio 2 T=15 12/13/22 11:01 T 16.9 Tempo (s) Condutividade molar, k (mS/cm) CA XA CB XB Ln 14.3 8.5 0.044265 0 0.0496790087 -0 0 20.5 8.46 0.0437576648 0.0114613181 0.0491716735 0.0102122658 0.0011237819 24.8 8.42 0.0432503295 0.0229226361 0.0486643382 0.0204245317 0.0022696939 30.7 8.37 0.0426161605 0.0372492837 0.0480301692 0.033189864 0.0037342138 36.3 8.32 0.0419819914 0.0515759312 0.0473960001 0.0459551963 0.0052356966 41 8.27 0.0413478223 0.0659025788 0.0467618311 0.0587205286 0.0067755612 47.6 8.21 0.0405868195 0.0830945559 0.0460008282 0.0740389273 0.0086761699 54.3 8.15 0.0398258166 0.100286533 0.0452398253 0.0893573261 0.0106369316 59.9 8.1 0.0391916476 0.1146131805 0.0446056563 0.1021226584 0.0123189405 67.1 8.04 0.0384306447 0.1318051576 0.0438446534 0.1174410571 0.0143976661 75.4 7.97 0.037542808 0.1518624642 0.0429568167 0.1353125224 0.0169101586 86.6 7.91 0.0367818052 0.1690544413 0.0421958139 0.1506309211 0.0191425736 95.7 7.84 0.0358939685 0.1891117479 0.0413079772 0.1685023863 0.0218443438 104.5 7.77 0.0350061318 0.2091690544 0.0404201405 0.1863738515 0.0246570379 116.4 7.69 0.0339914613 0.2320916905 0.03940547 0.2067983832 0.0280163593 129.1 7.6 [NaOH] 0.08853 limitante 0.032849957 0.2578796562 0.0382639657 0.2297759814 0.0319939368 143.7 7.51 [AcEt] 0.0993580174 0.0317084527 0.2836676218 0.0371224614 0.2527535795 0.0361988938 157.1 7.43 V NaOH (mL)-A 100 0.0306937822 0.3065902579 0.0361077909 0.2731781112 0.040143725 173.4 7.34 V Acetato de etilo (mL)-B 100 0.0295522779 0.3323782235 0.0349662866 0.2961557093 0.0448350203 185.5 7.27 CA0(mol/L) 0.044265 0.0286644413 0.3524355301 0.03407845 0.3140271745 0.0486846139 204 7.18 CB0(mol/L) 0.0496790087 0.027522937 0.3782234957 0.0329369457 0.3370047727 0.0539152388 222.2 7.09 θ 1.1223090187 0.0263814327 0.4040114613 0.0317954414 0.3599823708 0.0594912271 242.3 7 K0 8.5 0.0252399284 0.4297994269 0.0306539371 0.3829599689 0.0654480477 263.6 6.91 K∞ 5.01 0.0240984241 0.4555873926 0.0295124328 0.4059375671 0.0718262129 284.7 6.83 0.0230837536 0.4785100287 0.0284977623 0.4263620987 0.0778868429 307.4 6.74 k 0.0531953337 0.0219422493 0.5042979943 0.027356258 0.4493396969 0.0851934482 337.1 6.65 0.020800745 0.5300859599 0.0262147537 0.472317295 0.0930762776 359.4 6.57 0.0197860745 0.553008596 0.0252000832 0.4927418267 0.100624308 386.1 6.49 0.018771404 0.5759312321 0.0241854127 0.5131663584 0.1087418403 420.5 6.4 0.0176298997 0.6017191977 0.0230439084 0.5361439565 0.1186389861 449 6.33 0.016742063 0.6217765043 0.0221560717 0.5540154217 0.1269656208 482.7 6.25 0.0157273926 0.6446991404 0.0211414013 0.5744399534 0.1372420814 523 6.17 0.0147127221 0.6676217765 0.0201267308 0.5948644851 0.1484339075 560.3 6.1 0.0138248854 0.6876790831 0.0192388941 0.6127359503 0.1590783081 599 6.03 0.0129370487 0.7077363897 0.0183510574 0.6306074155 0.1706238549 649.3 5.95 0.0119223782 0.7306590258 0.0173363869 0.6510319472 0.1850776176 696.5 5.88 0.0110345415 0.7507163324 0.0164485503 0.6689034124 0.1989887778 754.4 5.81 0.0101467049 0.770773639 0.0155607136 0.6867748776 0.2142628286 811.7 5.74 0.0092588682 0.7908309456 0.0146728769 0.7046463428 0.2311124481 878.3 5.67 0.0083710315 0.8108882521 0.0137850402 0.7225178081 0.2497974926 955.6 5.6 0.0074831948 0.8309455587 0.0128972036 0.7403892733 0.2706390049 1074.8 5.51 0.0063416905 0.8567335244 0.0117556993 0.7633668714 0.3012620778 1184.4 5.44 0.0054538539 0.8767908309 0.0108678626 0.7812383366 0.3287187056 14.3 20.5 24.8 30.7 36.299999999999997 41 47.6 54.3 59.9 67.099999999999994 75.400000000000006 86.6 95.7 104.5 116.4 129.1 143.69999999999999 157.1 173.4 185.5 204 222.2 242.3 263.60000000000002 284.7 307.39999999999998 337.1 359.4 386.1 420.5 449 482.7 523 560.29999999999995 599 649 .29999999999995 696.5 754.4 811.7 878.3 955.6 1074.8 1184.4000000000001 8.5 8.4600000000000009 8.42 8.3699999999999992 8.32 8.27 8.2100000000000009 8.15 8.1 8.0399999999999991 7.97 7.91 7.84 7.77 7.69 7.6 7.51 7.43 7.34 7.27 7.18 7.09 7 6.91 6.83 6.74 6.65 6.57 6.49 6.4 6.33 6.25 6.17 6.1 6.03 5.95 5.88 5.81 5.74 5.67 5.6 5.51 5.44 Tempo (s) Condutividade molar (ms) 14.3 20.5 24.8 30.7 36.299999999999997 41 47.6 54.3 59.9 67.099999999999994 75.400000000000006 86.6 95.7 104.5 116.4 129.1 143.69999999999999 157.1 173.4 185.5 204 222.2 242.3 263.60000000000002 284.7 307.39999999999998 337.1 359.4 386.1 420.5 449 482.7 523 560.29999999999995 599 649.29999999999995 696.5 754.4 811.7 878.3 955.6 1074.8 1184.4000000000001 4.4264999999999999E-2 4.3757664756447004E-2 4.3250329512893981E-2 4.2616160458452707E-2 4.1981991404011466E-2 4.1347822349570199E-2 4.0586819484240699E-2 3.9825816618911179E-2 3.9191647564469911E-2 3.8430644699140384E-2 3.7542808022922633E-2 3.678180515759312E-2 3.5893968481375355E-2 3.5006131805157589E-2 3.3991461318051579E-2 3.2849957020057302E-2 3.1708452722063032E-2 3.0693782234957018E-2 2.9552277936962749E-2 2.866444126074498E-2 2.7522936962750714E-2 2.6381432664756448E-2 2.5239928366762181E-2 2.4098424068767908E-2 2.3083753581661894E-2 2.1942249283667628E-2 2.0800744985673358E-2 1.9786074498567341E-2 1.8771404011461323E-2 1.7629899713467054E-2 1.6742063037249285E-2
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