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Welding and Joining of Advanced High Strength Steels (AHSS) Related titles The Welding Engineer’s Guide to Fracture and Fatigue (ISBN 978-1-78242-370-6) Control of Welding Distortion in Thin-plate Fabrication (ISBN 978-0-85709-047-8) Thermochemical Surface Engineering of Steels (ISBN 978-0-85709-592-3) Woodhead Publishing Series in Welding and Other Joining Technologies: Number 85 Welding and Joining of Advanced High Strength Steels (AHSS) Edited by Mahadev Shome and Muralidhar Tumuluru AMSTERDAM • BOSTON • CAMBRIDGE • HEIDELBERG LONDON • NEW YORK • OXFORD • PARIS • SAN DIEGO SAN FRANCISCO • SINGAPORE • SYDNEY • TOKYO Woodhead Publishing is an imprint of Elsevier Woodhead Publishing is an imprint of Elsevier 80 High Street, Sawston, Cambridge, CB22 3HJ, UK 225 Wyman Street, Waltham, MA 02451, USA Langford Lane, Kidlington, OX5 1GB, UK Copyright © 2015 Elsevier Ltd. All rights reserved. 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Because of rapid advances in the medical sciences, in particular, independent verification of diagnoses and drug dosages should be made. British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library Library of Congress Control Number: 2014957593 ISBN 978-0-85709-436-0 (print) ISBN 978-0-85709-858-0 (online) For information on all Woodhead Publishing publications visit our website at http://store.elsevier.com/ Typeset by TNQ Books and Journals www.tnq.co.in Printed and bound in the United Kingdom mailto:permissions@elsevier.com http://elsevier.com/locate/permissions http://store.elsevier.com/ http://www.tnq.co.in Contents List of contributors ix Woodhead Publishing Series in Welding and Other Joining Technologies xi 1 Introduction to welding and joining of advanced high-strength steels (AHSS) 1 M. Shome, M. Tumuluru 1.1 Introduction 1 1.2 Overview of major welding processes for AHSS 4 References 7 2 Properties and automotive applications of advanced high-strength steels (AHSS) 9 T.B. Hilditch, T. de Souza, P.D. Hodgson 2.1 The automobile body 9 2.2 AHSS microstructures and tensile properties 14 2.3 Formability and fracture of AHSS 22 2.4 Automotive in-service properties 24 2.5 Current and future trends in AHSS 25 References 27 3 Manufacturing of advanced high-strength steels (AHSS) 29 M.-C. Theyssier 3.1 Introduction 29 3.2 Key challenges faced in producing AHSS grades 30 3.3 Future trends 51 References 51 4 Resistance spot welding techniques for advanced high-strength steels (AHSS) 55 M. Tumuluru 4.1 Introduction 55 4.2 Characterizing welding behavior 56 4.3 General considerations in resistance spot welding of AHSS 59 4.4 Coating effects 64 4.5 Microstructural evolution in welds 65 vi Contents 4.6 Weld shear tension strength and cross-tension strength (CTS) 67 4.7 Summary 69 References 69 5 Laser welding of advanced high-strength steels (AHSS) 71 S.S. Nayak, E. Biro, Y. Zhou 5.1 Introduction 71 5.2 Background 72 5.3 Laser welding of AHSS 72 5.4 Microstructure of laser-welded AHSS 73 5.5 Hardness 78 5.6 Performance of laser-welded AHSS 84 5.7 Future trends 90 References 90 6 High-power beam welding of advanced high-strength steels (AHSS) 93 L. Cretteur 6.1 Introduction 93 6.2 Back to basics: fundamentals of high-power beam welding 95 6.3 Metallurgical phenomena in laser welding of AHSS 100 6.4 Laser-welded blanks (LWBs): issues related to the use of AHSS 106 6.5 Body-in-white joining applications 109 6.6 Conclusions 117 Acknowledgments 118 References 118 7 Hybrid welding processes in advanced high-strength steels (AHSS) 121 S. Chatterjee, T. van der Veldt 7.1 Introduction 121 7.2 Laser–arc hybrid process description 122 7.3 Laser–arc hybrid process parameters for welding automotive AHSS 124 7.4 Applications in the automotive industry 132 7.5 Costs and economics 133 References 134 8 Metal inert gas (MIG) brazing and friction stir spot welding of advanced high-strength steels (AHSS) 137 M. Shome 8.1 Introduction 137 8.2 MIG brazing 138 8.3 Friction stir spot welding (FSSW) 146 8.4 Conclusions 163 Acknowledgements 164 References 164 viiContents 9 Adhesive bonding techniques for advanced high-strength steels (AHSS) 167 K. Dilger, S. Kreling 9.1 Introduction: the exigency of adhesive bonding of high-strength steels 167 9.2 Challenges in adhesive bonding of AHSS 169 9.3 Boron–manganese steels: anticinder coatings and their influence on adhesive bonds 174 9.4 Weldbonding of AHSS 176 9.5 Conclusions 177 References 178 10 Mechanical fastening techniques for advanced high-strength steels (AHSS) 181 C. Hsu 10.1 Introduction 181 10.2 The use of drawn arc welding (DAW) for attaching studs to metals 181 10.3 Assessing the feasibility of DAW for stud welding of AHSS 183 10.4 Robotic stud welding 184 References 185 Index 187 This page intentionally left blank List of contributors E. Biro ArcelorMittal Global Research, Hamilton, ON, Canada S. Chatterjee Tata Steel Research and Development, Joining and Performance Technology, Wenckebachstraat, The Netherlands L. Cretteur ArcelorMittal R & D, Automotive Application Research Center, Montataire, France K. Dilger TU Braunschweig, Institute of Joining and Welding, Braunschweig, Germany T.B. Hilditch Deakin University, Waurn Ponds, Victoria, Australia P.D. Hodgson Deakin University, Waurn Ponds, Victoria, Australia C. Hsu Consultant, UK S. Kreling TU Braunschweig, Institute of Joining and Welding, Braunschweig, Germany S.S. Nayak University of Waterloo, Waterloo, ON, Canada M. Shome Research & Development, Tata Steel, Jamshedpur, India T. de Souza Deakin University, Waurn Ponds, Victoria, Australia M.-C. Theyssier ArcelorMittal R & D Center, Maizières les Metz, France M. Tumuluru Research and Technology Center, United States Steel Corporation, Pittsburgh, PA, USA T. van der Veldt Tata Steel Research and Development, Joining and Performance Technology, Wenckebachstraat, The Netherlands Y. Zhou University of Waterloo, Waterloo, ON, Canada This page intentionally left blank Woodhead Publishing Series in Welding and Other Joining Technologies 1 Submerged-arc welding Edited by P. T. Houldcroft 2 Design and analysis of fatigue resistant welded structures D. Radaj 3 Which process? A guide to the selection of welded and related processes P. T. Houldcroft 4 Pulsed arc welding J. A. Street 5 TIG and plasma welding W. Lucas 6 Fundamentals of welding metallurgy H. Granjon 7 Fatigue strength of welded structures S. J. Maddox 8 The fatigue strength of transverse fillet welded joints T. R. Gurney 9 Process pipe and tube welding Edited by W. Lucas 10 A practical guide to TIG (GTA) welding P. W. Muncaster 11 Shallow crack fracture mechanics toughness tests and applications Conference Proceedings 12 Self-shielded arc welding T. Boniszewski 13 Handbook of crack opening data T. G. F. Gray 14 Laser welding C. T. Dawes 15 Welding steels without hydrogen crackingN. Bailey and F. R. Coe 16 Electron beam welding H. Schultz 17 Weldability of ferritic steels N. Bailey 18 Tubular wire welding D. Widgery 19 Stress determination for fatigue analysis of welded components: Recommendations of IIW Commissions XIII and XV Edited by E. Niemi 20 The ‘local approach’ to cleavage fracture C. S. Wiesner xii Woodhead Publishing Series in Welding and Other Joining Technologies 21 Crack arrest concepts for failure prevention and life extension Seminar Proceedings 22 Welding mechanisation and automation in shipbuilding worldwide R. Boekholt 23 Heat treatment of welded steel structures D. Croft 24 Fatigue design of welded joints and components: Recommendations of IIW Joint Working Group XIII-XV Edited by A. Hobbacher 25 Introduction to the non-destructive testing of welded joints R. Halmshaw 26 Metallurgy of basic weld metal T. R. Gurney 27 Fatigue of thin walled joints under complex loading T. R. Gurney 28 Handbook of structural welding J. F. Lancaster 29 Quality assurance in adhesive technology A. W. Espie, J. H. Rogerson and K. Ebtehaj 30 Underwater wet welding and cutting TWI/Paton Electric Welding Institute 31 Metallurgy of welding Sixth edition J. F. Lancaster 32 Computer technology in welding Conference Proceedings 33 Exploiting advances in arc welding technology Conference Proceedings 34 Non-destructive examination of underwater welded structures V. S. Davey 35 Predictive formulae for weld distortion G. Verhaeghe 36 Thermal welding of polymers R. J. Wise 37 Handbook of mould, tool and die repair welding S. Thompson 38 Non-destructive testing of welds B. Raj, C. V. Subramanian and T. Jayakumar 39 The automotive industry: joining technologies TWI 40 Power generation: welding applications TWI 41 Laser welding TWI 42 Fatigue: welding case studies TWI 43 Fracture: welding case studies TWI 44 The welding workplace R. Boekholt 45 Underwater repair technology J. Nixon 46 Fatigue design procedure for welded hollow section joints: Recommendations of IIW Subcommission XV-E Edited by X.-L. Zhoa and J. A. Packer xiiiWoodhead Publishing Series in Welding and Other Joining Technologies 47 Aluminium welding N. R. Mandal 48 Welding and cutting P. T. Houldcrof and J. A. Packer 49 Health and safety in welding and allied processes J. Blunt 50 The welding of aluminium and its alloys G. Mathers 51 Arc welding control P. Julian 52 Adhesive bonding R. D. Adams 53 New developments in advanced welding Edited by N. Ahmed 54 Processes and mechanisms of welding residual stress and distortion Edited by Z. Feng 55 MIG welding guide Edited by K. Wenem 56 Cumulative damage of welded joints T. R. Gurney 57 Fatigue analysis of welded components: Recommendations of IIW Commissions XIII and XV E. Niemi 58 Advanced welding processes J. Norrish 59 Fatigue assessment of welded joints by local approaches D. Radaj 60 Computational welding mechanics Edited by L. E. Lindgren 61 Microjoining and nanojoining Edited by Y. N. Zhou 62 Real-time weld process monitoring Edited by Y. M. Zhang 63 Weld cracking in ferrous alloys Edited by R. Singh 64 Hybrid laser-arc welding Edited by F. O. Olsen 65 A quick guide to welding and weld inspection Edited by S. E. Hughes 66 Friction stir welding Edited by D. Lohwasser and Z. Chen 67 Advances in structural adhesive bonding Edited by D. Dillard 68 Failure mechanisms of advanced welding processes Edited by X. Sun 69 Advances in laser materials processing Edited by J. Lawrence and J. Pou 70 Welding and joining of magnesium alloys Edited by L. Lui 71 Fracture and fatigue of welded joints and structures Edited by K. MacDonald 72 Minimization of welding distortion and buckling Edited by P. Michaleris 73 Welding processes handbook Second edition K. Weman xiv Woodhead Publishing Series in Welding and Other Joining Technologies 74 Welding and joining of aerospace materials Edited by M. C. Chaturvedi 75 Tailor welded blanks for advanced manufacturing Edited by B. Kinsey and X. Wu 76 Adhesives in marine engineering Edited by J. R. Weitzenböck 77 Fundamentals of evaluation and diagnostics of welded structures A. Nedoseka 78 IIW recommendations for the fatigue assessment of welded structures by notch stress analysis W. Fricke 79 IIW recommendations on methods for improving the fatigue strength of welded joints P. J. Haagensen and S. J. Maddox 80 Advances in brazing Edited by D. P. Sekulic 81 Advances in friction-stir welding and processing M.-K. Besharati-Givi and P. Asadi 82 Self-piercing riveting Edited by A. Chrysanthou and X. Sun 83 Control of welding distortion in thin plate fabrication: Design support exploiting computa- tional simulation T. Gray, D. Camilleri and N. McPherson 84 The welding engineer’s guide to fracture and fatigue P. L. Moore and G. S. Booth 85 Welding and joining of advanced high strength steels (AHSS) Edited by M. Shome and M. Tumuluru Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00001-1 Copyright © 2015 Elsevier Ltd. All rights reserved. Introduction to welding and joining of advanced high-strength steels (AHSS) M. Shome1, M. Tumuluru2 1Research & Development, Tata Steel, Jamshedpur, India; 2Research and Technology Center, United States Steel Corporation, Pittsburgh, PA, USA 1 1.1 Introduction Fuel efficiency, lowering carbon emissions and passenger safety have been the main drivers in designing automobiles for the past two decades. Vehicle weight reduction was identified as a key strategy to minimize fuel consumption. For enhanced passenger safety, automotive structures that have a higher energy absorption in a crash situation would be ideal. Advanced high-strength steels (AHSSs) were developed to support these strategic requirements. A recent report from World Steel Dynamics projected that by 2025 the usage of AHSSs would reach 23.7 million tons. This means that a significant part of the low-carbon steel parts would be replaced by AHSSs (http://www.autosteel.org, report of October 4, 2014). Reductions in automotive mass and government regulations on crash requirements seem to have mutually opposing directions: fuel economy is ensured but safety can seemingly be endangered by lighter vehicles. However, studies to date using AHSSs for automobile designs have shown that reducing the weight of vehicles can be achieved without compromising passenger safety. AHSSs are extensively used in the automobile industry for manufacturing several body-in-white parts of vehicles. Auto designers have introduced these steels in critical structural parts such as the A, B and C pillars; the roof rails and bow; cross-members; door beams; front and side members; and as bumper reinforcement. They also are exten- sively used in internal panels made of tailor-welded blanks. AHSSs exhibit ultimate tensile strengths of 600 MPa or higher, allowing vehicle manufacturers to make major strides in terms of the strength and rigidity of thinner-gauge sheets. In addition to high tensile properties these steels have good ductility, the capacity for high energy absorption and a high work-hardening coefficient over the uniform elongation regime. Dual-phase (DP), complex-phase (CP), transformation-induced plasticity (TRIP) and martensitic steels are the prevalent AHSS grades that are currently in commercial use. These grades are referred to as first-generation AHSSs. The relationship between the strength and ductility (as measured by elongation) of these steel grades is shown in Figure 1.1. AHSS are multiphase steels that contain various concentrations of ferrite, bainite, mar- tensite and retained austenite phases. The proportion of these phases and their morpholo- gies are engineered to obtain the functional characteristics of a steel (Bhattacharya, 2011, p. 163; Davies, 2012; Galán,Samek, Verleysen, Verbeken, & Houbaert, 2012; Kuziak, Kawalla, & Waengler, 2008; Senuma, 2001). DP steels are commercially available http://www.autosteel.org 2 Welding and Joining of AHSS from 500 to 1180 MPa, whereas TRIP and CP steels are available up to 980 MPa strength. These steel grades are used in applications that require high strength and high ductility (and hence good formability), as well as good weldability. Several stud- ies have clearly shown the excellent weldability of these steel grades (Radakovic & Tumuluru, 2012; Sharma & Molian, 2011; Tumuluru, 2013). Some of the applications of these steels include B pillars and body inners. The microstructure of DP steels consists of ferrite and martensite, which provide the necessary strength and meets elongation requirements. Higher strength implies that there is a larger volume fraction of martensite in the steel. DP steels are used in both hot-rolled and cold-rolled con- ditions. Hot-rolled DP steel is mostly used for the structural parts and wheels of cars. Continuous yielding characteristics are a special feature of DP steels that ensures a smooth surface after the forming operation. TRIP steels contain ferrite, bainite and retained austenite phases. The retained austenite is transformed into martensite under a strain-induced deformation effect, absorbing significant amounts of energy; there- fore TRIP steel is a designer’s choice for making crash-resistant components. Another category of AHSSs is martensitic steel. These steels are currently available with strength from 900 to 1900 MPa. The microstructure of these steels consists essentially of martensite. These steels are alloyed with carbon, manganese and chromium to achieve the required strength. Martensitic steels have high stiffness and anti-intrusion characteristics for passenger safety. Because of their higher carbon content—more than is contained in either DP or TRIP steels—martensitic steels are used in applications that generally do not require welding. Some examples of their application include door intrusion beams and bumpers. Cold-rolled DP and TRIP steels are processed in continuous annealing lines. Typi- cal production methods for DP and TRIP steels are shown in Figure 1.2. For DP steel Figure 1.1 The strength versus elongation relationship for first-generation advanced high- strength steels. HSLA, high strength, low alloy; TRIP, transformation-induced plasticity. 3Introduction to welding and joining of AHSS production, the cold-rolled, fully hard strip is subjected to intercritical (α + γ) annealing, followed by rapid cooling so that the austenite transforms into martensite. A uniform distribution of about 10% volume fraction of martensite in the ferrite matrix results in an excellent strength–ductility combination, low-yield strength–to–tensile strength ratio and a high work-hardening index. TRIP steels are produced by applying a two-stage heat treatment process. The cold-rolled sheets are heated to the intercritical temperature and held there for a short time, allowing austenite to form. The annealing tempera- ture and time determine the austenite volume fraction and carbon concentration. In the second stage the coils are rapidly cooled and isothermally held at a temperature at which a bainitic reaction occurs. The carbon rejected during the bainitic transforma- tion enriches the remaining austenite and stabilizes it. For galvanized and galvannealed steels, the same heat treatment concept is followed. For coating purposes, the sheets are cooled from the intercritical temperature and passed through a galvanizing bath kept at 460 °C (Liu et al., 2012). The silicon content in AHSSs is kept very low to avoid adhesion problems in galvanizing baths. Strength improvements for coated AHSSs are achieved through alloying with elements such as manganese and chromium. While these steels have a combination of superior mechanical properties, their application in terms of forming and welding requires a different approach than the one used for low-carbon steels. During welding, the heat produced alters the micro- structure of the base material and therefore the mechanical properties. The heating and cooling rates are extremely rapid in all welding processes during automotive body manufacturing. The peak temperature observed in the fusion zone (FZ) is above the melting point of steel and is somewhat lower in the heat-affected zone (HAZ). In the HAZ there is significant austenite grain growth followed by phase transformation; consequently, the microstructure formed is different from that of the base metal. The task, therefore, is to control the thermal conditions by applying appropriate welding parameters. Solid-state welding and alternative joining techniques have recently been tested to preserve the functional properties of AHSSs without worrying much about temperature-related damage to the microstructure caused by conventional welding. Ferrite α α αM γ Pearlite Bainite M α γ Ferrite Pearlite Bainite M Hold Soak α αM (a) (b) Figure 1.2 Typical production methods for dual-phase (a) and transformation-induced plasticity steels (b). 4 Welding and Joining of AHSS Welding is an integral part of automobile manufacturing and is carried out through various processes. There are advantages and disadvantages of each process. An over- view of the most common processes with respect to welding and joining AHSSs are briefly discussed. 1.2 Overview of major welding processes for AHSS 1.2.1 Resistance spot welding DP steels are easily weldable and have been commercially implemented in current automo- tive designs (Radakovic & Tumuluru, 2012). The typical requirement for spot welds is to have a minimum load-bearing capacity equivalent to or greater than that of the base metal. The load capacity formula includes the thickness of the sheet, the weld nugget diameter and the ultimate tensile strength of the steel (Radakovic & Tumuluru, 2008, 2012). The nugget diameter depends on the welding parameters and is critical for AHSS because it largely controls the type of weld failure under quasi-static and dynamic loading conditions. Spot welds can fail in any of the following three modes: interfacial failure, in which the fracture propagates through the nugget; pull-out failure, in which the weld nugget separates from the parent metal; and partial interfacial failure, in which the fracture initially propagates through the nugget and then deviates through the sheet thickness, similar to pull-out failure. Pull-out failure is preferred because it is associated with high-load bearing capacity and high energy absorption. Recent work has shown that interfacial fractures are the expected mode in AHSSs and that welds that fail with the interfacial fracture mode have a load-bearing ability that is 90% of welds that fail with a pull-out mode (Radakovic & Tumuluru, 2008; Tumuluru, 2006b). Work done on the entire range of DP steels of 590-, 780- and 980-MPa strength shows a certain pattern of nugget failure during shear tensile tests. Full-button pull-out fracture occurs when the weld nugget size is large, and interfacial fracture occurs when the nuggets are small (Tumuluru, 2008; Radakovic & Tumuluru, 2012). A separate study of DP600 spot welds showed that thicker sheets are more prone to interfacial failure (Tumuluru, 2006a). The crack is initiated at the edge of the weld nugget and at the inter- face between the two sheets because of strain localization (Ma et al., 2008; Dancette et al., 2012). However, the load-bearing capacity of the nuggets with interfacial failure was high and acceptable. For AHSSs, the strength of the spot weld is given prominence over the type of fracture while qualifying the welds (Radakovic & Tumuluru, 2012). In the case of spot-welded TRIP780 steel, the hardness of the FZ depends on the composition of the steel. Carbon (C)–manganese (Mn)–aluminium, C–Mn–aluminium– silicon (Si)or C–Mn–Si steel welds have varying proportions of ferrite, bainite and martensite. The weld nugget of the first steel contains a mixture of ferrite, bainite and martensite, whereas in the second it is mostly martensite with some bainite. C–Mn–Si steel welds contain only martensite, and therefore the hardness was the highest among all the TRIP compositions (Nayak, Baltazar Hernandez, Okita, & Zhou, 2012). Properly designed welds rarely fail under actual conditions, and confirmation tests indicate that the failure loads are on par with the base metal strengths. Still, any attempt to weld high-strength steels calls for special attention in terms of nugget 5Introduction to welding and joining of AHSS diameter, defects in the FZ and the type of microstructure. While large nugget diame- ters may seem to be the panacea for the problem, they have to be viewed in the context of HAZ softening, zinc loss in coated steels and electrode life. 1.2.2 Gas metal arc welding Gas metal arc welding (GMAW) is mostly applied in chassis parts, where it is import- ant to secure the strength and rigidity of the joint. The process also has the freedom to join parts of various shapes to structural members such as pipes and brackets. Long fatigue life of the weld joint is a prerequisite. Spatter, fit-up and gap issues need to be dealt with in parts formed during welding. Certain component designs preclude the use of resistance spot welds. Further, there are closed parts that cannot be reached with resistance spot welding guns. For such applications, the GMAW process is preferred. The GMAW process is also known as metal inert gas or metal active gas weld- ing. Carbon dioxide is the active shielding gas in the latter process. Consumables with matching strengths are preferred to meet the mechanical property requirements of the joint, but lower-strength wires have been used to attain mechanical properties by depos- iting extra material. One can refer to auto steel partnership program reports in which welding parameters and weld joint properties for various AHSS combinations have been reported (A/SP Joining Technologies, 2004). Consumable ER70S3 wires and shielding gas comprising 90% argon and 10% carbon dioxide produced acceptable welds. Higher heat input GMAW causes the HAZ to soften in DP steels, which in turn affects the fatigue properties. Studies have been carried out to correlate the effect of weld geome- try and microstructure on the fatigue properties of AHSS butt welds. Some showed that the bead geometry and microstructure could act as a notch for the initiation and propagation of cracks under fatigue conditions. The lowest hardness point is in the subcritical HAZ of DP590 steel, and most samples fail in this location during tensile testing, regardless of the bead geometry. Specimens with large beads (convex profile with higher height to width ratio) show a significantly shorter fatigue life, with fractures initiated at the toe of the weld. A shallow bead, that is, lower height/width ratio, with appropriate microstructure can improve fatigue performance in GMAW welds (Ahiale & Jun Oh, 2014). For welding galvannealed AHSS, wires with chemical composition of low silicon to manganese ratio have typically been used with a welding angle less than 30°. The weld pool flows in the direction of the arc and prevents the formation of blow holes and porosities, which is a major issue during arc welding of zinc-coated sheets. The beads are flatter with a smooth curvature at the toe region. In fact, a welding wire with low silicon content and a base metal with higher silicon content gives the best bead profile. 1.2.3 Laser welding In the past two decades laser welding has become popular because lasers have high power density (108 W/cm2) and hence are able to weld steels at high speeds to meet stringent productivity targets. It provides a narrow HAZ compared with that in con- ventional arc welding processes. This feature augers well for AHSSs. Carbon dioxide lasers are the most common lasers used for sheet metal fabrication, particularly for 6 Welding and Joining of AHSS manufacturing tailor-welded blanks involving combinations of AHSS and low-carbon formable steel. However, high-power fibre and disc lasers are being extensively used to weld AHSSs by several automotive manufacturers. With high heating and cooling rates, AHSSs normally form martensite in the weld metal. The small HAZ, even if softened, has a minimal effect on the overall mechan- ical properties. Welded samples usually fail in the parent metal, indicating that the joints are sound (Nemecek, Muzik, & Misek, 2012). Laser welding of galvanized steel in a zero-gap lap joint configuration is challenging because of the vigorous gen- eration of zinc vapour at the faying surface, which causes porosity. Dual-beam laser welding has recently been successfully used to join galvanized sheets in a zero-gap lap joint configuration. In the first beam a defocused laser is used to burn the zinc on the top surface and the interface, which prepares the surface for better absorption during the second pass. In the second pass a stable keyhole is formed to help vent any zinc vapour produced. Welding of coated DP980 steel resulted in porosity-free, partially penetrated lap joints without any spatter or blow holes. The welding process was sta- ble. During tensile shear testing, the joints failed in the HAZ zone, with satisfactory mechanical properties (Maa, Konga, Carlsonb, & Kovacevica, 2013). 1.2.4 Adhesive joining and weld bonding Adhesives serve the purpose of enhancing the stiffness of a member by providing a continuous joint. As there are concerns regarding the durability of adhesive joints under different environmental conditions, the weld bonding process is preferred by several manufacturers. This process involves a combination of spot welding and adhe- sive joining, wherein the benefits of durability provided by spot welding and stiffness provided by adhesives are leveraged. For AHSSs, high-strength structural adhesives with good wettability and flow char- acteristics have been used. They are spread over the overlap area and cured to obtain a suitable bond strength. In the case of weld bonding, spot welding is done soon after the adhesive is applied. Hence the adhesive thickness must be kept small to allow spot welding to happen. A thick and dense adhesive may either impede the passage of a current or cause heavy expulsion, neither of which is acceptable. Hybrid joints have several advantages such as reduced stress concentration around the nugget in spot welds, enhanced strength and higher energy absorption for failure and improved stiffness (Bartczak, Mucha, & Trzepiecinski, 2013). In weld-bonded joints of DP600 and DP800 steels the shear strength has been reported to be greater than that of a spot-welded joint (Bartczak et al., 2013; Hayat, 2011). Epoxy-based, high-strength structural adhesives have provided the requisite shear strength value. During shear tensile testing, a high level of shearing stress exists at the outer and inner edges of the overlap. Due to of the presence of the adhesive layer, a lower stress exists at the notch of the weld nugget in weld-bonded joints as compared to spot welds. The weld-bonded joint strength of DP590 steel was 40% higher than that of a spot-welded joint and 15% higher than an adhesive joint. For DP780 weld bonds, the strength was higher by 58% over spot-welded joints and 39% higher than adhesive joints. An identical adhesive was used for both the weld bond and adhesive joints (Sam & Shome, 2010). 7Introduction to welding and joining of AHSS 1.2.5 New technology Over the years there have been major advances in machine technology. The use of inverter- based medium-frequency direct current spot and seam welding processes has become common, especially in countries where power costs are high. This technology has addi- tional benefits when weldingAHSS because of the low and sustained energy input. Metallurgical alterations and burn through caused by high heat input are common problems during arc welding of thin AHSS sheets. Therefore, low welding currents using small-diameter wires (e.g. 0.8 mm) are preferred to ensure low heat input. The recently developed cold metal transfer technology does provide low heat input and low spatter compared with direct current metal active gas systems. The cold metal transfer wire feeder unit can control the forward and backward movement and syn- chronize it with the current wave form. By doing so it can shorten the arcing time and hence the welding heat input. As a result, shallow beads with a low wetting angle at the toe region are obtained (Kodama et al., 2013). The alternating current GMAW process has been recently developed to overcome the burn through problem of sheet metal. In this process the advantage of the arc stability of direct current electrode-positive mode and the high melting rate of direct current elec- trode-negative mode are combined. In the latter mode, the wire melting rate is high and therefore penetration is limited. Consequently, there is a better gap-bridging effect (Arif & Chung, 2014). The control of drop size and drop transfer governs the gap-bridging ability in the alternating current GMAW process and is significant for obtaining defect-free welds. In the laser welding space the introduction of high-power disk lasers and fibre lasers have recently had a widespread impact. These lasers are available in powers exceeding 5 kW in continuous wave mode, and they have high efficiency and excel- lent beam quality that enable deep penetration at high welding speeds. Ytterbium:yt- trium–aluminium–garnet disk lasers produce excellent beam characteristics. Major automotive companies are using these lasers for three-shift production at lower operating costs than conventional lasers (Sharma & Molian, 2011). Application of ytterbium:yttrium–aluminium–garnet lasers on prestrained, cold-rolled DP980 and TRIP780 steels created butt welds without any porosity, undercut, burn through or convexity. Though HAZ softening in DP980 steel continues to be an issue, such softening was highly localized and narrow. Therefore, the impact of HAZ softening was minimized and did not affect the overall mechanical properties of the welded coupons. References A/SP Joining Technologies Committee Report. (2004). Advanced high strength steel (AHSS) weld performance study for auto body structural components. Ahiale, G. K., & Jun Oh, Y. (2014). Microstructure and fatigue performance of butt-welded joints in advanced high-strength steels. Material Science Engineering A, 597, 342. Arif, N., & Chung, H. (2014). Alternating current-gas metal arc welding for application of thin sheets. Journal of Materials Processing Technology, 214, 1828. Bhattacharya, D. (2011). Metallurgical perspectives on advanced sheet steels for automotive applications. In Advanced steels (p.163). Berlin: Springer. 8 Welding and Joining of AHSS Bartczak, B., Mucha, J., & Trzepiecinski, T. (2013). Stress distribution in adhesively-bonded joints and the loading capacity of hybrid joints of car body steels for the automotive indus- try. International Journal of Adhesion & Adhesives, 45, 42. Dancette, S., Fabrègue, D., Massardier, V., Merlin, J., Dupuy, T., & Bouzekri, M. (2012). Inves- tigation of the tensile shear fracture of advanced high strength steel spot welds. Engineer- ing Failure Analysis, 25, 112. Davies, G. (2012). Material for automobile bodies. London: Butterworth-Heinemann. Galán, J., Samek, L., Verleysen, P., Verbeken, K., & Houbaert, Y. (2012). Advanced high strength steels for automotive industry. Revista de Metalurgia, 48(2), 118. Hayat, F. (2011). Comparing properties of adhesive bonding resistance spot welding and adhe- sive weld bonding of coated and uncoated DP 600 steel. JISR International, 18(9), 70. Kodama, S., Ishida, Y., Furusako, S., Saito, M., Miyazaki, Y., & Nose, T. (2013). Arc welding technology for automotive steel sheets. Nippon Steel Technical Report, 103, 83. Kuziak, R., Kawalla, R., & Waengler, S. (2008). Advanced high strength steels for the automo- tive industry. Archives of Civil & Mechanical Engineering, VIII. Liu, H., Li, F., Shi, W., Swaminathan, S., He, Y., & Rohwerder, M. (2012). Challenges in hot-dip galvanizing of high strength dual phase steel: surface selective oxidation and mechanical property degradation. Surface Coating & Technology, 206, 3428. Maa, J., Konga, F., Carlsonb, B., & Kovacevica, R. (2013). Two-pass laser welding of gal- vanized high-strength dual-phase steel for a zero-gap lap joint configuration. Journal of Materials Processing Technology, 213, 495. Ma, C., Chen, D. L., Bhole, S. D., Boudreau, G., Lee, A., & Biro, E. (2008). Microstructure and fracture characteristics of spot-welded DP600 steel. Material Science Engineering A, 485, 334. Nayak, S. S., Baltazar Hernandez, V. H., Okita, Y., & Zhou, Y. (2012). Microstructure-hardness relationship in the fusion zone of TRIP steel welds. Material Science Engineering A, 551, 73. Nemecek, S., Muzik, T., & Misek, M. (2012). Differences between laser and arc welding of HSS steel. Physics Procedia, 39, 67. Radakovic, D. J., & Tumuluru, M. (2008). Predicting resistance spot weld failure modes in shear tension tests of advanced high-strength automotive steels. Welding Journal, 87, 96-s–105-s. Radakovic, D. J., & Tumuluru, M. (2012). An evaluation of the cross-tension test of resistance spot welds in high strength dual phase steels. Welding Journal, 91, 8S–15S. Sam, S., & Shome, M. (2010). Static and fatigue performance of weld bonded dual phase steel sheets. Scientific World Journal, 15, 242. Senuma, T. (2001). Physical metallurgy of modern high strength steel sheets. Iron and Steel Institute of Japan International, 41, 520. Sharma, R. S., & Molian, P. (2011). Weldability of advanced high strength steels using an Yb:YAG disk laser. Journal of Materials Processing Technology, 211, 1888. Tumuluru, M. D. (August 2006a). Resistance spot welding of coated high strength dual-phase steels. Welding Journal, 31. Tumuluru, M. (2006b). A comparative examination of the resistance spot welding behavior of two advanced high strength steels. In SAE Technical Paper No. 2006-01-1214, presented at the SAE Congress, Detroit, MI. Tumuluru, M. (2008). Some considerations in the resistance spot welding of dual phase steels. In Paper presented at the 5th International Seminar on advances in resistance welding, Septem- ber 24–26, 2008, Toronto, Canada. Weston, Ontario, Canada: organized by Huys Industries. Tumuluru, M. (2013). Evolution of steel Grades, joining Trends and Challenges in the automo- tive Industry. In Invited keynote presentation, American welding society FABTECH Weld- ing Show and Conference, Chicago IL. Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00002-3 Copyright © 2015 Elsevier Ltd. All rights reserved. Properties and automotive applications of advanced high-strength steels (AHSS) T.B. Hilditch, T. de Souza, P.D. Hodgson Deakin University, Waurn Ponds, Victoria, Australia 2 2.1 The automobile body The automobile body is a highly complex structure that must simultaneously meet numerous functional, cost and aesthetic requirements. These requirements range from being a simple fixture to which other key subsystems are attached, such as the power- train and suspension, to providing controlled crush zones for crashworthiness. These functions must generally be low cost and suitable for mass production. The automo- bile body also establishes its unique style, an extremely critical design and marketing function. Vehicle styling is often one of the more dominant design factors and often the first point at which the vehicle’s form is developed. A typical mass-produced, passenger vehicle body is a large assemblyof stamped sheet metal components. Each component can serve a variety of specific structural and functional requirements. As a result, the geometry, material type and grade of the components vary significantly. 2.1.1 Body structure design requirements The key performance requirements of an automobile body structure include structural static stiffness, durability, safety or crashworthiness and noise vibration and harsh- ness. While the entire body structure must meet these requirements, at a basic level the many individual components can be categorised into two classes (Malden, 2011): 1. Parts that react to loads with minimal deformation 2. Parts that react to loads with significant deformation, which enhances the functions of the part. It is, therefore, important to distinguish between these two functions. The first is dominated by stiffness properties, and the second depends on the strength and energy absorption characteristics of the structure. Stiffness: The stiffness of a structural member is a function of the material’s modulus of elasticity and the geometry of the component, in particular its moment of inertia. Most components require a suitable amount of stiffness to meet loading requirements, in particular body components that support chassis/suspension components, and provide suitable reductions in noise vibration and harshness. Furthermore, the automobile body itself must have high levels of static bending and torsional stiffness to accommodate 10 Welding and Joining of AHSS road input loads and allow the ride and handling to be tuned. The elastic modulus of all steel grades is constant; therefore, component geometry is the primary design parameter. Substituting a steel grade with a higher strength or advanced high-strength steel (AHSS) does not improve component stiffness; however, the added formability of AHSS allows additional geometric form to be added to improve component stiffness. The additional component stiffness allows for reductions in the sheet thickness to reduce mass. Strength: The strength of a component depends on its geometry and the material yield and tensile strengths. Strength-dominated components may be required to sup- port a significant load with a controlled level of deformation to the structure. Other components may require a high level of energy absorption for very little deformation. For these strength-dominated components there is an obvious advantage of applying higher-strength materials, such as AHSS. 2.1.2 Body structure types Numerous body structure types have been explored, all with their own level of success for specific applications. The most common forms are described below and shown in Figure 2.1. A summary of the advantages and disadvantages of each architecture type is also provided. 1. Body on frame: the upper body structure is separated from a lower frame. The frame consists of a series of longitudinal and lateral closed-profile beams forming a ladder structure. This frame is the major load-bearing member. The body-on-frame architecture progressed from coach building and was one of the first vehicle architectures. Its use these days is limited to light trucks and niche vehicles. 2. Spaceframe: a three-dimensional network of constant cross-sectional beams connected by shared nodes. These nodes are often welded intersections of the beams or cast joints or sometimes are adhesively bonded. The spaceframe structure separates itself from the styling surface and, as a result, can be optimised towards a structural and lightweight solution. The complexity of the joining methods, however, often limits production volumes to small num- bers and high-performance niche vehicles. 3. Central tunnel: dominated by a large, closed-profile structural member situated along the symmetrical axis of the vehicle. This closed tunnel integrates with suspension loading points and provides the majority of the vehicle’s structural integrity. The large tunnel is obtrusive to the occupant compartment and limited to applications in two- and four-seater vehicles. Body on frame Spaceframe Central tunnel Monocoque (d)(c)(b)(a) Figure 2.1 Comparison of various automobile body architectures: body on frame (a), spaceframe (b), central tunnel (c) and monocoque (d). Adapted from Malden (2011). 11Properties and automotive applications of AHSS 4. Monocoque construction: integration of the vehicle’s exterior body and structural frame. The monocoque is the most common body structure type. It consists of stressed thin-wall panels, which form the exterior styling surface, integrated with closed-profile members. The combination of stressed skins and beam sections forms the major load-bearing members. The vehicle’s style dictates the initial form of the body; therefore a trade-off between the most structurally efficient solutions is made early. However, the monocoque construction provides a good balance in meeting this trade-off. Automated stamping lines and robotic spot-welding facilities make it cost-effective at high production volumes. Being the most common automobile body architecture, the requirements of the sheet material have driven the development of steel over the years, in particular the development of AHSS. The design approaches for monocoque construction of automobile bodies are the primary focus of the subsequent sections. 2.1.3 The elements of an automobile body The typical passenger vehicle body makes up approximately 20% of the total mass of the vehicle (Davies, 2012), yet is the largest physical subsystem. The body in white (BIW) is the primary subassembly of the vehicle’s body and is often described as the ‘skeleton’ of the vehicle. The BIW can be segregated into the ‘body-less doors’ and the ‘hang-on’ skin panels. At a high level, the automobile body has two distinct safety features: an impene- trable safety cell or occupant compartment and dedicated crumple zones. The safety cell must withstand extremely high loads with minimal deformation or intrusion. The dedicated crumple zones, however, are optimised to collapse in a controlled manner, absorbing the maximum amount of energy possible. Numerous crash-testing scenarios and standards are continually being introduced to ensure occupant safety in vehicles is improved. For conventional monocoque construction, a combination of thin-sheet panels, closed-profile beams, joints and supporting brackets is used to perform its many func- tions. The primary structure typically consists of longitudinal and lateral floor mem- bers and a three-dimensional frame (safety cell). The safety cell consists of vertical pillars (A, B, C/D pillars), lateral roof beams, corner joint supports and the roof panel itself, as shown in Figure 2.2. Each of these structural elements is designed to suit various loading requirements and meet specific functional requirements. • Exterior body panels, such as door skins, bonnets and the roof panel, require high levels of stiffness and resistance to dent for out-of-plane loads. They require an ‘A’ class surface finish and their geometry is usually complex, requiring highly formable materials. • The main floor and front/rear bulkheads react to in-plane loading, requiring moderate strength levels and rigidity. Some complex geometric form is required for stiffness; therefore suitable material formability is needed. • Longitudinal and lateral beam sections provide tensile/compressive/bending stiffness and controlled impact resistance. These components often consist of an inner, outer and internal reinforced stamped profile spot-welded together along a common flange. A variety of strength grades are needed for these components, depending on their function. Structural elements in the safety cell require very high strength but little or no deformation, whereas elements in the crushable zones undergo significant deformation to absorb maximum energy. 