Trabalho - Termo de equilíbrio com reação

Esta é uma pré-visualização de arquivo. Entre para ver o arquivo original

Nossa resolução
	DeltaG 298	Estequiometria	T = 1400 K
	T	H2O	CO	CO2	i	H2	CO	H2O	CO2	N2	Total	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new
	1000	-192420	-200240	-395790	n i,0	0	0	1	0.5	1.88	3.38	0.1	0.7	959.1497005863	324.4304498458	-2277.0370025216	197.3372489441	52.6292942215	-1074.8055385977	0.4492933096	0.3238506196	0.5492933096	1.0238506196
	1100	-187000	-209110	-395960	ej	0.5493	1.0239	-232.5220200523	-75.2117941591	-3087.9323373889	-113.6524026807	-47.364220202	-1400.5642832139	-0.073415124	-0.051218316	0.4758781856	0.9726323036
	1200	-181380	-217830	-396020	j=1	0	2	0	-1	0	1	0.4759	0.9726	-6.1220422548	-1.9185352865	-2956.5581845876	-62.904252474	-31.5498319889	-1348.3162690317	-0.0020414074	-0.0013751441	0.4738367782	0.9712571594
	1300	-175720	-226530	-396080	j=2	1	1	-1	0	0	1	0.4738	0.9713	-0.004664356	-0.0014128318	-2952.9376850207	-61.4950931307	-31.1252365497	-1346.8917701549	-0.0000015585	-0.0000010129	0.4738352197	0.9712561465
	1400	-170020	-235130	-396130	0.4738	0.9713	-0.0000000027	-0.0000000008	-2952.9349454914	-61.4940188126	-31.1249237892	-1346.8907039516	-0	-0	0.4738352197	0.9712561465
	1500	-164310	-243740	-396160	0.4738	0.9713	0	0	-2952.9349454899	-61.4940188119	-31.124923789	-1346.890703951	0	0	0.4738352197	0.9712561465
	DeltaG0	k	T = 1500 K
	1000	1100	1200	1300	1400	1500	1.7578803422791309	11.404528813093613	53.155302543560964	194.79021704622548	583.34312236020503	1514.118052851386	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new
	-4690	-22260	-39640	-56980	-74130	-91320	2.5614721469	11.2190009309	38.6086391834	110.0638119316	268.7643140716	583.5770491014	0.1	0.7	2515.4053843675	719.2056195732	-5795.3662397782	569.6472211406	147.0731147304	-2296.2789505135	0.4677682235	0.3431646443	0.5677682235	1.0431646443
	-7820	-22110	-36450	-50810	-65110	-79430	0.5678	1.0432	-607.0498515598	-171.1759574685	-7833.7667334719	-189.7571342201	-66.9164814923	-3002.221085646	-0.0761514451	-0.0553191007	0.4916167783	0.9878455435
	0.4916	0.9878	-16.0209912278	-4.4739672912	-7502.792769452	-66.1499767641	-32.4207598898	-2887.9561130344	-0.0021218884	-0.0015253605	0.48949489	0.9863201831
	delta eA	=	dfA/deB	fB	-	fA	dfB/deB	0.4895	0.9863	-0.0123835015	-0.0034226548	-7493.5960837176	-62.7064217999	-31.4695801169	-2884.7916070228	-0.0000016428	-0.0000011685	0.4894932472	0.9863190145
	dfA/deA	dfB/deB	-	dfB/deA	dfA/deB	0.4895	0.9863	-0.0000000074	-0.000000002	-7493.5889834203	-62.7037562953	-31.4688514501	-2884.7891720389	-0	-0	0.4894932472	0.9863190145
	0.4895	0.9863	0	0	-7493.5889834161	-62.7037562937	-31.4688514497	-2884.7891720375	0	0	0.4894932472	0.9863190145
	T = 1000 K	T (K)	Quociente	y H2	y CO	y CO2	y H2O	y N2	Soma
	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new	1000	3.8630088706	0.1381	0.1119	0.1425	0.1207	0.4867	1
	0.1	0.7	-13.2608240677	-9.3879139278	-78.6447876938	-35.2968478631	-27.2315583559	-41.9385119299	-0.0961788437	-0.161398529	0.0038211563	0.538601471	1100	4.2133285672	0.1691	0.2265	0.0900	0.0683	0.4462	1
	0.0038211563	0.538601471	-2.546418051	-1.2484017389	-49.7224292816	-20.9775283077	-20.3621993612	-30.5622219202	-0.0472647954	-0.0093575184	-0.0434436391	0.5292439527	1200	4.5519268628	0.1879	0.3271	0.0402	0.0318	0.4130	1