12 Welding and Joining of AHSS While geometryplays a pivotal role in each of these component categories, the materials applied are equally if not more important. Therefore, to meet these per- formance requirements, a number of different material types and grades are used in the automobile body. Furthermore, demands by government legislation and consumer requirements for improved safety and vehicle efficiency have become more stringent over the past two decades. These performance changes have challenged automotive designers and material suppliers to develop new technologies to meet these growing needs. 2.1.4 Material usage trends Steel is the primary material used for automobile body structures because of its versa- tility and cost. Sheet steels used in the automotive industry have conventionally been chosen for their good formability characteristics, allowing them to be conveniently stamped at room temperature into the designed component shapes. These initial steels had a predominantly ferrite microstructure, resulting in relatively low strength levels and high ductility. The strengthening of steel using mechanisms such as solid solution strengthening, grain refinement and precipitation strengthening all typically result in a decrease in formability. This trade-off in formability had previously limited the use of higher-strength steel (and hence thinner-gauge steel) in the automotive industry. Figure 2.3 shows the reduction in elongation with increasing yield strength for a range of steels, including conventional high-strength steel (HSS) currently used in automo- tive body structures, such as high-strength low-alloy (HSLA) and bake-hardenable steels. These traditional steels have an ultimate tensile strength less than 600 MPa. In the 1980s, low-strength, drawing quality steel dominated the automobile body, with only a small fraction of hot-rolled higher-strength steel used. Figure 2.2 A brief overview of some key body structure elements. Adapted from AISI (1998). 13Properties and automotive applications of AHSS In the past several decades, the importance of safety and vehicle emissions has increased. This has led to the need for higher-strength steels to improve the crash per- formance of automotive structures while allowing for a reduction in thickness. There was also an imperative to introduce higher-strength sheet steels while maintaining formability to allow automotive manufacturers to retain existing manufacturing pro- cesses and equipment, as well as to maintain design flexibility. The Ultralight Steel Auto Body (ULSAB) project (AISI, 1998) provided a launch- ing pad for the introduction of AHSS for use in automobile bodies, to the point that current passenger vehicles have a significant amount of AHSS in key structural and crash-optimised areas. The first-generation AHSS introduced in sheet metal struc- tures, such as dual-phase (DP) and transformation-induced plasticity (TRIP) grades, had a yield strength range similar to that of conventional HSS grades, with higher work-hardening rates and formability. This was achieved using a ferrite matrix to pro- vide ductility with a harder second phase to provide strength. In the case of TRIP steels, metastable austenite was retained in the microstructure to provide further ductility and work hardening to higher strain levels. This improved strength–ductility combination for these grades is shown in Figure 2.3 as a deviation above the normal elongation–strength curve that the lower-strength sheet steel grades follow. Increasingly stringent emissions laws between 2000 and 2010 led to the need for increasingly higher strength grades. The introduction of higher-strength DP and TRIP grades (tensile strength of 800 MPa) posed greater challenges; while they can be cold Figure 2.3 Elongation versus yield strength for the different classes of sheet steel. AHSS, advanced high-strength steel; BH, bake-hardenable; CMn, carbon–manganese; CP, complex phase; DP, dual phase; HSLA, high strength, low alloy; HSS, high-strength steel; IF, interstitial-free; MS, martensitic; TRIP, transformation-induced plasticity; TWIP, twinning-induced plasticity. 14 Welding and Joining of AHSS stamped, the significantly higher press forces cause difficulties in terms of dimen- sional control because of springback and curl, as well as tool wear. The introduction of 1000-MPa tensile strength DP and TRIP grades and 1000–1500-MPa martensi- tic grades has resulted in the need for changes in the forming processes from tradi- tional cold stamping, with alternative processes such as roll forming, hydroforming and hot stamping. This has led more recently to a range of alternative methods to produce martensitic sheet grades based on stamping the material, either at high temperatures or while in a softened state and heat treating afterwards, to achieve necessary strength levels. In addition to the more widespread usage of DP, TRIP and martensitic steels in automotive structures, several more specialised grades have also been developed. Ferrite–bainite (FB) grades were developed and introduced in response to the poor performance of steel containing martensite in stretch-flange or hole expansion appli- cations, whereas complex-phase (CP) steels were developed for components requiring low strain to form and for which a high yield strength is beneficial. There are a number of newer-generation steels being developed with the automo- tive sheet steel industry in mind. Twinning-induced plasticity (TWIP) steels are part of the second-generation AHSS that cover the same tensile strength ranges as DP and TRIP but have significantly higher ductility. This greater ductility comes at a large alloying cost, which is a major barrier to widespread usage. Other variations of multi- phase microstructures also are being developed, particularly based on austenite as the dominant microstructural constituent. 2.2 AHSS microstructures and tensile properties There are a number of different steel grades typically classified as either first- or second-generation AHSSs that are available or being developed for use in automotive applications. The Future Steel Vehicle Program (WorldAutoSteel, 2011), designed to highlight the potential of steels for use in 2015–2020 vehicles, used a number of these, including DP, TRIP, CP, FB, martensitic, hot-forming and TWIP. AHSS grades are commonly designated by their nominal tensile strength (e.g. DP600 has a nominal minimum tensile strength of 600 MPa). 2.2.1 Dual phase DP steels have a microstructure that typically consists of martensite islands surrounded by a ferrite matrix, as shown in Figure 2.4. Basic steel processing involves a short annealing time in the intercritical (ferrite and austenite) region of the phase diagram to produce a structure of ferrite and austenite. Partitioning occurs during annealing, causing the austenite to become enriched with carbon. Sufficiently rapid cooling follows to transform the austenite to martensite. The chemical composition is based on an approximate weight percentage of 0.1 carbon and 1.5 manganese, though this varies slightly depending on the grade. The higher carbon and manga- nese contents compared with conventional sheet steels are important to obtain the 15Properties and automotive applications of AHSS necessary hardenability, which assists in preventing pearlite or bainite from forming during processing. Silicon can be added to promote the partitioning of carbon to austenite. DP steels are typically characterised by continuous yielding and a low yield-to-tensile strength ratio that results in high initial work-hardening rates. The continuous, low yield strength is related to the soft ferrite phase, whereas the high tensile strength is related to the hard martensite regions. The volume change associated with the austenite-to-martensite transformation during processing generates dislocations in the ferrite matrix, which fur- ther contribute to the low yield strength and thecontinuous yielding behaviour. The increased strain-hardening rate of DP steels compared with conventional low-carbon and HSLA steels is shown in Figure 2.5. A higher work-hardening rate means that after forming, the DP steel has a higher flow stress/strength level than the HSLA grade. This higher flow stress is beneficial in part for both fatigue and crash behaviour, and it allows thinner-gauge material to be used. The common range of DP grades designed for the automotive industry is DP500 to DP1000. The tensile strength of DP steels increases with an increase in the volume fraction of martensite, as shown in Figure 2.6 (Davies, 1978). Lower-strength grades have approximately 20% martensite. There is a reasonably linear trade-off between tensile strength (volume fraction of martensite) and ductility for DP grades (Sakuma, 2004). The ductility of DP steels is comparable to or better than HSLA grades with a similar tensile strength. Figure 2.6 shows that the yield strength of a DP steel also increases linearly with increasing martensite volume fraction (Davies, 1978). Because the soft ferrite matrix is primarily responsible for the deformation that occurs within the materials, the dis- tribution or ‘island’ size of martensite has an effect on the uniform elongation and the tensile strength (Llewellyn & Hudd, 1998), whereas the ferrite grain size can influence the yield strength for a given martensite volume fraction (Ramos, 1979). It has been suggested that the optimum combination of strength and formability is obtained by a very fine distribution of martensite islands and a very fine ferrite grain size (Llewellyn & Hudd, 1998). DP600 and DP780/800 are widely used in the automotive industry. Figure 2.4 Scanning electron image of a dual-phase steel microstructure showing ferrite (F) and martensite (M) (Kang, Han, Zhao, & Cai, 2013). 16 Welding and Joining of AHSS 9000 8000 7000 6000 5000 4000 3000 2000 1000 0 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0.22 HSLA 350 DP 600 IF steel True strain St ra in -h ar de ni ng ra te (M Pa ) Figure 2.5 Increase in strain-hardening rate of dual-phase (DP) steels compared with conventional steels for a range of true strains. HSLA, high strength, low alloy; IF, interstitial-free. Tensile strength Percent martensite 10 20 30 40 50 60 70 80 90 100 Flow stress (ε = 0.002) 30 0 20 0 10 00 0 20 00 10 0 0 730 740 760 780 800 820 840 Quench temp. °C K Si St re ss (M Pa ) Figure 2.6 Effect of martensite volume on both the yield and tensile strength of dual-phase steel (Davies, 1978). 17Properties and automotive applications of AHSS 2.2.2 Transformation-induced plasticity TRIP steels are a multiphase steel typically containing ferrite, retained austenite, and bainite and/or martensite, as shown in Figure 2.7. Austenite can be made stable at room temperature by accumulating enough carbon during processing to depress the temperature at which austenite transforms to martensite below room temperature. TRIP steels are intercritically annealed in the ferrite and austenite region, similar to DP steels, but are cooled to a temperature of approximately 400 °C (austempering temperature) to develop the transformation product (bainite). During intercritical annealing, the carbon partitions to the austenite. During austempering, the bainite formation rejects more carbon into the austensite. The austempering time and tem- perature thus are a trade-off between the amount of bainite formed, the stability of the austenite (and hence the martensite formed upon cooling) and the amount of austenite retained at room temperature. The chemical composition of a TRIP steel is based on carbon–manganese, with either silicon or aluminium additions. Both carbon and manganese concentrations are higher in TRIP steels than in DP steels, with a weight percentage of approximately 0.1–0.15 carbon and ∼2.0 manganese for a TRIP600 steel. The addition of silicon or aluminium assists in suppressing carbide formation during bainitic transformation, thus making it easier for carbon to be rejected into the austenite. Available TRIP steel grades cover the same approximate ultimate tensile strength range as DP steels (500–1000 MPa). Higher-strength grades of TRIP steel typically retain more austenite and other transformation products (bainite and/or martensite) and hence less low-strength ferrite. While TRIP steels have higher yield strength than DP steels for a given ultimate tensile strength, they also have greater elongations. The instantaneous work-hardening rate of TRIP steels is lower Figure 2.7 Scanning electron image of a transformation-induced plasticity steel micro- structure showing bainite (B), martensite (M) and retained austenite (RA) in a ferrite matrix (Chiang, Lawrence, Boyd, & Pilkey, 2011). 18 Welding and Joining of AHSS than DP steels at low strains, but the improved ductility results in an increase in work-hardening rate with increasing strain, whereas that of DP steel decreases (Figure 2.8). In addition to the higher relative yield strength, TRIP steels also tend to show discontinuous yielding, although the amount of yield point elonga- tion is generally low. The superior strength/ductility combination of TRIP steels, as shown in Figure 2.3, compared with conventional steels grades is due to the transformation of the retained austenite to martensite during room temperature deformation. This transformation occurs as the austenite that is retained at room temperature is metastable and transforms into martensite if subjected to enough strain. The transformation delays the onset of necking, leading to a high uniform elongation. Not all austenite transforms during straining (Streicher, Speer, & Matlock, 2002), however, and this is because the carbon content of the retained austenite is too high or, alternatively, the orientation, size or morphology of the retained austenite regions are unsuitable for transformation. The volume fraction of austenite transformation is also dependent on the strain path, though it does not appear to vary significantly between different forming modes (Sugimoto, Kobayashi, Nagasaka, & Hashimoto, 1995). 2.2.3 Complex phase CP steels have an ultimate tensile strength of around 800–1200 MPa while retain- ing a reasonable level of ductility (approximately 7–15%). They have higher carbon Figure 2.8 Comparison of instantaneous work hardening (n-value) between high-strength, low-alloy (HSLA), transformation-induced plasticity (TRIP) and dual-phase (DP) steels. 19Properties and automotive applications of AHSS and manganese concentrations than DP and TRIP steels (around 0.15 wt% carbon and 2 wt% manganese) and a microstructure that often contains ferrite and bainite with small amounts of pearlite, martensite and retained austenite. These steels have a very fine microstructure obtained via alloying additions such as titanium, vanadium and niobium that form precipitates to assist in preventing grain growth during processing. The highly refined grain size, combined with the presence of precipitates and harder phases such as martensite, ultimately results in a material with a high yield strength. The high yield strength (approximately 600–1000 MPa) means that these steels have a lower work-hardening rate compared with DP and TRIP steels, although they are still formable using conventional cold stamping processes (though to less complex geometry). 2.2.4 Ferrite–bainite FB steels are a variation of DP steel that combines ferrite with bainite as a sec- ond phase instead of martensite. The properties of FB steels are thus similar to ferrite–martensite DP steels, though with slightly lower strength values for a given second-phase volume fraction due to bainite being a lower-strength phase than martensite. FB steels cover a tensile strength range of approximately 500–900 MPa, with a corresponding total elongation of 30–10%. The FBsteels were primarily developed for edge-stretching applications where DP and TRIP steels can result in poor formability because of premature cracking (particularly for sheared edges). The improved performance of FB steels in these applications is due to the decreased likelihood of cracks forming in bainite during shearing operations (such as hole punching or blanking). 2.2.5 Martensitic steels Martensitic steels have a predominantly lath martensite microstructure, as shown in Figure 2.9, and are formed by continuous annealing in the austenite region followed by rapid quenching of the steel. Higher hardenability is achieved by increased carbon content, typically of the order of 0.25 weight percent carbon. The manganese content is also reasonably high, around 1.5 Mn, and small additions of boron may also be included to further increase hardenability. The increased hardenability via alloying reduces the quenching time necessary to achieve a fully martensitic structure. Martensitic sheet steels have tensile strengths ranging from 900 to 1600 MPa, with total elongations typically around 4–7%. The yield stress ranges from 800 to 1350 MPa, meaning that these steels have very low work-hardening behaviour. The strength is also related to the carbon content of the microstructure, with increasing carbon resulting in increasing strength. Forming martensitic steels is difficult because of the exceptionally high yield stress and low ductility. At room temperature, roll forming is the primary shaping method. Roll forming limits the complexity of part design using martensitic steels, thus limit- ing the potential uses of martensitic steels. 20 Welding and Joining of AHSS 2.2.6 Hot-formed steels Hot-formed steels are a variation of martensitic steels that are designed to be formed at temperatures in excess of 850 °C and quenched at rates faster than 50 °C/s. The preheated sheet steel typically has an aluminide coating to limit oxidation and is formed at temperatures in the austenite region where the formability is high. The component is then rapidly quenched via water jets while still under load in the die/ press (Vaissiere, Laurent, & Reinhardt, 2002). Hot-formed steels typically have small boron additions (between 0.002% and 0.005%) for high hardenability to ensure that martensite is formed during quenching. There are two alternative pro- cesses: the direct process, where all forming is done at elevated temperatures, and the indirect process, where some forming is initially done at room temperature with steel in a softened state before final forming at elevated temperatures. The processes have much lower productivity than conventional cold stamping, but are achieving increased usage as the only way to produce complex shapes at strength levels of approximately 1000–1300 MPa. 2.2.7 Post-forming heat-treated steels Post-forming heat-treated steels are fully formed at room temperature while the steel is in a softened state. After forming, the component is heat treated and quenched to obtain a high-strength microstructure. Fast quenching to obtain a martensitic micro- structure often requires fixtures to prevent distortion, although some air-hardening grades that show a bainitic and/or martensitic microstructure are currently available. These air-hardened steels are based on a composition of approximately 0.15% carbon, with additions of silicon, manganese, chromium, molybdenum, vanadium and nitro- gen. Yield and tensile strengths are similar to those of the martensitic sheet steels, with ductility similar to HSLA steels. 20kV ×3000 2 µm Figure 2.9 Scanning electron image of a martensitic microstructure (M1200) (Wang et al., 2013). 21Properties and automotive applications of AHSS 2.2.8 Twinning-induced plasticity TWIP steels have an austenitic structure at room temperature that is stable because of a high manganese content (ranging from 15% to 30%) and a carbon content of 0.6%. As TWIP steels are strained, deformation-nucleated twins (Frommeyer, Brux, & Neumann, 2003; Prakash, Hochrainer, Reisacher, & Reidel, 2008) typically form in the austenitic structure because of a low stacking fault energy (SFE). The twins act as dislocation barriers and reduce the effective mean free path of dislocations, which increases the flow stress. These twins are quite thin, and there is a continuous nucleation of new, increasingly smaller deformation twins. These steels also have a high rate of dislocation accumulation independent of twin formation due to reduced cross-slip resulting from the low SFE. The resulting tensile strength ranges of TWIP steels are similar to those of DP and TRIP steels (600–100 MPa); however, the tensile ductility range is significantly higher at 40–80% (Figure 2.10). Ductility and strength are related to the manganese content; smaller manganese additions typically show higher strength and lower ductility. The high total elongation levels present a chal- lenge for automotive usage because significantly higher strains need to be imparted to the component than those that normally occur in traditional stamping processes to get similar final component strength levels in TRIP and DP steels. Aluminium and silicon are other alloying additions that are often made to TWIP steels. Aluminium increases the SFE, which suppresses martensite transformation, whereas silicon decreases the SFE, which sustains the martensite transformation (Frommeyer et al., 2003). As a result, steels with larger silicon additions have a higher strength and tend to transform to martensite rather than twin (behaving more like a TRIP steel), whereas aluminium additions lower tensile strength and work hardening. Figure 2.10 Strength versus ductility ranges for common twinning-induced plasticity steels. Al, aluminium; C, carbon; Fe, iron; Mn, manganese; N, nitrogen; Si, silicon; TS, tensile strength; YS, yield strength (DeCooman, Chin, & Kim, 2011). 22 Welding and Joining of AHSS 2.3 Formability and fracture of AHSS There are a range of issues related to the manufacturing and performance of automo- tive structures. The forming mode in particular can have a major effect on the way a steel is able to meet shape requirements without extensive thinning or cracking. Sheet formability is generally expressed through a forming limit diagram (FLD), whereas other forming issues relate to hole expansion and fracture behaviour. Elastic recovery after a part is formed is a major issue with AHSS, and this is reflected in springback behaviour. 2.3.1 Forming limits There are a range of different forming modes that are relevant in sheet metal stamp- ing of AHSS. The forming limits are often characterised as the critical necking strain for a strain mode using an FLD. In general, increased formability is related to the distribution of strain during forming, and as such work hardening is a key parame- ter. The higher work hardening of DP and TRIP steels compared with conventional HSLA steels results in higher forming limits in most forming modes (Keeler & Brazier, 1975). TWIP steels have better stretch-forming properties than AHSS of simi- lar strength. DP, TRIP and TWIP steels are fairly isotropic, however, and r values tend to be around 1. Lower r values limit the deep drawability of AHSS. When stamping mild and conventional HSS, failure is typically localised neck- ing, followed by splitting. Failure behaviour of DP and TRIP steels can be accurately described using an FLD in cases where localised necking occurs. When stamping an AHSS, such as DP980, with a large amount of bending under tension or on stretched edges, fracture can occur where there is limited thinning. While there is a ductile frac- ture surface, there are very large cracks and a large amount of elastic energy release. This fracture initiation can be difficult to predict. This type of fracture has occurred in DP steel in biaxial stretching rather than normal thinning and splittingand was poten- tially related to differences in the strength of the different phases, that is, soft ferrite and hard martensite (Nikhare, Hodgson, & Weiss, 2011), as shown in Figure 2.11. 2.3.2 Hole expansion Shearing processes, such as blanking and punching, are commonly used in sheet metal stamping either before or during forming. In many instances the sheared edge of the sheet may be exposed to a subsequent forming process that causes it to elongate, such as stretch-flanging or hole expansion. While the hole expansion limit tends to decrease with an increase in material tensile strength, inhomogeneous microstructures, partic- ularly those containing martensite, have poorer hole expansion limits (such as DP and TRIP steels). The implication means that many of the AHSS grades that contain martensite are not suited to stamping processes such as stretch-flanging (AISI, 2003a). This particular limitation is the main impetus in the development of FB steels; bainitic or ferrite–bainitic microstructures are significantly better in this particular forming mode than those containing martensite. 23Properties and automotive applications of AHSS 2.3.3 Dimensional accuracy Dimensional accuracy is of vital importance in sheet-formed body structure compo- nents because of subsequent assembly requirements. Elastically driven shape changes such as springback and curl can occur once the component is released from the die. Since these shape changes increase in magnitude with increasing flow strength and decreasing material thickness, they are a significantly greater issue in the use of AHSS compared with conventional drawing steels (Davies, 1984). Considerable recent research is directed toward both quantifying and predicting the amount of springback in a given forming process. Tooling design can compensate for these shape changes using methods such as increasing the blank holder force; however, this often requires accurately predicting the shape change using numerical simulations. Hot-formed and post-forming heat-treated steels are advantageous in this instance because forming is completed while the steel is in a softened state; hence shape change due to elastic recovery processes is not a significant issue. 2.3.4 Bake hardening After an automotive body structure has been assembled it typically is painted. The rela- tively high dislocation density present in both the unstrained (as received) and strained (after forming) ferrite means that DP and TRIP steels typically show bake-harden- ing properties (Fredriksson, Melander, & Hedman, 1989). This means that there is a significant increase in flow stress after exposure to times and temperatures similar Figure 2.11 Forming limit diagram (FLD) of dual-phase (DP) versus transformation-induced plasticity (TRIP) versus high-strength, low-alloy (HSLA) steels, showing the higher forming strains before necking for the advanced high-strength steels and lower fracture limits (Nikhare et al., 2011). 24 Welding and Joining of AHSS to that encountered in the automotive paint-baking process (approximately 170 °C for 20 min). The flow stress increase is due to the diffusion of soluble carbon (and nitrogen) to mobile dislocations within the structure that results in the dislocations being pinned and resistant to further motion. This strength increase is beneficial in most aspects of automotive applications, including dent resistance (Dicello & George, 1974), fatigue and crash behaviour (AISI, 2003b). 2.4 Automotive in-service properties Automotive body structures often are designed to provide stiffness to the vehicle, withstand vibration and fatigue loading during normal use, as well as provide pas- senger safety in crash events. While in most cases it is assumed that fatigue failure will be dominated by the joints in the structure, crash safety is provided by both the geometry of the component and the properties of the metal. Components that are used in crash applications require either deformation resistance or high energy absorption during deformation. These are both required at high strain rates, often up to 200/s. 2.4.1 Deformation resistance The passenger safety cage requires high deformation resistance; hence the higher strength the better. AHSSs are better than conventional steels for deformation-resistance applications because of their higher yield strength; martensitic steels have the high- est yield strength, in excess of 800 MPa. Because of the low yield strength-to-tensile strength ratio of DP steels, these steels require higher levels of strain during forming to achieve higher strength levels in the final part/application. As with all steels, an increase in strain rate results in an increase in both the yield stress and tensile strength of AHSSs (AISI, 2003b; Choi et al., 2002). The magnitude of the increase depends on the initial strength of the steel; higher-strength steels are generally less sensitive to strain rate (AISI, 2003b). This effect is shown in Figure 2.12, where the ultimate tensile strength ratio at 100/s to 10−3/s is plotted against the tensile strength of various steel grades. Thus, while AHSSs do not achieve the same increase in strength as conventional sheet Figure 2.12 Reduction in the increase in tensile strength as a result of an increase in strain rate with increasing tensile strength for a range of different steels (ULSAB, 2001). BH, bake-hardenable; CP, complex phase; DP, dual phase; HSLA, high strength, low alloy; IF, interstitial free; Mart, martensite; UTS, ultimate tensile strength. 25Properties and automotive applications of AHSS steels, there is still a noticeable positive increase. While the n value tends to decrease with increasing strain rate for conventional steels, for many AHSSs the n value remains fairly constant with increasing strain rate. 2.4.2 Energy absorption The motor compartment is predominantly designed for crush and hence is suited to steels that allow higher energy absorption. The strength and thickness of these com- ponents typically need to be balanced with section size such that under axial load- ing the sections collapse in a stable and uniform manner (Horvath & Fekete, 2004). Energy absorption is the area under a stress–strain curve and thus highly depends on the tensile strength of a material. Energy absorption can be calculated either at neck- ing, showing the total energy that can be absorbed by a material, or, alternatively, at a specified strain level to allow materials to be compared for a given strain. In crash sit- uations it has been suggested that the majority of energy is absorbed at plastic strains of up to 10% (ULSAB, 2001), and this strain level is often used to compare the energy absorption capability of different materials. There can be a significant difference in the energy absorption ability of a particular steel grade, depending on the strain level spec- ified (AISI, 2003b; Bleck, Larour, & Baumer, 2004). When examining AHSS, higher elongation grades such as TRIP600 and TRIP780 have the highest energy absorption at necking, as shown in Figure 2.13, whereas higher-strength grades such as TRIP980 have a higher 10% strain energy absorption, as shown in Figure 2.10. The higher yield strength means that CP steels have very high energy absorption capacity in the elastic and low plastic strain range, which is useful for applications where very little forming strain is introduced into the material. Martensitic steels typically have only around 6% elongation and are thus not considered for energy absorption applications. The work-hardening exponent of a material is also an important factor in energy absorption during a crash. Higher work hardening distributes strain more evenly and causes a greater volume of material within a part to undergo deformation, hence greatly increasing the total energy absorption. TWIP, TRIP and DP steels have higher n values compared with conventional steels, whereasboth CP and martensitic steels have relatively low n values. Work-hardening values typically decrease with increas- ing strength of the AHSS. 2.5 Current and future trends in AHSS In recent years there has been significant research into developing the third generation of AHSSs. While second-generation AHSSs such as TWIP steels show superior strength– ductility combinations, they are often considered incompatible with current automo- tive stamping processes because of the exceedingly high deformation levels required to obtain maximum strength, and the significantly higher alloying contents make cost and welding significant issues. A number of concepts are currently being used to develop third-generation AHSSs that show improved combinations of strength and ductility compared with the first generation, without the alloying cost of the second generation. 26 Welding and Joining of AHSS One example is lowering the manganese content from the typical TWIP con- centrations to between 4 and 6 wt%. These steels exhibit a combination of TRIP and TWIP behaviours. However, this manganese concentration can still lead to pro- cessing difficulties and associated costs. Other attempts have included combining ultrafine ferrite grain sizes in a TRIP steel by controlled thermomechanical process- ing. Again, laboratory results show promise, but implementation in a production 0.200 0.180 0.160 0.140 0.120 0.100 0.080 0.060 0.040 0.020 0.000 0.001 0.01 0.1 Strain rate (1/s) (T S+ YS )* U E/ 2 (J /m m 3 ) 1 10 100 1000 DP600-Gl DP600-HR DP800-GA TRIP590-EG TRIP600-CR TRIP780-CR TRIP980-CR (a) 0.1 0.09 0.08 0.07 0.06 0.05 0.04 0.03 0.02 0.01 0 0.001 0.01 0.1 1 10 100 1000 Strain rate (1/s) E 10 % (J /m m 3 ) DP600-GlDP600-HR DP800-GA TRIP590-EG TRIP600-CR TRIP780-CR TRIP980-CR (b) Figure 2.13 Effect of strain rate on energy absorption before necking (a) and at 10% strain (b) for different transformation-induced plasticity (TRIP) and dual-phase (DP) steels. AISI (2003b), with kind permission from the Steel Market Development Institute. 27Properties and automotive applications of AHSS environment seems difficult. Overall, this is one of the major concerns with any new steel grade. The cost pressures are such that these steels really do need to be able to be processed along with other grades without major processing changes. They also need to demonstrate high levels of product uniformity and repeatability within and between batches. This is a real challenge for these more complex strip compositions and processing routes. One option that has attracted considerable research interest is the quenching and partitioning process; this involves compositions that are similar to current grades and a heat treatment process that is commercially feasible, although to date the work is restricted to the laboratory. Quenching and partitioning steels have a higher range of tensile strength than TRIP and DP steels (1300–1800 MPa), with elongation in the range of 16–18% (Cao, Wang, Shi, & Dong, 2010). References AISI. (1998). UltraLight steel auto body final report. American Iron and Steel Institute. AISI. (2003a). Formability characterization of a new generation of high-strength steels. American Iron and Steel Institute/U.S. Department of Energy Technology Roadmap Program. Report No. TRP 0012. AISI. (2003b). Characterization of fatigue and crash performance of new generation high-strength steels for automotive applications. American Iron and Steel Institute/U.S. Department of Energy Technology Roadmap Program. Report No. TRP 0038. Bleck, W., Larour, P., & Baumer, A. (2004). High strain rate tensile testing of modern car body steels. In J. F. Nie, & M. Barnett (Eds.), Paper presented at the 3rd International Conference on Advanced Materials Processing (pp. 21–29). Australia: Institute of Materials Engineering. Cao, W., Wang, C., Shi, J., & Dong, H. (2010). Application of quenching and partitioning to improve ductility of ultrahigh strength low alloy steel. Materials Science Forum, 654–656, 29–32. Chiang, J., Lawrence, B., Boyd, J. D., & Pilkey, A. K. (2011). Effect of microstructure on retained austenite stability and work hardening of TRIP steels. Materials Science and Engineering A, 528, 4516–4521. Choi, I. D., Bruce, D. M., Kim, S. J., Lee, C. G., Park, S. H., Matlock, D. K., et al. (2002). Deformation behavior of low carbon TRIP sheet steels at high strain rates. ISIJ Interna- tional, 42(12), 1483–1489. Davies, R. G. (1978). Influence of martensite composition and content on the properties of dual- phase steels. Metallurgical Transactions A, 9A, 671–679. Davies, R. G. (1984). Side-wall curl in high strength steels. Journal of Applied Metalworking, 3(2), 120–126. Davies, G. (2012). Materials for automobile bodies. Boston, MA: Butterworth-Heinemann. DeCooman, B. C., Chin, K., & Kim, J. (2011). High Mn TWIP steels for automotive applications. In M. Chiaberge (Ed.), New trends and developments in automotive system engineering. InTech, ISBN: 978-953-307-517-4. http://dx.doi.org/10.5772/14086. Available from http://www.intechopen.com/books/new-trends-and-developments-in-automotive-system- engineering/high-mn-twip-steels-for-automotive-applications. Dicello, J. A. G., & George, R. A. (1974). Design criteria for the dent resistance of auto body panels. SAE Technical Paper No. 740081. Detroit, MI: SAE World Congress. http://dx.doi.org/10.5772/14086 http://www.intechopen.com/books/new-trends-and-developments-in-automotive-system-engineering/high-mn-twip-steels-for-automotive-applications http://www.intechopen.com/books/new-trends-and-developments-in-automotive-system-engineering/high-mn-twip-steels-for-automotive-applications 28 Welding and Joining of AHSS Fredriksson, K., Melander, A., & Hedman, M. (1989). Influence of prestraining and ageing on the fatigue properties of a dual-phase sheet steel with tensile strength of 410 MPa. Scandinavian Journal of Metallurgy, 18, 155–165. Frommeyer, G., Brux, U., & Neumann, P. (2003). Supra-ductile and high-strength manganese TRIP/TWIP steels for high energy absorption purposes. ISIJ International, 43(3), 438–446. Horvath, C. D., & Fekete, J. R. (2004). Opportunities and challenges for increased usage of advanced high strength steels in automotive applications. Paper presented at the Interna- tional Conference on Advanced High Strength Sheet Steels for Automotive Applications, Winter Park, CO. Kang, Y., Han, Q., Zhao, X., & Cai, M. (2013). Influence of nanoparticle reinforcements on the strengthening mechanisms of an ultrafine-grained dual phase steel containing titanium. Materials and Design, 44, 331–339. Keeler, S. P., & Brazier, W. G. (1975). Relationship between laboratory material characteriza- tions and press shop formability. Microalloying, 75, 517–530. Llewellyn, D. T., & Hudd, R. C. (1998). Steels – metallurgy and applications (3rd ed.). Oxford: Butterworth Heinemann. Malden, D. E. (2011). Fundamentals of automobile body structure design. SAE International. Nikhare, C., Hodgson, P., & Weiss, M. (2011). Necking and fracture of advanced high strength steels. Materials Science and Engineering A, 528, 3010–3013. Prakash, A., Hochrainer, T., Reisacher, E., & Reidel, H. (2008). Twinning models in self-consistent texture simulations of TWIP steels. Steel Research International, 79(8), 645. Ramos, L. F. V. (1979). A study of strengthening mechanisms of the Fe-C-Mn dual-phase steels. M.S. Thesis No. T-2189. Golden, CO: Colorado School of Mines. Sakuma, Y. (2004). Recent achievements in manufacturing and application of high-strength steel sheets for automotive body structure. In Paper presented at the International Conference on Advanced High Strength Sheet Steels for Automotive Applications, Winter Park, CO. Streicher, A. M., Speer, J. G., & Matlock, D. K. (2002). Forming response of retained austenite in a C-Si-Mn high strength TRIP sheet steel. In Paper presentedat the International Conference on TRIP Steels, Ghent, Belgium. Sugimoto, K., Kobayashi, M., Nagasaka, A., & Hashimoto, S. (1995). Warm stretch-formability of TRIP-aided dual phase sheet steels. ISIJ International, 35(11), 1407–1414. ULSAB. (2001). ULSAB-AVC body structure materials. Technical Transfer Dispatch #6. Available from http://www.autosteel.org/∼/media/Files/Autosteel/Programs/ULSAB-AVC /avc_ttd6.pdf. Accessed 12.11.12. Vaissiere, L., Laurent, J. P., & Reinhardt, A. (2002). Development of pre-coated boron steel for applications on PSA Peugeot Citroen and RENAULT bodies in White. SAE Paper No 2002-01-2048. Detroit, MI: SAE World Congress. Wang, W., Li, M., He, C., Wei, X., Wang, D., & Du, H. (2013). Experimental study on high strain rate behavior of high strength 600–1000 MPa dual phase steels and 1200 MPa fully martensitic steels. Materials and Design, 47, 510–521. WorldAutoSteel. (2011). Future steel vehicle overview report. Available from http://c315221. r21.cf1.rackcdn.com/FSV_OverviewReport_Phase2_FINAL_20110430.pdf. Accessed 12.11.12. http://www.autosteel.org/%7E/media/Files/Autosteel/Programs/ULSAB-AVC/avc_ttd6.pdf http://www.autosteel.org/%7E/media/Files/Autosteel/Programs/ULSAB-AVC/avc_ttd6.pdf http://c315221.r21.cf1.rackcdn.com/FSV_OverviewReport_Phase2_FINAL_20110430.pdf http://c315221.r21.cf1.rackcdn.com/FSV_OverviewReport_Phase2_FINAL_20110430.pdf Welding and Joining of Advanced High-Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00003-5 Copyright © 2015 Elsevier Ltd. All rights reserved. Manufacturing of advanced high-strength steels (AHSS) M.-C. Theyssier ArcelorMittal R & D Center, Maizières les Metz, France 3.1 Introduction For any advanced high-strength steels (AHSS) family,1 the automotive customer is awaiting a differentiation in a product’s properties. This can be summarized through the following simplified requirements: • Higher yield strength (YS) and tensile strength (TS) associated with a minimum required elongation • Adapted range of the YS-to-TS ratio • Better bending properties and/or an improved hole expansion ratio • Good weldability in homogeneous and heterogeneous configurations These requirements are achieved thanks to a combination of phase constituents with an appropriate mix of soft and hard phases. This necessitates higher alloying contents compared with reference grades (such as classical interstitial-free [IF] steels or high-strength, low alloyed [HSLA] grades). To successfully achieve the final required properties, the best or optimal combina- tion of metallurgical phase constituents in the final product necessitates the optimal adaptation of alloying content and process settings: the so-called ‘metallurgical route’. For steels with high strength levels (>780 MPa) in particular, this implies the appro- priate adjustments of carbon (C) and manganese (Mn) and additions of all types of alloying and micro-alloying elements, including silicon (Si), chromium (Cr), molybde- num (Mo), aluminium (Al), boron (B), vanadium (V), titanium (Ti) and niobium (Nb). The metallurgical concepts are obtained through the optimal balance of the different phases (ferrite, austenite, bainite, martensite) with suitable mixing and structures. This higher alloying content not only has a positive impact on the final properties, as required by the automotive customer in the context of making vehicles lighter (car- bon dioxide emissions control), it also has an impact on the production of the grades and generates technical challenges all along the processing route. This chapter gives an overview of key challenges faced when producing AHSS grades during steelmaking, from liquid steel to coated strips. Internal soundness and 1 The final delivery state of the considered AHSS product – hot rolled, cold rolled and annealed, cold rolled and annealed and electrogalavanized or cold rolled and galvanized states. A general remark about this chapter: even if several of the comments could apply to them, the chapter is not specifically adapted to very high amounts of manganese (e.g. twinning-induced plasticity steels) nor very high contents of aluminium (‘low density’ steels), which are at the first steps of their industrial history. 3 30 Welding and Joining of AHSS quality, the possible occurrence of surface defects, phase transformation along the route and the hardness value of semi-finished products are described and linked with the consequences on production capability. Globally, these challenges have been addressed by steelmaking plants for the past 5–10 years but recently with higher intensity. Indeed, to enable customers to propose concepts for lighter vehicles without sacrificing passengers’ safety, the automotive industry promotes rapid development of ever-higher-strength steel. The return on experience regarding the associated production challenges is indeed being consoli- dated by a few available publications. A particular example is the dedicated first conferences on advanced steels (Yuqing, Dong, & Gan, 2011, Advanced Steels – Proceedings of the First International Confer- ence on Advanced Steels; International symposium on new developments in advanced high strength sheet steels, AIST, Colorado, USA, June 23–27, 2013) 3.2 Key challenges faced in producing AHSS grades 3.2.1 Steelmaking 3.2.1.1 Liquid steel refining/analysis In liquid steel production, the first related challenge is linked to the analysis of achieve- ments to ensure the appropriate standard deviations of alloying element contents. Those standard deviations must be defined to allow a good range of mechanical prop- erties as required by consumers of the final product (e.g. minimum and maximum YS). For higher alloying contents (as is the case for AHSS grades), the choice of raw materials may be adapted and tighter control over this might be required. This can also imply an improvement of chemical mastery through improvements in analytical measurement sensors and the definition of reference samples. Depending on the AHSS product being considered, the level of control over residual elements may have a significant impact on the optimization of the final product’s prop- erties. This necessitates defining the suitable maximum limits of phosphorous, sulphur and nitrogen contents (ppm); sulphur and nitrogen contents are mainly linked to better control of inclusions such as manganese sulphide (MnS) and aluminium nitride (AlN). Slag/metal reactions, as well as oxide and non-oxide inclusions or precipitates, can be mastered thanks to the well-known thermodynamic laws and conveniently using integrated software as the one developed by ArcelorMittal Global R&D: Ceqcsi.2 This software takes into account: • all phases, such as the slag, liquid and solid, of iron-based alloys covering most composi- tions from cast iron, low-carbon steels, alloys and stainless steels; • oxide, sulphur, carbide and nitride phases (either stoechiometric or in a solid solution state, such as spinels and carbonitrides); • and gaseous phase. 2 Calculs d’EQuilibre Chimique pour la Sidérurgie (Chemical EQuilibrium Calculations for the Steel Industry). 31Manufacturing of AHSS The history and latest developments of these models and software have been described by Lehmann et al. (2009). Thus evaluating the nature and quantity of oxides and inclusions (in parts per mil- lion) that are created during the elaboration step and the casting step is possible. As an illustration, the results of oxide calculations are shown in Figure 3.1. In this particular example, if it seems that formation of calcium sulphide too early could be detrimental to the hole expansion property of the final product, the formation would need to be delayed. The only way to do this is to decrease the calcium addition and keep the same level of cleanliness (i.e. the small concentrations of total oxygen and sulphur). Other examples provided in Figures3.2–3.4 show the large difference in the inclu- sions content between a low-carbon steel and a higher alloyed steel (only the non- oxide inclusions are plotted here; precipitation is not computed until the product exits the casting machine). As shown in these figures, the nature and quantity of metallic inclusions may vary greatly with the AHSS grade. Depending on the harmfulness of the inclusions along the production route and in the final product, the inclusions population, quantity and size may have to be opti- mized. In AHSS grades the properties gap between soft and hard phases is a critical location for damage; this can be greatly enhanced by the occurrence of defects such as inclusions. The hardness, morphology and position of the inclusions vary with each product application and may thus be detrimental to in-use properties by creating privileged locations for cracks (see the example in Figure 3.5). Figure 3.1 Result of Ceqcsi software at the high temperature level, calculated precipitation of calcium sulphide and reaction with the oxides during metal cooling. CA2 = CaO–2Al2O3; CA = CaO–Al2O3; LO = liquid oxides. Figure courtesy of Lehmann. 32 Welding and Joining of AHSS Temperature (°C) 15 50 80 0 0.0 ALN MNS FCC BCC LIQUID 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.01200 1000 800 600 400 200 0 85 0 90 0 95 0 10 00 10 50 11 00 11 50 1500 1400 1300 1200 1100 1000 900 800 12 00 12 50 13 00 13 50 14 00 14 50 15 00 M et al lic fr ac tio n C on te nt s (p pm ) Figure 3.2 Results of Ceqcsi software in the case of a low C steel grade containing 0.09% Al and 300 ppm S. Figure courtesy of Lehmann. Temperature (°C)1 55 0 80 0 0.0 BN M2B_TETR FCC NBTICN MNS BCC LIQUID 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.01200 1000 800 600 400 200 0 85 0 90 0 95 0 10 00 10 50 11 00 11 50 1500 1400 1300 1200 1100 1000 900 800 12 00 12 50 13 00 13 50 14 00 14 50 15 00 M et al lic fr ac tio n C on te nt s (p pm ) Figure 3.3 Results of Ceqcsi software in the case of a HSLA-Nb steel grade containing 20 ppm Nb, controlled S. Figure courtesy of Lehmann. Damage can be controlled, case by case, through steel chemical analysis adjustments, calcium treatment and/or electromagnetic swirl stirring. As an example of chemical analysis adjustment, a ‘classical’ case is verifying the harm- fulness of manganese sulphide inclusions when forming automotive parts. In the laboratory 33Manufacturing of AHSS 15 50 80 0 0.0 NBTICN TI4C2S2 M2B_TETR FCC ALN MNS BCC LIQUID 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.01200 1000 800 600 400 200 0 85 0 90 0 95 0 10 00 10 50 11 00 11 50 1500 1400 1300 1200 1100 1000 900 800 12 00 12 50 13 00 13 50 14 00 14 50 15 00 M et al lic fr ac tio n C on te nt s (p pm ) Temperature (°C) Figure 3.4 Results of Ceqcsi software in the case of a TRIP-type steel grade with higher C, Mn, Si, Al contents; controlled S. Figure courtesy of Lehmann. Figure 3.5 Example of damage initiation (here beside titanium nitride (TiN) inclusion). Image courtesy of A. Perlade. this can be evaluated through tension, bending or hole expansion tests, with analysis of the cause of fracture. Such analysis may lead to the definition of maximum suitable sulphur content. This type of limitation is then discussed with the production units and can thus be introduced in the plant’s production control plans for the grades concerned. In particular, refer to Nadif et al. (2009) for details on desulphurization industrial practices. 34 Welding and Joining of AHSS Calcium treatment can be applied during the secondary metallurgy step. It has three main objectives: • To improve the steel casting ability by avoiding nozzle clogging • To minimize slab surface defects associated with the presence of inclusions • To modify the sulphide morphology, as shown in Figure 3.6. This third objective has differ- ent beneficial effects, among which is included better compatibility between the matrix and the inclusion during hot deformation. Electromagnetic swirl stirring necessitates that an appropriate device be installed at the top level of the mould. The functioning principle of the device consists of pushing the inclusions away from the surface through electromagnetic agitation of melted steel. When parts are being formed, for example, by bending, the high strain near the surface of certain products can be facilitated by the absence of inclusions as potential loca- tions of damage nucleation. In the same way optimizing dephosphorization at high temperatures adapts to the detrimental consequences encountered along the production route and at the level of a product’s properties, which occur to a larger extent in higher alloyed grades. As an illustration, Maier and Faulkner (2003) studied the influence of Mn and phosphorous (phosphorus being ‘of great interest because it causes Al2O3 Al2O3 CaO Al2O3 + MnO MnS (Mn Ca) S + SiO2 Silico aluminates Figure 3.6 Effect of calcium treatment on the control of inclusion morphology. 35Manufacturing of AHSS embrittlement’) on the arc weld of C–Mn materials used in pressure vessels. They detailed the state of Mn and phosphorus segregations at the grain boundaries as dependent on the size of the microstructure. Solutions can be found by the cus- tomer in part during the welding process. On the other hand, controlling phospho- rus during the upstream production step through imposing limited phosphorous content (depending on the grade) is also a valuable technical option. This control necessitates dephosphorization pretreatments to pig iron and/or mastering slag metal engineering. 3.2.1.2 Continuous casting and slab yard Internal soundness During solidification along the casting process, inclusions and precipitates are formed (see Chapter 2), but micro- and macrosegregations patterns also appear. The composi- tion of the slab is not homogeneous throughout its thickness. The microsegregation pattern results from solute redistribution (C, Mn, Si, phosphorus, sulphur) during solidification at the level of the dendrites. This leads to a variation in the solute concentration between the centre and the outside of a dendrite arm. The distribution of the solute in the dendrites can be derived using mass balance equations taking into account diffusion of the solute in the liquid and solid phase. During solidification, significant concentration gradients occur in the solid at the solid–liquid interface for substitution elements (e.g. Mn, Si, Cr, nickel, Mo), whereas no concentration gradient is associated to interstitial elements (e.g. C, hydrogen, nitrogen), for which the diffusion coefficient is 10–10,000 times higher. The Fourier number (αi) characterizes the diffusion length of the solute (i) in the solid during solidification compared with the microstructure scale. This classi- cal parameter can be used to qualify the intensity of microsegregation (Bobadilla & Lesoult, 1997; Brody & Flemings, 1966; Clyne & Kurz, 1981): αi = (Dsi ts) /(λs/2) 2 where Dsi is the diffusion coefficient in the solid for the solute i; ts is the solidification time corresponding to the solidification range divided by the cooling rate; and λs is the spacing of the secondary dendrite arm. Figure 3.7 summarizes the fact that the level of microsegregation for the solute (i) increases as both the partition coefficient of the solute (ratio of the solid and liquid compositions at the solid–liquid interface) and the diffusion coefficient in the solid decrease. It illustrates in particular the fact that the intensity of microsegregation is higher for substitutional solute elements than for interstitial solute elements. Moreover, because the diffusion coefficient of solute elements in the γ-phase (austenite) is lower than in the δ-phase (ferrite), alloys undergoing the solidification sequence (l → l + δ) exhibit less microsegregationthan alloys with γ occurring during the solidification phase. 36 Welding and Joining of AHSS Depending on the nominal composition of the alloy, this might result in a more or less critical scheme of microsegregation pattern. As an example, Figure 3.8 shows that for a pseudo-binary iron–C–Mn diagram at 1.6% Mn, the higher the C content, the higher the γ occurring during solidification, and so the higher the microsegregation level. Solidification is initiated from the skin in contact with the cold wall of the mould to the midthickness of the slab. At midthickness, the remaining liquid steel in the last moments of solidification is the richer alloyed part of the ‘in-formation’ slab. The following are the main causes of solute-enriched liquid displacements in the mushy zone during continuous casting (Myazawa & Schwerdtfeger, 1981): • Deformations of the solid shell caused by compressive cooling or expansive reheating and by the discontinuity and imperfection of the mechanical support of the caster (bulging, roll position defect). This induces alternative variations of the mushy volume and sucking or ejection flows of the interdendritic segregated liquid. • Deformations of the solid skeleton in the mushy zone caused by solidification shrinkage during cooling. This contraction of the solid leaves free volume, which attracts some solute-enriched liquid. Once the solidification of the whole thickness is completed, the scale of the chem- ical heterogeneity at the slab’s ‘midplane’ is 10 or 100 times higher than that of the dendritic structure. This chemical heterogeneity is called ‘macrosegregation’. Throughout the process after casting, segregations are at the origin of the alternate layers of hard and soft phase through the product’s thickness, the so-called banded structure. The morphology of the bands, present at the hot coil (after hot rolling) and cold coil levels (after hot rolling, cold rolling and annealing or coating), may have an influence on the final bending or hole expansion, that is, on the forming properties of the hot-rolled or cold-rolled products. Figure 3.7 Information about the microsegregation behaviour of various solute elements depending on the coefficient partition and solid diffusion. Figure courtesy of Bobadilla (1999). 37Manufacturing of AHSS δ δ δ δ δ δ γ γ γγ γ γ γ γ γ γ 1540 1520 1480 T (° C ) 1440 1400 0.1 Soft, extra soft Semi-hard Medium carbon 0.2 0.3 0.4 Carbon (%) (a) (a) (b) (b) (c) (c) L L+δ γ L+δ+γ L→L+δ L→L+δ→L+δ+γ L→L+δ →L+δ+γ →δ→δ+γ → δ+γ→γ → L+γ→ γ L→L+γ →γ →γ δ+γ δ L+γ (d) (d) Hard Figure 3.8 Pseudo-binary iron–carbon–manganese diagram at 1.6% Mn. The solidification sequence depends on the carbon content in the alloy as is illustrated in the different schemes for soft and extra soft grades (a), medium carbon (b), semi-hard steel (c) and hard steel (d). (δ indicates “ferrite phase” and γ indicates “austenite phase”). Figure courtesy of Bobadilla (1999). 38 Welding and Joining of AHSS Macrosegregation and microsegregation patterns strongly depend on the chemical composition of the alloy. But some process specificities and parameters also have an impact: • Soft reduction devices (when available at the casting machine level) allow controlled com- pression of solid skins to be applied by roll pinching. This results in a beneficial ejection of the interdendritic segregated liquid, which has a direct impact on the macrosegregation pattern, lowering it (Figure 3.9). • The type of caster (especially when considering a classical >200-mm-thick slab or a thinner slab caster for <140-mm-thick slabs) also has an impact. • The main casting parameters (mainly influencing microsegregation) are all the process parameters that can have an impact on heat extraction at the skin level and, consequently, on the solidification rate and thermal gradient; this is the case for the casting speed, the super heat (difference of temperature between the liquid steel in the mould and the liquidus tem- perature) and the secondary cooling (Segunpta et al., 2011). The resulting banded structure (alternated bands of different phases) is also affected by thermal control at the hot rolling stage. The most influential parameter is the coiling temperature, which has a direct impact on the Carbone diffusion and thus, in the end, on the repartition of the phase in the thickness of the coil. After cold rolling, during the annealing step, well-known grain nucleation and growth mechanisms produce a topology with more or less band heredity. This is strongly depen- dent on the heating speed and on the soaking temperature, whether it is in the austen- ite–ferrite or fully austenitic domain. This is, of course, not without consequences on Figure 3.9 Fraction areas of Mn and P segregations, according to the type of the support (bar block, one-piece roll or divided roll) and soft reduction (SR) optimization: if the block bars (walking bars which carry out a soft reduction in a quasi continuous way) give a result close to the perfection, the soft reduction with the divided rollers represents a very significant improvement compared to the quality obtained without any soft reduction actuator. Image courtesy of J.M. Jolivet. 39Manufacturing of AHSS the final product properties. As an example, if the annealing conditions of a particular grade are such that they promote the heredity of the banded structure through the whole thickness of the strip, the risk of damage being initiated during product bending may be enhanced at the level of the hard bands that are close to the surface. Slab surface defects To guarantee good surface quality of continuous cast steels, avoiding carbon concen- trations that are in a critical peritectic range, at which the risk of longitudinal cracks increases, is desirable. Two models are available to predict the critical peritectic range of a steel grade: • The carbon equivalent (Ceq) criterion is the classical approach: the effect of the alloying elements is taken into account to calculate the effective carbon composition for a particular grade. Various values of coefficients for the different elements are found in the literature (Wolf, 1991). These coefficients are obtained from thermal analysis, thermodynamics calcu- lations or plant observations. If the calculated carbon equivalent is in the critical peritectic range (0.08–0.15 wt%), the grade is assumed to be sensitive to the formation of longitudinal cracks. • The peritectic predictor equations developed by Blazek, Lanzi, Gano, and Kellogg (2007) were obtained by calculations using Thermocalc (version M with the TCFE3 database) and were tuned to match experimental data. The investigated compositions span a large range of alloying elements, including high manganese, aluminium and silicon contents. Non-linear regression equations for the lower and upper limits of the critical peritectic range have been proposed. Based on these equations, if the carbon content of the grade is in the critical range, the grade is assumed to be peritectic. Both approaches have been compared and similar results obtained for the grade Fe–0.9wt%Mn–0.3wt%Si. Nevertheless, the carbon equivalent formula was not adapted for high-alloyed steels and some improvements were needed to take into account the effect of aluminium. The carbon equivalent formula has been updated to span a larger range of alloying elements (Bobadilla team); see the Ceq formulae (*) below. The available thermo- dynamic databases were critically analysed to select the most coherent database to determine the coefficient. The predictions made with the peritectic predictor equations with the Ceq criteria or the new formulation are similar. Ceq defined as (*) Ceq = [C] + 0.0146 [Mn]– 0.0027 [Si] – 0.0385 [Al]2 – 0.0568 [Al] – 0.064 [Mo] + 0.0021 [Cr] + 0.02 [Ni] – 0.006 [W] – 0.012 [V] + 0.8297 [S] + 0.0136 [Mn][Si] – 0.0104 [Si][Al] + 0.0026 [Si][Al]2+ 0.0134 [Mn][Al] + 0.0031[Mn][Al]2. Courtesy of M. Bobadilla When 0.07 < Ceq < 0.15, the risk of longitudinal cracks occurrence is enhanced. This work is a good illustration of the necessary continuous adaptation of knowledge to newly developed products for which the previously established formulae sometimes reach their limits of validity. 40 Welding and Joining of AHSS The toughness property of solid matter at the slab level might also be insufficient to ensure a bending–unbending step, free of transverse cracks. Indeed, for high alloying contents, the ductility might be too low to ensure a deformation free of defects all along the casting (temperature and deformation speed) range. As shown by Tuling et al. (2011), the level of ductility depends on several factors: • Solidified austenitic grain size (bigger grains are more prone to damage). • Phase transformation: among the different products, the peritectic range is still a risky zone. But equally, for a given grade, the ferrite phase quantity and structure may also play a detri- mental role. Indeed, at the slab bending–unbending stage, the quantity of ferrite that already precipitated – and, more precisely, its structure – are possible weak areas during slab defor- mation where cracks could initiate. This is particularly the case if, at that level of the caster, the ferrite phase forms a film all along the grain boundaries. • An AlN inclusion or other precipitates characteristics. In general, phase type transformation at cooling (with ferrite growth at the grain boundaries): type, location and size of precipitates and austenitic grain size play a crucial role on the risk of transverse cracks occurring. For a given grade on a given casting machine, adjusting the secondary cooling helps avoid defects; it consists in adapting the cooling flow of the slab along the cast- ing machine to obtain the suitable temperature at the bending–unbending level for the given grade. The principle is to avoid the most fragile structure at that stage of the caster. In severe cases, slab surface defects require a repairing step through grinding or scarfing. After continuous casting, all the different production steps, including the slab cool- ing to atmosphere temperature, storage and transportation in the slab yard and reheat- ing in the furnace (which is located at the hot rolling entry) are made difficult in the case of fragile slabs. As far as AHSS products are concerned, preexisting defects, grain size and tough- ness may not be favourable for those intermediate steps. When the risk of slab breaks is evaluated to be high, some cautious production practices are used, for example, slab cooling in stacks and hot charging. The principle of those practices consists of avoiding transporting the slab at low temperatures (<250 °C) between exit from the continuous casting machine and entry into hot rolling. Indeed, the toughness of the matter is lower at those temperatures and the slabs are thus more fragile. 3.2.2 Hot rolling 3.2.2.1 Reheating furnace Slab reheating remains of primary importance for controlling the amount of microal- loying elements taken into solution and for controlling starting grain size. Titanium nitride (and, to a lesser extent, niobium carbonitrides and AlN precipi- tates) is the most stable compound with poor dissolution in the usual range of reheating temperatures. Remaining precipitates (including fine carbides) participate to the control of grain size in the subsequent stages of production. 41Manufacturing of AHSS In the reheating furnace the scale layer, which is formed along the temperature– time path, is not composed of a simple single layer. Once again, depending on the grade composition and alloying content, a wide range of oxide chemistries and asso- ciated morphologies can be formed – simple wüstite, magnetite, hematite, fayalite, silice – in local or continuous layer configurations (Alaoui Mouayd et al., 2011) (see the example in Figure 3.10). Some elements that have a lower melting temperature, such as copper, are prone to melting along the grain boundaries at the metal–scale interface, possibly inducing specific defects at the coil surface in the subsequent hot rolling process. When oxides remain at grain boundaries, or depending on the scale mechanical properties, different surface defects may form, from different types of slivers to sur- face diverse heterogeneous morphologies. Those heterogeneities of surface morphol- ogy can induce dispersions of the product emissivity, which may result in a poor thermal control in the last stages of the hot rolling process (during cooling on the run out table cooling and during coiling). As a consequence, to avoid defects on the hot coil surface, the thermal path along the hot strip mill as well as the primary and the secondary descalings must be optimized. In the roughing and finishing mills stands’ roll gaps, the scale intervenes as an intermediate body between the rolls and the metal being hot rolled. The chemical nature of the scale and the thickness of the layer can lead to different friction coef- ficients and possibly localized defects on the roll’s surface. Once again, this directly impacts product and process achievements. NAS: NAS+1.6%Si: 2 sub-layers: -Internal (2): Thin (#14 µm), Si 6%At, O 47%At => Fe–Si oxide -External (3) : Thin (#13 µm), Si 0.9%At, O 46%At => FeO => Similar to SAIS! Mono-layer(1): Thin (#7 µm) O 50%At => FeO (wustite) => Representative of NAIS .. Figure 3.10 Scanning electron microscopic scale images and their chemical composition through X-ray diffraction showing oxidation of pilot samples. NAS, nonalloyed steel. Figure courtesy of Alaoui Mouayd. 42 Welding and Joining of AHSS 3.2.2.2 Hot rolling Depending on the grade composition (alloying and microalloying contents) and on the hot rolling schedule, the strain hardening at each pass of the roughing and finishing mills and the dynamic recrystallization ability between the passes vary. The temperature of no-recrystallization (Tnr) can differ from grade to grade and depends on the hot rolling schedule. This Tnr value determines the state of recrystallization of the hot coil matter when it exits the hot rolling mill. The mate- rial at this stage is partially or fully recrystallized, depending on whether the temperature when exiting the finishing mill is higher or lower compared with the Tnr value. All this explains the interest of optimizing the rolling schedule for the given grade. Of course, this must be done in coherence with all other production constraints. In its optimized version, the microstructural design of the hot-rolled product, including austenite grain morphology and ferrite precipitation control when exiting the mill, is better known as thermomechanical processing (TMP). It consists of modifying the thermomechanical treatment for a given composition of steel to achieve the required grain size and phase distribution, both of which control the properties of the steel. In the case of AHSS grades, TMP in the reheating furnace to finishing mill area is fairly advanced but still under development (Perlade et al., 2008). As far as hot strain hardening is concerned, the tendency is that the higher the alloying content (up to approximately 5–7% total in AHSS grades), the higher the hot deformation resistance through the influence of the Si, carbon, manganese, Nb, Ti. The consequence is higher rolling forces for the same hot rolling reduction rate com- pared with that of HSLA grades. Figure 3.11 summarizes the maximum stress as measured with the hot axial com- pression test for different temperatures and strain rates and several different AHSS grades. In the context of reducing carbon dioxide emissions, the usage of AHSS grades in car bodies allows vehicles to be made lighter. This can be obtained by decreasing the strips’ thickness, while keeping tight control of the strips’ width and flatness.To achieve dimensional requirements at hot and cold coil levels, the hot rolling schedule of AHSS grades must be adapted to the higher hardness of the product, taking into account the specific expectations for delivering low thicknesses and the technical characteristics of the mills. Optimizing the hot rolling schedule concerns the main parameters of the schedule setting: temperatures, thickness reductions per pass, rolling speed and stand roll profiles. In this task one also has to consider the friction coefficient, which may vary with the product (see Section 3.2.2.1) and also depends on the mill settings (e.g. lubrication of the rolls). Optimizing the grade chemistry to lower the product hardness at hot rolling is a possible way to help achieve the coils’ dimensional targets. An example of such a tun- ing attempt is described by Mostert et al. (2013), who showed that a DP600 grade with reduced Si content allows the dimensional feasibility to be enlarged. This is explained in that paper by the composition dependence of the mean flow stress as obtained from industrial trials. The contribution from Si is only approximately 16% less than the Mn contribution. 43Manufacturing of AHSS When exiting the hot strip mill, control of the product properties through TMP in the run out table to coiling area is already fairly advanced thanks to the development of several thermodynamic and physics/metallurgy-based models, like those described by Perlade et al. (2005) and Pethe et al. (2011). Those models’ hearth calculates the repartition of the phase and the precipitation strengthening of the steel at the hot-rolled coil level (case of carbon–Mn and carbon– Mn–Nb grades). In particular, the heat evolution linked to the phase transformation during cooling is taken into account. 3.2.2.3 Coiling and coil yard Linked to phase transformation when exiting the hot rolling mill along the run out table, the coiling step and at the coil yard level, the choice of finishing mill tem- perature, coiling temperature and temperature–time paths have a major influence on achieving product property targets and the homogeneity of the product properties throughout the whole coil body. This is, of course, particularly true in the case of hot- rolled AHSS products for which the final microstructure is directly produced in the hot rolling mill. For each of the metallurgical concepts, the typical phase transformation curves (continuous cooling transformation curves) are specific; ferrite, perlite, bainite and martensite domains are more or less extended and translated along the temperature and transformation axis. As examples, elements like carbon, Mn, Cr, Mo and boron delay the ferrite and perlite transformations; carbon, Mn and Cr delay the bainite transformation. On the other hand, Si and Al expand the ferrite domain to the left and increase the Ac1 and Ac3 temperatures. 400 350 300 250 200 150 100 50 0 800 850 900 950 1000 1050 1100 1150 1200 1250 1300 0.1 s–1 1 s–1 10 s–1 50 s–1 Higher alloying content within: C < 0.25% Mn < 2.5% Si < 1.8% Cr < 0.4% Al < 1.4% Others: B, Nb, Ti... St re ss (M Pa ) Temperature (°C) Figure 3.11 Maximum stress (MPa) obtained after hot compression tests for different advanced high-strength steel grades. 44 Welding and Joining of AHSS In general, thermal heterogeneities encountered in the run out table, during coiling and at the coil yard level, may be at the origin of possible phase transformations in localized areas and, as a consequence, of property and hardness heterogeneities. These heterogeneities necessitate particular attention to avoid ‘out-of-tolerance’ dimensions in some parts of the coils, especially out-of-tolerance thickness variations at the cold coil level. Poliak et al. (2009) illustrate an example of this production issue that is a direct consequence of the head and tail overhardness at the AHSS hot coils extremities – the so-called gauge hash effect. During coil cooling, some parts of the coils are cooled at higher rates than others, especially in the outer rings. This creates a pseudo-periodic overhardness localized at the coil extremities, which finally results in thickness irregu- larities after cold rolling. In severe cases this necessitates adaptations to the hot rolling schedule. 3.2.3 Pickling Most pickling lines are continuous, meaning that coils are welded head to tail, one to another to allow a continuous production flow. Flash butt welding at entry to the pickling line is a solid-state welding process that is followed by a weld grinding step to remove the flash-formed weld. AHSS welding through flash butt requires adaptations to welding process parameters (welding speed, power) to ensure a robust and safe enough weld that is able to pass through the entire line, whether the production line is limited to the pickling baths or comprises a contin- uous pickling and cold rolling process. Laser welding is also sometimes used and may offer higher production flexibility (Wallmeyer, 2013). In particular, welding with various heterogeneous configurations (implying an AHSS grade on one side and a different accompanying steel grade on the other side of the weld joint) can be facilitated. Ichiyama and Kodama (2007) presented an innovative proposition involving high currents during the flash butt welding process. This specific practice goal is to extrude internal oxides and inclusions, since those defects are the main possible causes of embrittlement of flash butt welds. Because of the wider variety of scales coming from the hot rolling process (see Section 3.2.2), management of pickling baths sometimes needs to be adapted. When necessary, this means changing the acid concentration, changing the pickling inhibi- tor, tuning the temperature of the baths and adapting the line speed. In any case, the solutions implemented to improve the product quality are the result of the best tech- nical compromise between the production flow constraints and the options for better management of the acid baths. In difficult cases, for example, when oxides penetrate the grain boundaries or when the intermediate layer oxides change the pickling kinetics, acids stron- ger than hydrogen chloride or sulphuric acid or a mix of specific acids might be considered. 45Manufacturing of AHSS 3.2.4 Cold rolling The main challenge of cold rolling AHSS steels consists of achieving the required dimensions (width × thickness × flatness) for steels that exhibit higher cold strain hardening and, in some cases, higher risks of breakage at higher reduction rates. As for hot rolling (Section 3.2.2), market evolution makes the rolling of harder grades necessary, with the goal of achieving thinner strips. In Figure 3.12 one can see the evolution of stress up to a 90% reduction rate in a cold compression test machine (plane strain deformation configuration) in a laboratory. The increase in the hardness of higher alloyed grades during cold rolling requires the optimization of cold rolling schedules and especially of the reduction rates at each stand, using the full benefits of the mill’s total capacity. Another difficulty is linked to the possible occurrence of defects, either at the prod- uct surface, bulk or strip edges (heterogeneities are inherited from upstream produc- tion steps or result from difficult edge trimming). This increases the risk of strip breaks during cold rolling. Indeed, after high cold reduction rates, the high internal stresses resulting from cold strengthening (Figure 3.12) are accompanied by a reduced total elongation of the material being cold rolled. This favours the initiation of cracks at critical-sized defects. In those conditions a situation of high tension at the strip edges during the cold rolling process enhances the risk of cracks opening in the transverse direction. Figure 3.12 Stress on different types of AHSS grades after cold plane strain compression tests in alaboratory. The equivalent strain of 0.8 is obtained for a reduction rate of 50%, and the equivalent strain of 1.6 is obtained for a reduction rate of 75%. 46 Welding and Joining of AHSS 3.2.5 Annealing and coating 3.2.5.1 On-line welding Seam welding is the most expanded technique for on-line welding as a continu- ous process to ensure coil-to-coil assembly at the entry of continuous annealing lines and galvanizing lines. This is a resistance welding technique that requires an overlap of the two extremities of the coils so one can be joined to another. Seams are copper-based, round electrodes that ensure current conduction and the Joule heating effect. The general trend is that when spot welding is difficult, the same is true for on-line seam welding. The processing of hard AHSS often requires adapting param- eters, such as the level of pressure that is applied between the seams, the welding speed, the temperature, the use of a device to post heat the weld and a better and tighter in-line control. As in the case of flash butt welding (Section 3.2.3) and for the same reasons, laser welding at this stage of production is considered as a relevant technical alternative. 3.2.5.2 Thermal issues and challenges As for any other steel grade, controlling the temperature of the product during anneal- ing is of prime importance to achieve the targeted properties because they result from the appropriate volume fraction of the phase and recrystallization kinetics. This implies the ability to properly measure the strip temperature along its path in the continuous annealing line in the different furnace zones: heating, soaking and cooling. In the case of AHSS grades, as explained in previous chapters, there may remain some surface heterogeneity linked to specific roughness and surface topog- raphy after the oxide layer is removed through the pickling process. This may be at the origin of dispersions of the product’s surface emissivity, which itself results in heating heterogeneities. That is why appropriate sensors for measuring temperature are necessary: the use of wedge pyrometers that take advantage of the dark body principle, among others, can be of great help in overcoming this difficulty. The particular case of water quenching, which makes specific flatness and surface difficulties arise (as in full martensitic grades (Hurtig et al., 2008)), necessitates adapted control and modelling. In an analogous manner, ‘new’ developments in cooling paths implying quench and partitioning (Li et al., 2013) open the door for necessarily overcoming various product and process challenges. 3.2.5.3 Oxidation and coating issues The higher the alloying content of the annealed grade (especially regarding Mn, Si and Al contents), the greater the risk of external selective oxidation at continuous anneal- ing lines or galvanizing lines. At continuous annealing lines, such a surface defect can result in remaining oxides or colouration issues. This high sensitivity of the surface to the furnace atmosphere 47Manufacturing of AHSS and cooling fluid (e.g. water for quenched products) makes adapting the surface engineering of those products necessary. Particular care when in contact with gas in the furnace and with liquids (degreasing baths, pickling baths, temper mill lubricants and the rinsing section) is required. At galvanizing lines, a report by Staudte (Staudte, Mataigne, Loison, & Del Frate, 2011) summarizes the main difficulties associated with the surface oxidation prob- lem that affects product coatability, namely, coverage and adherence of the zinc coating. This article recommends furnace atmosphere dew point control to improve wettability and adherence in the case of transformation-induced plasticity grades (Mn–Al or Mn–Si). The coating adheres well at dew points in the range of −20 °C to +10 °C. Dew points of −20 °C and higher significantly improve coatability by ensuring Al and Si diffusion into the bulk of the material. Because the manganese oxide at the surface is not a continuous layer, the enrichment of Mn at the surface does not seem to be detrimental for hot-dip coatability in case of this Mn–Al grade. Even higher dew points must be applied for Mn–Si grades compared with Mn–Al grades, allowing the transition from external to internal selective oxidation. See also Mataigne (2001) on that particular topic. With high dew point annealing, excellent hot-dip coatability can be obtained. The benefit of this technology has even been con- firmed industrially. Apparently, coating quality of the DP grade with higher Mn (2–3% Mn, low Al and Si) could not be improved by increasing the oxidation potential via increasing the dew point during annealing. Any increase in the oxidation power leads to thickening of the exter- nal Mn-rich oxide (iron participation in surface oxidation). This results in poor wettability. In general, the galvanizing difficulties associated with high Mn, Si and Al contents are being studied. Another example (Blumenau et al., 2012) shows that preoxidation can ensure coat- ing success when using direct flame furnace galvanizing lines. The conditions of this preoxidation are strongly dependent on the alloying content and strip dimensions. Preoxidation method is even claimed to be useful in the case of very high Mn contents (products containing 20–25% Mn, such as Twin Induced Plasticity (TWIP) steels). Norden (2013) also described the interest of reducing preoxidation of radiant tube furnace galvanizing lines in case of a iron–Mn–Al transformation-induced plasticity steel. 3.2.6 Robustness along the route As for any other product, the inheritance of defects along the industrial route is a possible issue whether at the coil surface, at the coil edges or in the material bulk. In high-strength steels, however, this ‘whole route’ question is more acute in the sense that higher risks of defects and heterogeneities occur from the very first steps of production: • surface or internal defects coming from brittleness or poor internal soundness of the slab; • specific microstructures such as banded structures; 48 Welding and Joining of AHSS • high macrosegregation in the midthickness; and • imperfections of the trimmed edge. In some cases this makes not only study of the origin of the defect but also its evolution along the route necessary to be able to find the appropriate preventive or curative solu- tion. This comment is particularly true for the question of varying mechanical and in-use properties along coils or between coils. This is an important issue because it directly relates to customers’ final requirements and satisfaction. As an example, overhardness that is sometimes obtained at the head and tail of the coils and at the coil edges may be related to an uncontrolled cooling rate of the outer parts of the coils along the hot process. Another example is the achievement the flatness targets of the delivered coils, which results in mastering this parameter along the route, through the rolling mills and the annealing and cooling steps. Hardness of the product during rolling, phase heterogeneities along the route and buckling risk at the quench step of the continuous annealing line make optimizing the usage of available actuators and adapting repairs at the temper mill and leveller tools necessary. As far as process risks along the route are concerned, one important topic is the risk of hydrogen (H) pickup, which can result in delayed fracture in the final stamped part. This so-called delayed fracture risk is an unexpected cold cracking that occurs on a stamped part after several hours or days. The condition necessary for the delayed frac- ture phenomenon to occur include a critical combination of applied or residual stresses, metallurgical factors such as crystallographic structures and the presence of diffusible H. High-strength steels are all the more sensitive to delayed fracture whenthe strength is high; indeed, high strengths often are associated with high applied residual stresses. Combined with this factor, the higher the diffusible H content (resulting from a balance between H pickups along the industrial route and H diffusion in the steel bulk), the higher the risk. For AHSS grades that combine a large variety of phases – ferrite, bainite, martensite – allowing rather good diffusion of H in the bulk of the material, the major process risks associated with H are located at the end-of-route coating lines and, more specifically, at electrogalavanizing lines. Dedicated laboratory trials making possible a comparison of the behaviour of different high-strength grades have been developed (e.g. Lovicu, Bottazzi et al., 2012). Those testing procedures allow a controlled strain or stress to be applied to samples that may have been previously electrochemically hydrogenated. In parallel, other laboratory efforts concentrate on the development of accurate mea- surements of diffusible H, such as thermal desorption analysis (Georges, 2009). Those studies allow the risk for each of the considered high-strength steels to be evaluated and the diffusible H content under which this risk is eliminated to be defined. Achieving the required H content in the final product was also a main topic of those research efforts. 3.2.7 Elements of manufacturing issues from the customer’s perspective Karbasian and Tekkayya (2010) give an overview of the technical challenge that hot stamping represents, especially in controlling phase transformation at the cooling 49Manufacturing of AHSS stage, the details of which are not described in this chapter. As far as the cold stamp- ing process is concerned, some particular difficulties arise in the case of high-strength steels. Because of their low anisotropy coefficient (r value around 1), high-strength steels are not particularly good material in ‘shrink drawing’ deformation mode, which is a quite common deformation mode during stamping. Deformation of the corners is not easy and may result in rupture or risk of wrinkling. In the same way, depending on the strain hardening exponent ‘n’, the ‘stretching’ as deformation mode might be more or less difficult: the lower the n coefficient (for high Ys/Ts values); the more difficult the deformation in stretching mode is. For most AHSS grades, optimum bending properties and hole expansion minimum values are requested by the customer. These specifications depend on the grade and the automotive parts that are targeted. One of the most severe difficulties encountered during AHSS forming remains the spring-back effect, which is clearly higher for higher stress levels (for equivalent Young modulus values). In this context hot stamping presents the largest factor of interest, among others, to more or less annihilate this drawback. The behaviour of high-strength steels during forming is still not fully understood. Structural parameters explaining the bending ability of high grades are being studied (Sadagopan and Urban, 2003). Another large domain of investigations regarding AHSS formability is again linked to the risk of delayed fracture associated with H embrittlement. In general, the higher the mechanical resistance of the product, the higher the risk. This can be particularly enhanced at locations where wrinkles appear. For example, Carlsson (2005) recom- mends forming process parameters to avoid wrinkling as much as possible and, in this way, lower the delayed fracture risk. Higher strengths of stamped products result in rapid wear of the press tools (espe- cially at the level of the small radii). This can lead to the necessity of applying hardening techniques either through local thermal treatment or specific additions at the surface involving hard coatings such as Cr or Ti carbides. Moreover, with harder grades to be formed, the total required power for the press is obviously higher (if cold stamping). This partly explains the reasons for the current success of hot stamping. 3.2.8 Elements of costs and economics The high volatility of raw materials is a current economic trend that cannot but be taken into account in AHSS product development globally. As an illustration, Table 3.1 gives an idea of the evolution of the cost of some of the main ferro alloys used in AHSS compositions. This makes it necessary, in a context of high worldwide industrial competition, the special attention to the most appropriate alloy mix to obtain an optimal set of product properties. In parallel, it is required to optimize the choice of ferro alloys in order to obtain the best possible compromise between cost and required analytical/product quality. 50 W elding and Joining of A H SS Table 3.1 Evolution of ferro alloy costs, showing rapid change over time Alloy Cost ($/T ferro) by year Source2000 2002 2004 2006 2008 2010 2011 2012 HC FeMn 423 483 1274 737 2662 1449 1379 1164 Metal Bulletin Mn metal — — 1617 1389 3730 2942 — — AM purchasing Sdt SiMn 469 492 1272 749 2222 1445 1313 1217 Metal Bulletin Sdt FeSi75 535 557 921 870 2006 1761 1846 1454 Metal Bulletin HC FeCr 875 688 1586 1376 5082 2717 2708 2387 Metal Bulletin MC FeCr 1388 1350 2161 2350 9361 4483 5002 4649 Metal Bulletin FeMo 7021 9920 44,269 59,054 69,370 40,139 38,322 31,414 Metal Bulletin FeV 9790 7721 27,206 38,454 61,182 30,062 28,742 24,976 Metal Bulletin FeTi70 3675 3962 10,548 16,371 7577 6763 8349 7395 Metal Bulletin FeNb 9208 9220 8750 9459 23,249 22,767 26,377 24,309 COMEXT Ni cash 8638 6772 13,823 24,244 21,104 21,804 22,890 17,533 LME Cu cash 1813 1559 2865 6721 6955 7534 8821 7949 LME 51Manufacturing of AHSS 3.3 Future trends Requirements for ever safer and lighter vehicles will guide the trends of the steel market for the design of future vehicles. That is the reason why new generations of AHSS grades are already being studied and even starting development in the market. Those new generation steels will include higher alloying contents (from 8 to 10%, up to 20–30%) and result in interesting properties such as lower density and a better combination of strength and formability, with improved performance regarding crashes and the ability to make vehicles lighter. Manufacturing challenges will, of course, be specific to those new grades, whatever their final process: hot or cold stamping or roll forming. Even though we know the automotive sector strongly promotes competition between materials (e.g. Al, plastic, carbon fibres, reinforced composites), the vari- ety of production tools and the possibility for adaptations are high in the steel industry; there is thus great scope for the provision of new recyclable materials for the automotive industry. In parallel and in addition, press tools used by customers follow the general trends for high productivity (wide progressive press; develop- ments in hot press stamping). This will also provide greater potential for new steel product offers. References Alaoui Mouayd, A., Sutter, E., Tribollet, B., & Koltsov, A. (2011). Pickling and over-pickling mechanisms of high alloyed steel grades. Eurocorr 2011, Stockholm. Blazek, K. E., Lanzi, O., Gano, P. L., & Kellogg, D. L. (2007). Calculation of the peritectic range for steel alloys. In AIST 2007. Blumenau, M., Gusek, Ch.O., Norden, M., & Schönenberg, R. (2012). Industrial use of pre- oxidation during continuous hot dip coating of high alloyed steels. Bobadilla, M., & Lesoult, G. (1997). Chapitre 4: La coulée et la solidification des aciers. Les aciers Spéciaux. Technique & Documentation. ISBN: 2-7430-0222-0. Brody, H. D., & Flemings, M. C. (1966). Solute redistribution in dendritic solidification. Trans AIME, 236, 615. Carlsson, B. (2005). 