	-0.0434436391	0.5292439527	-0.220555142	-0.0207996922	-41.2288394485	-16.7389580899	-19.9639296034	-28.1283238689	-0.0070933008	0.0042949756	-0.0505369399	0.5335389283	1300	4.7458651532	0.1972	0.3785	0.0147	0.0136	0.3961	1
	-0.0505369399	0.5335389283	-0.0019917781	0.0008804715	-40.4201210791	-16.3308238786	-20.1467300885	-28.020224491	-0.0000873465	0.0000942255	-0.0506242864	0.5336331537	1400	4.8250913662	0.2013	0.3977	0.0054	0.0060	0.3896	1
	-0.0506242864	0.5336331537	-0.0000001284	0.00000015	-40.4135422181	-16.3274516295	-20.1507404628	-28.0207586242	-0.0000000075	0.0000000108	-0.0506242939	0.5336331645	1500	4.8558122617	0.2031	0.4047	0.0022	0.0028	0.3872	1
	-0.0506242939	0.5336331645	0	0	-40.4135418673	-16.3274514447	-20.1507409211	-28.0207587896	0	0	-0.0506242939	0.5336331645
	Quociente	=	3,38+eA	 +eB
	T = 1100 K
	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new
	0.1	0.7	2.8683721755	1.4686271673	-115.1091189135	-31.4381884748	-24.6342997207	-75.5297236119	0.0215256049	0.0124237045	0.1215256049	0.7124237045
	0.1215	0.7124	-0.0698835172	-0.0185159862	-120.1797773112	-33.9026744258	-25.2706294515	-77.4079548715	-0.0005661527	-0.0000543736	0.1209594522	0.7123693308
	0.1210	0.7124	-0.0000321707	-0.000001669	-120.0713094734	-33.8487505597	-25.2678444888	-77.3755621152	-0.0000002884	0.0000000726	0.1209591638	0.7123694035
	0.1210	0.7124	-0	0	-120.0712633883	-33.8487271031	-25.2678482078	-77.3755518773	-0	0	0.1209591638	0.7123694035
	0.1210	0.7124	0	0	-120.0712633883	-33.8487271031	-25.2678482078	-77.3755518773	0	0	0.1209591638	0.7123694035
	T = 1200 K
	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new
	0.1	0.7	72.6756658528	35.815233536	-272.9270436147	-14.7378789826	-16.417408245	-181.8015200316	0.2568971453	0.1738029925	0.3568971453	0.8738029925
	0.3569	0.8738	-15.3372027262	-5.2802551633	-364.4842678779	-55.8972157893	-30.0798249722	-222.3685687885	-0.039251864	-0.0184359057	0.3176452813	0.8553670868
	0.3176	0.8554	-0.3083081938	-0.0768047014	-351.5762416145	-49.9331857299	-28.6306035137	-217.1220264815	-0.0008424687	-0.0002426484	0.3168028126	0.8551244384
	0.3168	0.8551	-0.0001229051	-0.0000195202	-351.3195733383	-49.8113006165	-28.6115292527	-217.0273585762	-0.0000003435	-0.0000000447	0.316802469	0.8551243938
	0.3168	0.8551	-0	-0	-351.3194759124	-49.8112530905	-28.6115257422	-217.0273263389	-0	0	0.316802469	0.8551243938
	0.3168	0.8551	0	0	-351.3194759124	-49.8112530905	-28.6115257422	-217.0273263389	0	0	0.316802469	0.8551243938
	T = 1300 K
	eA	eB	fA	fB	dfA/deA	dfA/deB	dfB/deA	dfB/deB	delta eA	delta eB	eA new	eB new
	0.1	0.7	309.4892429013	125.4200201623	-808.3070204347	41.9160868185	5.0191435795	-459.0475902947	0.3972791704	0.2775616822	0.4972791704	0.9775616822
	0.4973	0.9776	-75.2121257466	-26.5676371961	-1102.915114221	-78.3548099176	-36.6328204935	-590.8662778579	-0.0652871159	-0.0409161716	0.4319920544	0.9366455106
	0.4320	0.9366	-1.9387973319	-0.6186094182	-1055.7912290529	-58.7779023037	-30.4927838183	-570.425617887	-0.0017812719	-0.0009892499	0.4302107825	0.9356562607
	0.4302	0.9357	-0.0013756765	-0.0003917133	-1054.5404406517	-58.2488562032	-30.3443332094	-569.900982206	-0.0000012703	-0.0000006197	0.4302095122	0.935655641
	0.4302	0.9357	-0.0000000007	-0.0000000002	-1054.539572234	-58.24848235	-30.344240215	-569.9006303796	-0	-0	0.4302095122	0.935655641
	0.4302	0.9357	0	0	-1054.5395722336	-58.2484823498	-30.344240215	-569.9006303794	0	0	0.4302095122	0.935655641