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In Proceedings of the international symposium on new developments in advanced high strength sheet steels, June 23–27, 2013. USA Colorado: AIST. This page intentionally left blank Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00004-7 Copyright © 2015 Elsevier Ltd. All rights reserved. Resistance spot welding techniques for advanced high-strength steels* (AHSS) M. Tumuluru Research and Technology Center, United States Steel Corporation, Pittsburgh, PA, USA 4 4.1 Introduction Based on the expressed objectives of various automotive companies to build more fuel-efficient and safer cars, as well as the trends in steel usage to meet increasingly stringent government requirements across the globe, it is anticipated that advanced high-strength steel (AHSS) usage in automotive bodies will climb to 50% by 2015 (Horvath, 2004; Pfestorf, 2006). For example, over 50% of the body in white (BIW) of the 2014 MDX vehicle from Honda was made from AHSS grades with strength levels in excess of 590 MPa (Keller, 2014). In addition, AHSS in the Hyundai Sonata accounted for 21% of parts in the 2010 model year, whereas in the 2014 model, AHSS accounted for nearly 53% of the parts in BIW applications (Chang, 2015). Resistance spot welding is the main method of joining used in the automotive indus- try, with each vehicle containing several thousand welds (Tumuluru, 2006a). Further- more, resistance spot welding alone or in combination with other joining processes, such as adhesive joining or laser welding, accounts for more than 70% of all welding done in BIW applications (Tumuluru, 2013). Recent investment and equipment upgrade trends in automotive assembly plants across the globe suggest that the resistance spot welding process will continue to be the most dominant process for automotive joining for several years to come. Therefore, weldability assessment of AHSS grades using the resistance spot welding process is a critical step in the implementation of these steels in automotive applications. To be able to successfully use these steels, characterizing and understanding the resistance spot welding behavior of AHSS grades is important. To provide corrosion protection for BIW applications, most steels are used with either galvannealed (zinc–iron alloy) or galvanized (pure zinc) coatings. These coatings are typically applied eitherby dipping incoming steel coils in a molten pool of zinc or by electrolytically plating zinc onto steel surfaces. The typical coating weights for steel in automotive applications range from 40 to 60 g/m2 for galvannealed applications and * Disclaimer: The material in this chapter is intended for general information only. Any use of this material in relation to any specific application should be based on independent examination and verification of its unrestricted availability for such use and a determination of suitability for the application by professionally qualified personnel. No license under any patents or other proprietary interest is implied by the publication of this chapter. Those making use of or relying on the material assume all risks and liability arising from such use or reliance. 56 Welding and Joining of AHSS 50–70 g/m2 per side for galvanized applications. Therefore, understanding the effect of these coatings on the resistance spot welding behavior of these steel grades is important. The two most commonly used grades of AHSS in automotive BIW welded applications are dual-phase and transformation-induced plasticity (TRIP) steels (Ducker Worldwide report 2007). Although other AHSS grades such as complex- phase and twinning-induced plasticity steels are commercially available, they have limited applicability in the automotive industry because of their high cost and limited global availability. According to Ducker Worldwide report 2007, by 2020 dual-phase steels will account for nearly 280 lb, and TRIP steel, along with complex-phase steel, will account for approximately 55 lb, of a typical passenger vehicle. Given the pro- jected extensive use of these two steel grades, this chapter focuses on the weld charac- terization and the welding behavior of these two commonly used AHSS grades. 4.2 Characterizing welding behavior Several tests are generally used to characterize the resistance spot welding behavior of AHSS. These include the welding current range, metallographic characterization of the microstructures in the weld and the heat-affected zone, microhardness, and weld tensile tests (American Welding Society D8.9M-2012; Tumuluru, 2006b). 4.2.1 Welding current range The useful current range is the difference between the welding current required to pro- duce a minimum weld size (Imin) and the current that causes expulsion of weld metal (Imax). The minimum weld size is typically defined as 4√t, where t is the nominal sheet thickness. This definition is generally used in the automotive and steel industries. The procedure to determine the current range is described in detail in a specification from the American Welding Society D8.9M-2012. Peel test coupons measuring 140 × 50 mm2 are generally used in determining the current range (Figure 4.1). The coupons overlap by Anchor weld Test weld Overlap W 50 mm 50 mm 140 mm L Figure 4.1 Schematic of a peel test coupon (Tumuluru, 2006b). Source: Tumuluru, M. (2006b). A comparative examination of the resistance spot welding behavior of two advanced high strength steels. In: SAE technical paper No. 2006-01-1214, presented at the SAE congress, Detroit, MI. Copyright © SAE International. Reprinted with permission from 206-01-1214. 57Resistance spot welding techniques for AHSS 25 mm, and a shunt or anchor weld is made on one side of each coupon pair. On the other side, test welds are made 35 mm from the edge. The test welds are peeled open and the weld sizes are measured using calipers. The current range is useful because it provides a range of welding currents over which welds of an acceptable size can be produced. Before determining the current range, the electrode tips are generally conditioned by making about 100 welds. Current ranges are identified by first determining the lowest welding current that produces the minimum acceptable weld size. Then, the current is gradually increased until weld metal expulsion results. The range of current between Imin and Imax is regarded as the welding current range. 4.2.2 Weld lobes Another way to characterize the suitability of a given grade of AHSS is to determine the weld lobes for the steel. Weld lobes are graphical representations of the useful current ranges that provide acceptable welds without expulsion and button sizes that are above the minimum required sizes. In other words, weld lobes are similar to the welding current ranges. Weld lobes are typically determined using three different weld times. Before determining weld lobes, generally 100 conditioning welds are made to condi- tion the electrode tips. To determine weld lobes, the welding currents that produced minimum weld sizes are determined at each of the weld times chosen. Weld times (the duration of the passage of welding current through the electrodes) are chosen based on a suggested nominal welding time for a given thickness of steel. These weld times vary depending on the specification to which a given grade of steel is being tested. The welding current then is increased until expulsion occurs. The expulsion current is determined for three specified weld times chosen. When the nominal welding time is known, it is typical to use ±10% of this time to select the other two weld times. 4.2.3 Weld shear tension and cross-tension tests Weld shear tension strength and cross-tension strength (CTS) are determined to assess the load-bearing ability of welds (Tumuluru, 2006a) For determining the shear tension strength, 140- × 60-mm samples are sheared and a single spot weld is made at the center of an overlapped area measuring 45 mm (Figure 4.2). For cross-tension tests, the test coupons used are 150 mm long and 50 mm wide (Figure 4.3). Two coupons are placed at 90° to each other and a spot weld is made at the center of the overlapped area. 140 mm 45 mm 60 mm Figure 4.2 Shear tension test coupon dimensions (top) and layout (bottom) (Tumuluru, 2006a). 58 Welding and Joining of AHSS Before making the weld test samples, the electrode tips are conditioned by making 100 welds on flat panels. Per the American Welding Society D8.9M-2012, all shear and cross-tension test samples are generally prepared with a specified weld size. This is normally the electrode face diameter weld size, which is slightly bigger than 90% of the electrode face diameter. Additional details on the testing methodology are avail- able from the American Welding Society D8.9M-2012. 4.2.4 Weld fracture appearance Appearance of fractures in the welds is generally determined on all weld tensile test samples after the tests. Weld fractures are typically classified as full button pull-out, an interfacial fracture, or a partial interfacial fracture. In the full button pull-out fracture mode the entire weld nugget pulls out from the sheets because of a fracture occur- ring outside of the weld area. In an interfacial fracture, the entire weld fails through the plane of the weld. In a partial interfacial fracture, part of the weld nugget fails through the plane of the weld and some portion of the weld pulls out as a partial button (Figure 4.4). It is also possible to have a combination of two failure modes in which a portion of the nugget is pulled out of one of the sheets and the rest of the nugget shears at the Figure 4.3 Cross-tension test specimen dimensions and layout (Tumuluru, 2006a). Figure 4.4 Weld fracture types showing interfacial (top) and button pull mode (bottom). 59Resistance spot welding techniques for AHSS interface. A detailed description of various fracture morphologies that are possible in resistance spot welds is provided by the American Welding Society D8.1M-2007. 4.2.5 Weld microhardness Microstructures of the weld and heat-affected zone are generally examined to check for any imperfections, such as voids and cracks, and to provide an understanding of the tensile properties of the weld. Weld microhardness profiles are determined by measuringhardness at 0.4-mm intervals along a diagonal in a weld cross section (American Welding Society D8.9M-2012). If more information about softening in the heat-affected zone is required, indentations can be spaced more closely, at 0.2-mm intervals. In such a case, however, the indentations may need to be staggered to main- tain a sufficient distance between successive indentations. 4.3 General considerations in resistance spot welding of AHSS In resistance welding the materials to be joined are heated through I 2 Rt, where I is the current used for welding, R is the resistance offered to the passage of current, and t is the duration of the current’s passage. Therefore, the resistance offered by the steel is an important factor that controls weld nugget development. The term R here is a sum of all resistances, including the resistivities of the two steel sheets being welded, the interfa- cial resistance at the sheet-to-sheet interface, as well as the two interfacial resistances at the sheet-to-electrode interfaces. The interfacial resistances between the sheets and the bulk resistivities are critical to heat development because cooling the electrodes in water removes the heat at the sheet-to-electrode interfaces. However, the steel resistiv- ity must be controlled to prevent the generation of excessive heat. Excessive or uncon- trolled heat generation can lead to weld metal expulsion, which is undesirable. Because of the high alloy content of AHSS compared with low-strength steel, AHSS has high resistivity and is therefore likely to heat rapidly at the sheet-to-sheet interface. If heat generation is not controlled properly, weld metal expulsion will result. One way to control the effect of the higher resistivity of AHSS is to use higher electrode force compared with that used for welding low-strength steels, such as inter- stitial-free steels. The beneficial effect of using a higher electrode force can be seen in Figure 4.5 (Tumuluru, 2008a). As the electrode force increased from 2.9 kN (650 lbf) to 5.3 kN (1200 lbf), the welding current increased from 0.6 to 1.4 kA. A current of 1.0 kA is generally regarded as acceptable for production use. It is clear from Figure 4.5 that a welding force of 3.6 kN (800 lbf) is required to obtain the 1-kA current. It is cautioned that with the use of high force, the indentation of the electrode into the base mate- rial should be monitored because higher electrode force causes deeper indentation. In general, the indentation at a given force is greater in a low-strength steel than in a high-strength one. As a general guideline, the electrode indentation should be less than 25% of the base material thickness to avoid the possibility of creating a stress raiser. 60 Welding and Joining of AHSS 4.3.1 Welding dual-phase steel The resistance spot welding behavior of coated dual-phase steel has been the focus of previous research (Tumuluru, 2006a, 2006b). This understanding led to the successful implementation of dual-phase steel, ranging in nominal strength from 590 to 980 MPa, into automotive production. The microstructure of dual-phase steel contains a fine dis- tribution of a hard martensite phase in a soft and ductile ferrite phase. The amount of martensite depends on the strength of the steel; 780-MPa steel typically contains about 25% martensite. This unique combination of martensite and ferrite gives dual-phase steel high strength and high ductility. The welding currents obtained for various dual- phase steels are shown in Figure 4.6 (Tumuluru, 2006a). This indicates that production welding of dual-phase steels can be accomplished with relative ease using a variety of suitable welding conditions and that welds of acceptable quality can be achieved. Because dual-phase steel has higher alloy content than low-strength steel, it has high resistivity and generally requires much lower welding currents to weld. AHSS can be welded using a wide variety of electrode tip shapes. The two most commonly used tip shapes are a truncated cone and a dome (also known as a ball nose). A description of these and other electrode tip designs is provided by ISO 5821:2009. Figure 4.7 shows the effect of the electrode tip shape on welding current ranges. It is clear that dome-shaped tips provide more consistent welds than a truncated cone-shaped tip. The dome-shaped (also referred to as ball-nosed) tips produced a broader current range and more welds that meet a certain mini- mum strength requirement for 1.6-mm steel, which is typically around 8800 N. The dome-shaped tips also provide a larger contact area than the cone-shaped Figure 4.5 A plot showing welding current range as a function of electrode force for 1-mm, 780-MPa, dual-phase steel (Tumuluru, 2008a). 61Resistance spot welding techniques for AHSS electrodes and thereby reduce the current density (Chan et al., 2006). As a result, dome-shaped electrodes increase the current required to produce a weld. This, in turn, increases the welding current range. From Figure 4.7 it is also apparent that the use of pulsed currents did not widen the welding current range for the 1.6-mm 980 dual-phase steel. In general, the use of pulsed currents is useful for thinner-gauge steel to better control nugget growth and avoid expulsion. It is also apparent from Figure 4.7 that, in the case of 980 dual-phase steel, the use of the dome-shaped electrode significantly increased the welding current range. 4.3.2 Welding TRIP steel TRIP steel contains austenite and bainite in a matrix of ferrite. When subjected to plastic deformation, the austenite transforms into martensite. This strain-induced transformation of austenite to martensite gives added ductility to the steel. As a result, TRIP steel pos- sesses better formability than dual-phase steel. The properties and the physical metallurgy of dual-phase and TRIP steel have been extensively studied and reported in the literature (Baik, Kim, Jin, & Kwon, 2000; Takahashi, Uenshi, & Kuriyama, 1997). While both types of steel can contain up to 0.15 weight-percent carbon, TRIP steel generally contains addi- tional alloying elements to avoid the formation of cementite so that the austenite phase is enriched in carbon. These alloying additions can cause differences in the weld hardness. A comparative study completed to examine the welding behavior of 780-MPa dual-phase and TRIP steels reported that both types of steel exhibited similar weld lobes (Figure 4.8). This suggests that the welding behavior of the two is similar (Tumuluru, 2006b). Except for the current required to produce the minimum weld size Figure 4.6 A plot showing the welding current ranges obtained for 1.6-mm dual HDGA steel at various strengths (Tumuluru, 2006a). 62 Welding and Joining of AHSS for the dual-phase steel, the welding currents required to produce welds of a minimum diameter and those that resulted in the first instance of expulsion were almost iden- tical. Even the welding current required to obtain a weld of minimum diameter was only 200 A lower for dual-phase steel when compared with TRIP steel. At the 18-cycle weld time that was used to prepare the tensile test samples in the study reported by Biro, Mingsheng, Zhiling and Zhou (2008), the weld lobe for the dual-phase steel was only 100 A lower than that of the TRIP steel. This small difference could be from the inherent variation present in the determination of the lobes. The practical implications Figure 4.7 The effect of electrode tip shape on the welding current range for 780-MPa (a) and 980-MPa (b) dual-phase steels (1.6-mm). The steels contained hot-dipped galvannealed coating. Panel (b) also shows the effect of the use of pulsed currents on current ranges. 63Resistance spot welding techniques for AHSS of these observations reported by Tumuluru (2006b) are that 780-MPa TRIP steel can be welded with similar welding parameters as those required to weld 780-MPa dual- phase steel.The second implication from this study was that acceptable welds with no imperfections can be obtained, even with the use of simple-to-use and easily adopt- able welding parameters. It should, however, be noted that in auto body fabrication under shop-floor conditions, fit-up of parts generally dictates the welding parameters Figure 4.8 Weld lobes obtained for 780-MPa dual-phase (a) and transformation-induced plasticity (TRIP) (b) steel (1.6-mm) (Tumuluru, 2006b). Copyright © SAE International. Reprinted with permission from 206-01-1214. 64 Welding and Joining of AHSS required to obtain acceptable welds, and these parameters may differ from those that produce acceptable welds under laboratory conditions. 4.4 Coating effects Two types of coatings are generally applied to steel sheets used in the automotive industry, namely, galvanized and galvannealed coatings. Galvanized coatings con- tain essentially pure zinc with about 0.3–0.6 weight-percent aluminum. The term galvanize comes from the galvanic protection that zinc provides to a steel substrate when exposed to a corroding medium. A galvannealed coating is obtained by heating the zinc-coated steel at 450–590 °C immediately after the steel exits the zinc bath. This additional heating allows iron from the substrate to diffuse into the coating. Because of the diffusion of iron and its alloying with zinc, the final coating contains around 90% zinc and 10% iron. There is no free zinc present in the galvannealed coating because of this alloying. Dipping coils of steel into a molten bath of zinc is known as the hot-dip process. HDGA refers to hot-dipped galvannealed products, whereas HDGI refers to hot-dipped galvanized products. HDGA coatings contain less alumi- num (about 0.15–0.4 weight-percent) than HDGI coatings. Another way of applying the coatings is through an electrolytic plating process. Scanning electron micrographs showing cross-sectional views of HDGI and HDGA coatings are shown in Figure 4.9. In an investigation undertaken to examine whether differences in the resistance spot welding behavior of 780-MPa dual-phase steel with an HDGA coating exist compared with steel with an HDGI coating, the welding current ranges, weld shear tension strength and CTS, and weld microhardness profiles across the welds were examined (Tumuluru, 2008b). The results indicated that 780-MPa dual-phase steel showed similar overall welding behavior with HDGA and HDGI coatings. This work also showed that the weld shear tension strength and CTS were independent of the type of coating. HDGA-coated steel was able to be welded at a slightly lower current than Research and technology center 2 µm Mag = 2.50 K X WD = 6 mm EHT = 15.00 kV Signal A = SE2 (a) (b) Figure 4.9 Scanning electron microscope views of cross sections of hot-dipped galvanized (a) and hot-dipped galvannealed (b) coatings on 780-MPa dual-phase steel (Tumuluru, 2008b). 65Resistance spot welding techniques for AHSS the HDGI-coated steel: the reason for this behavior was attributed to the differences in surface resistitivity between the coatings (Figure 4.10). 4.5 Microstructural evolution in welds Because electrodes are cooled in water in resistance spot welding, the weld cool- ing rates are extremely rapid. Spot welds with a thickness up to 2 mm typically solidify in less than three or four cycles. It has been shown through modeling that even at 500 °C the cooling rates in spot welding were in excess of 1000 °C/s (Li, Dong, & Kimchi, 1998). For steel, the critical cooling rate (ν) required to achieve martensite in the microstructure is determined using the following equation (Easterling, 1993): log v = 7.42 − 3.13 C − 0.71 Mn − 0.37 Ni − 0.34 Cr − 0.45 Mo For 780-MPa dual-phase steel, the critical rate is about 240 °C/s. As a result, a martensitic structure is typically present in both the weld and the heat-affected zone. Even in the near heat-affected zone, martensite is the predominant constit- uent (Figure 4.11). However, in the far heat-affected zone (the part of the heat-af- fected zone that is closer to the unaffected base material), some of the martensite is tempered and a decrease in the hardness can be noted (Figure 4.12). As can be seen from Figure 4.12, this drop in the far heat-affected zone increases from the 780–980-MPa strength level because of the higher alloying content in the 980- MPa steel. This phenomenon of heat-affected zone softening in welds was studied Figure 4.10 Plot of welding current ranges for hot-dipped galvannealed (HDGA)- and hot-dipped galvanized (HDGI)-coated 780 MPa dual phase steels. Notice the higher current required to obtain the minimum weld size for the HDGI-coated steel (Tumuluru, 2008b). 66 Welding and Joining of AHSS Research and technology center 1µm 1µm 1µm Mag = 5.00 K X Mag = 5.00 K X Mag = 5.00 K X WD = 13 mm WD = 19 mmWD = 18 mm EHT = 15.00 kV EHT = 15.00 kVEHT = 15.00 kV Signal A = SE2 Signal A = SE2Signal A = SE2 (a) (b) (c) Figure 4.11 Scanning electron micrographs showing the microstructure of welds (a), the near heat-affected zone (b), and the far heat-affected zone (c). 100 150 200 250 300 350 400 450 500 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 H ar dn es s (V H N ) Indentations 780 DP 980 DP Figure 4.12 A plot showing weld microhardness traverses for 780- and 980-MPa dual-phase steel. The heat-affected zone showed a decrease in hardness of about 30 VNH for the 980-MPa steel. 67Resistance spot welding techniques for AHSS by Biro et al. (2008), who found evidence of martensite tempering in dual-phase steel welds. Other researchers have confirmed these findings, as well (Okita, Baltazar Hernandez, Nayak, & Zhou, 2010). 4.6 Weld shear tension strength and cross-tension strength (CTS) 4.6.1 Shear tension strength Results of actual testing and finite element modeling (FEM) show that the shear ten- sion strength in AHSS grades increases as the base material strength increases. The fracture mode in shear tension testing of AHSS grades up to 980 MPa shows that there are essentially two types of fracture modes, namely, the full button pull-out mode (also known as button pull or plug-type fractures) and the interfacial fracture mode. For pull-out failure, the results of the finite element simulations by Radakovic and Tumuluru (2008) showed that there was a strong correlation between failure load and the material strength, sheet thickness, and weld diameter. The load required to cause interfacial failure was more strongly dependent on the weld diameter and less depen- dent on the sheet thickness. The predicted failure loads were found to adhere to the following correlations: FPO = kPO · σUT · d · t (4.1) FIF = kIF · σUT · d2 (4.2) where FPO is the failure load for pull-out failure, FIF is the failure load for an interfa- cial fracture, σUT is the tensile strength of the material, d is the weld diameter, and t is the sheet thickness. These equations were derived based on the fact that the force required to cause failure is equal to the product of the strength of the material and the cross section of the failed area. In this analysis the material was assumed to be homo- geneous. Therefore the strengths of the weld and the base metal are both equal to σUT. In Eqns (4.1) and (4.2), kPO and kIF were constants determined from the modeling. Radakovic and Tumuluru (2008) also determined that there is a critical sheet thick- ness above which the expected failure mode could move from pull-out to interfacial fracture. Further, they found that as the strength of the sheet increases, the fracture toughness of the weld required to avoid interfacial fractures must also increase. In higher-strength, less ductile steel this is not likely to occur, and interfacial fracture could become the expected failure mode. The load-carrying capacity of the samples that failed via interfacial fracture was more than 90% of the maximum loadassociated with the full button pull-out. This indicates that the load-bearing capacity of these welds is not significantly affected by the fracture mode. The mode of failure should therefore not be the only criteria used to judge the results of the shear tension test. The load-carrying capacity of the weld should be considered the most important parameter when evaluating the shear tension test results in AHSS. 68 Welding and Joining of AHSS 4.6.2 Cross-tension strength (CTS) The results of cross-tension testing for both 780 and 980 steel grades are shown in Figure 4.13 (Radakovic & Tumuluru, 2012; Tumuluru & Radakovic, 2010). In Figure 4.13 the weld CTS was plotted as a function of weld size. As the plot shows, the CTS increased with weld size for both grades. In this test the full button pull-out fracture mode occurred in both grades and at all weld sizes. As can be seen in Figure 4.13, CTS for the 980-MPa steel was slightly lower than that for the 780-MPa steel; this differ- ence was more noticeable at weld sizes larger than 4√t. Tumuluru and Kashima (2009) reported that CTS decreased as the carbon content of the base material increased from 0.05% to 0.2% in dual-phase steel. This research also showed that as the carbon con- tent increased, the tensile strength of the base material also increased and the ductility decreased (Tumuluru & Kashima, 2009). This indicates an inverse relationship between the tensile strength of the base material and the weld CTS. A similar trend in CTS with increasing base material strength was observed by Sakuma and Oikawa (2003). The modeling performed by Tumuluru and Radakovic (2010) indicated that the failure load in the cross-tension test is related to the sheet thickness and the strength and ductility of the heat-affected zone. Actual cross-tension test results supported the model predictions that there was a correlation between failure load and weld size. In the cross-tension testing, at all weld sizes tested, full button pull-out fractures occurred in the two steel grades tested. This result agreed with the model results, which indi- cated that the weld would not overload until the button size became much smaller than those achieved in the test samples. In the cross-tension test, the constraint of the sample grips prevents lateral movement of the sheet as the sample is pulled vertically. Modeling also showed that this constraint causes high tensile force to develop in the sample perpendicular to the direction of the applied load. For this reason, pull-out failures are the preferred failure mode in this test, even for very small weld sizes. 2 4 6 8 10 12 2 3 4 5 6 7 8 9 780 DP 980 DP C TS (k N ) Weld size (mm) Figure 4.13 Cross-tension test results for 1.2-mm, 780- and 980-MPa dual-phase steels. The cross-tension strength (CTS) is shown as a function of weld size. Full button pull-out failures occurred at all weld sizes in both the grades (Radakovic and Tumuluru, 2008). 69Resistance spot welding techniques for AHSS Tumuluru and Radakovic examined an actual crash-tested vehicle and found that the deformation of the sheets around the welds in this vehicle was similar in appearance to that which occurred in the cross-tension test, with buckling of the joined sheets between spot welds. However, this type of buckling or crumpling in the crash-tested vehicle was the result of compressive loading and not tensile loading as predicted by the finite element method for the cross-tension test. Based on this work, it was concluded that the cross-tension test is neither a discriminating test for assessing the weldability of high-strength steel nor does it represent the type of loading that the spot welds in a vehicle undergo in a real crash event. 4.7 Summary Resistance spot welding is the predominant method of joining used in automotive assembly plants for welding a wide variety of parts, a trend that is likely to continue for the foreseeable future. Several new grades of AHSS, including dual-phase and TRIP steel, have been commercialized between 2000 and 2010. These steel grades are being increasingly used, especially in BIW applications, to meet the ever-increasing demands across the globe for improved fuel efficiency and occupant protection. Research com- pleted to date indicates that these AHSS grades are easily weldable. In general, AHSS grades require the use of higher electrode forces and larger tip sizes to achieve accept- able welding current ranges. AHSSs with a tensile strength of 980 MPa or higher show softening in the far heat-affected zone, which can affect their cross-tension test behav- ior. Research has also demonstrated that the fracture morphology from weld tension testing should not be used as the sole criterion to assess the results of shear tension tests. Load to failure is an important attribute of the test that should be emphasized. References American Welding Society Specification D8.1M-2007. (2004). Specification for automotive quality – Resistance spot welding of steel. Miami, FL: American Welding Society. American Welding Society Specification D8.9M-2012. (2012). Recommended practices for test methods for evaluating the resistance spot welding behavior of automotive sheet steel materials. Miami, FL: American Welding Society. Baik, S. C., Kim, S., Jin, Y. S., & Kwon, O. (2000). Effects of alloying elements on mechanical properties and phase transformation of cold rolled steel sheets. In SAE technical paper 2000-01-2699, Detroit, MI. Biro, E., Mingsheng, X., Zhiling, T., & Zhou, N. (2008). Effects of heat input and martensite on HAZ softening in laser welding of dual phase steels. ISIJ International, 48(6), 809–814. Chang, I. (2015). Recent trend of welding and joining application in automotive industry. In Paper presented at the international congress of the International Institute of Welding, Seoul, South Korea. Chan, K., Scotchmer, N., Bohr, J. C., Khan, I., Kuntz, M., & Zhou, N. (2006). In Effect of elec- trode geometry on resistance spot welding of AHSS, 4th international seminar on advances in resistances in resistance welding, November 14–16, 2006, Wels, Austria. Ducker Worldwide report 2007, www.duckerworldwide.com. http://www.duckerworldwide.com 70 Welding and Joining of AHSS Easterling, K. E. (1993). Modeling the weld thermal cycle and transformation behavior in the heat affected zone. In H. Cerjak, & K. E. Easterling (Eds.), Mathematical modeling of weld phenomena. The Institute of Materials. Horvath, C. D. (2004). The future revolution in automotive high strength steel usage. In Paper presented at great designs in steel, American Iron and Steel Institute, Southfield, Mich. ISO 5821:2009: Resistance welding – spot welding electrode caps, www.iso.org. Keller, J. (2014). Weight down….Value up … and the new MDX. www.cargroup.org. Li, M. V., Dong, D., & Kimchi, M. (1998). Modeling and analysis of microstructure devel- opment in resistance spot welds of high strength steels. SAE Technical Paper 982278. Warrendale, PA: SAE International. Okita, Y., Baltazar Hernandez, B. H., Nayak, S. S., & Zhou, N. (2010). Effect of HAZ-softening on the failure mode of resistance spot-welded dual-phase steel. In Paper presented at the sheet metal welding conference XIV, May 11–14, Livonia, MI. Pfestorf, M. (2006). BMW – functional properties of the advanced high strength steels in the body-in-white. In Paper presented at great designs in steel, American Iron and Steel Insti- tute, Southfield, Mich. Radakovic, D. J., & Tumuluru, M. (April 2008). Predicting resistance spot weld failure modes in shear tension tests of advanced high-strength automotive steels. Welding Journal, American Welding Society, Miami, FL, 96S–105S. Radakovic, D. J., & Tumuluru, M. (2012). An evaluation of the cross-tension test of resistance spot welds in high strength dual phase steels. Welding Journal, 91, 8S–15S. Sakuma, Y., & Oikawa, H. (2003). Factors to determinestatic strength of spot-weld for high strength steel sheets and development of high-strength steel sheets with strong and stable welding characteristics. Nippon Steel Corporation, Japan, Nippon Steel Technical Report No. 88. Takahashi, M., Uenshi, A., & Kuriyama, Y. (1997). Properties of high strength TRIP steel sheets. Automotive Body Materials. IBEC. Tumuluru, M. (2006a). An overview of the resistance spot welding of coated high strength dual phase steel. Welding Journal, 85(8), 31–37s. Tumuluru, M. (2006b). A comparative examination of the resistance spot welding behavior of two advanced high strength steels. In SAE technical paper No. 2006-01-1214, presented at the SAE congress, Detroit, MI. Tumuluru, M. (2008a). Some considerations in the resistance spot welding of dual phase steels. In Paper presented at the 5th international seminar on advances in resistance welding, September 24–26, 2008, Toronto, Canada, organized by Huys Industries, Weston, Ontario, Canada. Tumuluru, M. (June 2008b). The effects of coatings on the resistance spot welding behavior of 780 MPa dual phase steel. Welding Journal, American Welding Society, Miami, FL, 161S–169S. Tumuluru, M. (2013). Evolution of steel grades, joining trends and challenges in the automotive industry. In Invited keynote presentation, American Welding Society FABTECH welding show and conference, Chicago, IL. Tumuluru, M., & Kashima, T. (2009). Effect of alloying elements on resistance spot weld per- formance in dual phase steels. In Paper presented at AWS FABTECH conference, Chicago, November 17, 2009. Miami, FL: American Welding Society. Tumuluru, M., & Radakovic, D. J. (2010). Modeling of cross-tension behavior of dual phase and TRIP steels. In Sheet metal welding conference XIV. Livonia, MI: American Welding Society. http://www.iso.org http://www.cargroup.org Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00005-9 Copyright © 2015 Elsevier Ltd. All rights reserved. Laser welding of advanced high-strength steels (AHSS) S.S. Nayak1, E. Biro2, Y. Zhou1 1University of Waterloo, Waterloo, ON, Canada; 2ArcelorMittal Global Research, Hamilton, ON, Canada 5 5.1 Introduction In recent years the use of advanced high-strength steel (AHSS) has increased in popu- larity in the automotive industry because of its excellent combination of high strength and ductility, which allows the thickness of steel used to make auto body parts to be decreased, which in turn facilitates a reduction in vehicle weight while improving safety (Blank, 1997; Gan, Babu, Kapustka, & Wagoner, 2006). Typical AHSS families used in automotive construction, for example, dual-phase (DP) steel, transformation- induced plasticity (TRIP) steel, complex phase steel, martensitic steel, and twinning- induced plasticity (TWIP) steel, are characterized by yield strengths and ultimate tensile strengths higher than 300 and 600 MPa, respectively (Bhadeshia & Honeycombe, 2006; World Auto Steel, 2009). Understanding the individual microstructures of these steels is critical to understand the changes that occur during laser welding. TRIP steel has a microstructure consisting of retained austenite and martensite islands dispersed in a ferrite matrix. TWIP steel contains a fully austenitic microstructure because of its high manganese content, that is, 17–24 wt% (De Cooman, Kwon, & Chin, 2012). Finally, martensitic steel contains a fully martensite microstructure, as is suggested by its name. Of all AHSS, only DP steel and TRIP steel have been identified as potential candidates for car body fabrication because of their better formability compared with martensitic steel and their low manufacturing cost compared with TWIP steel. Because of this, the research on AHSS has mainly focused on DP and TRIP steels; therefore, this chapter outlines a review of the work on these two steels carried out so far. A design technique that is unique to the laser welding process is the production of laser-welded blanks (LWBs), which are also known as tailor-welded blanks. LWBs are composed of two or more sheets of similar or dissimilar materials, thicknesses and/or coating types welded together, which are formed to fabricate three-dimensional auto- motive body parts (Auto/Steel Partnership, 1995). The advantages of LWBs include weight reduction, cost minimization, material usage and scrap reduction with improved part integration. In general, LWBs are made with mild or interstitial free steels; how- ever, in recent years the ability of LWBs to reduce weight has been increased by using high-strength steels such as high-strength low-alloy (HSLA) steel and AHSS, which also improves the crash performance of the blanks (Kusuda, Takasago, & Natsumi, 1997; Shi, Thomas, Chen, & Fekte, 2002; Uchihara & Fukui, 2006). LWBs are almost 72 Welding and Joining of AHSS exclusively joined in a butt joint configuration. Hence this chapter likewise focuses on butt joints in various AHSSs, mainly DP steels and TRIP steels. Before discussing the microstructure and properties in laser welding of AHSS, however, a brief background of the laser welding process is provided in Section 5.2. 5.2 Background The beam intensity, average power and flexibility of beam delivery at different loca- tions make laser welding a popular welding process. Traditional carbon dioxide lasers have been predominately used in industry because of their plug efficiency when compared with solid-state lasers such as neodymium:yttrium–aluminium–garnet (Nd:YAG). However, ytterbium fibre lasers have recently gained industrial acceptance because of their high plug efficiencies, lower capital costs and the flexibility of deliv- ering the laser with a flexible fibre instead of fixed optics, as is needed for carbon dioxide lasers. Further information about the physics and operation of lasers can be found in laser-welding textbooks (Dawes, 1992; Duley, 1999). The automotive industry uses a keyhole mode for laser welding, which has a high power density, resulting in deep penetration and narrower welds. Therefore laser welding does not require any special joint preparation or addition of filler materials. High welding speeds are achieved in laser welding because of the high power density, which significantly increases the production rate. The combination of high power density and speed leads to lower heat input in laser welding, which minimizes metallurgical heterogeneities across the weldments, for example, extension of the fusion zone and heat-affected zone (HAZ). Lower heat input also reduces the thermal distortion of the workpieces, minimizing the machining requirements after welding. Laser welding allows the joining of sheets where access to only one side is possible, allowing greater flexibility of the joint design. Based on the above-mentioned advantages, mentioning that laser welding is a potential process for welding AHSS, especially for body-in-white applications, is worthwhile. 5.3 Laser welding of AHSS Automakers can conveniently tailor the design of automotive parts through the combi- nation of strength, formability and crashworthiness by incorporating AHSS in LWBs. Before the analysis of forming and crashworthiness of LWBs, however, various weld- ability issues must be understood to design and produce high-quality parts with rea- sonable production and tooling costs. In industry LWBs are manufactured in a keyhole laser welding mode; however, laboratory-based research also has examined welds made in a conduction mode to understand the metallurgical and mechanical behaviour of laser-welded AHSS (Biro, McDermid, Embury, & Zhou, 2010; Panda, Hernandez, Kuntz, & Zhou, 2009; Sreenivasan, Xia, Lawson, & Zhou, 2008; Xia, Tian, Zhao, & Zhou, 2008a; Xia, Tian, Zhao, & Zhou, 2008b). Therefore this chapter reports results of AHSS welded with both these laser welding modes. 73Laser welding of AHSS 5.3.1 Key issues Laserwelding of AHSS involves many challenges, and the most important ones are described in this section. AHSS is welded in a butt weld configuration when manu- facturing LWBs to eliminate the issues involved in forming and die design. In butt welding the zinc coating present on the AHSS would not be harmful, but if lap weld- ing is used it would be harmful (Li, Lawson, Zhou, & Goodwin, 2007). However, butt welding requires precise fit-up and alignment of the workpieces because of the narrow beam size compared with other fusion welding processes. Any gap between the steel sheets may result in significant weld concavity and undercut, which degrades weld performance. In addition, misalignment of the workpieces produces a notch that reduces the fatigue life of the LWBs. Most industrial laser welding processes use keyhole mode welding because it gives deep penetration and fast welding speeds. The rapid fluid velocity, as high as 3000 mm/s (Zhao, White, & DebRoy, 1999), associated with keyhole mode laser welding and the instability of the keyhole often lead to rough and ropy bead surfaces. This can be an issue when considering the auto body parts where weld surface appearance is important, for example, in automotive applications where the welds are visible. However, a smooth and acceptable bead surface can be obtained by controlling the welding parameters. In addition to these challenges, metallurgical issues such as softening (i.e. a decrease in the hardness relative to the base metal) have consistently occurred at the tempered region or subcritical HAZ of DP steel welds (Biro et al., 2010; Li et al., 2013; Panda et al., 2009; Sreenivasan et al., 2008; Xia et al., 2008a; Xia et al., 2008b; Xu et al., 2012). The HAZ softening phenomenon occurs because the martensite phase in DP and martensitic steels is tempered; the extent of softening increases with the martensite content. Thus more HAZ softening generally occurs in DP steels with higher martensite volume fractions. The details of these steels are discussed in Sections 5.4.2 and 5.5.1. 5.4 Microstructure of laser-welded AHSS As in all other welding processes, the microstructure of laser welds in AHSS are broadly made of three parts, namely, a base metal, a HAZ and a fusion zone. A typical example of laser-welded DP steel is illustrated in Figure 5.1(a). The microstructure of a DP steel base metal consists of ferrite grains and martensite islands elongated in the rolling direction (Figure 5.1(b)). The HAZ, in turn, is composed of three subparts based on the peak temperature experienced by the workpiece during welding and the critical transformation temperature of the AHSS. The three subparts of HAZ are a tempered region, or subcritical HAZ, where the peak temperature experienced during welding is below the Ac1 temperature of the steel (Figure 5.1(c)); the intercritical HAZ, where the peak temperature during welding is between the Ac1 and Ac3 temperatures of the steel (Figure 5.1(d)); and the supercritical HAZ, where the steel is heated above its Ac3 temperature (Figure 5.1(e)). In the fusion zone the peak temperature exceeds the melting point of the steel. The microstructure of the HAZ depends only on solid-state 74 Welding and Joining of AHSS transformations, whereas the microstructure of the fusion zone is based on both the solidification behaviour of the steel and the solid-state transformations as the fusion zone cools from melting temperature to room temperature. The geometry of the fusion zone and the HAZ is dependent on the welding param- eters and the type of laser welding. Table 5.1 compares the different laser welds based on the geometry of the fusion zone and the HAZ in DP980 steel (Xu et al., 2013). It should be noted that a 4-kW diode laser weld in a 1.2-mm-thick DP980 steel sheet has a very wide HAZ and fusion zone compared with other laser welding processes. Figure 5.1 Microstructure developed in fibre laser welding (6-kW power and welding at 16 m/min) of DP980 (1.2-mm-thick) steel: weld profile (a), base metal (b), subcritical heat-affected zone (HAZ) (c), intercritical HAZ (d), supercritical HAZ (e), and fusion zone (f). F, ferrite; M, martensite; RD, rolling direction; TM, tempered martensite (Westerbaan et al., 2012). 75 L aser w elding of A H SS Table 5.1 Comparison of different laser welding processes based on the size of the heat-affected zone (HAZ) and fusion zone formed in DP980 steel (Xu et al., 2013) Welding type Power (kW) Welding speed (m/min) Spot size (mm) Thickness of the workpiece (mm) Average width of the HAZ (µm) Average width of the fusion zone (µm) Reference Diode 4 1.6 12 × 0.5 1.2 4000 3000 Xia, Sreenivasan, Lawson, Zhou, and Tian (2007) Nd:YAG 3 3 0.6 1.17 1000 750 Sreenivasan et al. (2008) CO2 6 6 – 1.8 1000 1000 Kim, Choi, Kang, and Park (2010) Fibre 6 16 0.6 1.2 250 450 Xu et al. (2013) 76 Welding and Joining of AHSS This is because of the considerably larger laser beam spot size in diode laser weld- ing, which produces a lower energy density, leading to conduction mode welding. By contrast, in fibre laser welding, the higher energy density causes keyhole mode weld- ing, which is more efficient when compared with the conduction mode in diode laser welding; in this case the fibre laser welding could occur at higher speeds, resulting in a narrower weld. 5.4.1 Fusion zone As mentioned previously, the fusion zone melts and solidifies during laser weld- ing. Because of the high welding speeds and narrow weld widths, the cooling rates experienced in laser welding are very high (Gould, Khurana, & Li, 2006). Thus, the microstructure within the fusion zone consists of the constituents formed via nonequi- librium solidification of the liquid base metal. Epitaxial solidification occurs in the fusion zone, starting at the fusion boundary (i.e. the area of contact between the weld pool and the unmelted substrate of the workpiece) and gradually growing towards the weld centre line to meet growing columnar grains from the opposite fusion boundary (Figure 5.1(a)). Epitaxial solidification involves the growth of the solid in the direc- tion in which the grains at the fusion boundary are oriented. In AHSS the fusion zone microstructure and that of its constituents depend on two important factors: cooling rate and chemistry. The following sections discuss the influence of cooling rate and chemistry in detail. The cooling rate in laser welding is directly related to the welding speed, that is, the higher the welding speed, the higher the cooling rate. However, the cooling rate in the laser welding process is commonly higher than the critical cooling rate to form the martensite phase in most AHSS, which has high hardenability because of its high alloying content. Thus martensite is commonly observed in the fusion zone of almost all AHSS laser welds. For example, Gu, Yu, Han, Li, and Xu (2012) reported that Nd:YAG laser welding (3 kW) of hot-stamped (martensitic) steel forms a fusion zone with only a martensite phase in the entire range of welding speeds (3.6–7.8 m/min). In addition, Xia et al. (2008b) also concluded that no significant variation in the fusion zone microstructure is expected when the welding speed increases from 1.2 to 2.2 m/ min in diode laser welding of TRIP steel. This was based on the observation that there was an insignificant increase in the fusion zone hardness with welding speed. The fusion zone microstructure in laser-welded AHSS is strongly dependent on the carbon content. For example, it was recently reported that martensite content in the fusion zone microstructure in diode laser welding of AHSS decreased with car- bon and alloying additions (Santillan Esquivel, Nayak, Xia, & Zhou, 2012). A mixed microstructure containing martensite, ferrite and bainite phases is formed in the fusion zone, containing less than 0.12 wt% carbon, which is also confirmed by the hardness values,which measured lower-than-predicted martensite hardness with similar carbon content (Santillan Esquivel et al., 2012). Carbon increases the hardenability of AHSS and shifts the continuous cooling transformation curve toward the right. In addi- tion to carbon, other alloying additions in AHSS, for example, manganese, silicon, aluminium, chromium and molybdenum, also enhance the formation of martensite by 77Laser welding of AHSS retarding the kinetics of ferrite and bainite formation and increasing the hardenability of the steel. Therefore, because of the carbon and other alloying elements used in AHSS and the high cooling rates associated with laser welding, the fusion zone is usually highly martensitic. TRIP steel is unique because it is generally alloyed with high amounts of either silicon or aluminium to delay carbide precipitation (De Cooman, 2004). Interestingly, microstruc- ture in the weld pool of TRIP steel laser welds is reported to be strongly influenced by the alloying addition (Xia et al., 2008a). For example, in diode laser welding silicon-alloyed TRIP formed a fully martensite structure (Figure 5.2(a)) for the reasons discussed above. However, since aluminium is a ferrite stabilizer, it transformed the TRIP steel fusion zone into a mixed microstructure consisting of high-temperature ferrite (δ-ferrite) as a primary Si-alloyed Al-alloyed (a) (b) Figure 5.2 Fusion zone microstructure of silicon-alloyed (a) and aluminium-alloyed (b) transformation-induced plasticity steel in diode laser welding. F, ferrite (Xia et al., 2008b). 78 Welding and Joining of AHSS phase, which subsequently transformed into side-plate ferrite (Figure 5.2(b)), martensite and bainite (Xia et al., 2008a). The solidification sequence in aluminium-alloyed TRIP is as follows. In the first stage δ-ferrite solidifies as the primary-phase dendrites and grows into the liquid. These dendrites are rich in aluminium, so the remaining liquid, which is depleted in TRIP with a lower aluminium content, solidifies to form stable austenite via a peritectic reaction. This sequence leads to a unique microstructure of δ-ferrite dendrites with interdendritic austenite, which upon further cooling decomposes to either marten- site or bainite, depending on the welding speed, which in the range of 1.6–2.2 m/min leads to a cooling rate of 50–100 K/s (Xia et al., 2008a). 5.4.2 Heat-affected zone In the HAZ of AHSS laser welds the temperature rises rapidly to a peak and then quickly cools again. The heating and cooling rates depend on the welding parameters and the distance from the fusion boundary. Based on the peak temperature, different transfor- mations occur within the HAZ. In the supercritical HAZ the base metal microstructure changes to austenite during heating. Depending on how high above the Ac3 temperature of the steel the peak temperature is, grain growth may also occur. When the region of the HAZ with a temperature above the steel’s Ac3 temperature cools, it typically transforms into martensite because of the high hardenability of AHSS (Figure 5.1(e)). In the inter- critical HAZ the base metal microstructure starts forming austenite, which nucleates at the grain boundaries. Again, upon cooling the austenite typically transforms into mar- tensite and the ferrite remains unchanged. The volume fraction of martensite in this area of the HAZ increases as the peak temperature rises from the Ac1 to the Ac3 temperature. For example, the intercritical HAZ microstructure in DP steel contains fine martensite grains in a ferrite matrix (Figure 5.1(d)), which is very different from the base metal (Figure 5.1(b)). It should be noted that the intercritical HAZ microstructure in DP steel may resemble that of the base metal (Biro & Lee, 2004). The subcritical HAZ experi- ences a peak temperature below the Ac1 line of the steel, wherein the martensite phase in the base metal is tempered (Figure 5.1(c)), causing the HAZ to soften or the hardness to drop below that of the base metal. Because of a decrease in tempering temperature, the severity of HAZ softening decreases with increasing distance from the Ac1 iso- therm. Martensitic and DP steels are more prone to HAZ softening. For example, many researchers have reported the severity of HAZ softening of DP steels increases with increasing heat input and the steel grade (Biro et al., 2010; Xia, Biro, Tian, & Zhou, 2008). HAZ softening has been reported as detrimental to the performance of laser welds, the details of which are discussed in Section 5.6. 5.5 Hardness Hardness across the LWBs is determined by the corresponding microstructure, which has been discussed as being dependent on the welding parameters, steel chemistry and initial microstructure. The effects of these on the performance are discussed separately. Welding parameters such as welding speed, power and laser spot size affect heat input, which has a large effect on the properties after welding. Figure 5.3 compares 79Laser welding of AHSS microhardness profiles across the DP980 LWBs made using different laser-welding param- eters. The readers may note that HAZ softening (marked as ‘softening’ in Figure 5.3(c)) may occur in the outer part of the HAZ, irrespective of the laser welding process used. ν ν µ ν Figure 5.3 Hardness profile across the DP980 steel welds made using a diode laser at 1.0 m/min (a), a neodymium:yttrium–aluminium–garnet laser at 3.0 m/min (Sreenivasan et al., 2008) (b), and a fibre laser at 16 m/min (Westerbaan et al., 2012) (c). BM, base metal; HAZ, heat-affected zone. 80 Welding and Joining of AHSS However, the width of the soft zone decreases with increasing welding speed and decreasing beam width. As mentioned in earlier sections, HAZ softening has been asso- ciated with tempering of the martensite phase of the base metal (Baltazar Hernandez, Panda, Kuntz, & Zhou, 2010; Biro et al., 2010; Xia et al., 2008). The hardness of the HAZ increases between the edge of the tempered region and the fusion boundary. This is related to an increase in the martensite volume fraction in the supercritical region of the HAZ (Figure 5.1(c) and (d)). The hardness of the HAZ smoothly merges with the fusion zone hardness, which shows a maximum value because the fusion zone experi- ences the highest cooling rate in the weldment. The microstructure of the fusion zone is typically fully martensitic because of the high cooling rates experienced and high hardenability of AHSS (Figure 5.1(f)). It should be noted that minimal HAZ softening has been reported in TRIP steel welds, in which decomposition of retained austenite in the base metal occurs in the temperature below the Ac1 line, resulting in an increase in hardness (Xia et al., 2008a, 2008b). The hardness of the fusion zone of AHSS strongly depends on its carbon con- tent. Santillan Esquivel et al. (2012) carried out diode laser welding of several AHSSs (DP600, DP780, TRIP780) with similar and dissimilar combinations. Three different regions were identified when fusion zone hardness was plotted versus carbon con- tent (weight percent) and compared with the theoretical martensite hardness (calcu- lated from the carbon content), as depicted in Figure 5.4. Region I comprised the fusion zone, which has high carbon content, resulting in a completely martensitic structure and hardness similar or close to that of theoretical martensite hardness. A mixed microstructure of martensite and bainite was seen in region II, which resulted in slight decrease in hardness from the theoretical martensite hardness. In region III a significant diversion from the martensite hardness was noticed because AHSS with low carbon content (<0.1 wt%) formed a ferritic microstructure with little bainite and/or martensite (Santillan Esquivel et al., 2012). Figure 5.4 Fusion zone hardness versus carbon content in laser welding of various advanced high-strength steels in similar and dissimilar combinations (SantillanEsquivel et al., 2012). ν 81Laser welding of AHSS 5.5.1 Factors affecting HAZ softening Laser welding heat input and the amount of alloying in the steel are two factors that influence HAZ softening and its characteristics in DP steels. With decreasing heat input there is less time available to complete the martensite tempering reaction in the base metal. It should be noted that the HAZ of laser welds may not fully temper. Therefore the time that the HAZ of laser welds are at the elevated temperatures do not allow for as much diffusion as processes using higher heat. However, higher heat input increases the time that the subcritical area of the HAZ is at elevated temperatures and hence results in more severe softening (Biro et al., 2010; Xia et al., 2008). A typical example of difference in martensite morphology in HAZ of one DP780 steel welded with low and high heat input is shown in Figure 5.5. Higher heat input has resulted in severe decomposition of the martensite grain shown, whereas at lower heat input there still remains a large fraction of untempered martensite in the subcritical HAZ. Another recent study (Nayak, Hernandez, & Zhou, 2011) of the effects of chemistry on HAZ softening in DP steels concluded that when the same welding parameters are used the degree of softening is more for lean composition (DPL) steel when compared with moderate (DPM) and rich (DPR) steels. Note that DPL represents the steel with lower content of alloying elements (e.g. manganese, chromium and silicon), the con- tents of which are higher in the DPR steel; for the DPM steel, their concentrations are between that of lean and rich steel. This was attributed to the severity of martensite decomposition (Figure 5.6(a)–(c)), which was suggested by the size of the precipi- tated cementite particles (Figure 5.6(d)–(f)) in the tempered region of the welds. In the tempered region of HAZ, DPL steel (Figure 5.6(d)) formed coarser cementite par- ticle and DPR steel (Figure 5.6(f)) formed a finer one with DPM steel (Figure 5.6(e)), forming cementite particles with a size between those formed in the DPL and DPR steels. It has been reported that the tempering characteristics in DP steel strongly depend on the martensite morphology in the base metal (Baltazar Hernandez, Nayak, & Zhou, 2011; Nayak et al., 2011). Therefore DPR steel, which contained a twinned structure of martensite because of higher martensite carbon content (0.36 wt%) in the Figure 5.5 Effect of heat input (low (a) and high (b)) on martensite tempering in DP780 steel (Biro et al., 2010). 82 Welding and Joining of AHSS (a) (d) (e) (f) (b) (c) Figure 5.6 Effect of chemistry on the severity of martensite tempering in DP980 steels. Microstructures showing tempered martensite in the subcritical heat-affected zone of lean composition dual-phase (DPL) (a), moderate composition dual-phase (DPM) (b), and rich composition dual-phase (DPR) steel (c) welds. The representative bright field images of the extracted cementite and corresponding selected area diffraction patterns in the inset images showing [010] zone axis of cementite from DPL (d), DPM (e), and DPR steels (f) (Nayak et al., 2011). 83Laser welding of AHSS base metal, formed finer cementite, whereas other lower martensite carbon contents in DPL (0.273 wt%) and DPM steels (0.269 wt%) resulted in a martensitic lath structure (Nayak et al., 2011). It should be noted that although DPM steel contains similar car- bon content as DPL steel, it has a higher amount of alloying elements, which retard the coarsening kinetics of the cementite (Chance & Ridley, 1981; Miyamoto, Oh, Hono, Furuhara, & Maki, 2007) formed during the martensite tempering reaction, which resulted in finer precipitates compared with those formed in DPL steel. The effects of heat input during welding on the kinetics of the martensite tempering or HAZ softening has been studied recently (Biro et al., 2010; Xia et al., 2008). In their (Xia et al., 2008; Biro et al., 2010) study they compared the martensite decomposition with the heat input of the welding process. They have provided a modified formula for calculating heat input at the subcritical HAZ, that is, at the Ac1 temperature, which was based on Rosenthal’s solution for a moving line power source in a thin plate. The calculated heat input then was used to determine the time constant, that is, the time required to heat the material from an ambient to the Ac1 temperature (Eqn (5.1)). τ = 1 4πeλρc [Qnet/ (vd)] 2 (TAc1 − T0) 2 (5.1) In Eqn (5.1), Qnet is the laser power (watts), v is welding speed (millimetres/second), d is sheet thickness (millimetres), λ is the thermal conductivity (30 W/m/K), ρ is the steel density (7860 kg/m3), c is the specific heat capacity of steel (680 J/kg/K), TAc1 is the Ac1 temperature (Kelvin) and T0 is the ambient temperature (298 K). The term Qnet/(vd) is the heat input (more precisely, the thickness-normalized net energy absorbed per unit weld length), which was calculated from the difference in distance between the weld centre line to the Ac1 isotherm and the weld centre line to the fusion boundary (Xia et al., 2008). The plots of the HAZ softening kinetics measured from laser welds in various grades of DP steel are presented in Figure 5.7, which show the change in hardness increases with DP steel strength (martensite volume fraction), and softening kinetics increases with increasing martensite carbon content and decreases with increasing alloying with carbide-forming elements. For example, the change in hardness is much greater for DP780 than either DP600 or DP450 (Figure 5.7(a)). The rate of martensite decomposition increased with increasing carbon content and when similar amounts of carbide-forming alloying additions were used. However, the steel with less alloying showed a faster rate of decomposition for its respective martensite carbon content (Figure 5.7(b)). Also, one should note the degree of softening increased with heat input, that is, diode laser welding resulted in higher softening. Figure 5.7(c) shows an example indicating the effect of chemistry on HAZ softening in DP980 steel. One can see that steel with rich composition (DPR) has higher resistance to softening compared with lean (DPL) and moderate (DPM) composition steels, which is attributed to the smaller degree of decomposition of martensite (Figure 5.6(c)) and finer cementite (Figure 5.6(f)) observed in the tempered region of the welds (Nayak et al., 2011). Therefore process parameters should be tailored to material chemistry and microstructure to make DP steel LWBs with minimum softening. 84 Welding and Joining of AHSS 5.6 Performance of laser-welded AHSS 5.6.1 Strength and durability Hardening in the fusion zone and supercritical HAZ increases the strength of the weld- ment, which in turn decreases the ductility when strained in a direction parallel to Figure 5.7 Comparison of the softening kinetics in dual-phase (DP) steels: the effect of grade (Xia et al., 2008) (a), the effects of DP steel chemistry and grade (Biro et al., 2010) (b), and the effect of chemistry (c) on the softening of DP980 steel welds (Nayak et al., 2011). C, carbon; Cr, chromium; DPL, lean com- position dual-phase steel; DPM, moderate composition dual-phase steel; DPR, rich composition dual- phase steel; Mo, molybdenum; Nd:YAG, neodymium:yttrium– aluminium–garnet. τ φ τ ν 85Laser welding of AHSS the weld line. Conversely, HAZ softening reduces the local strength when the load- ing direction is perpendicular to the weld line, which resulted in strain localization, leading to premature failure at the tempered region at low loads and elongations (Panda, Sreenivasan, Kuntz, & Zhou, 2008; Westerbaan et al., 2012; Xu et al., 2012). Figure 5.8(a) shows engineering stress–strain curves from tensile tests of the base metal and transverse to the laser weld in samples of DP980 steel (Sreenivasan etal., 2008). The yield strength and ultimate tensile strength (UTS) of the welded samples were lower than the base metal values with reduction in the overall specimen elongation. This was due to necking in the subcritical HAZ in all the welded specimens (Panda et al., 2008; Sreenivasan et al., 2008). The Nd:YAG laser welds had higher strength and ductility (elongation) compared with the diode laser welds because of a narrower tempered region and less severe HAZ softening associated with the Nd:YAG laser welding. Thus it is concluded that the transverse strength and ductility of laser-welded Figure 5.8 Comparison of (a) the tensile test plots (Sreenivasan et al., 2008) and (b) the S (Stress)–N (number of cycles) curves (Xu et al., 2012) of DP980 laser-welded blanks fabricated using different lasers. BM, base metal; DLW, diode laser welding; FLW, fibre laser welding; S, single linear weld; M, multiple linear welds; Nd:YAG, neodymium:yttrium–aluminium–garnet. 86 Welding and Joining of AHSS DP980 is dependent on the properties of the tempered HAZ. For example, high weld- ing speed achieved using fibre laser resulted in a narrower tempered zone (Xu et al., 2012), which in turn gave rise to a 96% joint efficiency, that is, the ratio of the UTS of the laser welds and the base metal, whereas diode laser welding resulted in a lower joint efficiency because of the wider and softer tempered HAZ. The LWBs prepared by fibre laser welding also lead to improved fatigue life when compared with diode laser welding (Figure 5.8(b)), even with multiple linear welds present in the gauge length of the fatigue test coupons (Xu et al., 2012). For example, the fatigue strength at 1 × 107 cycles (sometimes called the conditional fatigue limit) was about 100 MPa lower for diode laser welds than the base metal, whereas it was even lower (∼150 MPa) in the low cycle fatigue region at 2 × 103 cycles (Figure 5.8(b)). On the other hand, fibre laser welds had a fatigue life close to that of the base metal at stress amplitudes above 300 MPa. However, the fatigue strength became lower and more scattered at stress amplitudes below 300 MPa. This suggested that the narrower tempered zone in fibre laser welding did not affect the tensile properties of the weldment, but fatigue resistance is susceptible to HAZ softening, irrespective of the size of the tempered zones. The fatigue data for the multiple linear welds (Figure 5.8(b)) exhibited a larger scatter and lower fatigue strength, indicating that the probability of dynamic fatigue failure at lower stress amplitudes increased with an increasing number of tempered zones. It should be noted that the failure location in both tensile and fatigue testing of the DP980 steel was at the tempered region of the HAZ, irrespective of the laser weld- ing type (Sreenivasan et al., 2008; Westerbaan et al., 2012; Xu et al., 2012). 5.6.2 Formability The formability of AHSS is reduced significantly after welding, which makes forming LWBs a challenging task. The forming behaviour of an LWB can be predicted by understanding a few important points: (1) material property changes occur in the HAZ of the weld; (2) non-uniform deformation occurs because of differences in thickness, properties and/or surface characteristics; (3) the effects of the welded zone on the strain distribution, failure site and crack propagation; and (4) how the weld line moves during the forming process. Among these complexities, the welding process plays the major role. Factors arising in laser welding processes that influence formability can be classified into four categories, namely, the type of laser, welding parameters, prop- erties of the base materials, and changes in material properties of the weld and HAZ). This section discusses the effects of these factors on the formability of AHSS LWBs. Formability properties, such as hardness, tensile strength and fatigue strength depend on heterogeneity in the microstructure across the LWBs and is represented by the lim- ited dome height (LDH) obtained in formability tests. In general, formability can be related to the hardness and strength of a weld. For instance, Sreenivasan et al. (2008) observed a significant decrease in the LDH of welds due to HAZ softening in the subcritical HAZ; more severe HAZ softening led to larger reductions in the LDH. Furthermore, when the location of the failure in LDH samples was analysed, that fail- ure always occurred in the tempered HAZ. Figure 5.9 shows the relation between the LDH and softening in DP980 laser welds. Larger reductions in hardness led to lower 87Laser welding of AHSS formability of the welded blanks. The formability of the diode welds was less than that of the Nd:YAG welds because the tempered zone in the diode welds is wider than in the Nd:YAG welds (Figure 5.9). With an increase in the welding speed, the formability of the welded DP steel samples approached that of the base metal. These results indi- cate that when using higher power densities and higher speed keyhole welding mode, there is narrower, less softened, tempered HAZ, which leads to better formability. Therefore, for DP steel, it is better to weld with an Nd:YAG laser, and probably a fibre laser, in keyhole mode and at the maximum achievable welding speed. No significant difference in the formability of the DP980 steel was observed with respect to welding orientation relative to the rolling direction or how the weld was positioned relative to the punch (on the face or root side of the weld), as HAZ soften- ing dominated the formability behaviour (Sreenivasan et al., 2008). Another study of DP800 showed that the formability of equal-thickness LWBs was 20% lower than the base metal because of microstructural changes and an increase in microhardness of the fusion zone and HAZ (Wu, Gong, Chen, & Xu, 2008). It also was noted that when samples were stretched parallel to the weld, cracks nucleated and propagated normal to the weld line (Saunders & Wagoner, 1996), whereas when samples were stretched per- pendicular to the weld, failure occurred in the weaker materials (Panda, Li, Hernandez, Zhou, & Goodwin, 2010; Sreenivasan et al., 2008). The forming behaviour changes when different material combinations and weld line positions are used in LWB fabrication. Figure 5.10 shows the change in the LDH with weld line positions for DP600 (1.2 mm)–HSLA (1.14 mm) and DP980 (1.2 mm)– HSLA (1.14 mm) LWBs. The welded samples always had a lower LDH compared with the parent metals, which is attributed to the presence of the tempered HAZ and the difference in material properties within the blank, which induced nonuniform Figure 5.9 Formability of the laser-welded blanks versus the reduction in weld metal hardness in DP980 steel (Sreenivasan et al., 2008). LDH, limited dome height; Nd:YAG, neodymium:yttrium–aluminium–garnet. 88 Welding and Joining of AHSS deformation. Interestingly, with larger differences in parent material properties, lower formability was observed because of higher nonuniformity in the deformation during stretch forming (Panda et al., 2010). For instance, the LDH of DP980–HSLA was lower than that of the DP600–HSLA combination. The lower LDH values were mea- sured for DP600–HSLA LWBs when welds were positioned at −15, 0 and +15 mm from the punch pole, whereas the LDH increased (27–33%) when the weld was placed −30 mm away from the punch pole. Similarly, for DP980 (1.2 mm)–HSLA (1.14 mm) LWBs, the LDH was lower when the weld line was positioned +15 mm from the punch pole, and it increased by (∼150%) when the weld was placed −30 mm away from the punch pole. This suggested that the position of the weld line has a strong influence on the forming behaviour of dissimilar LWBs, and the formability can be increased by keeping the weld line away from the punch. However, the level of increase in form- ability with respect to weld line position (either toward the positive side or negativeside) depends on the material combination. It was also noted that the load progression curve for an LWB is between that of the parent metals, and the slope of the curve depends on the amount of each parent metal in the LWB. Interestingly, the percentage of elongation from a uniaxial tensile test does not reflect the same trend as that of LDH for LWBs (Panda et al., 2010). Uniaxial tensile tests could not predict the actual press performance of LWBs. The strain distribution profile across the LWBs generally cor- relates well with the LDH and the failure location (Panda et al., 2010). It is interesting to note that the failure location in the LDH tests of the dissimilar LWBs were mostly in the HSLA base metal because its hardness was even lower than that of the tempered HAZ of the DP600 and DP980. Weld line geometry also plays an important role in the forming behaviour of LWBs. A recent study by Li et al. (2013) of the effects of weld line geometry and posi- tion on DP (1.2-mm-thick) steel and HSLA (1.14-mm-thick) steel LWBs reported that the hardness across the welds is correlated to predict the failure location and the Figure 5.10 Comparison of formability (limited dome height) of laser-welded blanks with different weld line positions (Panda et al., 2010). DP, dual phase; HSLA, high strength low alloy; TWB, tailor welded blank. 89Laser welding of AHSS LDH values. The formability is dependent on the weld line position and increases when the weld is located farther from the blank centre because of the develop- ment of more uniform strain during LDH tests (Li et al., 2013; Panda et al., 2010). The curvilinear welds form an inconsistent extension of the HAZ on either side of the weld line; more severe HAZ softening, the difference in the base metal hardness and minimum hardness at the HAZ, is observed at the inner region of the curvilin- ear welded blanks (Li et al., 2013). The effect of weld line geometry on formability is insignificant for DP980 and HSLA steels because the effect of HAZ softening dominated in DP980 steel and laser welding does not alter the HSLA steel. A strong correlation between HAZ softening and failure location in DP980 steel is observed; fracture consistently occurs in the soft zone located 3–5 mm away from the weld centre line (Figure 5.11). In general, predicting the failure location in cur- vilinear welded DP steels is easier compared with HSLA because fracture always occurred in the soft zone at the inner region of the curve (Li et al., 2013). Weld line geometry typically has a stronger influence on the formability of lower-grade DP steel. For instance, the strain distribution profiles indicate that formability of only DP600 LWBs is affected significantly by weld line geometry, whereas both HSLA and DP980 showed comparable strain profiles in the linear and curvilinear welds (Li et al., 2013). Figure 5.11 Failure locations in formed DP980 laser-welded blanks with different weld locations of linear welds: 0 mm (a), 15 mm (b) and 30 mm from centre (c); and curvilinear welds: 0 mm (d), 15 mm (e) and 30 mm from centre (f) (Li et al., 2013). 90 Welding and Joining of AHSS 5.7 Future trends Although a considerable amount of work on the laser welding of AHSS has been reported so far, there is a lack of study on the entire AHSS family (namely TWIP, CP and martensitic steels) in relation to the effect of laser welding on microstructure, ten- sile properties, fatigue life and formability. Furthermore, with the increased inclusion of fully martensitic press-hardened steels in applications such as B pillars and rails, open literature on the impact performance of these joints is critical. However, these applications have further challenges because the part welds will be hot formed; there- fore the welds will undergo further transformations. 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Zhao, H., White, D. R., & DebRoy, T. (1999). Current issues and problems in laser welding of automotive aluminium alloys. International Materials Reviews, 44(6), 238–266. http://www.worldautosteel.org Welding and Joining of Advanced High-Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00006-0 Copyright © 2015 Elsevier Ltd. All rights reserved. High-power beam welding of advanced high-strength steels (AHSS) L. Cretteur ArcelorMittal R & D, Automotive Application Research Center, Montataire, France 6 6.1 Introduction The automotive industry is facing the complex challenge of improving passen- ger safety while reducing fuel consumption and maintaining acceptable cost and comfort for the user. Many different solutions to address these issues are being developed. Among them, the use of high-strength steel (HSS) allows mass to be reduced (and therefore the fuel consumption to be reduced) by decreasing the sheet thickness applied while keeping the same mechanical behavior. The assem- bly of different parts into a global car body, however, becomes one key issue. In mild steel automotive structures, the weld is usually stronger than the base metal and is not considered to be a factor limiting part integrity. In HSS structures the weld may become the weak point of the assembly. Increasing the alloying content of HSS leads to the formation of very hard metallurgical microstructures in the welds, which may limit weld ductility and toughness. As the base metal becomes stronger, the welds can carry higher loads. Therefore validation of the car body design must integrate specific weld properties, not only base metal proper- ties. Furthermore, weld behavior must be improved to reach the target properties of the welded component. Laser welding applications in the automotive industry has increased tremen- dously since the early 1990s. During the 1990s, laser welding was mainly used to produce laser-welded blanks (LWBs), which were made using carbon dioxide (CO2) lasers. In spite of their high cost and limited flexibility, CO2 lasers were par- ticularly adapted to the production of LWBs for the automotive industry. Indeed, the large volumes of parts requested by the automotive industry could make the laser welding cost-efficient because of its high welding speed and quality, result- ing in a productive process with low scrap rates. Conversely, laser welding on the complete body in white (BIW) was rare during this decade, mainly because of the low flexibility of CO2 lasers in three-dimensional applications. Once high- power lasers with increased flexibility and optic fibers came to the market, new automotive applications became possible. Laser welding and brazing then became major processes, competing with the traditional resistance spot welding process used by many car makers. Indeed, laser welding has unique qualities that make it 94 Welding and Joining of AHSS particularly adapted to the requirements of the automotive industry. Some of these characteristics include the following: • High welding speed: a high production rate is a requirement in the automotive industry. Lasers may reach welding speeds of several meters per minute, allowing a large number of welds in a short time. • High quality of the welded components: because of the highly concentrated energy of the laser beam, very limited distortions of the final parts occur. The welded components do not need to be reworked after welding and are “ready to use.” • Versatility in terms of weld geometry and accessibility: laser welding needs access to only a single side, and many different weld shapes can be made. • Adaptation to mass production: laser welding is highly repeatable and, with proper auto- mation, may be easily automated. This is in line with the production needs of automotive manufacturing. During the same period of time, automotive designs also included massive use of advanced high-strength steel (AHSS). Various AHSS families were introduced and used successfully to meet passive safety and lightweight design requirements. While until the 1990s car body design was mainly based on low-carbon and high-strength, low-alloy (HSLA) grades, AHSSs typically have increased carbon and alloy content, which needs to be accounted forwhen designing weldments and welding procedures. Currently, AHSS with tensile strengths in the range of 600–1500 MPa, with various chemistries and microstructures, are commonly used. In terms of weldability, how- ever, different issues remain. • The chemical composition of automotive AHSS is characterized by increased alloying com- pared with the traditional deep drawing or HSLA grades. In particular, carbon and man- ganese are frequently added to increase the strength of the base metal and promote the formation of strengthening phases. Considering the high production rates imposed by the automotive industry, and particularly the high welding speed of laser welding, these chem- istries have a tendency to form hard welds with martensitic and bainitic microstructures because of their highly hardenable chemistries. • Many AHSS have multiphase microstructures and have a high martensite content (nearly 100% for the highest steel grades). Martensite within these structures tempers in the tem- pered area of the heat-affected zone (HAZ). This results in local areas of the microstructure that are softer than the surrounding base material. • The influence of weldments comprising various areas containing hard and soft microstruc- tures on the final in-use properties of the joint needs to be clarified. The aim of this chapter is to give an overview of the different issues occurring during laser welding of AHSS in BIW applications. The influence of the laser weld- ing process on the local metallurgy in the fusion zone and in the HAZ is presented. Finally, because welds are designed to transfer loads within a structure, the mechan- ical properties of AHSS laser welds are highlighted. Most of the discussion on weld strength is concerned with single welds; however, some results of how welds function globally within a structure also are presented. 95High-power beam welding of AHSS 6.2 Back to basics: fundamentals of high-power beam welding 6.2.1 Principles of the keyhole welding process The aim of this section is not to detail the physics of the laser welding process but to recall basics to facilitate the understanding of the following sections. The interested reader can find more details about the fundamentals of laser welding in the literature (AWS welding handbook, 2007; Mazumder, 1993a,b). 6.2.1.1 Keyhole formation High-power beam welding is mainly applied by two different energy sources: high- power lasers and electron beams. In both cases the interaction between the beam and the steel sheet is relatively similar. The energy from the beam is concentrated on a small surface (the so-called spot) to obtain a very high energy density. The key factor is to obtain, by focusing the beam, an energy density in excess of 106 W/cm2. This is the equivalent of a 2-kW beam focused to a 0.5-mm diameter spot, which may easily be achieved by various high-power laser systems. When energy densities above 106 W/cm2 are achieved, the metal at the impingement point is heated well above its melting temperature and vaporizes to form a capillary filled with metallic vapors (so-called deep-penetration mode or keyhole welding mode). The keyhole allows the beam to deeply penetrate inside the material, resulting in a deep and narrow weld (typically 1–2 mm wide). For comparison, in gas tungsten arc welding or gas–metal arc welding the energy densities at the workpiece are on the order of 104 W/cm2. With this lower energy density, the heat transferred from the source to the sheet is capable of melting only the sheet surface. Heat is transferred farther into the material by conduction. As a result, the weld tends to be relatively wide (centimeter scale) and have a lower penetration. A deep-penetration welding mode may be applied by a variety of laser sources delivering both continuous and pulsed beams. Most laser applications in the automotive industry today use continuous-wave lasers. The laser source may be a CO2 type or based on a solid-state active medium such as neodym- ium:yttrium–aluminum–garnet (Nd:YAG) crystals, fiber, or diodes. While the laser source significantly influences production issues by determining the wave- length (affecting the choice of optics, shielding gases, potential use of optic fiber, and health and safety issues), the basic thermal mechanisms (formation of the molten pool) and consecutive metallurgical transformations are not sig- nificantly affected by the type of laser as long as the keyhole welding mode is used. The metallurgical phenomena described hereafter concern welding with all laser sources and, by extension, electron beam welding because the electron beam welding process is also characterized by a transfer of the beam energy to the metal through a keyhole. 96 Welding and Joining of AHSS 6.2.1.2 Welding in keyhole mode Welding in keyhole mode occurs by translating the keyhole, which results from the laser–metal interaction, at a high speed along the metal surface. As a result, a fusion line is obtained. Depending on the design needs, both linear and curved weld lines can be easily obtained thanks to the flexibility of modern laser cells. The solid metal in front of the beam is melted by the beam, flows around the keyhole wall, and solid- ifies at the rear of the keyhole (Figure 6.1). The final fusion zone is a mixture of both materials being welded. Once the laser beam source has been selected (CO2, Nd:YAG, fiber, diode), the following main factors influence the weld quality: • Heat input can be expressed as the ratio between the beam power and the welding speed. Heat input strongly influences weld depth and width. In most automotive laser welding applications the maximum power capacity of the laser (typically 3–8 kW) is used to weld, and the speed is adjusted to obtain full penetration. Depending on the sheet thickness and available power, typical welding speed ranges from 1 to 10 m/min. In fully penetrated welds the keyhole is open at the bottom of the weld. Because of travel speed, it was also observed that the keyhole is not vertical but is instead elongated and inclined (Fabbro, 2002; Fabbro, Slimani, Coste, & Briand, 2005; Pan & Richardson, 2011). • Spot size mainly influences the weld width. The spot size depends on both intrinsic beam properties and the choice of optics used in the process and represents the sharpness of the welding tool. The highly concentrated energy from a small spot increases the energy density, increasing the ability to create the keyhole and to penetrate deeper into the sheet. A small spot (diameter <0.4 mm), however, also represents a very sharp and sensitive tool, which may be destabilized by misalignments or gaps between the sheets to be welded. As a result, most automotive applications use spots diameters ranging from 0.4 to 0.7 mm (Brockmann, 2010; Kielwasser, 2009; Larsson, 2007). • Joint geometry. Because laser welding is a contactless process, it is a very versatile tool that may be applied to various joint configurations. The automotive industry typically welds in the butt, lap, and overlap joint configurations; however, other joint designs may also be used. Figure 6.1 Principle of fluid flow in high-power beam welding. 97High-power beam welding of AHSS 6.2.1.3 Influence of a metal’s physical properties on weldability The formation of the weld is the result of the interaction of the beam with the metal; therefore it is clear that the physical properties of the base metal significantly influence the laser welding process. Keyhole formation results from the local melting and vapor- ization of the metal caused by a highly concentrated energy. It is therefore obvious that the melting and vaporization temperatures of the workpiece are very important properties during laser welding. The reflectivity of the metal dictates the amount of energy that is reflected away from the material surface during laser impingement. This affects the amount of remainingenergy that is absorbed by the workpiece. It must be noted that reflectivity is a function of the beam wavelength and material temperatures (reflectivity decreases with temperature). Finally, heat conductivity determines how quickly heat flows from the weld. More heat is needed to weld materials with high thermal conductivity to compensate for the heat lost to the surrounding material. Considering the current range of AHSS (complex-phase, dual-phase, transformation- induced plasticity, and press-hardened steels), the physical properties do not vary significantly from one product to the other (Table 6.1). The slight differences in physi- cal properties of AHSS products do not significantly influence keyhole formation and the process efficiency. The variations of physical properties influence the process only when different classes of materials are compared (e.g., comparing AHSS with stainless steel). 6.2.2 Thermal cycle in laser welding The keyhole deep-penetration welding process is characterized by a low heat input and a high welding speed. As a result, the weld cools very quickly. Measuring the cooling rate of laser welds is relatively complex because the weld and its corresponding HAZ are very narrow. However, the use of thin thermocouples allows the cooling rate to be evaluated at different positions in the HAZ. An example of an experimental measurement of cooling rate is given in Figure 6.2. Thermocouples were positioned on the surface of the sheet at different distances from the sheet edges before welding in a butt joint configuration. The sheets used were 1.5-mm thick, and the welding was done using a 4-kW Nd:YAG laser at 5 m/min. Table 6.1 Typical properties of various materials DP600 DP980 CP800 Aluminum alloy (6061) Stainless steel (austenitic) Thermal conductivity (W/m °K) 37 36 42 160 15–17 Melting temperature (°C) 1483 1473 1454 585 1500 Thermal conductivity and melting temperature data are from internal ArcelorMittal projects. 98 Welding and Joining of AHSS Using this experimental setup, the HAZ was exposed to very rapid heating followed by rapid cooling, without a hold time at a high temperature. In this case the cooling rate (Δ700–300) was approximately 250 °C/s. The cooling rate in any case depends on the specific welding parameters, but this example shows the order of magnitude of typical cooling rates in automotive laser welding applications. It was also noted that similar cooling rates were observed at different locations away from the fusion line. This means that although various positions in the HAZ differ in terms of the maximum temperature reached during welding, cooling rate and hold time did not change as a function of distance from the weld. From a metallurgical point of view, the laser welding process can be compared to ultrafast heating instantaneously fol- lowed by a rapid quench. The metallurgical modifications that are induced by the laser welding process are driven mainly by the maximum temperature reached at each point within a very limited time. Because of this, diffusion-based metallurgical phenomena rarely occur or do so only at very short distances. 6.2.3 Material flow in the weld As presented in Figure 6.1, a laser weld line is obtained by moving the keyhole across the sheet surface. The metal is melted in front of the laser beam and flows around the keyhole. A turbulent weld pool collects behind the keyhole, leading to a mixing of both constitutive materials A and B in the weld before solidification occurs. Because of the fast cooling rate and corresponding fast solidification, the weld zone is not homogeneously mixed in spite of the turbulent pool. This is observed very clearly on overlap-welded joints. Figure 6.3 illustrates overlap laser welds made of mild steel (1.5 mm) and DP1180. It is clear from the micrograph that the microstructures of the weld metal in the top and bottom sheets are not identical. The difference in these microstructures is due to local differences in chemical composition. Indeed, during Figure 6.2 Thermal gradient during laser welding. ArcelorMittal internal report. 99High-power beam welding of AHSS keyhole welding, the base metal melted in front of the keyhole tends to flow mainly along a horizontal plane toward the rear of the weld, where it solidifies, allowing only limited time for mixing. In butt welds, the mixture of both materials A and B being welded is much better; however, even butt welds do not have homogenous weld zones. The weld illustrated in Figure 6.4 is made of two different steel grades with significantly different chem- ical compositions. A TRIP780 grade (1.5-mm thick) with a high manganese content (1.6%) was welded to a deep drawing mild steel (1.8-mm thick) containing only 0.1% manganese. Welding was performed with a 4-kW Nd:YAG laser at a welding speed of 3.5 m/min. When the weld was etched using nital, the fusion zone appeared to be relatively homogeneous. However, the use of other etchants (picric acid solution; Figure 6.4b) reveals heterogeneities. Further chemical analysis then was done using a microprobe on a scanning electron microscope. From the microprobe analysis it is clear that the manganese content in the weld is not homogeneous. A higher concentration of manganese is observed on the TRIP780 side of the fusion zone. Although segregation was observed, the influence of mixing was also observed as a gradient of composition across the weld. The lack of mixing is due to the rapid cooling during laser welding. In spite of a turbulent flow within the weld pool, the fusion zone solidified before homogeneous mixing occurred. The areas with various compositions illustrate the fluid flow occurring in the weld pool. Figure 6.3 Segregation in overlap welds of mild steel (top) with DP1180 (bottom). ArcelorMittal internal report. 100 Welding and Joining of AHSS The average weld composition can be considered as the average composition of both constitutive materials, but this assumption is not true locally. Very strong gradi- ents can be observed at a microscopic scale. Local chemical composition represents a mixture of both constitutive materials in various proportions. Similar phenomena were reported by Mujica, Webera, Pinto, Thomy, and Vollersten (2010) on laser welds made with iron–manganese alloys with high manganese content. The lack of homogeneity of the solidified laser weld pool is not a large problem. However, it explains why microhardness measurements across welds may exhibit some scatter, as areas with various compositions may be indented. Also, guidelines or conclusions drawn about the average composition of the weld must be considered with care because the local composition in the weld may differ from the nominal average composition. 6.3 Metallurgical phenomena in laser welding of AHSS From a microstructural point of view, a laser weld can be divided into two different areas: the fusion zone, where the metal melted during the welding process undergoes solidification, and the HAZ, where peak temperature during welding was less than the melting temperature but still high enough for the material to undergo solid-state metal- lurgical transformations. Both areas, as shown in Chapter 2.2, are characterized by the maximum temperature reached locally, followed by rapid cooling. It should be noted that the cooling rate in laser welding is so rapid that the as-welded microstructures cannot be predicted by an equilibrium phase diagram. Typical hardness profiles across the weld are depicted in Figure 6.5. The weld cen- ter systematically has a very high hardness compared with the unaffected base mate- rial. The HAZ, adjacent to the fusion zone, can either harden or soften. TRIP780 and lower-strength dual-phase (DP) steels such as DP450 exhibit only hardening. Some softening can occur in higher-strength DP steels with an ultimate tensile strength Figure 6.4 Cross section of laser-weldedTRIP780 (right) and DC04 (left) with different etching/analysis: nital etching (a), picric acid solution (b), and microprobe analysis of manganese concentration (c). ArcelorMittal internal report. 101High-power beam welding of AHSS (UTS) higher than 600 MPa; however, this is most prevalent in DP980 and stronger DP steels. Finally, as would be expected, the base metal hardness may be correlated to its strength. 6.3.1 Weld microstructure The microstructure of the fusion zone results from the fast solidification and cooling of the molten pool. From a metallurgical point of view, the cooling of the weld can be considered as a fast quench. As a result, considering the chemical composition of most AHSSs (with carbon varying from 0.06% to 0.22% and manganese varying from 1% to 2.5%), the fusion zone has a predominantly martensitic structure, as illustrated in Figure 6.6. Depending on the chemical composition of the steel, some bainite may also be found in the fusion zone. Because the fusion zone is mainly martensitic, its hardness can be easily predicted. The hardness of a martensitic structure is a function of its carbon content (Grange, Hribal, & Porter, 1977). In the current range of AHSS chemical contents, the weld hardness linearly depends on the carbon content of the base material (Figure 6.7). Many different carbon equivalent (Ceq) approaches have been developed to evaluate the weldability of various steel grades (ASM, 1997, chapter 13). The main objectives of 0 50 100 150 200 250 300 350 400 450 500 550 600 –3.00 –2.00 –1.00 0.00 1.00 2.00 3.00 Position (mm) H ar dn es s (H V0 .5 ) DP980 TRIP800 DP780 DP590 DP450 Base metal HAZWeldHAZ Base metal Figure 6.5 Hardness profiles of laser welds on various advanced high-strength steels. HAZ, heat-affected zone. ArcelorMittal internal report. 102 Welding and Joining of AHSS Ceq approaches are to evaluate the risk of forming martensite and related cold cracking issues in arc welds. It should be noted that a Ceq formula defined for arc welding pro- cesses must be carefully applied to laser welds because the welding process dynamics are fundamentally different. The cooling rate of laser welds is much faster, and the residual stresses and distortions occurring around the weld are very low because of limited heat loss around the weld during the process. Finally, laser welding typically Figure 6.6 Martensitic microstructure in a DP980 laser weld. ArcelorMittal internal report. Figure 6.7 Influence of carbon content on the average hardness of laser butt welds (2-mm sheets). ArcelorMittal internal study. 103High-power beam welding of AHSS is done without adding any filler wire. These three factors are fundamentally different from gas metal arc welding. Because these factors differ from arc welding, the resulting weld metallurgy in laser welding is also completely different from that of arc welding. In laser welds the Ito–Bessyo definition of Ceq (Eqn (6.1)) can be applied to predict the final microstructure. Based on experiments, CeqIto >0.2 systematically leads to a fully martensitic microstructure. CeqIto = C + Si/30 + (Mn + Cu + Cr) /20 + Ni/60 + Mo/15 V/10 + 5B (6.1) Considering the typical chemical composition of AHSSs, particularly with regard to carbon and manganese, most AHSSs exhibit a CeqIto >0.2; therefore, most laser welds are expected to have a martensitic microstructure. However, even though laser- welded AHSSs often have a martensitic microstructure because of the rapid cooling, the small distortions and low residual stresses that occur around a laser weld mean that there is also not a high risk of cracking upon cooling. 6.3.2 HAZ softening As described in Chapter 2.2, the HAZ is characterized by a temperature peak followed by fast cooling, where the peak temperature is high enough to induce metallurgical trans- formations but low enough that melting does not occur. Even if the duration at the peak temperature is short, significant metallurgical modifications may occur. Many AHSS fam- ilies have partially or fully martensitic microstructures. The martensite volume fraction of the base metal could be relatively low, as in DP600, but may also represent a unique microstructure, as in press-hardened steels, for which the final microstructure is obtained by hot stamping and die quenching. Martensite is obtained when the face-centred cubic (FCC) crystal structure of austenite (stable at high temperatures) does not have sufficient time to rearrange into the body-centred cubic (BCC) structure of ferrite (stable at low temperatures) during cooling. When this occurs, the FCC lattice shears, forming a body centered tetragonal (BCT) structure, entrapping the carbon atoms that were dissolved in the austenite structure. This microstructure is metastable. Upon reheating, carbon tends to migrate out of the martensite structure, forming a ferritic matrix and carbides, which reduce the distortions in the BCT matrix and relieve internal stressors in a process known as tempering. This transformation can be measured by a local reduction in hardness. This process is thermally activated (Badeshia, 2006). Martensite tempering can be observed when holding for a long time at a temperature of 150–200 °C, but it occurs particularly quickly at temperatures higher than 500 °C. Figure 6.8 illustrates the hardness profile across a laser butt weld in DP1180. The hardness profile can be decomposed into the following areas: • The fusion zone, typically exhibiting a martensitic microstructure, is the result of the fast solidification and cooling of the molten pool, as mentioned in Chapter 3.1. • The HAZ, which can be divided into two parts: – The supercritical HAZ, which is closest to the fusion zone. Like the fusion zone, this area of the HAZ is also martensitic. During welding, the peak temperature experienced in this area exceeds the Ac3 temperature and then cools rapidly. 104 Welding and Joining of AHSS – The subcritical HAZ, which is adjacent to the base material. In this area, the peak tem- peratures during welding remain below the Ac1 temperature. Martensite initially present in the base metal is partially or completely tempered. Because of the short duration at a high temperature, softening the material to levels achievable using furnace heat treatment is impossible. In the HAZ of a laser weld (Figure 6.8), the resulting microstructure is then a mix of the initial martensite, tempered martensite, and ferrite. Depending on the distance to the weld and the corresponding peak temperature reached locally, the propor- tion of the different phases varies. This results in a continuous variation in hardness from the minimal hardness (to the location of the Ac1 isotherm, where the strongest tempering occurs) to the base metal hardness. • The base metal is not sufficiently heated to undergo any transformations. The typical micro- structure of a DP1180 steel grade is shown in Figure 6.8. The base metal microstructure is mainly martensitic, with some islands of ferrite. In AHSS containing martensite, the HAZ softening phenomena can be observed for all welding processes and all welding configurations because this is a metallurgical phe- nomenon that is not related to the welding process. However, the width of the HAZ depends on the welding process (and the related time/temperature of each point of the HAZ). Figure 6.9 depicts the influence of the welding process conditions for a given material. Thin sheets (1 mm) of electrogalvanized DP1180 have been welded in a butt joint configuration under various welding conditions. A narrow weld was obtained using a 6-kW CO2 laser at a welding speed of 8 m/min, whereas the wide weld was made at 3 m/min. It can be clearly seen that the profiles are relatively similar, showing severe Figure 6.8 Hardness profile and typical microstructure of a DP1180 laser weld (1-mm thick- ness) using a 4-kW neodymium:yttrium–aluminum–garnetlaser at 3.5 m/min. HAZ, heat- affected zone. ArcelorMittal internal report. 105High-power beam welding of AHSS tempering of the HAZ. At low speed (high heat input), the HAZ is clearly wider; more heat is transferred to the work piece, so heat is able to be conducted farther from the weld zone. This results in a wider area in which the material was exposed to tempera- tures sufficient to induce tempering (>300 °C). Finally, the minimum hardness measured in the HAZ also depends on the heat input. At higher heat input, the time spent above the tempering temperature by each point of the HAZ is longer than in the weld made at low heat input, which led to more pronounced tempering. A similar tempering phenomenon in fully martensitic press-hardened steel welded in overlap configuration was described by Gu et al. (2011). From a macroscopic point of view, HAZ softening tends to decrease the local mechan- ical properties of the weldment. The affected local mechanical properties may influence the global mechanical behavior of the complete part. The consequences of HAZ soft- ening depend both on the width of the softened area and on the load case applied to the weld. Transverse tensile load has been applied to the wide and narrow welds mentioned above. In the case of the narrow weld, the strength reduction due to the presence of the softened HAZ was only 6% of the initial sheet strength and remained above the minimal strength required for a DP1180 grade (Figure 6.10). Even in the case of a large weld with more significant softening, the strength reduction was only 13% compared with the base metal. Because of the narrow dimensions of laser welds, the properties of the neighbor- ing material restrict the thinning of the softened material, which reduces the detrimental effects of HAZ softening. Figure 6.9 Heat-affected zone softening in a DP1180 laser weld under various welding conditions. ArcelorMittal internal report. 106 Welding and Joining of AHSS Vickers hardness usually is considered to be linearly correlated to the UTS of a material (ISO 18265). This simple rule cannot, however, be used in the case of HAZ softening. The above-mentioned results clearly show that, in spite of the decrease in hardness corresponding to 25% of the base metal hardness for a narrow weld (and 35% for large weld), the ultimate strength of the weld was only reduced by 6% (and 13%, respectively). The linear correlation between hardness and UTS is to be used only in the case of a homogeneous material, not for materials exhibiting small-scale changes in mechanical properties, since the properties of the surrounding areas restrict the deformation of the soft zone The same trend was observed by Xia et al. (2007), Panda et al. (2009), and Panda, Sreenivasan, Kuntz, and Zhou (2008): When the weld and the width of the corresponding HAZ are further increased in very large welds made by direct diode welding on DP980, the weld strength in the transverse direction tends to decrease. It may therefore be concluded that both HAZ softening and the width of the softened area must be accounted for when estimating the mechanical properties of welding exhibiting HAZ softening. 6.4 Laser-welded blanks (LWBs): issues related to the use of AHSS 6.4.1 Principle and typical applications of LWBs LWBs, also called tailor-welded blanks, are composite blanks that are made of two or more sheets that are laser welded before stamping. The sheets making up an LWB Figure 6.10 Influence of the width of the heat-affected zone (HAZ) on tensile properties. ArcelorMittal internal report. 107High-power beam welding of AHSS can be of different grades or thicknesses or even the same material, depending on the application. LWBs allow blanks to be designed so that the final part uses the most appropriate material at the right place of the component (ULSAB, 1998) or, in the case of LWBs made of the same material, decreased material scrap. By combining different steel grades and thicknesses in a part, it is possible to simultaneously opti- mize the weight and the properties of the final component. Figure 6.11 illustrates the crash behavior of a front rail made of two different materials. The front section of the part is made of a 600-MPa steel grade with good ductility, while the rear section has a 1500-MPa strength. During a crash, the front section deforms and absorbs energy, while the rear section remains stable and ensures the safety of the car’s occupants. The following are typical applications of tailored blanks (FSV, 2011; ULSAB, 1998): • Front and rear rails, which optimize the management of crash energy by absorbing energy at the vehicle’s extremities • B-pillars, where a softer material is used in the bottom area to obtain localized energy absorption and deformation in the seat area, while the upper area remains stable to protect the passenger in the case of a side impact • Door inners, where the door panel is reinforced at the hinges to support the weight of the door, while a thin gauge is used for the majority of the part to minimize its weight in the section that does not carry a load. 6.4.2 Issues in AHSS applications The process of producing LWBs can be briefly divided into two steps. 1. Laser butt welding of the sub-blanks in flat conditions. The key issue in this phase is ensur- ing a good joint fit-up with a very narrow gap. 2. Stamping the welded blank as a single component. Stamping is characterized by significant deformation of the sheets. The key issue for the weld is being able to support the same level of deformation as the surrounding material. Figure 6.11 Principle of crash management through the application of a laser-welded blank. ArcelorMittal internal study. 108 Welding and Joining of AHSS The main concern regarding the introduction of AHSS in LWBs is the formability of the weld and the surrounding HAZ. As described in Section 6.3, because of the combination of the chemical composition and the cooling speed of the weld, welding AHSS usually leads to a highly martensitic microstructure. It is well known that the formability of martensite is very low. However, the formability of the weld does not solely depend on the formability of martensite. An LWB can be briefly described as the combination of three elements: each of the adjacent base materials and the weld joining them. Each element has its own mechanical properties. The formability of an LWB cannot be defined as the formability of each independent element (Gaied, Pinard, Schmit, & Roelandt, 2007). This is particularly true for a weld because it rep- resents only a narrow portion of the component. The formability of the weld is highly influenced by the surrounding materials. The following results (Figure 6.12) illustrate the capacity of laser welds made of different materials to be deformed plastically. Tensile tests have been carried out using a standard geometry, with the weld located in the middle of the sample, orientated parallel to the tensile direction. In spite of its high hardness and its martensitic microstructure (Figure 6.6), the welded coupon can have a uni- form elongation of up to 12%, which is much higher than would be expected of martensite. Because of the limited width of a laser weld, its behavior is highly influenced by the surrounding materials. As a result, significant formability of the weld is obtained in spite of its high hardness. Its high formability allows the LWB to be successfully formed (Gaied, Cretteur, & Schmit, 2013). Figure 6.12 Weld elongation in longitudinal tensile tests. ArcelorMittal internal report. 109High-power beam welding of AHSS 6.5 Body-in-white joining applications 6.5.1 Why use lasers for body-in-white joining? The development of solid-state laser sources in the past decade has offered new weld- ing solutions for BIW assembly. In particularly improved electrical efficiency (cost reductions) and the capability to combineoptic fibers and long working distances (tool flexibility) offers new possibilities (Brockmann, 2010; Kessler, 2010). As a result, between 2000 and 2010, laser welding has been widely introduced to the assembly line, replacing the resistance spot welding process for various applications (Radscheit & Löffler, 2004). The reasons to use lasers can be summarized in three categories: • Cost reduction: Compared with the standard spot welding process, laser welding allows much higher productivity. This is because of the laser’s ability to move almost instantly between welds by directing the weld to the workpiece using rapid tilting mirrors, without the need for moving heavy mechanical parts. As a result, the production time is mainly used for welding and is not taken up by robot movement. In spite of the higher investment required, the improved productiv- ity leads to a global cost reduction (Forrest, Reed, & Kizymsa, 2007; Kielwasser, 2009). • Flexibility in design: Laser welding requires joint accessibility from only one side, whereas resistance spot welding usually requires both sides to be accessible. One-sided access allows sheets to be joined to tubes or profiles, as well as joining parts with tight spaces that will not fit a spot welding gun. Because of the narrow width of the laser line, laser welding also allows flange widths to be reduced, allowing, for example, for wider windows with better visibility for the driver (Larsson, 2007, 2009, pp. 6–11). • Weldment performance: One of the main advantages of the laser welding process is the flexibility in the design of the joints. Long welds can be made to improve the stiffness of the assembly. Various weld geometries (e.g., C-shape, S-shape) can be made to improve the static or dynamic behavior. This topic is detailed in Section 5.2. Laser welding is being used industrially at two stages of the BIW assembly: • For sub-assembly of components: The main reason to use lasers is to increase the produc- tivity. Short stitches are done to replace resistance spot welds. Welds can either be linear or have more complex shapes to optimize their behavior (Figure 6.13). Figure 6.13 C-shaped welds on a mass-produced part. ArcelorMittal internal study. 110 Welding and Joining of AHSS • To weld the entire BIW during vehicle assembly, lasers are used to make preferentially long welds on large panels. The main advantage of using long welds is to increase the stiffness of the BIW. Figure 6.14 shows an industrial application at Volvo Car Corporation, where the roof is laser welded to the car body. 6.5.2 Properties of AHSS laser welds and laser-welded components While the formability of the laser weld is a key issue for LWB applications, static and dynamic strength are key properties when laser welding is used for BIW assembly. 6.5.2.1 Static strength The main advantage of laser welding over resistance spot welding is the ability to adjust the weld length to tailor the strength of the joint to the mechanical require- ments of the welded component. Although in spot welding there is some flexibility to change weld size, the diameter is limited by the diameter of the welding elec- trodes (it is difficult to make a spot weld much larger than the electrode diameter without risking expulsion). However, it is easy to program a longer laser stitch to increase the weld strength. As a base approximation, one may assume that, when loaded in tensile shear, the weld strength is proportional to the weld length. A refined analysis shows that this linear trend is valid as long as the failure mode remains the same (Figure 6.15). Short welds are more prone to interfacial failure, whereas long welds lead to failure of the HAZ or the base metal. Similar behavior can be observed in resistance spot welds when loaded similarly; small-diameter welds tend to fail at the interface, whereas larger welds exhibit button pull-out (van der Aa, 2013). Figure 6.14 Laser welding on an XC90 car body. Courtesy of Volvo Car Corporation, personal communication from Mr Larsson. 111High-power beam welding of AHSS The failure mode can be understood as the result of a failure along the weakest load-bearing area of the assembly. The weakest area can be either: • Interfacially through the weld, at the faying surface. This failure mode depends on the fusion zone properties (martensite under shear loading) and weld width. • Near the weld, in the HAZ, where softening may reduce the local properties. • Far from the weld, in the base metal, where failure strength depends on the base metal properties (under axial loading) and thickness. Thin sheets and low-strength steel grades are more prone to base metal failure. It is obvious that the failure mode depends on the local properties of the area of concern; however, it is also strongly dependent on the local load-bearing section. As a consequence, for a given steel grade, the ratio w:t, where w is the weld width and t is the sheet thickness, is a major factor driving the failure mode. Gu et al. (2011) also reported interfacial failure occurring in press-hardened steel welds in spite of significant HAZ softening. This highlights the influence of the weld geometry on the weld properties. Because of the keyhole energy transfer mode, laser welds are very narrow. The weld width depends primarily on the beam diameter and, to a lesser degree, on the total heat input. For a given laser configuration (power and optical conditions), the w:t ratio decreases rapidly with increasing sheet thickness, leading to interfacial failure in thick sheets. The failure mode is therefore not intrinsic to the base metal weldability but is mainly driven by sample geometry. This is demonstrated in Figure 6.16, where the percentage of welds made in a wide range of steels is graphed against steel thick- ness. It clearly shows that interfacial failure becomes the predominant failure mode in sheets thicker than 1.5 mm, irrespective of metallurgy. It should be noted that a similar trend occurs in spot welding of AHSS (Radakovic & Tumurulu, 2008). Figure 6.15 Tensile shear strength on laser weld stitches of different lengths. ArcelorMittal internal study. 112 Welding and Joining of AHSS The comparison of spot and laser weld strengths cannot be restricted to the basic tensile shear test. Other loading modes must also be taken into account. The following results were extracted from a test campaign performed to evaluate the weld strength of various AHSS combinations in both quasi-static and dynamic conditions. The trials were per- formed on a high-speed testing machine at 5 mm/min for quasi-static tests and 0.5 m/s for dynamic tests in pure shear, pure tear (cross-tension), or mixed loading modes (Figure 6.17). From those trials, the strength at failure and the energy absorbed during the trial were measured. Figure 6.16 Influence of sheet thickness on the failure mode of overlap welds for a wide range of products, including DP450-600-780-980; TRIP700-800; FB450-600; and M800-1200. ArcelorMittal internal report. Figure 6.17 Sample geometry for quasi-static and dynamic tests. Cretteur, Bailly, Pic, Tchorbadjiysky, and Cotinaut, 2010. 113High-power beam welding of AHSS It must be noted that the energy absorbed depends on the deformation of the sample and is not just due to the mechanical properties of the weld. However, because all the trials used the same sample geometry, this comparison is relevant. Laser stitches were made using a length of 27 mm. C- and S-shaped welds with the same overall weld length were created. This leads to various apparent lengths and widths of the welds. A shape factor, expressed as the width-to-length ratio of the weld, can be defined according to Table 6.2. The weld strength at failure can be easily described with an elliptic representation, with major axes representing pure shear and normal loading (Figure 6.18). The different laser weld geometries arecompared with an 8-mm-diameter resistance spot weld. Based on Figure 6.18, the following can be observed: • In quasi-static conditions the resistance spot weld and the various laser welds have equiva- lent failure strengths. Replacing a spot weld with 25–30 mm of laser weld has been shown to be valid in other work when involving ultra-high-strength steel with thicknesses between 1.5 and 2 mm (Pic, Tchorbadjisky, & Faisst, 2010). Table 6.2 Definition of the shape factor Length of fused zone (mm) Shape length l (mm) Shape width w (mm) Shape factor (w/l) Linear stitch 27 27 1 0.04 C-shape 27 16 5 0.31 S-shape 27 14.7 5 0.34 Figure 6.18 Quasi-static (a) and dynamic strength (b) of DP600 2-mm and 1.5-mm welds. Cretteur et al. (2010). 114 Welding and Joining of AHSS • Laser welds have higher failure strengths than spot welds when dynamically loaded. Laser weld geometry did not affect dynamic weld strength. The energy absorption characteristics of these welds also were analyzed. Figure 6.19 illustrates the failure strength and energy absorption for welds joining press-hardened steel to DP steel: • In tearing conditions the failure strength is lower for resistance spot welds than for the var- ious laser-welding geometries. The energy absorbed by the spot-welded sample was also significantly lower than that measured for the laser-welded samples. • In shear the failure strength is equivalent for all the welding processes. However, energy absorption is slightly better for the resistance spot welds because of the different failure modes of the welds. The laser welds failed interfacially under shear loading. This failure mode led to lower total energy absorption (Figure 6.20). The failure mode can be significantly influenced by the outer dimensions of the weld. Figure 6.21 shows how the weld shape factor influences the probability of Figure 6.19 Strength at failure (left) and energy absorption (right) of Usibor1500P 1.8-mm and DP600 1.5-mm samples for various welding conditions. Cretteur et al. (2010). Figure 6.20 “Plug out” failure mode in an S-shaped (a) and C-shaped weld (b). ArcelorMittal internal report project. 115High-power beam welding of AHSS interfacial failure during the mechanical tests of various weld shapes and material combinations. A shape factor of 1 (corresponding to any geometry with equal width and length, for example, a circle or any shape that could be inscribed within a square) is more favorable to “plug out” failure modes. This is related to the different stress concentrations around the weld for different shape factors. The influence of various weld shape factors on the failure mode was also observed to scale up in larger components. Crash tests were performed on hat channel-shaped structures with various welding conditions: resistance spot welding, laser stitch, and S-shaped laser welds, as well as weld bonding (combination of spot welding with Beta- mate 1496 high-strength adhesive). These crash tests clearly show that laser stitches have the highest rate of failure during crash testing (33%), as may be seen in Figure 6.22. Resistance spot welding also showed some weld failures. By shaping the laser welds, however, no more weld failures occurred during testing, even in cases where the parts were severely deformed during the test. In terms of energy absorption the best laser-welded solution (S-shaped welds of 21 mm × 12 mm) was able to absorb 10% more energy than the spot weld reference (Cretteur, Bailly, Pic, Tchorbadjiysky, & Cotinaut, 2010). 6.5.2.2 Stiffness The reduction in sheet thickness allowed by the use of ultra-high-strength steel has a direct and negative impact on the component stiffness. However, the choice of the join- ing technique can compensate for the loss of stiffness (Audi, 2007; Daimler, 2009; Pic et al., 2010). In particular, laser welding offers the possibility of producing continuous joints, increasing the component’s stiffness. Figure 6.23 shows the torsional stiffness = Figure 6.21 The occurrence of interfacial failure depends on the weld shape factor. Pic, Tchorbadjiysky, Faisst and BeaLaser (2010). 116 Welding and Joining of AHSS of DP600 clam shell beams (made of two hat sections). The hat sections were welded using various laser weld geometries. Then the beams were torsionally loaded, and the corresponding stiffness was calculated. It should be noted that the stiffness is highly dependent on the initial geometry (Cretteur et al., 2010) of the component; therefore, × × × Figure 6.22 The influence of the welding process on weld integrity during frontal crash tests of TRIP800 1.5-mm-thick steel. ArcelorMittal internal report project. Figure 6.23 Evolution of torsional stiffness of DP600 1.2-mm beams with the joining process. ArcelorMittal internal report project. 117High-power beam welding of AHSS values presented in Figure 6.23 must not be considered absolute and only illustrate a trend. When component stiffness was measured, a continuous weld line increased stiffness by 15%. Weld geometry also plays a role in the final stiffness. An interrupted line of 50-mm stitches led to an intermediate improvement in stiffness. This linearly corresponded to the proportion of the welded length of the beam flanges. Using curved welds instead of linear stitches tends to lower the beneficial effect of laser welding on stiffness. With C-shaped welds, the key factor is not the effective weld length but the apparent weld length l, as defined in Table 6.2. This shows that while C-shaped welds are preferred for crash conditions, linear welds are promoted for stiffness-driven components. The versatility of laser welding allows the weld design to be adapted, depending on the main function of the AHSS component. 6.6 Conclusions The rapid evolution of laser technologies between 1990 and 2010 has led to a wide range of laser-welding applications in the automotive industry, both for the manufac- ture of components and the assembly of the BIW. AHSSs also penetrated the automotive market during the same period. The rapid heating and cooling cycles experienced in laser welding, combined with the complex microstructure and relatively high alloying content of AHSS, lead to significant mod- ifications of the base metal in the vicinity of the weld. Specifically, the fusion zone is prone to being highly martensitic. However, it was proven that the fusion zone’s high hardness does drastically not limit the strength and formability of the weld. Also, HAZ softening frequently occurs in AHSS welds, particularly on steels containing marten- site (such as DP or press-hardened steels). Even if the decrease in the hardness of the HAZ can be considered as a local reduction of the metal’s mechanical properties, it was proven that the properties of the welded component are only slightly affected by the presence of this locally weakened area. Because the HAZ in laser welds is typi- cally very narrow, the effect of HAZ softening on the overall mechanical properties is also limited because the mechanical properties of the neighboring base material and fusion zone dominate as the HAZ narrows. Although weld microstructure affects local properties, weld geometry is of primary importance when determining the overall strength and formability of the weld. Adapting the weld geometry to the targeted application is also a major advantage of the laser welding process. While many other welding processes are limited in terms of weld geometry, laser welding offers an infinite variety of weld shapes (lines, curves, C- or S-shapes of various dimensions). Modifying the weld definition on a given com- ponent could lead to improved stiffness and crash behavior. The use of AHSS in the automotive industry aims to optimize simultaneously car body weight and mechanical properties. Joining processes must also be considered when optimizing the auto body design. Laser welding offers the largest versatilityand potential solutions for improving properties. Laser welding offers solutions to optimize the behavior of an AHSS component. 118 Welding and Joining of AHSS Acknowledgments The author thanks J. Larsson from Volvo Car Corporation for providing images presented in this chapter. The author also thanks Ms Tainturier, Ms Laveau, Ms Bayart, Ms Gayet and Mr Luquet, Mr Gaied, Mr Marakchi, Mr Lucas, Mr Bobadilla, Mr Bailly, Mr Pic, and Mr Yin from ArcelorMittal R&D for their participation in the chapter, and particularly Mr Biro for reviewing the chapter. References van der Aa, E. (2013). Welding of pre-deformed AHSS. Results from RFCS project REFORM, Conf Joining in Car Body Engineering 2013, Bad Nauheim, Germany. ASM handbook weld integrity and performance. (1997). Chapter 13 ASM. Audi. (2007). Die Karosserie des neuen Audi A5 coupé. 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Journal of Engi- neering Materials and Technology, 129(3), 446–452. http://www.worldautosteel.org/projects/ulsab/ultralight-steel-auto-body-ulsab-programme/ http://www.worldautosteel.org/projects/ulsab/ultralight-steel-auto-body-ulsab-programme/ This page intentionally left blank Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00007-2 Copyright © 2015 Elsevier Ltd. All rights reserved. Hybrid welding processes in advanced high-strength steels (AHSS) S. Chatterjee, T. van der Veldt Tata Steel Research and Development, Joining and Performance Technology, Wenckebachstraat, The Netherlands 7 7.1 Introduction The laser beam welding process can be combined, in principle, with the arc welding process. When these two welding techniques are coupled as one process, the laser beam and arc (Gas Tungsten arc welding, plasma or gas–metal arc welding (GMAW)) interact at the same time in one zone (plasma and weld pool) and mutually influence and assist one another. Such process coupling is referred to by the term hybrid welding process (DVS, 2005). One of the remarkable characteristics of laser welding is the narrow and deep config- uration of the weld. This narrow weld is the result of the high energy concentration of the process and the high welding speed, which result in a low heat input into the workpiece. Automotive joining lines use the narrow weld characteristic and cost advantage of the high processing speed, but its narrow weld leads to some difficult metallurgical problems. Also, laser welding requires special attention because the narrow laser beam (a few microns) has intolerant to poor fit between the parts. The arc welding process, on the other hand, is more tolerant to the poor fit between the parts because of its relatively wider arc spot (a few millimetres). Also GMAW has the possibility to add filler metal to better bridge gaps and control the metallurgical influence on the weld microstructure. In GMAW, however, the speed of welding is relatively much lower than that of laser welding. In laser–arc hybrid welding, a laser beam is used in combination with an arc pro- cess to produce a weld seam. The laser ensures deep penetration at a higher welding speed, whereas the arc produces arelatively wider and smooth weld face and alleviates problems caused by misalignment or gaps in the joint configurations (Ataufer, 2005; Duley, 1999; Ishide, Tsubota, Watanabe, & Ueshiro, 2003; Kutsuna & Chen, 2002; Petring, Fuhrmann, Wolf, & Poprawe, 2003; Schubert, Wedel, & Kohler, 2002; Steen, 2003; Steen & Eboo, 1979; Steen et al., 1978; Tsuek & Suban, 1999). In the late 1970s at Imperial College London, a group of scientists lead by Professor William M. Steen performed the first attempts at combining a laser and an arc (tungsten inert gas) welding process (Steen et al., 1978; Steen & Eboo, 1979). This early investigation showed that the combination of a laser beam and arc within a common process zone is more than a simple combination of two heat sources. These experiments demonstrated that the laser radiation had an essential impact on the arc behaviour, leading to a stabilized arc column and a contraction of the arc spot. 122 Welding and Joining of AHSS This new hybrid laser–arc process can penetrate deeper with a narrow weld bead com- pared with both the solo laser and the solo arc welding techniques. A significantly higher welding speed can also be obtained with this hybrid technique. However, this inno- vation did not immediately find practical applications because the laser process itself was not viable on an industrial scale (Bagger, Flemming, & Olsen, 2005; Seyffarth & Krivtsun, 2002). In the early 1990s, when the multi-kilowatt laser systems become available, the challenges in developing welding applications changed from the perfor- mance of the beam sources (e.g. with respect to penetration or welding speed) to the requirements considering fit-up and part tolerances. Possibilities and limitations of the hybrid laser–arc welding technique were investigated all over the world (in the United States, Europe and Japan) (Beyer, Imholff, Neuenhahn, & Behler, 1994; Dilthey & Wieschemann, 1999; Ishide, Tsubota, & Watanabe, 2002; Magee, Merchant, & Hyatt, 1991). After renewed research efforts, promising success in industrial applications (e.g. in the shipyard industry) was accomplished quickly (Merchant, 2003; Denney, 2002; Dilthey, Wieschemann, & Keller, 2001). Hybrid laser–arc welding became one of the hot topics in laser processing. New industries such as the pipeline and the auto- motive industries, became interested. The continued development of high-power, sol- id-state lasers with smaller form factors, greater efficiency and lower cost has greatly influenced the usability of this hybrid welding in industries. New technologies, in particular the fibre delivery system, helped integrate the process into conventional motion systems such as robots, gantries and automation, which increased the accep- tance of the hybrid system in automotive industries. The recent development of laser sources with even more high-power density, such as disc lasers and fibre lasers, com- bine higher laser power in a higher beam quality. In thick-plate welding this enables deeply penetrating welds with high aspect ratios, but at the same time it increases even further demands on edge quality. A hybrid welding solution could reduce these fit-up problems. However, for very thin sheets, hybrid welding is not really suitable; the thinnest application is around 1 mm (Hansen, 2012). In that respect laser–GMAW hybrid welding has a limitation for many parts of the auto body. This chapter describes the laser–GMAW hybrid welding process from an automotive perspective. 7.2 Laser–arc hybrid process description The laser–arc hybrid welding process is schematically shown in Figure 7.1, along with a photograph of a laser–GMAW hybrid welding head. The arc, in addition to the laser beam, supplies heat to the weld metal in the upper weld region, giving the weld seam its ‘wine glass shape’ (a wider weld face and a narrower weld root). Filler metal is supplied to the weld pool by the electrode wire. The mutual influences exerted by the laser and arc during the process can differ in intensity as a function of the arc or laser process used and the process parameters. Understanding physical phenomena in hybrid welding is important because all states of solid, liquid, vapour and plasma exist in a small space. A keyhole is generally formed in the molten pool with the laser beam with high-power density and, simulta- neously, a plume (laser-induced metal vapour), and spatters are formed in the space. 123Hybrid welding processes in AHSS GMA plasma and droplets from the filler wire also exist above the molten pool. An increase in arc voltage is noted during hybrid welding, and the amount of this increase is in direct proportion to the power of the yttrium–aluminium–garnet laser. The plume, which evolves towards the incident laser beam, affects the phenomenon such that the arc column becomes brighter and longer, leading to an increase in the arc voltage in this hybrid welding (Naito, Mizutani, & Katayama, 2006). In the case of a hybrid carbon dioxide (CO2) laser and pulsed metal active gas welding, the arc approaches a laser-induced plume at low voltages but covers the molten pool just below the wire at higher voltages (Sugino, Tsukamoto, Nakamura, & Arakane, 2005). A laser-induced plume often acts as an arc current path between the electrode or wire and the plate when the laser beam and the heat source are close together. The inter- action between the arc and the laser-induced plume generally depends on the type of laser and shielding gas, the arc current, the distance between an electrode and the plate, the distance between a laser irradiation spot and an electrode target on the plate and the inclination of the electrode. Laser beam Electrode Arc Fusion zone Weld direction Workpiece Vapour cavity Plasma Laser-induced metal vapour (a) (b) Figure 7.1 (a) Principles of the laser–arc hybrid welding process (H. Staufer, M. Rührnößl and G. Miessbache, January 02, 2013, Hybrid welding for the automotive industry.) and (b) a laser–GMAW hybrid welding head. 124 Welding and Joining of AHSS 7.3 Laser–arc hybrid process parameters for welding automotive AHSS The hybrid laser–arc welding technique has proved its suitability in many indus- trial applications. However, a large number of parameters have to be set correctly to achieve proper joint quality. Some of these parameters are described below. 7.3.1 Energy input The heat input to which the weldment is exposed as a result of the hybrid pro- cess can be kept low compared with the standalone arc processes. In general, an increase in laser power increases the weld penetration. In the case of hybrid laser– arc welding (as opposed to the laser-only process) this increase in penetration is accentuated because the reflectivity of the workpiece metal is reduced as the metal is heated by the arc. The laser’s or the arc’s character may predominate, however, depending on the selected power input ratio. At Tata Steel, a series of experimental welding has been done by varying laser power and GMAW power; for a 2.5-kW laser power when the arc power exceeds 10% of the laser power, the weld penetra- tion decreases (Chatterjee, Mulder, and van der Veldt, 2013). Laser power is the dominant factor influencing weld penetration. The welding voltage has been shown not to influence the weld penetration depth by a great deal, but the weld bead gets wider if the welding voltage increases, giving a lower depth-to-width ratio for a same laser power. The arc voltage (and wire feed rate) therefore need to be increased for wider fit-up gaps to avoid any lack of fusion. The welding current generally is matched to the filler wire diameter (a higher welding current for a larger wire diameter). Considering a given wire diameter and voltage settings, an increase in welding current gives a deeper weld with a higher depth-to-width ratio. Nilsson, Heimbs, Engström, and Alexander (2003) studied the effect of Metal inertgas weld- ing (MIG) power on the weld geometry of hybrid welds and reported the width of the heat-affected zone increases with increasing MIG power. Also, the depth of the undercut increases with increasing MIG power (Figure 7.2). 7.3.2 Welding speed Ability to achieve a faster welding speed is one of the great advantages of the hybrid welding process. Because of the inherent high energy density, a laser beam can be moved very quickly during laser welding, but maintaining a stable arc at a high speed is a difficult task. However, Ono, Shinbo, Yoshitake, and Ohmura (2002) studied this and reported that the arc remains steady in hybrid welding, even at high speeds. They showed the welding speed limit for hybrid welding is at least seven times higher than that for arc welding (as shown in Figure 7.3). In arc welding the arc is actually main- tained by thermionic emission from the sheet. When the welding speed is high, the heating becomes insufficient and the arc becomes unstable. By contrast, during hybrid welding, the electron density in a keyhole formed by laser radiation reaches 1017–1020/ cm3 (Ono et al., 2002) Moreover, the surrounding area is in a molten state, so that 125Hybrid welding processes in AHSS Figure 7.2 (a) Width of the heat-affected zone (HAZ) and the weld seam, depending on the MIG power. (b) Depth of the undercut as a function of the MIG power. Nilsson K, Heimbs S, Engström H, Alexander FH. 2003. Parameter influence in CO2-laser/ MIG hybrid welding. IIW Doc. IV-843-03. © IIW. Figure 7.3 The welding speed limit for forming a uniform weld using hybrid and arc welding. Ono M, Shinbo Y, Yoshitake A, and Ohmura M. 2002. Development of laser-arc hybrid welding. NKK Technical Review, 86. 126 Welding and Joining of AHSS thermionic emission takes place very easily. In fact, the plume generated from the laser interaction with the material feeds the arc process. When arc welding is com- bined with laser welding in this region, a stable arc is maintained, even when the welding speed is high. The weld penetration increases when the welding speed is decreased because the heat input per unit length of the weld is higher. Also, the capability of the filler wire to fill the gap is improved at lower welding speeds (at a constant rate of filler wire feeding). The ratio between welding speed and filler wire feeding is important to the stability of the keyhole and thus to the stability of the process itself. 7.3.3 Relative arrangement of the laser and the MIG torch To get the maximum weld penetration, the laser is positioned perpendicular to the weld seam, and the arc torch is kept at an angle to the laser beam. For a fillet type of joint configuration, keeping the arc torch with an angle to the joint line can be beneficial. The leading or trailing position of the arc torch is a determining factor of the weld characteristics. The arc-leading configuration helps to obtain an increase in penetration. The distance between the laser and the filler wire tip is one of the most important parameters to control in hybrid laser–arc welding. A short distance, typically 1.5 mm, between the laser spot and the filler wire tip has been shown to be favourable for a steady keyhole. Nilsson et al. (2003) studied this by keeping the laser beam at the joint centre and laterally displacing the MIG torch up to 2 mm from the joint centre (Figure 7.4). With increasing lateral displacement of the MIG torch, the weld became more asym- metrical. When a lateral displacement is 2 mm, the distance between the laser beam and the arc becomes so large that the two processes started acting separately without any synergy. The arc is still attracted by the laser beam up to a 1.5 mm gap, so that the typical hybrid weld forms. 7.3.4 Focal point position The maximum weld penetration for the hybrid laser–arc process is generally obtained when the laser beam is focused below the surface of the top sheet. Depending on Figure 7.4 Micrographs of the weld seams with a lateral displacement B of the arc V-joint. Nilsson K, Heimbs S, Engström H, Alexander FH. 2003. Parameter influence in CO2-laser/ MIG hybrid welding. IIW Doc. IV-843-03. © IIW. 127Hybrid welding processes in AHSS the requirement of the weld shape, position of the focal point needs to be selected. Campana, Fortunato, Ascari, Tani, and Tomesani (2007) carried out hybrid welding experiments using 8-mm-thick plates and reported that the focal position of the laser beam must be kept below the surface of the upper substrate to achieve best result (Figure 7.5). The distance between the substrate surface and the laser beam focus depends on the GMAW metal transfer mode: it should be less for a short arc and more when using a pulsed/spray mode. 7.3.5 Angle of electrode The penetration of the weld increases with the angle of the electrode to the workpiece surface up to 50°. The gas flow along the welding direction provided by the arc torch deflects the plasma induced by the laser, and this plasma reduces the absorption of the laser beam when CO2 lasers are used. Therefore the angle of the electrode to the top surface of the workpiece is often set at around 40–50°. 7.3.6 Joint gap The laser–arc hybrid process is well known for its tolerance to inaccurate joint prepa- ration and joint fit-up. The capability of hybrid lap welding to bridge gaps is consid- erably greater than that of laser welding because the filler wire used in hybrid welding supplies enough weld metal to fill gaps. By contrast, when a gap is present in laser welding with no filler metal, the amount of molten metal tends to be insufficient to fill the gap, resulting in weld defects such as underfill or burn-through. Ono et al. (2002) used lap welding on sheets with different thicknesses and varied gaps to investigate the gap tolerance of hybrid welding vis-à-vis laser welding. Their results are shown in Figure 7.6(a) and (b), which illustrates that the gap tolerance for hybrid welding is much higher than that of laser welding alone. Nilsson et al. (2003) studied the gap tolerance of a hybrid process on butt joint configurations. They also found that the joint without a gap shows no undercut, but Figure 7.5 Influence of the laser beam’s focal position on hybrid weld penetration. Campana G, Fortunato A, Ascari A, Tani G, and Tomesani L. 2007. The influence of arc transfer mode in hybrid laser-mig welding. Journal of Materials Processing Technology 191, 111–113. 128 Welding and Joining of AHSS joints with a gap show varying levels of undercuts. This can be solved by increasing the speed of the wire feed. Nilsson et al. found a relationship between necessary wire feed speed and gap width (shown in Figure 7.7). The welding speed cannot be increased linearly. As the weld travel speed increases, increasingly larger amounts of filler wire have to be melted to fill the gap. This takes more time and requires lower process rates, and the speed has to be reduced for wider gaps. Figure 7.6 (a) Gap tolerance in laser lap welding. YAG, yttrium– aluminium–garnet. (b) Gap toler- ance in hybrid lap welding. Ono M, Shinbo Y, Yoshitake A, and Ohmura M. 2002. Development of laser-arc hybrid welding. NKK Tech- nical Review, 86. 129Hybrid welding processes in AHSS 7.3.7 Optimization of welding parameters: torch angle, stick-out and beam-to-wire distance Tata Steel performed welding experiments with different hybrid welding parameters using lap shear specimens. Parameters (Table 7.1) such as laser power, wire feed speed, welding travel speed and shielding gas composition were kept fixed during the experiments to observe the effects of torch angle, wire stick out (for arc voltage) and the gap between the laser beam and the arc during weld penetration. The experiments were designed as per the Box–Behnken method (Table 7.2). The results of these tests, shown in Figure 7.8(a)–(c), indicate how the weld pen- etration changes withtorch angle and at different stick outs. 0 0 0.5 1 Gap width (mm) 1.5 2 0 5 10 15 20 25 0.2 0.4 0.6 0.8 W el di ng tr av el s pe ed (m /m in ) W ire fe ed ra te (m /m in ) 1 1.2 1.4 1.6 1.8 2 Figure 7.7 Welding and wire speed as a function of gap width. Nilsson K, Heimbs S, Engström H, Alexander FH. 2003. Parameter influence in CO2-laser/MIG hybrid welding. IIW Doc. IV-843-03. © IIW. Table 7.1 Welding parameters Fixed parameters Laser power 2.5 kW Wire feed speed 7 m/min Welding travel speed 1 m/min Shielding gas 92% Ar + 8% CO2 Varied parameters Torch angle 5–65° Stick out 13–21 mm Distance between the laser beam and MIG wire 0.5–2.5 mm 130 Welding and Joining of AHSS Figure 7.8 illustrates that when a small stick out is used, the penetration is highest when the distance from the laser beam to the arc is larger. Similarly, for a large stick out, the laser-to-arc distance should be smaller to obtain higher penetration. Changing the torch angle does not change this trend but shifts the optimum. 7.3.8 Shield gas composition The predominant constituent of the shielding gas is generally an inert gas such as helium or argon (Ar). A shielding gas that provides a higher ionization potential is required because the plasma can deflect or absorb a portion of the laser energy when CO2 lasers are used. Helium is, therefore, often preferred over Ar for laser welding, but its lightness is a disadvantage; it is often combined with Ar, which is heavier, without substantially altering the weld penetration depth. The addition of reactive gases such as oxygen (O2) and CO2 has an influence on the weld pool wetting characteristics and bead smoothness. The weld penetration of hybrid welding varies with the plasma shape, which is determined by shielding gas parameters, especially the plasma height interacting with the incident laser. The higher the plasma height interacting with incident laser, the shallower the weld penetration. The effect of shielding gas parameters on plasma shape is achieved in two ways: laser–arc plasma interaction and the direction and velocity of gas flow. Figure 7.9 (Gao, Zeng, & Hu, 2007) shows the effect of the heli- um-to-Ar ratio on the plasma shape during the hybrid welding process. Dilthey et al. (2001) investigated the effect of shielding gas on the porosity of the bead surface and spattering in hybrid welding of galvannealed steel sheets in an over- lapping fillet joint configuration (without a gap in the flat position). They reported the Table 7.2 Experimental design as per the Box–Behnken method Experiment no. Torch angle (degrees) Stick out (mm) Distance between the laser beam and MIG wire (mm) 1 5 13 1.5 2 5 21 1.5 3 65 13 1.5 4 65 21 1.5 5 5 17 0.5 6 5 17 2.5 7 65 17 0.5 8 65 17 2.5 9 35 13 0.5 10 35 13 2.5 11 35 21 0.5 12 35 21 2.5 13 35 17 1.5 14 35 17 1.5 15 35 17 1.5 131Hybrid welding processes in AHSS Figure 7.8 Effects of stick out (mm) and laser-to-wire distance on weld penetration when torch angle is (a) 5°, (b) 35° and (c) 65°. 132 Welding and Joining of AHSS CO2 in Ar + CO2 shielding gas is effective in decreasing the pits, whereas O2 decreases the size but increases the number of pits. Increasing the CO2 and O2 gas ratio in Ar + CO2 and Ar + O2 shielding gas deepens the penetration and widens the weld bead, respectively. Both CO2 and O2, however, increase spattering. A mixture of Ar, CO2 and O2 as a shielding gas is most suitable for welding of galvannealed steel sheets because it produce less pitting, porosity and spatter. 7.4 Applications in the automotive industry Welding in the automotive industry predominantly involves joining sheet metals. Therefore the energy input to the substrate has to be very low compared with that when welding heavier-gauge steel and needs to be controlled precisely to avoid any distortion. The process has to be extremely fast to cope with the productivity of auto- motive production lines. Ease of automation or robotization is another criterion for such welding processes, as is robustness. Currently, resistance spot welding and laser welding are the two major welding processes that are considered most suitable for automotive manufacturing lines. With the increased use of advanced high-strength steels (AHSS) in recent years, however, welding in automotive manufacturing has become more challenging. As mentioned in previous chapters, AHSS grades differ significantly from conventional formable low-alloy automotive steels in terms of total alloy content, microstructures and different thermophysical properties, which require different welding practices for AHSS grades. There are some limitations for applying laser–GMAW hybrid welding to manufacturing of many auto body parts. It is not suitable for very thin sheets. Accessibility is also an issue because the welding heads are quite large. Still, this hybrid welding process is chosen by the automotive industry as an enabling technology to reduce both distortion and mass without compromising structural crashworthiness. Depending on the materials and joint configurations, each car contains some hybrid welds. The main application of hybrid welding in automobiles is in the chassis and suspension. Volkswagen and Audi in particular are two examples of companies con- vinced by the benefits of hybrid laser–MIG welding (Brettschneider, 2003; Beyer, Brenner, & Poprawe, 1996; Graf & Staufer, 2003; Staufer, 2003). For manufacturing Figure 7.9 Plume formation for different shielding gas mixtures. Gao M, Zeng X and Hu Q. 2007. Effects of gas shielding parameters on weld penetration of CO2 laser-tungsten inert gas hybrid welding. Journal of Materials Processing Technology 184, 177–183. 133Hybrid welding processes in AHSS the doors of the Volkswagen Phaeton, hybrid welding is applied, in addition to MIG and laser welding. One door includes 48 hybrid-welded seams with a total length of 3570 mm. The seams are mainly fillet seams on the lap joints and some butt joints. To meet rigidity requirements for the doors and to save weight at the same time, having a tailor-made combination of sheet, casting and extruded materials would be necessary. At some spots these parts can be jointed only by hybrid welding because of the required speeds and given tolerance. Without the hybrid process, Volkswagen would have had to use heavy casting material. The new Audi A8 also uses hybrid welding. Each vehicle comprises a total of 4.5 m of weld seam. Hybrid welding is used in the lateral roof frame, which is equipped with various functional sheets (Figure 7.10). Daimler also uses hybrid welding to produce the axle components of their C-class vehicles (Staufer, 2009). 7.5 Costs and economics Some important superior features of hybrid welding compared with pure laser or arc welding are listed below. • Higher welding speed. Productivity is improved through increased welding speed. For sheet material it is possible to enhance speed by 30% compared with conventional laser welding, without the addition of the arc power. • When using a hybrid combination, the investment cost for the power source is significantly less and the electrical efficiency is much higher. A 1-kW reduction in the neodymium: yttrium–aluminium–garnet laser beam power leads to a reduction of approximately 35 kVA in the electric power consumed. Thus, using a 2-kW laser instead of a 4-kW laser is possible in the hybrid process, resulting in savings in initial investment outlays. • Larger tolerance of the joint configuration due to gap bridging with the added GMAW wire. Therefore the cost of edge preparation and of poor quality due to improper joint fit-up is negligible, which improves the overall economics of the hybrid process. Figure 7.10 Hybrid welding in the Audi A8 roof area (green parts are made of sheet metal, red parts are casted structures and blue indicates extruded parts). Helten (2003). 134 Welding and Joining ofAHSS • Good weld quality, with low and predictable distortion, is obtained, which implies a reduction in the need for rework. This potentially reduces the labour costs incurred from rectification work. • Introducing AHSS materials that are non-weldable by autogenous laser welding is possible using hybrid processes. This, in turn, helps reduce the auto body weight, making it more fuel efficient, greener and a safer vehicle at an affordable cost. In conclusion, the hybrid laser–GMAW process combines the advantages of both arc and laser processes, resulting in high joint completion rates with increased tol- erance to fit-up and without compromising joint quality and distortion control. The benefits to the industry include increased productivity, simplified setup procedures and reduced reworking costs after welding. Table 7.3 summarizes the economic advan- tages of a welded component for the automotive industry (Staufer, 2009). References Ataufer, H. (2005). Laser hybrid welding and laser brazing: state of the art in technology and practice by the examples of Audi A8 and VW-phaeton. In: Proceedings of 3rd Interna- tional WLT Conference on laser in manufacturing, 2005, Munchen (pp. 203–208). Bagger, C., Flemming, O., & Olsen (February, 2005). Review of laser hybrid welding. Journal of Laser Applications, 17(1). Beyer, E., Brenner, B., & Poprawe, R. (1996). Hybrid laser welding techniques for enhanced welding efficiency. In: ICALEO proceedings, section D, Detroit, USA. Beyer, E., Imholff, R., Neuenhahn, J., & Behler, K. (1994). New aspects in laser welding with an increased efficiency. In: Proceedings of the laser materials processing – ICALEO ’94. Orlando, FL, USA: LIA (Laser Institute of America). Brettschneider, C. (September, 2003). A8 meets DY. Eurolaser (Zeitschrift für die Industrielle Laseranwendung). Campana, G., Fortunato, A., Ascari, A., Tani, G., & Tomesani, L. (2007). The influence of arc transfer mode in hybrid laser-mig welding. Journal of Materials Processing Technology, 191, 111–113. Table 7.3 Economic advantages of a welded component for the automotive industry Parameters Benefits Welding speed +30% Shop floor space −50% Wire consumption −80% Shop floor staff −30% Reduction of cost of materials Up to €7 Full penetration Fewer variants Need for quality control Absolutely stable process Staufer H. Industrial robotic application of laser-hybrid welding. Olsen, F.O. (Ed.): Hybrid Laser-arc Welding. Cambridge, Woodhead, 2009, 197–199. 135Hybrid welding processes in AHSS Chatterjee, S., Mulder, R., van der Veldt, T. (2013). Effect of Laser-MIG hybrid welding param- eters on properties of welded HSLA sheets for automotive applications. XII-2152–13. Denney, P. (September, 2002). Hybrid laser welding for fabrication of ship structural compo- nents. Welding Journal, 81(9), 58. Dilthey, U., & Wieschemann, A. (1999). 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Hybrid welding with arc and laser beam. Science and Technology of Welding and Joining, 4(5), 308–311. Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00008-4 Copyright © 2015 Elsevier Ltd. All rights reserved. Metal inert gas (MIG) brazing and friction stir spot welding of advanced high-strength steels (AHSS) M. Shome Research & Development, Tata Steel, Jamshedpur, India 8 8.1 Introduction To meet weight reduction targets of automobiles, several new grades of steel have been developed over the past two decades under the broad category of advanced high-strength steels (AHSSs). These new steels include dual-phase (DP), transformation-induced plas- ticity, ferrite–bainite, complex-phase and twinning-induced plasticity steels. AHSSs have tailored microstructures consisting of ferrite, bainite, martensite and retained austenite that provide an excellent combination of high strength and ductility (Kuziak, Kawalla, & Waengler, 2008; Zrnik, Mamuzic, & Dobatkin, 2006). To meet corrosion resistance requirements, a large percentage of these steels are produced in the form of galvanized and galvannealed products. Despite possessingexcellent mechanical properties, these steels require special precautions during forming and welding. Welding is an integral part of automotive manufacturing, and therefore the weld- ability of steels is an essential requirement for their application. The carbon equiv- alent, microstructure, mechanical properties, type of zinc coating and thickness are key factors that require attention while selecting the joining process and establishing the joining conditions for AHSSs. Under the influence of the welding thermal cycle, the microstructures of the base metal are altered in the heat-affected zone (HAZ). Consequently, the mechanical properties are impaired locally, resulting in poor joint performance. For example, in DP steels the HAZ tends to soften with tempering of martensite. In transformation-induced plasticity steels the hardness of the weld increases significantly, and therefore the joint is likely to suffer brittle fracture under loading and would also exhibit poor fatigue properties. Zinc is vaporized during laser welding or gas–metal arc welding (GMAW) of coated steels, causing porosities and exposing the surface to the atmosphere without sacri- ficial protection. Interfacial fracture, electrode life and zinc loss are issues that arise during resistance spot welding (RSW) of bare and coated AHSSs. The performance and durability of an automotive structure largely depends on the design and quality of the joints (Davies, 2012, p. 248). For increased usage of AHSS, addressing weldability requirements and exploring alternative joining processes is therefore important. In that direction, this chapter focuses on the welding of DP steels using two entirely different processes, namely, metal inert gas (MIG) brazing and friction stir spot welding (FSSW). 138 Welding and Joining of AHSS 8.2 MIG brazing Coated steel sheets encounter a number of difficulties during GMAW, also known as MIG/metal active gas welding. Excessive zinc evaporation leads to spatter, porosity for- mation, non-uniform bead geometry and, most important, loss of protection against corro- sion. All these problems lead to poor weld quality, increased cleaning costs after welding, more rework and lower productivity (Guimaraes, Mendes, Costa, Machado, & Kuromoto, 2007; Holliday, Parkar, & Williams, 1995, 1996; Howe & Kelly, 1988; Parker, Williams, & Holiday, 1988). To alleviate these issues a gas metal arc brazing (or MIG brazing) process is recommended. This process combines the advantages of both GMAW (a high deposition rate) and conventional brazing processes (cold joining). Because consumables with low melting points are used, the high welding speed and the low thermal input ensure stable operation and good joint properties in terms of appearance, HAZ microstructure, strength and resistance against corrosion (Quintino, Pimenta, Iordachescu, Miranda, & Pépe, 2006). MIG-brazed joints demonstrate good fatigue properties that ensure reliable performance during a vehicle’s life cycle (Lepisto & Marquis, 2004). During brazing, the torch is usually maintained at a 70° travel angle and a 20° working angle and is traversed along the edge of the upper sheet using both push and pull modes (Figure 8.1). Argon gas shielding is preferred. While this process has been successfully applied to galvanized low-carbon steels, its applicability to AHSSs is yet to be fully explored. In that direction, investigations assessing the performance of coated DP steel when MIG brazed were carried out. 8.2.1 Experimental methodology The composition and mechanical properties of galvanized DP590 steel and MIG braz- ing filler wire (CuAl8) are shown in Tables 8.1 and 8.2, respectively. The thickness of Direction of MIG brazing 70° Base metal - Base metal - Direction of MIG brazing Push mode Direction of MIG brazing Pull mode 200 mm 120 mm 100 mm Filler wire 20° Base metal Base metal BrM Figure 8.1 Metal inert gas (MIG) brazing setup and procedure. 139Metal inert gas (MIG) brazing and friction stir spot welding of AHSS the steel was 1.4 mm. As shown in Figure 8.1, MIG brazing was done in a lap joint configuration over a length of 300 mm using pulse-synergic conditions, wherein the current and the welding speed varied. The parameters for joining the steel are given in Table 8.3. Samples for metallographic, microhardness, shear tensile and high-cycle fatigue testing were sliced from the lap joint assembly. For microscopy the specimens were polished and etched using 2% nital. The specimens were examined under an optical microscope and a field emission scanning electron microscope equipped with energy dispersive X-ray spectroscopy. Micro-hardness was traversed from the braze metal to the base metal under a load of 100 gf using a standard Vickers micro-hardness testing Table 8.1 Chemical composition and mechanical properties of galvanized dual-phase steel Chemical composition (wt%) Mechanical properties Coating thickness (μm)Carbon Manganese Silicon Titanium Yield strength (MPa) Ultimate tensile strength (MPa) Braking load (kN) %El 0.097 1.631 0.24 0.002 386 626 17.53 24.5 19 UTS, Ultimate tensile strength; %El, %Elongation. Table 8.2 Chemical composition and mechanical properties of the filler wire Wire type Wire diameter (mm) Chemical composition (wt%) Ultimate tensile strength (MPa) Hardness (Hv)Copper Silicon Manganese Aluminium CuAl8 1.0 Bal. 0.113 0.318 8.01 450 100 Bal., Balance. Table 8.3 Metal inert gas brazing parameters Specimen Current (A) Voltage (V) Wire feed speed (m/min) Welding speed (mm/min) Heat input (J/mm) Welding mode DP1 108 18.0 5.0 600 136 Push DP3 108 18.0 5.0 400 204 Push DP3 128 19.0 6.0 600 170 Push DP4 108 18.0 5.0 400 204 Pull 140 Welding and Joining of AHSS machine. The sliced lap joint samples were machined to prepare standard shear tensile test specimens according to the DIN EN 10002-1 standard (Figure 8.2). The tensile shear tests were carried out in a universal testing machine with a 100-kN capacity at a cross- head speed of 0.5 mm/min. Three samples were tested for each heat input to evaluate the joint strength. High-cycle fatigue testing was performed on the tensile shear samples using a 50-kN resonant testing machine. For the tension–tension tests, the maximum load was equivalent to 80% of the ultimate quasi-static load under a load ratio of 0.1. The maximum load, minimum load, maximum and minimum crosshead displacement and the frequency were monitored during fatigue testing using data acquisition software. 8.2.2 Bead geometry and microstructure A schematic representation of the weld joint is shown in Figure 8.3. As demonstrated in Figure 8.4, the actual dimensions of the weld bead depend on the welding parameters. Fig- ure 8.5 shows that the width (W), leg length (L) and cross-sectional area (A) increase with increasing current. At the same time, the bead height (H) and wetting angle (θ) decrease. This is expected because the flowability of the melt increases with increasing temperature, causing a wider bead. The bead geometry varies with welding direction; in push mode (DP2) the bead is wider and flatter, whereas in pull mode (DP4) the bead is narrow and raised for the same heat input (204 J/mm). Lower capillary pressure associated with the push mode increases the wetting angle and produces a wider bead. The extent of zinc loss at the back side depends on the heat intensity. The zinc loss is least in DP1. Despite DP2 having a higher heat input than DP3, the zinc loss is less at the back of the sheet because the current is of a low order. Therefore the brazing heat intensity, which is directly related to the welding current, is critical in determining the extent of zinc evaporation. The microstructure at different locations of the weld joint (Figure 8.6) depends on the peak temperature attained and the subsequent cooling rate. While DP steel has dispersed martensitephases in a predominantly ferrite matrix, the HAZ contains lath martensite or bainite. The higher cooling rate (40–120 °C/s) produces these phases during phase transformation from austenite (Gould, Khurana, & Li, 2006). Hardness greater than 300 Hv confirms the presence of hard phases in the coarse grain HAZ (CGHAZ) compared with a base metal hardness of ∼180 Hv. While higher peak tem- perature (Tp) is responsible for coarsening of austenite grains, the ensuing rapid coo- ing condition enforces displacive transformation to form the hard phases. 100 120 35 130 35 20 20 30 1.4 Figure 8.2 Schematic diagram of a shear tensile specimen. All dimensions are in millimetres. 141Metal inert gas (MIG) brazing and friction stir spot welding of AHSS (a) (b) C L W A WM BM d θ BH Dilution of BM Weld metal Base metal HAZ HAZ Upper sheet Lower sheet D0.5 mm a CGHAZ cb FGHAZ Figure 8.3 Schematic diagram of a cross-section of a metal inert gas-brazed bead (a) and weld metal and the heat-affected zone (HAZ) (b). BM, base metal; CGHAZ, coarse grain heat-affected zone; FGHAZ, fine grain heat-affected zone; WM, weld metal. Figure 8.4 Effect of heat input on the bead appearance of metal inert gas-brazed joints. Distinct dendrites are observed in weld metals with copper matrix (Figure 8.6). These dendrites predominantly are supersaturated solid solutions of copper in iron, which are formed by localized melting of the base metal and mixing with the mol- ten copper, and remain scattered because of rapid cooling during solidification. The 142 Welding and Joining of AHSS dendritic constituents in welds made with higher heat input have a larger size and higher density because of the more dissolution of iron from the base metal by the Marangoni effect. The iron in the dendrites is responsible for the high hardness of the weld metal. The energy-dispersive spectroscopic analysis shown in Figure 8.7 reveals that the weld metal matrix essentially consists of a copper–aluminium alloy where the copper content θ Figure 8.5 Bead profile of metal inert gas-brazed joints at different heat inputs. H, height; L, length; W, width. Figure 8.6 Field emission scanning electron micrographs of metal inert gas-brazed joints of different heat inputs. CGHAZ, coarse grain heat-affected zone; Fe, iron; FGHAZ, fine grain heat-affected zone; WM, weld metal. 143Metal inert gas (MIG) brazing and friction stir spot welding of AHSS is about 85% and aluminium content is about 6%. The iron content in the iron-rich den- drites is about 80%. Some copper and aluminium also were found in the dendrites that are retained during the solidification process. The interface zone between the weld and the HAZ consists of mainly iron with some aluminium and copper. The interface thickness increased from 5.22 μm in DP1 to 6.07 μm in DP2 with an increase in heat input. Again, for the same heat input (e.g. 204 J/mm), the interface thickness was higher for pull mode than push mode. This indicates that more heat used in pull mode resulting in a thicker interface. The dendrite volume fraction, iron content in the dendrite and interface thickness are significant because they influence the strength of the weld metal and the overall perfor- mance of the weld joint. In the MIG welding process the weld metal attains high hardness values because steel consumables are used. In the MIG brazing process the copper-based consum- ables are of low strength; hence the hardness of the weld metal is of the order of that of the base metal (Figure 8.8). That also occurs because of the iron-rich dendrites in the weld metal. Compared with the weld metal and the base metal, the HAZ has the highest hardness because of its high martensite content. 8.2.3 Mechanical properties Shear tensile properties: Tensile properties corresponding to different MIG brazing parameters are listed in Table 8.4. When the heat input is increased from 136 to 204 J/ mm by decreasing the welding speed from 600 to 400 mm/min, the joint strength increases. When the heat input is increased from 136 to 170 J/mm by increasing the current from 108 to 128 A, the joint strength is significantly reduced. To explain this discrepancy, the load-bearing capacity of the joint needs to be considered from the perspective of bead geometry. In particular, the height of the bead H plays a major Figure 8.7 Energy-dispersive spectroscopic analysis of metal inert gas-brazed joints corre- sponding to different parameters. Al, aluminium; Cu, copper; Fe, iron; HAZ, heat-affected zone; WM, weld metal. 144 Welding and Joining of AHSS role in determining the strength of the joint. A bead with a smaller H/W value is likely to fail in the weld, and a larger value could lead to interfacial fracture. In DP1, that is, in the joint with the lowest heat input, the leg length L is small and hence there is insufficient bonding between the weld metal and the parent metal; therefore failure occurs through the interface under lower tensile loads (Figure 8.9). The best performance is provided by DP2 because the H and L values are large and the H/W ratio of 0.6 is favourable. In this case the joint efficiency is as high as 98% and fail- ure occurs in the HAZ. In DP3, however, failure takes place at the weld because of the smaller H value. For the same heat input (204 J/mm), push mode (DP2) shows greater strength than pull mode (DP4). Push mode has a lower wetting angle than pull mode (DP4) and results in a longer L and a shorter H (Figure 8.5). Fatigue properties: High-cycle fatigue results represented by the load (S) amplitude versus the number of cycles (N) to failure curve in Figure 8.10 indicate that the endurance 350 300 250 200 150 100 0 2000 4000 6000 8000 10,000 Distance (microns) DP1 DP2 DP3 DP4 WM HAZ BM H ar dn es s (H ν) Figure 8.8 Micro-hardness profile of a metal inert gas-brazed joint (top sheet). BM, base metal; HAZ, heat-affected zone; WM, weld metal. Table 8.4 Shear tensile test data for metal inert gas-brazed joints Specimen Heat input (J/mm) Tensile load (kN) Location of failure Joint efficiency (%) Welding process DP1 136 15.88 Interface 91 Push mode DP2 204 17.21 Heat- affected zone 98 Push mode DP3 170 14.84 Weld metal 85 Push mode DP4 204 16.84 Interface 96 Pull mode 145Metal inert gas (MIG) brazing and friction stir spot welding of AHSS limit of 2 × 106 cycles were attained at 10% of the tensile load. This is irrespective of the bead’s geometry. However, joints receiving greater heat input were able to withstand more cycles. At 60–80% tensile loading, fatigue failure occurred along the (1) interface in joints made with high heat input (e.g. DP1), (2) weld metal for intermediate heat input (e.g. DP2, DP3) and (3) in the HAZ for lower heat input (e.g. DP4). At a lower load, irrespective of the heat input, all joints failed in the HAZ. During fatigue testing, failure can occur at any one of the following three locations: the interface, the weld metal or the HAZ. As mentioned earlier, the weld geometry predominantly determines the type of failure. The weld root between two overlapping sheets acts as the default notch with stress concentration. In case of interfacial failure cracks are initiated at the weld root and propagate through the interface towards the weld toe. Again, in case of weld metal failure, the crack initiates at the weld root and propagates through the weld metal in a direction perpendicular to the applied load. For HAZ failure, however, the crack initiates from the weld toe and propagates through the fine grain HAZ (FGHAZ) across the sheet thickness (Figure 8.11). Small cracks may Figure 8.9 Cross-sectional view indicating failure location under quasi-static loading. 146 Welding and Joining of AHSS originate from several spots along the weld toe or weld root. They subsequently grow and coalesce to become larger cracks (Lassen & Recho, 2006). The remaining ligamentof the sheet or weld section eventually becomes too small to bear the load and failure takes place. This notch effect is more pronounced at higher loads as the gap Crack opening displacement between the two sheets increases during cyclic loading. 8.3 Friction stir spot welding (FSSW) FSSW is a relatively new process that recently received considerable attention from the automotive industry. FSSW has proven to be a cost-effective and productive means for joining light materials such as aluminium (Gerlich, Su, & North, 2005). This Figure 8.10 High-cycle fatigue plots of metal inert gas-brazed joints. Figure 8.11 Fracture location after high-cycle fatigue test. BM, base metal; COD, crack opening displacement; HAZ, heat-affected zone; WM, weld metal. 147Metal inert gas (MIG) brazing and friction stir spot welding of AHSS process avoids the severe heating and cooling rates experienced during RSW. It is an attractive technology for spot welding of high-strength and AHSSs. FSSW of steel is usually carried out using a cylindrical polycrystalline boron nitride (PCBN) tool with a convex, scrolled shoulder and a protruding pin, as shown in Figure 8.12. The tool is plunged into two overlapping sheets at a specific rate to a predetermined depth. The frictional heat generated by the interaction between the tool and material softens the metal, and the rotating pin causes material to flow in both circumferential and axial directions. The scrolls on the shoulder are such that when the tool is rotated in a counterclockwise direction, the scrolls assist in moving the material from the outer periphery of the shoulder towards the central pin. The tool is then retracted rapidly either immediately or after a dwell time. The rotational speed of the tool, plunge rate, plunge depth and dwell time are the four principal parameters in FSSW. The pressure applied by the tool shoulder enhances the stirring effect and produces an annular sol- id-state bond around the pin. Between 2000 and 2010 there have been successful attempts to join AHSSs by the friction stir process; however, the tool life and weld quality are still being assessed for widespread commercial purposes. Feng et al. (2005) reported that solid-state joints were produced in 1.6-mm-thick DP600 steel applying 1500 rpm of tool speed with a weld time varying between 1.6 and 3.2 s just by changing the plunge rate. The bond strength increased with increasing weld time as the width Figure 8.12 (a) Top view of a polycrystalline boron nitride tool. (b) Schematic detailed view of the tool tip. CCW, counter clockwise. 148 Welding and Joining of AHSS of the bonding ligament became larger. Interestingly, the thermo-mechanically affected zone (TMAZ) exhibited a microstructure and hardness similar to that of the base metal. Hovanski et al. (2007) successfully lap-joined hot-stamped boron steel by applying a rotational velocity of 800–2000 rpm and a weld cycle time of 1.9–10.5 s. Longer dwell time resulted in a direct increase in lap shear strength of 40–90% for all plunge rates. The effect of rotational speed on weld strength was dependent on the plunging conditions. The original microstructure containing martensite was mostly retained, except for a thin region of ferrite that formed at the interface region within the bond area. Cracks around the nugget propagated through this softer region. A comparative study between RSW and FSSW of 1.2-mm-thick zinc-coated DP600 steel revealed that the microstructure of the HAZ is similar in both cases. Martensite is observed in the fusion zone of RSW and stirred zone (SZ) of FSSW, but with different morphologies (Khan et al., 2007). However, the TMAZ contains a mixture of lath mar- tensite, bainite and ferrite. Furthermore, in both processes failure load increases with an increase in nugget size or bond area, which in turn depends on the energy input. Aota & Ikeuchi (2009) observed that failure load in thin, low-carbon sheets increased with plunge depth, and failure mode changed from interface rupture to plug rupture at plunge depths greater than 0.16 mm. The failure load corresponding to plug rupture conditions increased with dwell time and was almost completely unchanged over 0.4 s at a plunge depth of 0.14 mm. The body of information available, however, does not mention processing param- eters that can produce commercially feasible bond sizes equivalent to nugget sizes of RSW. The work mentioned in the subsequent section attempts to address this issue. FSSW of 1.6-mm-thick DP590 steels was carried out with the intent to produce a small bond with adequate mechanical properties. Efforts to evaluate and fine-tune parameters based on real-time thermo-physical response of the material during weld- ing and to investigate microstructural characteristics and mechanical performance of the joints also were made. 8.3.1 Welding of DP590 steel The composition and mechanical properties of DP590 steel are listed in Table 8.5. The PCBN tool used for welding had a shoulder diameter of 25 mm and a pin height of 1 mm with a base diameter of 3–4 mm. Lap shear tensile specimens of 175 × 45 mm with an overlap of 35 mm, as shown in Figure 8.13, were considered for testing and is shown in Figure 8.13. Two spacers 40 mm in length were attached to both ends of the specimen to induce pure shear and to avoid initial realignment during testing (Figure 8.12). 8.3.2 Processing parameters and mechanical response The parameters considered for lap welding are listed in Table 8.6. The welding cycle in FSSW begins as soon as the tool makes contact with the steel surface. As the pin enters the first sheet, the material gets work-hardened, and thereby 149Metal inert gas (MIG) brazing and friction stir spot welding of AHSS the force required to stir the material increases. The interaction between the tool and the material involves energy, which is calculated using the following formula (Khan et al., 2007): QFSW = N∑ n = 1 F (n) · [x (n) − x (n − 1)] + N∑ n = 1 T (n) ·ω (n) ·Δ t where F is the experimentally measured normal force, x is the displacement, T is the axial torque and ω is the angular velocity (2π*RPM/60). The values for the parameters given in Table 8.6 are plotted in Figure 8.14. As shown in Table 8.6, the bond (nugget) diameters obtained are acceptable by RSW standards. From the various parameter combinations attempted, it can be said that a high rotational speed of 1600 rpm applied for a longer time of 72 s (i.e. a feed rate of 2 mm/min) leads to large nugget diameters (>11 mm). For a feed rate of 10 mm/min, the nugget diameter reduces to 4.7 mm, but the welding time is 20 s. By judiciously adopting higher feed rates (228 or 300 mm/min) along with a higher rotational speed (2400 rpm), however, obtaining nuggets that are of appropriate size within a short time of ∼4 s is possible (Sarkar, Pal, & Shome, 2014). Since the feed rate is extremely high, a dwell time of 1 s at the end of the plunging stage ensured effective joining. The forces acting on the tool are the x-, y- and z-forces; however, the z-force is most critical because the tool penetrates along that direction. During this process, Table 8.5 Composition and mechanical properties of DP590 steel Composition (wt%) Mechanical properties Carbon Manganese Silicon Ultimate tensile strength (MPa) Yield strength (MPa) Elongation (%) 0.009 0.98 0.31 617 365 29 Figure 8.13 Dimensions of the lap shear tensile test specimen for friction stir spot welding. 150 Welding and Joining of AHSS heat is generated by the friction between the rotating pin and the workpiece, as well as by adiabatic heat during plastic deformation of the material, which is reflected in the decrease in the z-force (Figure 8.15). The softened material is displaced and the progressing pin encounters a fresh layer of material. Fourment & Guerdoux (2008) showed, through numerical simulation, that the maximum temperatureof the work- piece is located at the bottom of the pin. This causes the material under the pin to soften, facilitating tool progression (Khan et al., 2007). With increasing rotations per minute, the deformation as well as heat generation increase. As a result, the material is thermally softened more quickly with increasing rotations per minute. This effect can be seen in the z-force curves, where the first peak occurs sooner and at a lower load with increasing rotations per minute. The ensuing thermo-mechanical condition enables solid-state diffusion between the discretely mixed solid entities within the SZ. Because of the prevailing high strain and strain rate, the dynamic recrystallization process also becomes active. As the pin comes in contact with the second sheet, the z-force starts ris- ing again for the reasons stated above. This is the cause of the second peak in Figure 8.15(a).The rise and fall of the z-force is more pronounced in case of a 350 300 250 200 150 100 50 350 (b)(a) 300 250 200 150 100 50 2 4 6 8 10400 To ta l e ne rg y (k J) To ta l e ne rg y (k J) 600 800 1000 1200 1400 Rotational speed (rpm) Feed rate (mm/min) 1600 Figure 8.14 Change of energy with rotational speed (rotations per minute [rpm]) (a) and feed rate (b). Table 8.6 Correlation between welding parameters and bond diameter in lap welding Depth of penetration (mm) Rotations per minute Feed rate (mm/min) Dwell time (s) Weld time (s) Bond diameter (mm) 2.2 400 2 0 72 4.3 800 7.8 1200 11.7 1600 11.5 2.2 1600 10 0 20 4.7 2.4 2400 228 1 4 5.1 151Metal inert gas (MIG) brazing and friction stir spot welding of AHSS 400-rpm weld. At higher rotations per minute, the bottom sheet is further soft- ened and hence there is less variation in z-force. Material softening and pin immersion causes upward displacement of the extruded material. The axial force increases when the tool shoulder contacts the extruded material. The Figure 8.15 Force (a, c) and torque (b) plots for an identical feed rate, but different rotational speeds (rpm). 152 Welding and Joining of AHSS thermal expansion associated with heating of the metal adds to this effect. The peak force is caused by the extruded material squeezing between the tool shoul- der and the workpiece. Therefore, the z-force peaks at the last stage of plung- ing when the rotating tool shoulder is in firm contact with the workpieces. A relatively smooth z-force plot suggests that the FSSW process is more stable at higher rotations per minute. The spikes in x-force and y-force plots are caused by tool vibrations while pene- trating through the metal. Such vibrations reflect slow and delayed heating and cau- tions for adjustment of welding parameters. With increasing rotations per minute, sufficient heating followed by softening takes place early and is sustained through- out. Consequently, the spikes are reduced as the process stabilizes, for example, in the case of 1600 rpm. Again, when the shoulder comes in contact with the extruded material, the x and y directional forces encounter some oscillations. These are prob- ably caused by transversal load variations on the tool due to inadequate contact between the extruded material and the shoulder (Davies, 2012, p. 248). It has been observed that the z-force and spindle torque for the 400-rpm weld is significantly different from that obtained with higher rotations per minute but an identical feed rate (Zimmer, Langlois, Laye, & Bigot, 2010). This can be explained by the frictional heat input at the beginning of the plunge, at 400 rpm, being insufficient to cause proper stirring. This occurs because the tool experiences more resistance from the material at such low rotational speeds. Increasing rotations per minute marginally reduces the torque (Figure 8.15(b)) and gradually attains a steady state of operation. At higher feed rates, the ini- tial work-hardening rate is high because the workpiece is at ambient temperatures (Figure 8.16). However, fewer vibrations are created by the tool–metal interaction at higher feed rates (Figure 8.16(c)) because of better process stability. Of the two, rotational speed has a greater influence on process stability than feed rate. The high force and torque values observed at numerous rotations per minute (2400) and a high feed rate (228–300 mm/min) suggest that, with a very short welding time (∼4 s), the material offers substantial resistance to stirring because it does not soften to the extent reported earlier for lower parameters (Figure 8.17). Because the depth of penetration is greater, the tool shoulder meets the material early and contributes to maximum heat generation. This results in the stirring of a larger volume of material, and hence much resistance is encountered, which is reflected by the higher torque and z-force values. It may be noted, however, that assuming the spot size requirement of friction stir spot welds to be 3.5–5√t, as in the case of spot welding, the high parameter conditions are more favourable. They produce appropriately sized spots within a time cycle that is productive and close to the RSW nugget size. 8.3.3 Structure–property correlation The cross-section of an FSSW joint is shown in Figure 8.18, wherein the following four zones are observed: (1) the SZ, (2) the TMAZ, (3) the HAZ and (4) the base metal. It may be noted that the dimension of each of the zones increases with increasing heat 153Metal inert gas (MIG) brazing and friction stir spot welding of AHSS input. While the rotations per minute increase the heat input, the feed rate decreases the heat input as well as the weld time. The microstructure of the DP590 base metal is shown in Figure 8.19; it has a DP microstructure containing islands of hard martensite embedded in a softer ferritic matrix. Figure 8.16 Force (a, c) and torque (b) plots for identical rotational speeds but different feed rates. 154 Welding and Joining of AHSS Figure 8.17 Force (a, c) and torque (b) plots for different rotational speeds and feed rates. dt, dwell time. 155Metal inert gas (MIG) brazing and friction stir spot welding of AHSS The microstructures of the various zones shown in Figure 8.18 are given in Figures 8.19–8.21. The microstructure in the SZ consists of fine grains of ferrite (Figure 8.20(a)). Traversing farther inside, from the SZ through the TMAZ, the grain size progressively becomes larger. This microstructural variation is consistent with the strain and tempera- ture gradient that develops along the thickness of the sheet from the surface as an effect of stirring (Zimmer et al., 2010). With increasing rotations per minute, the grain size of the SZ increases. The TMAZ microstructure consists of blocky ferrite at fewer rotations per minute (Figure 8.19 (b)). The microstructure produced at higher rotations per minute, Figure 8.18 Schematic profile superimposed on macrograph of FSS weld – cross-section view. Base metal (BM), thermo-mechanically affected zone (TMAZ), heat-affected zone (HAZ), and stirred zone (SZ). Figure 8.19 Microstructure of the base metal (BM), thermo-mechanically affected zone (TMAZ), heat-affected zone (HAZ) and stirred zone (SZ) (800 rpm, 2 mm/min feed rate). 156 Welding and Joining of AHSS however, shows an increasing amount of bainite/acicular ferrite structure (Figure 8.20(b)). With increasing rotations per minute the grain size of the TMAZ increases. For 1200– 1600 rpm, as one travels from the TMAZ to the HAZ, the microstructure shows an increasing amount of bainite/acicular ferrite and a decreasing amount of ferrite. The microstructure in the subregions of the HAZ tend to develop in relation to the local thermal cycle experienced during welding. The HAZ exhibits a CGHAZ surrounding the TMAZ, an FGHAZ encompassing the CGHAZ and an inter-critical HAZ encompassing the FGHAZ. The HAZ in general has a finer structure than the base metal, consisting primarilyof polygonal ferrite and pearlite (Figures 8.19 and 8.20). With increasing rota- tions per minute, the grain size of the HAZ increases. The microstructures of the TMAZ and HAZ welded at higher feed rates are considerably finer than the ones welded with the same rotations per minute but a lower feed rate (Figures 8.20 and 8.21). The TMAZ shows a volume fraction of acicular ferrite and bainitic sheaves that are oriented ran- domly with respect to one another. There are also traces of martensite in the TMAZ of DP specimens welded with the maximum parameters. Metallographic evidence also suggests that at maximum parameters a thin region of ferrite is formed, originating from the interface of the two-sheet stack to a location near the pinhole at the centre of the nugget. This distinctive band of ferrite remains Figure 8.20 Microstructure of the stirred zone (a), thermo-mechanically affected zone (b) and heat-affected zone (1600 rpm, 2 mm/min feed rate) (c). 157Metal inert gas (MIG) brazing and friction stir spot welding of AHSS along both sheet surfaces, as well as throughout the weld nugget. The soft band of ferrite is shown in Figure 8.22. It may be noted that as we move towards the central pin hole, the coarse ferritic grains are gradually replaced by fine ferrite grains. The micro-hardness of the TMAZ and HAZ increases with increasing rotations per minute (up to 1200 rpm); this can be observed in Figure 8.23. The TMAZ region of the weld has a hardness above 210 Hv. The hardness of the HAZ also increases with an increas- ing feed rate. When compared with fewer rotations per minute and a lower feed rate, DP590 shows considerably high hardness values (302 Hv) under 2400 rpm and 228 mm/ min feed rate (Figure 8.23(c)). Interestingly, the maximum parameters cause softening in the HAZ. It has been reported that more rotations per minute result in thermal cycles with a higher peak temperature (Tp) (Cui, Fujii, Tsuji, & Nogi, 2007; Fourment & Guerdoux, 2008; Khan et al., 2007). Again, with increasing feed rate the heat input and Tp decrease. This is responsible for the coarser microstructure in the different zones that is obtained at higher rotations per minute, whereas a finer structure is observed with higher feed Figure 8.21 Microstructure of the thermo-mechanically affected zone at 1600 rpm, 10 mm/min feed rate (a) and 2400 rpm, 228 mm/min feed rate, 1 s dwell time (b) and the heat-affected zone (2400 rpm, 228 mm/min feed rate, 1 s dwell time) (c). 158 Welding and Joining of AHSS Figure 8.22 (a) Macrostructure of friction stir spot weld in DP590 steel showing the interfacial ferritic band. (b) Magnified view of region A in panel (a). Figure 8.23 Micro-hardness plots for different rotations per minute (rpm) (a), different feed rates (b) and maximum parameters (c). 159Metal inert gas (MIG) brazing and friction stir spot welding of AHSS rates. The heavy local deformation in the SZ is associated with a temperature increase up to 1100–1200 °C (Hovanski et al., 2007; Lienert, Stellwag, Grimmett, & Warke, 2003; Zimmer et al., 2010). This triggers dynamic strain-induced recrystallization followed by rapid cooling with the withdrawal of the tool. Consequently, a fine fer- rite microstructure is produced upon transformation from austenite. The strain and peak temperatures of the thermal cycles decrease with the depth of the sheet, and so does the phase transformation conditions. The TMAZ region experiences high Tp (<1100 °C) and longer time spent at a high temperature. This results in varying degrees of austenite grain coarsening. Microstructural evidence indicates that the Tp in the TMAZ attains the temperature of austenite, effecting appreciable grain growth. The final microstructure of the TMAZ depends on the effects of strain, strain rate, temperature and cooling rate. Mechanical stabilization of austenite causes the amount of bainite to vary from top to bottom in the TMAZ (Larn & Yang, 2000; Lee, Bhadesia, & Lee, 2003). When an externally applied stress exceeds the yield strength of austenite, it is pos- sible that the transformation of austenite into bainite is retarded. This is because displacive transformations occur by the advance of glissile interfaces, which can be hindered or rendered sessile upon encountering defects such as dislocations or grain boundaries. Such defects act as obstacles to the migration of the interface into austenite, similar to the effects that lead to work hardening when the passage of slip dislocation is obstructed. If the density of the dislocations is increased by deforming the austenite plastically, then these dislocations would limit the growth of the bainite plates. The final fraction of bainite may then become smaller in the deformed aus- tenite. If phase transformation immediately follows deformation, ferrite is nucleated intragranularly at the places with highest dislocation density, thus resulting in grain refinement, as seen in the SZ (Hickson, Hurley, Gibbs, Kelly, & Hodgson, 2002). Under these circumstances, ferrite nucleates on the unrecovered dislocation sub- structures in the austenite grains. If there is a delay between deformation and phase transformation, however, recovery alleviates the substructure from becoming the preferred site for ferrite nucleation. In the upper region of the TMAZ, the strain generated by stirring is con- siderably higher than in the lower region, resulting in a structure consist- ing primarily of ferrite with some amount of bainite. The lower part of the weld experiences lower strains and also greater undercooling, as the bot- tom surface dissipates heat to the backing plate, which acts as a heat sink. This leads to a larger amount of bainite. Sluggish transformation kinetics pre- vail in this region. The microhardness of the TMAZ represents the bainitic– acicular ferritic structures found. At 1600 rpm, the microhardness decreases because of excessive grain coarsening. The higher hardness values at the border of the TMAZ are caused by rapid cooling. This is probably because of the geom- etry of the FSSW process, wherein the temperature of the entire TMAZ region is expected to be high; therefore, the highest cooling rates are at the edges of the TMAZ, corresponding to higher hardness (Reynolds, Tang, Posada, & Deloach, 2003). The HAZ experiences considerably lower Tp than the TMAZ and hence shows a finer grain size. Material in the CGHAZ experiences the highest temperature in the HAZ. 160 Welding and Joining of AHSS The microstructure suggests that Tp was well above the effective A3 temperature, thus allowing some austenite grain growth. Farther away, the temperature experienced by the FGHAZ is less than the A3 temperature. The decomposition of austenite to ferrite and pearlite upon cooling promotes fine grains in this region. The inter-critical HAZ was characterized by a bimodal distribution of fine ferrite grain sizes surrounded by coarse grains as it was exposed to temperatures in the two-phase inter-critical region. In the case of samples welded at a higher feed rate (Figure 8.21), a characteristic lower Tp (because of less available time and low heat input), followed by a high cooling rate, result in a rel- atively finer structure in all the zones. The rapid cooling associated with low heat input conditions enable the formation of fine bainite, acicular ferrite and traces of lath marten- site in the TMAZ of DP steel. The high micro-hardness values are due to the presence of fine low-temperature transformation products, including martensite (>300 Hv). 8.3.4 Mechanical properties Lap shear specimens of different FSSW joints, shown in Figure 8.13, were first tested under quasi-static loading conditions. The tensile test results of weld joints are summa- rized in Table 8.7, which shows that the nugget diameter and maximum load increase with increasing rotational speed (rotations per minute) of the tool and decreases with an increas- ingfeed rate. Compared with the minimum prescribed breaking load of spot welds (Ref: BS1140:1993), the friction stir spot welds exhibited considerably higher breaking loads. Some of the tensile tests were interrupted to investigate crack propagation during shear tensile loading. A transverse cross-section of a partially failed weld specimen is demonstrated in Figure 8.24, showing crack propagation from the sheet interface along the thin ferrite region within the weld nugget. Examination of partially failed DP590 FSSW specimens show consistent failure along this softened region of fer- rite within the weld nugget. This ferrite band provides an easy route for failure with reduced strength. Failure ultimately takes places when the crack traverses the entire weld and reaches the central depression of the pin hole. The path of the final fracture is marked with dashed lines in Figure 8.24(a). Higher rotations per minute ensures Table 8.7 Shear tensile test results of friction stir spot welds of DP590 steel Welding parameters Dwell time (s) Nugget diameter (mm) Minimum acceptable breaking load (kN) Breaking load (kN) Penetration depth (mm) Rotations per minute Feed rate (mm/min) 2.2 400 2 0 4.30 11.65 18.6 1200 11.76 23.0 1600 11.51 24.3 1600 10 4.75 21.8 2.4 2400 228 1 5.14 12.61 23.7 161Metal inert gas (MIG) brazing and friction stir spot welding of AHSS favourable temperatures and greater intermixing and hence results in higher failure loads. Increasing the feed rate decreases the weld time and also the peak tempera- ture, resulting in decreasing failure loads. For optimized parameters, the tensile crack initiates at the original notch tip and propagates along the sheet interface into the weld along the softer ferrite band; it finally reaches the central depression of the pin hole, causing shear failure. The crack propagates along the ferrite band because of the favourable stress concentration and the presence of a region with less hardness. Based on the average failure loads under quasi-static loading, welded samples of DP590 steel were subjected to cyclic loading conditions with a load ratio of 0.1. The fatigue performance was evaluated to determine the number of cycles to failure as a function of load amplitude and load ratio. As shown in Figure 8.25, the lap shear fatigue test results indicate that the endurance limit of 2 × 106 cycles is obtained in DP590 steel at loads of 3.08 kN. Failure occurring in the lap joints under a load ratio of 0.2–0.6 is shown in Figure 8.26. Under cyclic loading conditions, friction stir spot welds fail from kinked cracks originating from the original notch tip and then propagating through the upper and lower sheet thickness either along the boundary between the TMAZ and the HAZ or along the outer fringes of the weld nugget, taking the shortest and weakest route. The favourable microstructure of the welds offers considerable resistance to the propagation of fatigue cracks, even when tested under high loads. Figure 8.24 (a) Macrostructure of an interrupted shear tensile test specimen. (b) Magnified view of region I. 162 Welding and Joining of AHSS The cracks subsequently open up at the surface of the sheets along the circumfer- ence of the bond diameter. Figure 8.27 shows the cross-section of specimens failed under a load ratio of 0.6. Under high-cycle loading conditions, fatigue cracks I and II appear to emanate from the original crack tips of the weld at A and B, respectively, and propagate through the upper and lower sheet thicknesses, respectively. A shear failure, marked by F, occurs at the end of fatigue cracks I and II. These two cracks finally cause the failure of the specimen. During high-cycle fatigue testing under lower loads (load ratio ≤0.6), cracks propagate through the upper and lower sheet thickness. Cracks I and II both become transverse through cracks that propagate across the width Figure 8.25 Fatigue plots: maximum load vs number of cycles (a) and load ratio vs number of cycles (b). Figure 8.26 Appearance of fatigue failure on the surface of a lap joint at a load ratio of 0.2 (a), 0.4 (b) and 0.6 (c). 163Metal inert gas (MIG) brazing and friction stir spot welding of AHSS of the specimen (Figure 8.27). These cracks finally cause the failure of the specimen. At higher load values (load ratio >0.6), after propagating through the upper and lower sheet thicknesses, fatigue cracks I and II become circumferential cracks that propagate along the nugget’s circumference. 8.4 Conclusions 8.4.1 MIG brazing A galvanized DP steel sheet could be successfully joined by MIG brazing using copper–aluminium base (CuAl8) filler wire. Proper selection of parameters could lead to an efficiency of more than 90%. The dispersed iron-rich phases in the copper matrix enhance the strength of the weld metal and are at par with DP590 steel hardness. The volume fraction of dendrites containing iron increases as the MIG brazing heat input is increased and therefore is parameter dependent. High shear tensile strength properties are associated with large bead sizes which results in failure in the HAZ. The push mode provides the most adequate dimensions with respect to weld height, leg length and wetting angle for superior weld perfor- mance. Fatigue endurance limit of 2 × 106 cycles is usually attained at 10% of the tensile load. However, larger bead geometries give better results. 8.4.2 Friction stir spot welding Two overlapping DP590 steel sheets, each of 1.6 mm thickness, were successfully spot welded with different rotational speeds and feed rates using the PCBN tool. With a rota- tional speed of 2400 rpm, a feed rate of 228 or 300 mm/min and a dwell time of 1 s, it is possible to achieve suitable nugget diameters between 5 and 6 mm, comparable with spot weld nuggets. With these parameters completing the entire welding cycle in 4 s is possi- ble, which is close to RSW practice. At higher parameter values the process in terms of z-force and torque is lower and more stable, and therefore longer tool life is expected. Figure 8.27 (a) Failure of lap joints under a load ratio of 0.6. (b) Schematic representation of crack propagation. 164 Welding and Joining of AHSS The frictional and adiabatic heat, tool pressure and stirring causes local mixing of discrete, plasticized entities, followed by solid-state diffusion between them for joining to happen. The microstructure of the SZ and TMAZ containing polygonal ferrite, acicular ferrite and bainite phases are refined. Dynamic recrystallization of the strained austenite, a low peak temperature and rapid cooling at the end of welding all combine to refine the microstructures in the different zones. A combination of a high rotational speed and a high feed rate produces the best microstructure, apart from meeting productivity requirements. The tensile loads of FSSW joints are much higher than the minimum acceptable loads for resistance spot welds. An out-of-plane notch tip between the two sheets seems to restrict crack initiation and propagation during lap shear tensile testing. This situation is advantageous. The amenable microstructures in all the zones of the joint produced with higher parameters ensure better ductility. Under quasi-static loading, the crack originates at the notch tip and propagates along the sheet interface through a softer ferritic band before culminating at the central pin hole, causing shear failure. Under cyclic loading conditions, the fatigue crack originates at the original notch tip and propagates through the sheet thickness along the TMAZ–HAZ boundary or the outer fringes of the weld circumference. Fatigue failures occur well away from the central pin hole under all load ranges. Acknowledgements The contents of this chapter were extracted from completion reports of two Tata Steel- sponsored projects carried out at the Welding Technology Centre of Jadavpur University, Kolkata. Theauthor sincerely thanks Prof. T.K. Pal of Jadavpur University for his sup- port during the course of these projects. Special thanks are extended to Sushovan Basak and Rajarshri Sarkar, Research Scholars at Jadavpur University, for generating some use- ful information on MIG brazing and friction stir spot welding, respectively. The author is indebted to the management of Tata Steel India for permitting this paper to be published and be part of this book. References Aota, K., & Ikeuchi, K. (2009). Development of friction stir spot welding using rotating tool without probe and its application to low-carbon steel plates. Welding International, 23, 572. Cui, L., Fujii, H., Tsuji, N., & Nogi, K. (2007). Friction stir welding of a high carbon steel. Scripta Materialia, 56, 637. Davies, G. (2012). Materials for automobile bodies (2nd ed.). BH, Kidlington, Oxford. p. 248. Feng, Z., Santella, M. L., David, S. A., Steel, R. J., Packer, S. M., Pan, T., et al. (2005). Friction stir spot welding of advanced high-strength steels – a feasibility study. SAE International. Fourment, L., & Guerdoux, S. (2008). 3D numerical simulation of the three stages of friction stir welding based on friction parameters calibration. International Journal of Material, 1, 1287. 165Metal inert gas (MIG) brazing and friction stir spot welding of AHSS Gerlich, A., Su, P., & North, T. H. (2005). Tool penetration during friction stir spot welding of Al and Mg alloys. Journal of Materials Science, 40, 6473. Gould, J. E., Khurana, S. P., & Li, T. (2006). Predictions of microstructures when welding auto- motive advanced high-strength steels. Welding Journal, 85, 111s. Guimaraes, A. S., Mendes, M. T., Costa, H. R. M., Machado, J. D. S., & Kuromoto, N. K. (2007). An evaluation of the behaviour of a zinc layer on a galvanised sheet joined by MIG brazing. Welding International, 21, 271. Hickson, M. R., Hurley, P. J., Gibbs, R. K., Kelly, G. L., & Hodgson, P. D. (2002). The produc- tion of ultrafine ferrite in low carbon steel by strain induced transformation. Metallurgical and Materials Transactions A, 33A, 1019. Holliday, R., Parkar, J. D., & Williams, N. T. (1995). Electrode deformation when spotwelding coated steels. Welding World, 3, 160. Holliday, R., Parkar, J. D., & Williams, N. T. (1996). Relative contribution of electrode tip growth mechanism in spot welding zinc coated steels. Welding World, 4, 186. Hovanski, Y., Santella, M. L., & Grant, G. J. (2007). Friction stir spot welding of hot-stamped boron steel. Scripta Materialia, 57, 873. Howe, P., & Kelly, S. C. (1988). A comparison of the resistance spot weldability of bare, hot- dipped, galvannealed, and electrogalvanized DQSK sheet steels. In International Congress and Exposition, Detroit, Michigan (p. 325). Khan, M. I., Kuntz, M. L., Su, P., Gerlich, A., North, T., & Zhou, Y. (2007). Resistance and fric- tion stir spot welding of DP600: a comparative study. Science and Technology of Welding and Joining, 12(2), 175. Kuziak, R., Kawalla, R., & Waengler, S. (2008). Advanced high strength steels for the automo- tive industry. Archives of Civil and Mechanical Engineering, VIII, 103–118. Larn, R. H., & Yang, J. R. (2000). The effect of compressive deformation of austenite on bainitic ferrite transformation in Fe-Mn-Si-C steels. Materials Science and Engineering, A278, 278. Lassen, T., & Recho, N. (2006). Fatigue life analyses of welded structures. London: ISTE. Lee, C. H., Bhadesia, H. K. D.H., & Lee, H. C. (2003). Effect of plastic deformation on the formation of acicular ferrite. Materials Science and Engineering: A, A360, 249. Lepisto, J. S., & Marquis, G. B. (2004). MIG brazing as a means of fatigue life improvement. Welding in the World, 48, 28. Lienert, T. J., Stellwag, W. L., Jr., Grimmett, B. B., & Warke, R. W. (2003). Friction stir welding studies on mild steel. Welding Journal, 1S–9S. Parker, J. D., Williams, N. T., & Holiday, R. J. (1988). Mechanism of electrode degradation when spotwelding coated steels. Science and Technology of Welding and Joining, 3, 65. Quintino, L., Pimenta, G., Iordachescu, D., Miranda, R. M., & Pépe, N. V. (2006). MIG brazing of galvanized thin sheet joints for automotive industry. Metal Manufacturing Processes, 21, 63. Reynolds, A. P., Tang, W., Posada, M., & Deloach, J. (2003). Friction stir welding of DH36 steel. Science and Technology of Welding and Joining, 8(6), 456. Sarkar, R., Pal, T. K., & Shome, M. (2014). Microstructures and properties of friction stir spot welded DP590 dual phase steel sheets. Science and Technology of Welding and Joining, 19, 436. Zimmer, S., Langlois, L., Laye, J., & Bigot, R. (2010). Experimental investigation of the influ- ence of the FSW plunge processing parameters on the maximum generated force and torque. International Journal of Advanced Manufacturing Technology, 47, 201. Zrnik, J., Mamuzic, I., & Dobatkin, S. V. (2006). Recent progress in high strength low carbon steels. Metalurgija, 45, 323. This page intentionally left blank Welding and Joining of Advanced High Strength Steels (AHSS). http://dx.doi.org/10.1016/B978-0-85709-436-0.00009-6 Copyright © 2015 Elsevier Ltd. All rights reserved. Adhesive bonding techniques for advanced high-strength steels (AHSS) K. Dilger, S. Kreling TU Braunschweig, Institute of Joining and Welding, Braunschweig, Germany 9 9.1 Introduction: the exigency of adhesive bonding of high-strength steels The motivations for building lighter car bodies are varied. First, the reduction of car- bon dioxide emissions and the accordant statutory laws represent a challenge to the automotive industry; furthermore, the reduced weight of the car body also allows an improvement in driving characteristics and the integration of comfort features while conserving the weight of the complete automobile. To achieve lighter car bodies, several methods can be applied, from new structural concepts to the application of advanced materials and adequate joining methods. These methods can be classified as construction lightweight design or material lightweight design, although both are always interconnected because design has to be chosen according to the material and vice versa. Fiber-reinforced plastics, especially carbon fiber-reinforced plastics, have been in the public focus lately for use as lightweight materials in various applica- tions including car body engineering. Even though these materials have excellent strength, stiffness-to-weight ratios, and several other advantages, their applicability— especially in large-volume vehicles—is limited by their high cost as well as by the lack of manufacturing techniques for producing high-quality parts in large batches. Light metals, such as aluminum or magnesium, generally have mechanical properties inferior to those of steel and also require complex pretreatment for aging-resistant adhesive bonding. Furthermore, weldbonding is not easily transferable to aluminum joints. For these reasons steel, especially advanced high-strength steels (AHSS), is a material class with a very high potential for building structural lightweight parts for medium- and large-volume vehicles. The key to lighter structural parts is reducing the sheet thickness while increasing the yield strength and thus keeping the part strength constant. Further improvement can be achieved by the use of cleverly bonded joint design concepts. Compared with spot welds only, improvements in relative stiffness of up to 40% can be realized by combining classical spot welds with adhesive bonding. This allows a further reduction of sheet thickness and thus a reduction of weight; the strength remains unchanged. A major challenge in the use of AHSS is to find joining methods that allow the full utilization of the material properties and thus the full lightweight potential. A main 168 Welding and Joining of AHSS problem is that welding always produces a heat-affected zone (HAZ) in the material andleads to a local change of microstructure, which is critical because the strength of AHSS is achieved by the carefully controlled microstructure. The material characteris- tics change because of recrystallization, grain growth, or precipitations. Depending on the material, its thermomechanical history, and the quantity of heat introduced into the welding process, either local softening or hard spots can occur. A typical failure mode of spot-welded joints, especially under crash loads, is unbuttoning—this failure mode is particularly critical because very low amounts of crash energy are absorbed. An example of changes in the mechanical properties is shown by the hardness profile of a spot weld in Figure 9.1. Figure 9.2 shows a specimen with typical unbuttoning failure. 500 450 400 350 300 250 7 6 5 4 3 2 1 0 Distance from center [mm] H V 0. 5 (a) (b) Figure 9.1 Vickers hardness distribution over a spot weld with a diameter of 6 mm (a). (b) Material of the upper adherend is boron–manganese steel (t = 1.5 mm), and that of the lower adherend is H300 (t = 1 mm). Figure 9.2 Plug failure of a spot weld. 169Adhesive bonding techniques for AHSS The impact of the warm joining techniques described above on material properties illustrates the interest in cold joining methods that do not lead to decreased strength or energy absorption. For this reason, adhesive bonding is especially interesting for joints of structural parts that are subjected to crash loads. The development of advanced toughened adhesives that achieve high strength as well as high fracture toughness and energy absorption has further increased the attractiveness of adhesive bonding as a joining method for automotive parts in recent years. Another advantage of adhesive bonding is its ability to deal with problems that often occur when diverging materials such as aluminum, magnesium, or carbon fiber-reinforced plastic are joined. These problems include differences in the thermal expansion coefficient or the risk of gal- vanic corrosion. Furthermore, bonded overlap joints allow the transmission of a lam- inar force, which leads to the reduction or elimination of local stress peaks caused by spot welds or flow drill screws. (Lutz & Symietz, 2009) Nevertheless, adhesive bonding itself also provides some technological challenges, and there are also disadvantages regarding the achievable joint strength, the depen- dence of adhesive properties on temperature, and the stability of the joints under aging conditions. Another point that is especially relevant for AHSS is the influence of sur- face layers such as zinc coatings or cinder on the strength of the whole part. Most of these challenges, however, can be met by choosing the right joint geometries, adhe- sives, and surface pretreatment methods. The following sections discuss the influences of joint geometry, several materials, and surface layers on the behavior of adhesive joints of AHSS. 9.2 Challenges in adhesive bonding of AHSS 9.2.1 Influence of joint geometry on the strength of adhesive bonds Most adhesive joints in real parts are subjected to nearly pure shear loads because this is the preferred loading condition for these joints, which often allows the highest bond strength. This joint geometry is well represented by the single-lap shear specimen, as described in DIN EN 1465 and shown in Figure 9.3. In addition to the adhesive and the overlap geometry (width and length), the joint strength of this simple geometry also depends on the thickness and the material of the adherends (Tong & Luo, 2011). To take a look at these correlations, the different tensions in a single-overlap joint are discussed here (Habenicht, 2009; Tong & Luo, 2011). First, shear tension occurs inside the adhesive layer; this is represented by the simple term τν = F/A. Second, the adherends are elastically or—with higher forces— plastically deformed; the parts of the adherend that are far from the end of the overlap carry higher loads and thus are more deformed. After the overlap ends the stress or the deformation is constant over the length of the joining partner. This is illustrated in Figure 9.3. In addition to the uniform shear tension, further tension caused by this deformation of the adherends is superposed and leads to stress peaks at both ends of the overlap. These stress peaks usually cause the first defects in the adhesive layer and then lead to the failure of the joint. 170 Welding and Joining of AHSS The influence of the overlap width on the joint strength is linear because stress dis- tribution over the width of the adherend is constant, so increasing the width is a simple approach for increasing the transferable load of a joint. Nevertheless, in most con- structions the ability to realize this is limited by geometric or design reasons. Unlike the width, an increase in the overlap length, which is easier to realize by design, does not linearly increase the transferable load. This is caused by stress peaks, as explained above. Figure 9.4 shows the correlation between overlap length, transferable load, and the yield point of the adherend material. At a small overlap (lo1) it is not the stress peaks, but the tensions caused by the displacement of the adherends, that are dominant. The transferable load is marginal τε τν σ σ Figure 9.3 Stress distribution in a single-overlap adhesive bond. 1, adherend 1; 2, adherend 2; 3, adhesive layer; t, adherend thickness; w, overlap with adherend; lo, overlap length; σ1, stress distribution in adherend 1; σ2, stress distribution in adherend 2; τν, uniform shear tension in the adhesive layer caused by displacement; τε, shear tension in the adhesive layer caused by deformation of the adherends. σ τ Figure 9.4 Formation of stress depending on the overlap length. 171Adhesive bonding techniques for AHSS because of the small bonded area and is considerably lower than the strength of the adherends; in this case the material strength Rp0,2 cannot be used. At a medium overlap (lo2) the bonded area is large enough so the adherend reaches the yield point Rp0,2. For this overlap geometry, an optimized usage of the adherend material is achieved because the strength of the adhesive joint is of the same magnitude as the yield point of the material. Further increase of the overlap length (lo3) leads to plastic deformation of the adherend, which cannot be sustained by the adhesive layer and therefore causes failure of the joint. This shows that increasing the overlap length does not further increase the joint strength if tensions in the magnitude of the material yield point are obtained. Because of the formation of stress peaks the central area of the joint bears only a small fraction of the load. Of course, in this context the transferred load has to be aligned to the thickness of the adherend. This illustrates the lightweight potential of adhesive bonds of AHSS. Because of the high yield point of these materials, either a decrease in the sheet gauge or an effective increase in the overlap, and hence of the transferable load at a constant sheet gauge, is possible. To use the maximum lightweight potential of the materials for each joint, the optimum sheet gauge and overlap according to the occur- ring loads have to be found, given that reducing the thickness or overlap also allows weight to be reduced. As also described by Adonvi (2005), however, the strength of adhesively bonded joints between AHSS parts is always limited to the cohesive strength of the adhesive itself, thus raising the question of whether the strength of commercially available structural adhesives is sufficient to use the full potential of advanced steel. Decreasing the sheet thickness to achieve a higher lightweight potential nonetheless also reduces the bending stiffness of the part, which again, depending on part design and load, results in the threat of peel loads occurring in the adhesive layer, significantlylowering the sustainable maximum strength. Considering AHSS with a very high yield point, this is especially critical because the strength is proportional to the thickness, while the bending stiffness decreases in relation to the thickness cubed, which means that the use of low gauges contains the threat of peel loads occurring. Considerations of the geometric aspects of the bonding area and adherends show that, because of their high yield strength, AHSS further enhances the strength of adhe- sively bonded joints. Nevertheless, the joint design always has to be taken into account to prevent peel loads and enable sufficient bond areas. 9.2.2 Crash behavior of adhesively bonded AHSS In addition to the static maximum and cyclic loads that occur during a vehicle’s life- time, the adhesively bonded joints also need to perform well during a crash. For con- ventional steel parts this means that the adhesive has to bear the highest possible loads during the crash so the metal parts can deform plastically and thus absorb most of the energy. If parts manufactured from AHSS are used the difference is that, because of the high yield point and low possibility of plastic deformations, far less energy is absorbed by the part itself. In this case it is even more important that the adhesive layer does not fail because of brittleness but absorbs as much energy as possible. Modern structural adhesive bonds, however, often show layer thicknesses of the magnitude far less than 1 mm; such thin layers are not able to absorb large amounts of crash energy. 172 Welding and Joining of AHSS Hence considering the function of the part, or at the part itself, is important. The B-pillar is, for example, a typical automotive structural part that is manufactured from AHSS. In a side crash it is important that the pillar does not deform massively; this would cause severe injuries to the car’s occupants. Thus the function of the adhesive layer bonding the inner and outer sheets of the B-pillar is not to absorb large amounts of energy, for example, by plastic deformations, but to ensure that the parts are kept together. Because of the low plastic deformation resulting from their high yield points, the function of most parts manufactured from AHSS is not to absorb energy by plastic deformation but to maintain the structure of the car and save the occupants. Hence the main function of the adhesive is to keep the joined parts together, not to fail because of brittleness, and to show tough behavior, even at low temperatures. 9.2.3 Bondability of different kinds of AHSS The adhesive bondability of high-strength steel strongly depends on the alloying ele- ments in the steel. The characteristics of the joint under mechanical loads and aging conditions also are influenced by surface layers or coatings that are applied during the manufacturing process for several reasons. In general, AHSS for automotive applica- tions can be categorized as coated and uncoated materials; among the coated materi- als, zinc coatings or coatings to prevent cindering during heat treatments are widely used. For this reason first uncoated and then zinc-coated and press-hardened steel with coatings to prevent cindering are described in the following sections. 9.2.4 Uncoated AHSS The application of uncoated AHSS is, as for other kinds of steel, quite limited because of their poor resistance against corrosion. These materials are commonly coated with oil to prevent corrosion during manufacturing processes or storage. Most structural hot-curing adhesives that are used in the automotive industry show a good tolerance toward oil contamination and are able to absorb the oil from the surface and build a durable bond. A typical threshold value for the amount of oil that can be absorbed by an adhesive is about 3 g/m². Thus when uncoated materials that have a high degree of oil contamina- tion are adhesively bonded, a prior cleaning step should always be considered. Another aspect to consider when adhesively bonding uncoated AHSS is the forma- tion of different oxides of the alloying elements on the bonding surface. This is espe- cially meaningful for AHSS because more alloying elements with a higher tendency to build oxides are used. Depending on the oxides that are built, local areas with either poor resistance against corrosion or poor adhesion to the adhesive can be formed. Hence when bonding uncoated AHSS taking a close look at the alloying elements and considering the resistance to corrosion of the oxides that can be built are essential. 9.2.5 Zinc coatings Conventional high-strength steels as well as AHSSs are often coated with zinc to inhibit corrosion. For this reason, special adhesives that show very good adhesion on 173Adhesive bonding techniques for AHSS the zinc layer as well as on certain amounts (up to several grams per square meter) of oil residues that can occur on the surfaces, for example, after the deep drawing process, have been developed. These adhesives are well established and state of the art for structural adhesive bonds; hence adhesion between the adhesive and zinc layer occurs in most cases. A common process for coating high-strength steel with zinc is galvannealing, which maintains the parts at elevated temperatures after the hot-dip coating process. In detail, first, the uncoated material is coated in a bath of liquid zinc and then heated at temperatures around 550°C. During the time spent at the elevated temperature, the zinc coating alloys with the iron by diffusing between the molten zinc and iron of the base material. As a consequence, the final coating contains about 90% zinc and 10% iron, which strongly depends on the diffusion temperature and time. Because of the diffusion process, this coating has a very strong bond to the base material. Another advantage of the galvannealing process is that the coating does not contain aluminum, as galvanized coatings do. The aluminum is added in the galvanizing pro- cess to improve adhesion between the coating and the base material. When adhesively bonding to the surface, there are also areas containing aluminum oxide, which usually have poor properties of creep corrosion and long-term stability. Thus, when adhesively bonding zinc-coated steel, it is always important to mind the type of the coating and possible influences, especially on the long-term durability of the joints. Compared with high-strength steel, AHSS grades use higher amounts of alloys such as manganese, silicium, molybdenum, or carbon, which have a higher affinity to oxygen than iron itself. This can lead to minor adhesion or defects inside the zinc layer (Li, 2011) because of the difficulties in reducing their more stable oxides. However, this problem is in the focus of steel manufacturers, and coatings with good adhesion to AHSS are available on the market. Good adhesion between the base material the and coating is especially important because, as discussed above, the transferable loads of adhesively bonded AHSS are usually significantly higher than those of conven- tional high-strength steel, and compared with mechanical joints or welds the load is transferred entirely through the interface between the steel and the coating. Bandekar (2009) reported that when coating delamination occurs, joint strength and impact load are decreased, and X-ray photoelectron spectroscopic analysis showed that the coating was removed mostly in extra deep drawing, interstitial-free steel samples, and it was at the gamma phase of the galvannealed layer. Furthermore, this reference indicates that if the joints failed cohesively, the joint strength was not sensitive to steel grades, which is plausibly explained above. 9.2.6 Press-hardened steels In the press-hardening process boron–manganese steel is heated to about 800°C and then plastically deformed. Heating often occurs inside an oven in an inert gas atmosphere; afterward the parts are transferred into